CN103721652B - 一种聚苯醚包覆环氧树脂微胶囊的制备方法 - Google Patents
一种聚苯醚包覆环氧树脂微胶囊的制备方法 Download PDFInfo
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- CN103721652B CN103721652B CN201310743482.5A CN201310743482A CN103721652B CN 103721652 B CN103721652 B CN 103721652B CN 201310743482 A CN201310743482 A CN 201310743482A CN 103721652 B CN103721652 B CN 103721652B
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- epoxy resin
- polyphenylether
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- coated
- microcapsules
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- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 65
- 239000003094 microcapsule Substances 0.000 title claims abstract description 53
- 229920013636 polyphenyl ether polymer Polymers 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 29
- 229920006380 polyphenylene oxide Polymers 0.000 claims abstract description 29
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 33
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 9
- 230000000903 blocking effect Effects 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 claims description 6
- 238000000967 suction filtration Methods 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 238000001291 vacuum drying Methods 0.000 claims description 6
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- 239000012046 mixed solvent Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- -1 glycidyl ester Chemical class 0.000 claims description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 4
- 229930185605 Bisphenol Natural products 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- ZXOATMQSUNJNNG-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,3-dicarboxylate Chemical compound C=1C=CC(C(=O)OCC2OC2)=CC=1C(=O)OCC1CO1 ZXOATMQSUNJNNG-UHFFFAOYSA-N 0.000 claims description 3
- 229940106691 bisphenol a Drugs 0.000 claims description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 3
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 claims description 3
- 238000006735 epoxidation reaction Methods 0.000 claims description 3
- WPYCRFCQABTEKC-UHFFFAOYSA-N Diglycidyl resorcinol ether Chemical compound C1OC1COC(C=1)=CC=CC=1OCC1CO1 WPYCRFCQABTEKC-UHFFFAOYSA-N 0.000 claims description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 2
- BQQUFAMSJAKLNB-UHFFFAOYSA-N dicyclopentadiene diepoxide Chemical compound C12C(C3OC33)CC3C2CC2C1O2 BQQUFAMSJAKLNB-UHFFFAOYSA-N 0.000 claims description 2
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 claims description 2
- 239000004843 novolac epoxy resin Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 8
- 229920001955 polyphenylene ether Polymers 0.000 abstract description 4
- 239000008346 aqueous phase Substances 0.000 abstract description 2
- 229920013657 polymer matrix composite Polymers 0.000 abstract description 2
- 239000011160 polymer matrix composite Substances 0.000 abstract description 2
- 238000011017 operating method Methods 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- 239000004727 Noryl Substances 0.000 description 2
- 229920001207 Noryl Polymers 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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- Manufacturing Of Micro-Capsules (AREA)
Abstract
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CN201310743482.5A CN103721652B (zh) | 2013-12-30 | 2013-12-30 | 一种聚苯醚包覆环氧树脂微胶囊的制备方法 |
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CN201310743482.5A CN103721652B (zh) | 2013-12-30 | 2013-12-30 | 一种聚苯醚包覆环氧树脂微胶囊的制备方法 |
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CN103721652A CN103721652A (zh) | 2014-04-16 |
CN103721652B true CN103721652B (zh) | 2015-10-28 |
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CN201310743482.5A Expired - Fee Related CN103721652B (zh) | 2013-12-30 | 2013-12-30 | 一种聚苯醚包覆环氧树脂微胶囊的制备方法 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104356604B (zh) * | 2014-12-02 | 2016-10-26 | 四川大学 | 介电材料组合物及其制备方法和用途 |
CN106215826B (zh) * | 2016-07-28 | 2019-01-29 | 苏州大学 | 一种自修复微胶囊及其制备方法 |
CN108794993B (zh) * | 2016-07-28 | 2020-10-30 | 苏州大学 | 一种多孔聚合物材料 |
CN107638850B (zh) * | 2017-10-20 | 2020-10-16 | 河南工业大学 | 一种环氧树脂/三聚磷酸钙钠复合微球及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58124536A (ja) * | 1982-01-21 | 1983-07-25 | Hodogaya Chem Co Ltd | マイクロカプセルスラリ−の製造法 |
CN101016369A (zh) * | 2007-03-02 | 2007-08-15 | 浙江大学 | 一种微胶囊潜伏型环氧树脂固化剂及其制备方法 |
CN101560322A (zh) * | 2009-04-30 | 2009-10-21 | 苏州大学 | 聚苯醚包覆环氧树脂微胶囊及其制备方法 |
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2013
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58124536A (ja) * | 1982-01-21 | 1983-07-25 | Hodogaya Chem Co Ltd | マイクロカプセルスラリ−の製造法 |
CN101016369A (zh) * | 2007-03-02 | 2007-08-15 | 浙江大学 | 一种微胶囊潜伏型环氧树脂固化剂及其制备方法 |
CN101560322A (zh) * | 2009-04-30 | 2009-10-21 | 苏州大学 | 聚苯醚包覆环氧树脂微胶囊及其制备方法 |
Non-Patent Citations (1)
Title |
---|
低介电高耐热环氧树脂/聚苯醚/POSS纳米复合材料研究;任强等;《功能材料》;20130531(第9期);第1320-1323页 * |
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