CN103704258A - Sterilization insecticidal combination containing abietic acid ketone - Google Patents
Sterilization insecticidal combination containing abietic acid ketone Download PDFInfo
- Publication number
- CN103704258A CN103704258A CN201310746481.6A CN201310746481A CN103704258A CN 103704258 A CN103704258 A CN 103704258A CN 201310746481 A CN201310746481 A CN 201310746481A CN 103704258 A CN103704258 A CN 103704258A
- Authority
- CN
- China
- Prior art keywords
- parts
- abietic acid
- acid ketone
- insecticidal composition
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a sterilization insecticidal combination containing abietic acid ketone. Imicyafos and the abietic acid ketone which serve as effective components are mixed; the weight ratio of the two effective components is (1-50):(1-50), and preferably the weight ratio is (3-25):(5-25). The sterilization insecticidal combination comprises 1-80 percent of the effective components by weight, preferably 5-35 percent of the effective components, and the balance being pesticidally available and acceptable auxiliary components. Wettable powder, a suspending agent, a microemulsion, an emulsion in water and a water dispersible granule can be prepared by a known method. The sterilization insecticidal combination containing the sulfoxaflor is mainly used for preventing and treating pest diseases of crops such as grains, cottons, oil, fruits, vegetables and flowers.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, be specifically related to a kind ofly contain agricultural chemicals Imicyafos and abietic acid ketone is two yuan of composite insecticidal and bactericidal compositions of active ingredient.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Copper rosinate is a kind of novel, efficient, broad-spectrum germicide, multiple fungus and bacterium disease to make inroads on crop has good control efficiency, copper rosinate medicine liquid spray is when crop surface, can form rapidly good " the medicine film " of one deck adhesion, copper ion on film can be killed the pathogen of dropping on medicine film effectively, thereby stops germ to be invaded.Copper rosinate has very strong adhesivity, spread and permeability, thereby lasting medicine, and compared with resistance of rainwater washing against; Even if meet rain after dispenser in half an hour, drug effect do not had a significant effect yet.It also has acaricidal action in addition, and mixed with miticide have notable synergistic effect,, a noresidue low to person poultry toxicity; To crop safety, be difficult for producing poisoning, be a kind of new and effective bactericide that has very much application value.Can be used for control and encroach on tens kinds of diseases such as the downy mildew of fruit tree, vegetables, cotton and grain and oil crop, epidemic disease, anthracnose, fusarium wilt, leaf spot, angular leaf spot.
Long-term use single insecticide or bactericide, insect or germ are easy to develop immunity to drugs, and pesticide dosage is increased, and cause large, residual many, the adverse consequences such as drug effect is poor of high poison, consumption, and effect field are more single.The different mechanisms of action and without the insecticide of cross resistance and bactericide rational mixture by a certain percentage, can improve crop disease prevention effect, reduce dosage, residual few, minimizing environmental pollution, effectively reduces the pesticide resistance of crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition that contains abietic acid ketone, said composition contains A, two kinds of effective active components of B, and component A selects novel pesticide Imicyafos; B is selected from abietic acid ketone; it is wide that the present composition has effect field, can desinsection again can sterilization, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention a kind ofly be take novel pesticide Imicyafos and abietic acid ketone and is carried out two yuan of insecticidal and bactericidal composition preparations that are mixed as active ingredient, wherein in insecticidal and bactericidal composition of the present invention, the ratio of weight and number of active ingredient novel pesticide Imicyafos and abietic acid ketone is 1～50: 50～1, on the basis of test recipe screening targetedly, the ratio of weight and number of active ingredient novel pesticide Imicyafos and abietic acid ketone can be preferably to 3～25: 25～5.
Agricultural insecticide bactericidal composition of the present invention is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules by the formulations of pesticide that the preparation method in pesticidal preparations field can be prepared into, in preparation, to account for the portion rate of gross weight in preparation be 1%～80% to active ingredient gross weight, on the basis of test recipe screening targetedly, in preparation, to account for the portion rate of gross weight in preparation be 3%～35% to active ingredient gross weight, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, abietic acid ketone are dissolved completely with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula, active principle A and active principle B and dispersant, wetting agent and filler are mixed, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active principle A and active principle B, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: by above-mentioned formula, active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, pulls open powder copper rosinate X., wetting and penetrating agent F, at least one in alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, the multiple fungal diseases of vegetables, flowers all has favorable effect, especially the fungal disease of vegetables, fruit tree, seeding corn and other crops is all had to good control efficiency, such as early blight and late blight, alternaria leaf spot of apple, pear scab, wheat rust, melon anthracnose and downy mildew, rice sheath blight disease and the rice blast etc. of preventing and treating the early blight of downy mildew of garpe, tomato and late blight, potato.Especially outstanding grade of downy mildew control efficiency had to excellent preventive effect.Insecticidal and bactericidal composition of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, thrips insect, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Semiptera insect, damp insects, centipede insects, thousand-legger class.Especially to destroy the insect of agriculture horticultural crop and trees etc., the insect of destroying the seed of agriculture horticultural crop and trees in soil, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, Semiptera insect preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.In addition the insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thrips are all had to favorable effect.
In addition, insecticidal and bactericidal composition of the present invention is compared similar medicament also a lot of other obvious advantages, the first, compare single dose sphere of action wider, can desinsection again can diseases prevention; The second, greatly delayed the drug-fast generation of crop, reduced agricultural chemicals Reusability number of times, reduced agricultural chemicals usage amount, reduce agricultural cost; The 3rd, the residual quantity of this insecticidal and bactericidal composition is lower, more friendly to environment; Finally in the application of this insecticidal and bactericidal composition, crops are had to general fresh-keeping production-increasing function, the increasing both production and income of agricultural region is significant.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio of below mentioning (comprising percentage) is all ratio of weight and number.
Embodiment 1: by imicyafos10 part, 15 parts of abietic acid ketone, 12 parts of lignosulfonates, 10 parts of lauryl sodium sulfate and 53 parts of mixing of diatomite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 2: by imicyafos6 part, 20 parts of abietic acid ketone, 8 parts of alkylphenol polyoxyethylene, 8 parts of oxygen ethene triphenylethylene phosphenylic acid salt and 58 parts of mixing of bentonite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 3: by imicyafos25 part, 5 parts of abietic acid ketone, 10 parts of dispersants, 12 parts of wetting agents and 48 parts of mixing of filler, uniform stirring in stirred tank is mixing after airslide disintegrating mill, makes the wetting powder of Pesticidal combination of the present invention.
Embodiment 4: by 8 parts of alkylphenol polyoxyethylene, 2 parts of glycerine, 4 parts of CMCs, 2 parts of silicone oil, 56 parts of mixing of water, through high speed shear, mix, add successively 10 parts of imicyafos18 part, abietic acid ketone, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 5: by 10 parts of dispersants, 2 parts of antifreezing agents, 5 parts of thickeners, 1 part of defoamer, 52 parts of mixing of water, through high speed shear, mix, add successively 15 parts of imicyafos15 part, abietic acid ketone, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 6: by 8 parts of dispersants, 2 parts of antifreezing agents, 4 parts of thickeners, 1 part of defoamer, 62 parts of mixing of water, through high speed shear, mix, add successively 8 parts of imicyafos15 part, abietic acid ketone, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 7: 5 parts of imicyafos16 parts, 10 parts of abietic acid ketone, 11 parts, turpentine oil, 5 parts of castor oil polyoxyethylene ethers, resorcinol are mixed, be dissolved into uniform oil phase; 1 part, part water, 2 parts of propane diols, silicone compound is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 5 parts of polyvinyl alcohol, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, and shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 8: 8 parts of imicyafos25 parts, 5 parts of abietic acid ketone, 15 parts of solvents, 10 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 9: 9 parts of imicyafos12 parts, 18 parts of abietic acid ketone, 18 parts of solvents, 8 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 10: 48 parts of imicyafos15 part, 8 parts of abietic acid ketone, 10 parts of aliphatic amine polyoxyethylene ethers, 8 parts of alkylnaphthalene sulfonates, 5 parts, aluminium chloride and bentonites are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 11: 53 parts of imicyafos15 part, 12 parts of abietic acid ketone, 8 parts of dispersants, 9 parts of wetting agents, 5 parts of disintegrants and fillers are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 12: 45 parts of imicyafos20 part, 12 parts of abietic acid ketone, 8 parts of dispersants, 12 parts of wetting agents, 3 parts of disintegrants and fillers are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 13: 24 parts of former medicine imicyafos6 parts, abietic acid ketone are dissolved completely with cosolvent, add again other compositions such as 8 parts of aliphatic acid polyethenoxy base esters, 2 parts of ethylene glycol, 4 parts of sodium citrates, 4 parts of resorcinols, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 14: 22 parts of former medicine imicyafos10 parts, abietic acid ketone are dissolved completely with cosolvent, then add other compositions such as 9 parts of emulsifier, 2 parts of antifreezing agents, 7 parts of stabilizing agents, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 15: 5 parts of former medicine imicyafos25 parts, abietic acid ketone are dissolved completely with cosolvent, then add other compositions such as 9 parts of emulsifier, 2 parts of antifreezing agents, 11 parts of stabilizing agents, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Field experiment: the control to Cucumber Pests And Diseases
(1) test method
Test dispenser twice altogether, check plot spray equivalent clear water.While making up a prescription, after first medicament fully being dissolved with a small amount of water, then add suitable quantity of water to carry out complete stool spraying processing, even spraying.During spray medicine, all adopting power driven sprayer, operating pressure is 0.3～0.4MPa, shower nozzle aperture 1.3mm.Community spouting liquid is 40～50kg/667m
2, dispenser twice continuously, 10 days intervals, sprays application to crop complete stool uniformly by liquid.
(2) investigation method
Experimental field be located at Shouguang, Shandong, select the medium cucumber field of occurring degree for experimental field, soil fertility is medium, and irrigation and drainage are convenient.Adopt bilinear sampling method, 5 points are got in every community, look into 5 caves at every, and during investigation, 2 blades in the fixing middle part of every strain fix a point to check.
According to cucumber downy mildew grade scale, carry out classification, record total strain number, diseased plant number, severity, calculate diseased plant rate, disease index and preventive effect.
Cucumber downy mildew grade scale is
0 grade: without scab;
1 grade: lesion area accounts for below 5% of whole leaf area;
3 grades: lesion area accounts for 6%～10% of whole leaf area;
5 grades: lesion area accounts for 11%～25% of whole leaf area;
7 grades: lesion area accounts for 26%～50% of whole leaf area;
9 grades: lesion area accounts for the more than 50% of whole leaf area.
Test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 10 days after the 1st medicine, 10 days and preventive effect investigation in 20 days after 2 medicines.
(3) poisoning investigation
After dispenser, whether 7d range estimation medicament has poisoning to crop continuously.
(4) drug effect computational methods
The total number of sheets * 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets * relative level numerical value at different levels)/(investigating the total number of sheets * 9) * 100
Control efficiency (%)=(disease index after the front disease index * treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index * treatment region medicine after blank district medicine)) * 100
(5) field control effectiveness test result of the test
The effect of each test medicine control cucumber downy mildew of table 1
As can be seen from Table 1, the effect of the combination control cucumber downy mildew that is mixed that the ratio of weight and number of 23%imicyafos copper rosinate is 8: 15 is very remarkable, and effect is significantly better than single dose, and its quick-acting and lasting effect are all relatively good, especially outstanding with lasting effect.Complex preparation control efficiency under the consumption of high concentration is significantly better than the effect under low concentration consumption.After after the 1st, 2 medicines, the best control efficiency of 10 days reaches respectively 90.03% and 92.08%, the 2 medicine, 20 days best preventive effects reach 90.24%.And 20 days best preventive effects are 84.81% after the 2nd medicine of single dose 15% copper rosinate EC, the effect of complex preparation is significantly better than single dose.According to field range estimation, with the cucumber of 23%imicyafos copper rosinate, substantially there is no insect pest, and growth fraction is more vigorous, and the cucumber of 15% copper rosinate EC single dose occurs that insect pest is more, than much approximately 15% left and right of insect pest plant with complex preparation.
Within the scope of test dose, plant growth is normal in addition, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.
Claims (5)
1. a Fungicidal insecticidal composition that contains abietic acid ketone, it is characterized in that: this Fungicidal insecticidal composition is to take A novel pesticide Imicyafos and B abietic acid ketone as two yuan of composite composite preparations of active ingredient, all the other components are usual auxiliaries in agricultural chemicals, and the structural formula of A novel agrochemical Imicyafos is as follows:
, in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 1～50: 50～1.
2. a kind of Fungicidal insecticidal composition that contains abietic acid ketone according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 3～25: 25～5.
3. a kind of Fungicidal insecticidal composition that contains abietic acid ketone according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, to account for the portion rate of gross weight in preparation be 1%～80% for effective constituents A and B gross weight.
4. a kind of Fungicidal insecticidal composition that contains abietic acid ketone according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation and be preferably 5%～35%.
5. a kind of Fungicidal insecticidal composition that contains abietic acid ketone according to claim 1, is characterized in that: the preparation formulation that insecticidal and bactericidal composition of the present invention can be mixed with is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310746481.6A CN103704258B (en) | 2013-12-30 | 2013-12-30 | A kind of Fungicidal insecticidal composition containing abietic acid ketone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310746481.6A CN103704258B (en) | 2013-12-30 | 2013-12-30 | A kind of Fungicidal insecticidal composition containing abietic acid ketone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103704258A true CN103704258A (en) | 2014-04-09 |
| CN103704258B CN103704258B (en) | 2016-04-27 |
Family
ID=50397932
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310746481.6A Expired - Fee Related CN103704258B (en) | 2013-12-30 | 2013-12-30 | A kind of Fungicidal insecticidal composition containing abietic acid ketone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103704258B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108041079A (en) * | 2017-12-19 | 2018-05-18 | 北京科威拜沃生物技术有限公司 | Wettable powder of T-22 containing trichoderma harzianum and copper rosinate and its preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
| JP2003081987A (en) * | 2001-09-06 | 2003-03-19 | Agro Kanesho Co Ltd | Imidazolidine derivative containing optically active organophosphorus group, method for producing the same and noxious animal controller containing the same as active ingredient |
| CN1860873A (en) * | 2005-05-12 | 2006-11-15 | 青岛科技大学 | Aqueous emulsion of copper rosinate and its prepn. method |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
-
2013
- 2013-12-30 CN CN201310746481.6A patent/CN103704258B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
| JP2003081987A (en) * | 2001-09-06 | 2003-03-19 | Agro Kanesho Co Ltd | Imidazolidine derivative containing optically active organophosphorus group, method for producing the same and noxious animal controller containing the same as active ingredient |
| CN1860873A (en) * | 2005-05-12 | 2006-11-15 | 青岛科技大学 | Aqueous emulsion of copper rosinate and its prepn. method |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108041079A (en) * | 2017-12-19 | 2018-05-18 | 北京科威拜沃生物技术有限公司 | Wettable powder of T-22 containing trichoderma harzianum and copper rosinate and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103704258B (en) | 2016-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102986700A (en) | Insecticide composition containing flutenzine and bistrifluron | |
| CN103651563B (en) | A kind of Fungicidal insecticidal composition containing brassin lactones | |
| CN103704255A (en) | Sterilization and insecticide composition containing pyraclostrobin | |
| CN108208000A (en) | A kind of nematicidal agent composition containing imicyafos | |
| CN102972430A (en) | Insecticidal composition containing thiamethoxam and acetamiprid | |
| CN102428922A (en) | Diacylhydrazine pesticide compounded pesticidal composition | |
| CN103125496A (en) | Novel insecticide composition compounding pymetrozine | |
| CN102293200B (en) | Sterilization composition containing zoxamide and copper pimaric acid | |
| CN105557739A (en) | Pest killing composition | |
| CN103704258B (en) | A kind of Fungicidal insecticidal composition containing abietic acid ketone | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN102972421A (en) | Insecticidal composition containing emamectin benzoate and triflumuron | |
| CN103734181B (en) | A kind of Fungicidal insecticidal composition containing cyflufenamid | |
| CN103749529B (en) | A kind of insecticidal and bactericidal composition | |
| CN103651561B (en) | A kind of Fungicidal insecticidal composition containing fenhexamid | |
| CN103734182B (en) | A kind of Fungicidal insecticidal composition containing mancozeb | |
| CN103734179B (en) | A kind of Fungicidal insecticidal composition containing bupirimate | |
| CN103719149A (en) | Sterilization insecticide composition with picoxystrobin | |
| CN103749530B (en) | A kind of Pesticidal combination containing Avermectin | |
| CN109392928A (en) | A kind of Pesticidal combination containing emamectin benzoate Yu second azoles mite nitrile | |
| CN103734183B (en) | A kind of Fungicidal insecticidal composition containing tetraconazole | |
| CN103734180B (en) | A kind of Fungicidal insecticidal composition containing sufluoxime | |
| CN107361072A (en) | A kind of Pesticidal combination containing emamectin benzoate and cyflumetofen | |
| CN103651562B (en) | A kind of Fungicidal insecticidal composition containing prothioconazoles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Tao Inventor before: Sun Mengmeng |
|
| COR | Change of bibliographic data | ||
| GR01 | Patent grant | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160407 Address after: 250101 Shandong city of Ji'nan province high tech Zone Xinyu Road on the west side of century wealth center AB block 1048-B Applicant after: JINAN SHUNXIANG MEDICINE SCIENCE & TECHNOLOGY CO., LTD. Address before: 256660, No. three, 5 village, old town, Binhu District, Shandong, Binzhou Applicant before: Sun Mengmeng |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160427 Termination date: 20171230 |