CN103694789A - Water-based ink with mosquito repelling effect for wallpaper and preparation method thereof - Google Patents
Water-based ink with mosquito repelling effect for wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN103694789A CN103694789A CN201310625186.5A CN201310625186A CN103694789A CN 103694789 A CN103694789 A CN 103694789A CN 201310625186 A CN201310625186 A CN 201310625186A CN 103694789 A CN103694789 A CN 103694789A
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- China
- Prior art keywords
- repelling effect
- wallpaper
- water
- use ink
- ink
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001846 repelling effect Effects 0.000 title claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 241000255925 Diptera Species 0.000 title abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 239000003094 microcapsule Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000012153 distilled water Substances 0.000 claims abstract description 6
- 239000002562 thickening agent Substances 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 238000013019 agitation Methods 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 8
- 230000008719 thickening Effects 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 230000007704 transition Effects 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 8
- 239000000077 insect repellent Substances 0.000 abstract description 4
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- 238000009736 wetting Methods 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 238000007639 printing Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000003197 gene knockdown Methods 0.000 description 2
- 238000009775 high-speed stirring Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 231100000749 chronicity Toxicity 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a water-based ink with a mosquito repelling effect for wallpaper and a preparation method thereof. The formula of the water-based ink comprises the following components in parts by mass: 30-40% of water-based filming emulsion, 40-50% of distilled water, 0.5-5% of wetting flatting agent, 0.1-1% of defoaming agent, 5-20% of microcapsule mosquito repellent, and 1-5% of thickener. The preparation method comprises steps of after weighting the raw materials according to the parts by weight, adding the water-based filming emulsion into a mixing tank and mixing, simultaneously, sequentially adding the distilled water, the wetting flatting agent, the defoaming agent and the thickener into the mixing tank and mixing uniformly through stirring; then adding the microcapsule mosquito repellent into the mixing tank and mixing uniformly through stirring; and finally, filtering by a 200-300-mesh sieve so as to obtain the ink with mosquito repelling effect. The water-based ink takes water as the solvent, does not volatilize toxic and organic solvents, and does not pollute the air; after being printed normally, the common wallpaper has a lasting mosquito repelling effect, can repel mosquitoes in a room with the wallpaper without a dead angle, is safe and has no toxicity.
Description
Technical field
The present invention relates to a kind of formula and complete processing with the wallpaper use ink of repelling effect.
Background technology
Along with the development of national economy and the raising of living standards of the people, shiploads of merchandise house and hotel, exhibition center emerge in large numbers, people improve constantly the requirement of house decorative material, and wallpaper is more and more subject to people's attention as the important component part of Modern Interior Decoration material.Because wallpaper has good decorative effect, the feature of construct convenient and environmental protection obtains applying more and more widely.From at first in hotel, the public arena such as office building, exhibition hall, be applied to by now ordinarily resident's house more and more in a large number.But wallpaper is except outward appearance on the market, function is comparatively single, and the functionalized application that how to improve wallpaper becomes industrial hot spot.
Summary of the invention
In order to realize above-mentioned effect, it is raw material that the present invention adopts microcapsule anophelifuge, and a kind of formula and complete processing thereof with the wallpaper use ink of repelling effect is provided, and the wallpaper that uses this ink to prepare has long-acting repelling effect.Traditional water color ink with repelling effect, in formula, use the water miscible extraction liquid extracting from mosquito repellent plant, repelling effect is easily subject to the impact of the environmental factorss such as scouring, Exposure to Sunlight, humidity and declines rapidly, adopts the coated anophelifuge of microcapsulary can address these problems easily.But the general non-refractory of wall capsule of microcapsule anophelifuge, is difficult to adapt to wallpaper printing water ink and dries residing hot environment (130～180oC).If use suitable siccative in ink, the bake out temperature that wallpaper is printed to ink is reduced to below 100oC, and the application of microcapsulary in wallpaper printing ink will become possibility so.
The present invention solves the scheme that its technical problem adopts: a kind of wallpaper use ink with repelling effect, adopting ethanol, glycerol is siccative, forms suitable volatilization gradient.It comprises the raw material of following parts by weight:
Described solvent is the arbitrary proportion mixture of water and alcohol.Described alcohol can be alcohol soluble in water and harmless under the normal temperature such as ethanol, glycerol.Preferably, water accounts for the 5%-10% of total weight, and alcohol accounts for 30-45%.
Preferably, described waterborne film-forming emulsion is aqueous acrylic emulsion, solid content 45～48%, acid number 30～60mgKOH/g, 20～40 ℃ of second-order transition temperatures, pH value approximately 7.5～9.5, viscosity 500～1000mPa.s.
Preferably, described moistening flatting agent is polyether siloxane copolymer, effective content 100%, the about 100mPa.s of viscosity.
Preferably, described defoamer is the mixture of fatty family mineral oil, effective content 100%, the about 100mPa.s of viscosity.
Preferably, the PCM-SF that described microcapsule anophelifuge is Hansi Chemical Article Co., Ltd., Changzhou, particle diameter 10 μ m, anionic emulsion shape.This microcapsule anophelifuge is to adopt the polymerization preparation of location, interface to take a kind of ball-type capsule that macromolecule resin is core, and capsule wall has thermoset nature, firm, is suitable for the mosquito-proof arrangement in the fields such as textiles, coating, ink, and weather resistance is splendid.
Preferably, described thickening material is association type polyurethane thickener, effective content 50～60%, viscosity 2000～3000mPa.s.
A kind of preparation method with the wallpaper use ink of repelling effect, according to described parts by weight, get raw material, described waterborne film-forming emulsion is added in agitation vat and stirred, successively described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir simultaneously; Then described microcapsule anophelifuge is added in agitation vat, stir; Finally, with 200～300 eye mesh screens, filter, obtain repelling effect ink.
Beneficial effect of the present invention: (1) adopts water, alcohol is solvent, without the volatilization of poisonous organic solvent, pollution-free to air; (2) concise production process of the present invention, equipment requirements is simple, and cost is low; (3) realize common wallpaper by normal typography after, realize repelling effect and keep chronicity, not only can realize lay room without dead angle mosquito repellent, and safety non-toxic evil.(4) by formula adjustment, reduce the bake out temperature (being reduced to 70～80oC from 130 original～180oC) of water color ink, solved the high temperature splintering problem of traditional microcapsule anophelifuge in water color ink.
Embodiment
With an embodiment, the present invention is further detailed explanation below, is not practical range of the present invention is confined to this.
Embodiment 1, a kind of wallpaper use ink with repelling effect described in the present embodiment, it by the raw material of following parts by weight add in agitation vat through mixing, stirring obtains:
Described in present case, waterborne film-forming emulsion is the aqueous acrylic emulsion that Green spring (Xiamen) environmental protection science and technology Materials Co., Ltd produces, solid content 47%, acid number 55,30 ℃ of second-order transition temperatures, pH value approximately 8.5, viscosity 800mPa.s; Moistening flatting agent is
flow425, polyether siloxane copolymer, effective content 100%, viscosity 100mPa.s; Defoamer is
foamex K8, the mixture of aliphatics mineral oil, effective content 100%, viscosity 100mPa.s; Microcapsule anophelifuge is the PCM-SF of Hansi Chemical Article Co., Ltd., Changzhou, particle diameter 10 μ m, anionic emulsion shape; Thickening material is
viscoPlus3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s; Preparation method is, according to described parts by weight, get raw material, described aqueous acrylic emulsion is added to agitation vat high-speed stirring (stirring velocity 800rpm), successively described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir simultaneously; Then described microcapsule anophelifuge is added to agitation vat stirring at low speed (stirring velocity 400rpm), stir; Finally, with 260 eye mesh screens, filter, obtain repelling effect ink.During printing, oven temperature is set as 60oC, and print speed is set as 40 ms/min, and printing effect is normal.Then according to GB GB18416-2001, repelling effect is tested, leading indicator KT50≤5.0min(note: KT50 characterizes drug effect, refer to knock down or to expel the time of mosquito), higher than the standard of KT50≤8.0min in GB, and effective time length >=6 month.
Embodiment 2, a kind of wallpaper use ink with repelling effect described in the present embodiment, it by the raw material of following parts by weight add in agitation vat through mixing, stirring obtains:
Described in present case, waterborne film-forming emulsion is the aqueous acrylic emulsion that Green spring (Xiamen) environmental protection science and technology Materials Co., Ltd produces, solid content 47%, acid number 55,30 ℃ of second-order transition temperatures, pH value approximately 8.5, viscosity 800mPa.s; Moistening flatting agent is
flow425, polyether siloxane copolymer, effective content 100%, viscosity 100mPa.s; Defoamer is
foamex K8, the mixture of aliphatics mineral oil, effective content 100%, viscosity 100mPa.s; Microcapsule anophelifuge is the PCM-SF of Hansi Chemical Article Co., Ltd., Changzhou, particle diameter 10 μ m, anionic emulsion shape; Thickening material is
viscoPlus3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s; Preparation method is, according to described parts by weight, get raw material, described aqueous acrylic emulsion is added to agitation vat high-speed stirring (stirring velocity 800rpm), successively described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir simultaneously; Then described microcapsule anophelifuge is added to agitation vat stirring at low speed (stirring velocity 400rpm), stir; Finally, with 260 eye mesh screens, filter, obtain repelling effect ink.During printing, oven temperature is set as 80oC, and print speed is set as 30 ms/min, and printing effect is normal.Then according to GB GB18416-2001, repelling effect is tested, leading indicator KT50≤4.0min(note: KT50 characterizes drug effect, refers to knock down or expel the time of mosquito), higher than the standard of KT50≤8.0min in GB, and effective time length >=1 year.
The above is only a preferred embodiment of the present invention, just for helping to understand method of the present invention and core concept thereof.It should be pointed out that for those skilled in the art, under the premise of not departing from the present invention, can also carry out some improvement and modification to the present invention, these modifications and modification also fall in the protection domain of the claims in the present invention.
Claims (9)
1. a wallpaper use ink with repelling effect, is characterized in that: it comprises the raw material of following parts by weight:
2. a kind of wallpaper use ink with repelling effect according to claim 1, is characterized in that: described solvent is the arbitrary proportion mixture of water and alcohol.
3. a kind of wallpaper use ink with repelling effect according to claim 2, is characterized in that: described alcohol comprises ethanol, glycerol.
4. a kind of wallpaper use ink with repelling effect according to claim 1, it is characterized in that: described waterborne film-forming emulsion is aqueous acrylic emulsion, solid content 45～48%, acid number 30～60mgKOH/g, 20～40 ℃ of second-order transition temperatures, pH value 7.5～9.5, viscosity 500～1000mPa.s.
5. a kind of wallpaper use ink with repelling effect according to claim 1, is characterized in that: described moistening flatting agent is polyether siloxane copolymer effective content 100%, viscosity 50～300mPa.s.
6. a kind of wallpaper use ink with repelling effect according to claim 1, is characterized in that: described defoamer is the mixture of fatty family mineral oil effective content 100%, viscosity 50～300mPa.s.
7. a kind of wallpaper use ink with repelling effect according to claim 1, is characterized in that: described thickening material is association type polyurethane thickener effective content 50～60%, viscosity 2000～3000mPa.s.
8. a kind of wallpaper use ink with repelling effect according to claim 1, is characterized in that: described microcapsule anophelifuge is powder or emulsion form particle diameter≤10 μ m.
9. a preparation method with the wallpaper use ink of repelling effect, comprise the steps: to get raw material according to parts by weight described in claim 1, described waterborne film-forming emulsion is added in agitation vat and stirred, successively described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir simultaneously; Then described microcapsule anophelifuge is added in agitation vat, stir; Finally, with 200～300 eye mesh screens, filter, obtain repelling effect ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310625186.5A CN103694789B (en) | 2013-11-28 | 2013-11-28 | A kind of wallpaper use ink with repelling effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310625186.5A CN103694789B (en) | 2013-11-28 | 2013-11-28 | A kind of wallpaper use ink with repelling effect and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103694789A true CN103694789A (en) | 2014-04-02 |
| CN103694789B CN103694789B (en) | 2015-10-28 |
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400285A (en) * | 2015-12-29 | 2016-03-16 | 广东天龙油墨集团股份有限公司 | High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof |
| CN106368397A (en) * | 2016-10-27 | 2017-02-01 | 广东玉兰集团股份有限公司 | Anti-mosquito wallpaper and preparation method thereof |
| CN106401099A (en) * | 2016-10-27 | 2017-02-15 | 广东玉兰集团股份有限公司 | Anti-acarid wallpaper and preparation method thereof |
| CN114921965A (en) * | 2022-06-13 | 2022-08-19 | 温多利遮阳材料（德州）股份有限公司 | Anti-mosquito coating, anti-mosquito sun-shading fabric containing same, and preparation method and application thereof |
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| CN105400285A (en) * | 2015-12-29 | 2016-03-16 | 广东天龙油墨集团股份有限公司 | High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof |
| CN106368397A (en) * | 2016-10-27 | 2017-02-01 | 广东玉兰集团股份有限公司 | Anti-mosquito wallpaper and preparation method thereof |
| CN106401099A (en) * | 2016-10-27 | 2017-02-15 | 广东玉兰集团股份有限公司 | Anti-acarid wallpaper and preparation method thereof |
| CN114921965A (en) * | 2022-06-13 | 2022-08-19 | 温多利遮阳材料（德州）股份有限公司 | Anti-mosquito coating, anti-mosquito sun-shading fabric containing same, and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
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| CN103694789B (en) | 2015-10-28 |
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