CN103304719A - Acrylic emulsion and preparation method and application in waterborne polyvinyl chloride (PVC) wallpaper ink thereof - Google Patents
Acrylic emulsion and preparation method and application in waterborne polyvinyl chloride (PVC) wallpaper ink thereof Download PDFInfo
- Publication number
- CN103304719A CN103304719A CN2013102819925A CN201310281992A CN103304719A CN 103304719 A CN103304719 A CN 103304719A CN 2013102819925 A CN2013102819925 A CN 2013102819925A CN 201310281992 A CN201310281992 A CN 201310281992A CN 103304719 A CN103304719 A CN 103304719A
- Authority
- CN
- China
- Prior art keywords
- acrylic emulsion
- component
- water
- methyl
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to the technical field of water-based ink and discloses acrylic emulsion. The acrylic emulsion comprises a first component, a second component and water; the acrylic emulsion comprises the following components in percentage by weight: the first component comprising 0-5 percent of emulsifier, 0-20 percent of styrene, 0-5 percent of cross-linking monomer and 10-40 percent of acrylate polymerization monomer; the second component comprising 5-15 percent of protection glue and 0.1-5 percent of initiator; the balance of water. The acrylic emulsion is prepared by the following steps: (1) uniformly mixing each component in the first component, thereby obtaining a solution A; (2) adding water into a reaction container, raising the temperature to be 75-95 DEG C, adding the protection glue, and stirring until the mixture is dissolved; (3) simultaneously dripping the solution A and the initiator into the reaction container, finishing dripping at a constant speed within 2-2.5 hours, and keeping the temperature for 30 minutes after dripping is finished; (4) cooling and discharging. The acrylic emulsion is high-temperature-resistant, has excellent adhesion force to polyvinyl chloride (PVC), does not contain harmful alcohol solvents and can be widely applied to the PVC wallpaper ink.
Description
Technical field
The present invention relates to the water color ink technical field, specifically a kind of ACRYLIC EMULSION and preparation method thereof and the application in water-based PVC wallpaper printing ink.
Background technology
The wallpaper of now China's production can be divided into paper substrate paper wallpaper by material, PVC wallpaper, fabric side wallpaper, natural materials surface wallpaper, sand surface wallpaper, diatomite wallpaper, non-woven fabrics wallpaper.The PVC wallpaper is take paper as base material, take PVC as surface layer, and the PVC top layer carried out the Lacquer finish sealing, then processes embossing printing etc. the PVC wallpaper is carried out the decoration.PVC material in the wallpaper printing is as a kind of non-absorbent material, what mostly use when printing is solvent type ink, the volatilization of its solvent not only can cause healthy infringement to on-the-spot press operator in printing process, people decorate wallpaper in family, and volatilize residual solvents wherein also can cause damage to kinsfolk's health.
Although existing ACRYLIC EMULSION type PVC wallpaper gloss oil is water-based system, VOC content is lower, basic symbols cyclization guaranteed request, and the allotment of most water color inks has still added a large amount of harmful alcoholic solvents such as Virahol, still can cause certain harm to human body.Existing emulsion of while and PVC wallpaper printing ink hot sticky cold crisp, resistance to elevated temperatures is not enough to satisfy the not hot sticky requirement of embossing.
Summary of the invention
For the problem of above-mentioned existence, a kind of aqueous acrylic emulsion is provided, it does not contain harmful alcohols equal solvent, high temperature resistant, PVC is had excellent adhesive attraction.
Another object of the present invention is to provide the preparation method of aforesaid propylene yogurt liquid.
A further object of the invention provides a kind of PVC wallpaper printing ink that contains aforesaid propylene yogurt liquid.
The present invention takes following technical scheme to be achieved for achieving the above object:
A kind of ACRYLIC EMULSION, comprise the first component, second component and water, the weight percent that each composition in the described component accounts for described emulsion is: the first component: emulsifying agent 0～5%, vinylbenzene 0～20%, cross-linking monomer 0～5%, acrylic monomer 10～40%; Second component: protection glue 5～15%, initiator 0.1～5%; Surplus is water.
Described emulsifying agent is formed by reactive emulsifier and anionic emulsifier interworking.Anionic emulsifier comprises carboxylate salt, sulfonate, sulfuric acid, phosphate ester salt, preferably uses alkyl diphenyl ether disulphonic acid sodium, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate and alkylphenol polyoxyethylene vitriol; Reactive emulsifier comprises the acrylamido sodium isopropyl xanthate, contains the vinyl alcohol ether sulfate, contains vinyl alcohol ether sulfosuccinic acid esters sodium salt, vinyl ether hydroxy alkyl sulfonic acid sodium.It is that alkylphenol polyoxyethylene vitriol and the vinyl ether hydroxy alkyl sulfonic acid sodium interworking of 1:1 forms that emulsifying agent among the present invention preferably adopts mass ratio.
Described cross-linking monomer is (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, acrylamide, N hydroxymethyl acrylamide, N, the mixture of one or more in N-diacetone-acryloamide(DAA), glycidyl methacrylate and the phosphoric acid ester function monomer.
Described acrylic monomer refers in vinylformic acid, (methyl) vinylformic acid, acrylate or (methyl) acrylate more than one mixture.Preferably, the acrylic monomer is more than one mixture in vinylformic acid, (methyl) vinylformic acid, (methyl) methyl acrylate, (methyl) ethyl propenoate, (methyl) butyl acrylate, (methyl) Isooctyl acrylate monomer and the isobornyl methacrylate.More preferably, the acrylic monomer is more than one mixture in (methyl) vinylformic acid, butyl acrylate, Isooctyl acrylate monomer, (methyl) methyl acrylate.
Described protection glue is any in polyvinyl alcohol, styrene-maleic anhydride copolymer, acrylate copolymer and the vinylformic acid-styrol copolymer.The present invention preferably uses acrylate copolymer or vinylformic acid-styrol copolymer.
Described initiator is any in inorganic peroxide initiator, organic peroxide evocating agent, azo-initiator and the redox class initiator.Inorganic peroxide initiator commonly used has Potassium Persulphate, ammonium persulphate; Organic peroxide evocating agent commonly used has benzoyl peroxide, tertbutyl peroxide; Azo-initiator commonly used then has Diisopropyl azodicarboxylate; Initiator system of ammonium persulfate of the present invention, Potassium Persulphate are as initiator.
The Tg of described ACRYLIC EMULSION is 20 ℃～80 ℃, can anti-220 ℃ high temperature, the PVC base material there is excellent adhesive attraction.
Aqueous acrylic emulsion among the present invention is synthetic especially for the application of PVC wallpaper printing ink, different from common aqueous acrylic emulsion is the special cross-linking monomer of having introduced phosphinylidyne-containing amine group and having contained vinyl phosphate, the adding of these special cross-linking monomers has improved the thermotolerance of emulsion and to the sticking power of PVC base material.
Another technical scheme of the present invention is as follows: a kind of preparation method of aforesaid propylene yogurt liquid may further comprise the steps:
(1) each composition in the first component is mixed, obtain solution A;
(2) add entry in reaction vessel, be warming up to 75 ℃～95 ℃, add protection glue, high-speed stirring is to fully dissolving;
(3) in reaction vessel, drip simultaneously solution A and initiator, at the uniform velocity drip in 2～2.5h, drip off insulation 30min;
(4) cooling, discharging.
Preferably be cooled to first 70 ℃ in the step (4), adding tertbutyl peroxide etc. is removed residual monomer, and then cooling, discharging.
Another technical scheme of the present invention is as follows: a kind of water-based PVC wallpaper printing ink that contains aforesaid propylene yogurt liquid, the following component that comprises mass percent: ethanol 0～10%, ACRYLIC EMULSION 30%～70%, aqueous color paste 10%～50%, wetting agent 0.5%～3%, flow agent 0.5%～3%, film coalescence aid 0.5%～3%, defoamer 0.1%～1%, wear-resistant scraping-resistant agent 0.5%～5%, surplus is water.
Described aqueous color paste is 10%～60% water soluble acrylic acid ester solution or waterborne polyester solution, 10～50% environmental-friendly pigment, 10%～40% water by mass percent, and 0～5% environmental protection dispersion agent, 0.1%～1% defoamer grind in sand mill and form.
Described wetting agent is nonionogenic tenside or polyether siloxane copolymer.The present invention is preferably the acetylenic diols nonionogenic tenside.
Described flow agent is any in fluorin modified crylic acid ester copolymer, polyether modified siloxane and the phosphate modified acrylic copolymer.The present invention preferably adopts polyether modified siloxane as flow agent.
Described film coalescence aid is any in propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether, Trivalin SF, diethylene glycol monobutyl ether, Diethylene Glycol butyl ether and the dipropylene glycol butyl ether.The preferred Diethylene Glycol butyl ether of the present invention or dipropylene glycol butyl ether are as film coalescence aid.
Described defoamer is any in polysiloxane, mineral oil, polyethers, higher alcohols and the vegetables oil.The present invention preferably adopts the polyethers defoamer.
Described wear-resistant scraping-resistant agent is one or more the mixture in polyethylene wax slurry, tetrafluoroethylene wax slurry, the organic silicon surfactant.The tetrafluoroethylene wax that the preferred fusing point of the present invention is higher is starched as anti-wear agent.
Beneficial effect of the present invention is as follows: the aqueous acrylic emulsion synthetic method among the present invention is consistent with prior synthesizing method, easy and simple to handle, is easy to control, and synthetic product emulsion is stable.Aqueous acrylic emulsion of the present invention is synthetic especially for the application of PVC wallpaper printing ink, different from common aqueous acrylic emulsion is the special cross-linking monomer of having introduced phosphinylidyne-containing amine group and having contained vinyl phosphate, the adding of these special cross-linking monomers, improved the thermotolerance of emulsion and to the sticking power of PVC base material, amide group and carboxyl phosphate-based and that the acrylic monomer is contained very easily occur crosslinked after drying loses amino simultaneously, emulsion film forming after crosslinked is good, transparency is high, attachment fastness is good, water resisting property is good, is applied to make it possess corresponding advantage in the PVC wallpaper printing ink.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1～5:
Prepare ACRYLIC EMULSION according to the described prescription of table 1:
Table 1 ACRYLIC EMULSION formula table (parts by weight)
Among the embodiment 1～5, emulsifying agent is formed by reactive emulsifier and anionic emulsifier interworking.Anionic emulsifier comprises carboxylate salt, sulfonate, sulfuric acid, phosphate ester salt, preferably uses alkyl diphenyl ether disulphonic acid sodium, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate and alkylphenol polyoxyethylene vitriol; Reactive emulsifier comprises the acrylamido sodium isopropyl xanthate, contains the vinyl alcohol ether sulfate, contains vinyl alcohol ether sulfosuccinic acid esters sodium salt, vinyl ether hydroxy alkyl sulfonic acid sodium.Alkylphenol polyoxyethylene vitriol and vinyl ether hydroxy alkyl sulfonic acid sodium interworking that preferred employing mass ratio is 1:1 form.
Cross-linking monomer is (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, acrylamide, N hydroxymethyl acrylamide, N, the mixture of one or more in N-diacetone-acryloamide(DAA), glycidyl methacrylate and the phosphoric acid ester function monomer.
The acrylic monomer refers in vinylformic acid, (methyl) vinylformic acid, acrylate or (methyl) acrylate more than one mixture.Preferably, the acrylic monomer is more than one mixture in vinylformic acid, (methyl) vinylformic acid, (methyl) methyl acrylate, (methyl) ethyl propenoate, (methyl) butyl acrylate, (methyl) Isooctyl acrylate monomer and the isobornyl methacrylate.More preferably, the acrylic monomer is more than one mixture in (methyl) vinylformic acid, butyl acrylate, Isooctyl acrylate monomer, (methyl) methyl acrylate.
Protection glue is any in polyvinyl alcohol, styrene-maleic anhydride copolymer, acrylate copolymer and the vinylformic acid-styrol copolymer.Preferred acrylate copolymer or the vinylformic acid-styrol copolymer of using.
Initiator is any in inorganic peroxide initiator, organic peroxide evocating agent, azo-initiator and the redox class initiator.Inorganic peroxide initiator commonly used has Potassium Persulphate, ammonium persulphate; Organic peroxide evocating agent commonly used has benzoyl peroxide, tertbutyl peroxide; Azo-initiator commonly used then has Diisopropyl azodicarboxylate; Initiator system of ammonium persulfate, Potassium Persulphate are as initiator.
Embodiment 6
The preparation method of the ACRYLIC EMULSION that table 1 provides may further comprise the steps:
(1) each composition with the first component among the embodiment 1～5 mixes in header tank, obtains solution A;
(2) add entry in the four-hole boiling flask that heating jacket, stirring arm, condenser, header tank are housed, start stirring, be warming up to 75 ℃, add protection glue, high-speed stirring is to fully dissolving;
(3) in four-hole boiling flask, drip simultaneously solution A and initiator, at the uniform velocity drip in the 2h, drip off insulation 30min;
(4) cooling, discharging.
Preferably be cooled to first 70 ℃ in the step (4), add an amount of tertbutyl peroxide and remove residual monomer, and then cooling, discharging.
The Tg of the ACRYLIC EMULSION that makes is 20 ℃～80 ℃, can anti-220 ℃ high temperature, the PVC base material there is excellent adhesive attraction, and good film-forming property, transparency is high, water resisting property is good.
Embodiment 7
The preparation method of the ACRYLIC EMULSION that table 1 provides may further comprise the steps:
(1) each composition with the first component among the embodiment 1～5 mixes in header tank, obtains solution A;
(2) add entry in the four-hole boiling flask that heating jacket, stirring arm, condenser, header tank are housed, start stirring, be warming up to 80 ℃, add protection glue, high-speed stirring is to fully dissolving;
(3) in four-hole boiling flask, drip simultaneously solution A and initiator, at the uniform velocity drip in the 2.5h, drip off insulation 30min;
(4) cooling, discharging.
Preferably be cooled to first 70 ℃ in the step (4), add an amount of tertbutyl peroxide and remove residual monomer, and then cooling, discharging.
The Tg of the ACRYLIC EMULSION that makes is 20 ℃～80 ℃, can anti-220 ℃ high temperature, the PVC base material there is excellent adhesive attraction, and good film-forming property, transparency is high, water resisting property is good.
Embodiment 8
The preparation method of the ACRYLIC EMULSION that table 1 provides may further comprise the steps:
(1) each composition with the first component among the embodiment 1～5 mixes in header tank, obtains solution A;
(2) add entry in the four-hole boiling flask that heating jacket, stirring arm, condenser, header tank are housed, start stirring, be warming up to 95 ℃, add protection glue, high-speed stirring is to fully dissolving;
(3) in four-hole boiling flask, drip simultaneously solution A and initiator, at the uniform velocity drip in the 2.2h, drip off insulation 30min;
(4) cooling, discharging.
Preferably be cooled to first 70 ℃ in the step (4), add an amount of tertbutyl peroxide and remove residual monomer, and then cooling, discharging.
The Tg of the ACRYLIC EMULSION that makes is 20 ℃～80 ℃, can anti-220 ℃ high temperature, the PVC base material there is excellent adhesive attraction, and good film-forming property, transparency is high, water resisting property is good.
Embodiment 9～13
Prepare water-based PVC wallpaper printing ink according to the described prescription of table 2:
Table 2 water-based PVC wallpaper ink formulations table (parts by weight)
ACRYLIC EMULSION among the embodiment 9～13 is prepared from by embodiment 6～8.
Ethanol is the solvent of nonessential interpolation, and quick-drying and a little levelling effect only are provided, and allows the non-noxious solvent that adds for national legislation.
Wetting agent is nonionogenic tenside or polyether siloxane copolymer.Be preferably the acetylenic diols nonionogenic tenside.
Flow agent is any in fluorin modified crylic acid ester copolymer, polyether modified siloxane and the phosphate modified acrylic copolymer.The preferred polyether modified siloxane that adopts is as flow agent.
Film coalescence aid is any in propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether, Trivalin SF, diethylene glycol monobutyl ether, Diethylene Glycol butyl ether and the dipropylene glycol butyl ether.Preferred Diethylene Glycol butyl ether or dipropylene glycol butyl ether are as film coalescence aid.
Defoamer is any in polysiloxane, mineral oil, polyethers, higher alcohols and the vegetables oil.The preferred polyethers defoamer that adopts.
Wear-resistant scraping-resistant agent is one or more the mixture in polyethylene wax slurry, tetrafluoroethylene wax slurry, the organic silicon surfactant.The tetrafluoroethylene wax that preferred fusing point is higher is starched as anti-wear agent.
Aqueous color paste is 10%～60% water soluble acrylic acid ester solution or waterborne polyester solution, 10～50% environmental-friendly pigment, 10%～40% water by mass percent, and 0～5% environmental protection dispersion agent, 0.1%～1% defoamer grind in sand mill and form.
Can prepare aqueous color paste according to the described prescription of table 3:
Table 3 aqueous color paste formula table (parts by weight)
Press the deployed rear 1:1 weight of pressing of table 3 prescription and add granulated glass sphere in iron flask, high speed dispersion is 3 hours on wobbler, namely makes aqueous color paste, and the mill base main performance index sees Table 4:
Table 4 aqueous color paste performance table
Utilize mill base and the collocation of the ACRYLIC EMULSION among the embodiment 9～13 stripping strength of the preparation of waterborne polyester solution can reach 100%, utilizing mill base and the collocation of the ACRYLIC EMULSION among the embodiment 9～13 stripping strength of the preparation of water-borne acrylic resin solution is 93% then, has part to come off.
Utilize the mill base of waterborne polyester solution preparation, be prepared into water-based PVC wallpaper printing ink according to table 2 prescription, as shown in table 5 with the external product performance comparison:
Table 5 performance comparison table
The water-based PVC wallpaper printing ink good film-forming property of making, transparency is high, attachment fastness good, water resisting property is good.
The above technical scheme that the embodiment of the invention is provided is described in detail, used specific case herein principle and the embodiment of the embodiment of the invention are set forth, the explanation of above embodiment is only applicable to help to understand the principle of the embodiment of the invention; Simultaneously, for one of ordinary skill in the art, according to the embodiment of the invention, all will change on embodiment and range of application, in sum, this description should not be construed as limitation of the present invention.
Claims (10)
1. an ACRYLIC EMULSION is characterized in that, comprises the first component, second component and water, the weight percent that each composition in the described component accounts for described emulsion is: the first component: emulsifying agent 0～5%, vinylbenzene 0～20%, cross-linking monomer 0～5%, acrylic monomer 10～40%; Second component: protection glue 5～15%, initiator 0.1～5%; Surplus is water.
2. a kind of ACRYLIC EMULSION as claimed in claim 1 is characterized in that, described emulsifying agent is that alkylphenol polyoxyethylene vitriol and the vinyl ether hydroxy alkyl sulfonic acid sodium interworking of 1:1 forms by mass ratio.
3. a kind of ACRYLIC EMULSION as claimed in claim 1, it is characterized in that, described cross-linking monomer is (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, acrylamide, N hydroxymethyl acrylamide, N, the mixture of one or more in N-diacetone-acryloamide(DAA), glycidyl methacrylate and the phosphoric acid ester function monomer.
4. a kind of ACRYLIC EMULSION as claimed in claim 1 is characterized in that, described acrylic monomer is more than one mixture in (methyl) vinylformic acid, butyl acrylate, Isooctyl acrylate monomer, (methyl) methyl acrylate.
5. a kind of ACRYLIC EMULSION as claimed in claim 1 is characterized in that, described protection glue is any in polyvinyl alcohol, styrene-maleic anhydride copolymer, acrylate copolymer and the vinylformic acid-styrol copolymer.
6. a kind of ACRYLIC EMULSION as claimed in claim 1 is characterized in that, described initiator is ammonium persulphate or Potassium Persulphate.
7. the preparation method of each described ACRYLIC EMULSION of claim 1～6 is characterized in that, may further comprise the steps:
(1) each composition in the first component is mixed, obtain solution A;
(2) add entry in reaction vessel, be warming up to 75 ℃～95 ℃, add protection glue, high-speed stirring is to fully dissolving;
(3) in reaction vessel, drip simultaneously solution A and initiator, at the uniform velocity drip in 2～2.5h, drip off insulation 30min;
(4) cooling, discharging.
8. water-based PVC wallpaper printing ink that contains each described ACRYLIC EMULSION of claim 1～6, it is characterized in that, the following component that comprises mass percent: ethanol 0～10%, ACRYLIC EMULSION 30%～70%, aqueous color paste 10%～50%, wetting agent 0.5%～3%, flow agent 0.5%～3%, film coalescence aid 0.5%～3%, defoamer 0.1%～1%, wear-resistant scraping-resistant agent 0.5%～5%, surplus are water.
9. water-based PVC wallpaper printing ink according to claim 8, it is characterized in that, described aqueous color paste is 10%～60% water soluble acrylic acid ester solution or waterborne polyester solution, 10～50% environmental-friendly pigment, 10%～40% water by mass percent, and 0～5% environmental protection dispersion agent, 0.1%～1% defoamer grind in sand mill and form.
10. water-based PVC wallpaper printing ink according to claim 8 is characterized in that, described wetting agent is the acetylenic diols nonionogenic tenside; Described flow agent is any in fluorin modified crylic acid ester copolymer, polyether modified siloxane and the phosphate modified acrylic copolymer; Described film coalescence aid is any in propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether, Trivalin SF, diethylene glycol monobutyl ether, Diethylene Glycol butyl ether and the dipropylene glycol butyl ether; Described defoamer is any in polysiloxane, mineral oil, polyethers, higher alcohols and the vegetables oil; Described wear-resistant scraping-resistant agent is one or more the mixture in polyethylene wax slurry, tetrafluoroethylene wax slurry, the organic silicon surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310281992.5A CN103304719B (en) | 2013-07-05 | 2013-07-05 | Acrylic emulsion and preparation method and application in waterborne polyvinyl chloride (PVC) wallpaper ink thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310281992.5A CN103304719B (en) | 2013-07-05 | 2013-07-05 | Acrylic emulsion and preparation method and application in waterborne polyvinyl chloride (PVC) wallpaper ink thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103304719A true CN103304719A (en) | 2013-09-18 |
| CN103304719B CN103304719B (en) | 2015-06-24 |
Family
ID=49130471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310281992.5A Active CN103304719B (en) | 2013-07-05 | 2013-07-05 | Acrylic emulsion and preparation method and application in waterborne polyvinyl chloride (PVC) wallpaper ink thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103304719B (en) |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694790A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Water-based inflaming retarding printing ink special for inflaming retarding wallpaper and preparation method thereof |
| CN103694789A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Water-based ink with mosquito repelling effect for wallpaper and preparation method thereof |
| CN103709864A (en) * | 2013-12-20 | 2014-04-09 | 吴江华尔美特装饰材料有限公司 | Emulsion for preparing metal slurry |
| CN104277512A (en) * | 2014-09-05 | 2015-01-14 | 天长市巨龙车船涂料有限公司 | High-viscosity rosin paint |
| CN104530870A (en) * | 2014-12-24 | 2015-04-22 | 宁波高佳环保涂料有限公司 | Special water-based printing crack pulp for wallpaper and preparation method and application thereof |
| CN104530302A (en) * | 2014-12-11 | 2015-04-22 | 华南理工大学 | Silica sol/polyacrylic ester emulsion with high silicon content and preparation method of silica sol/polyacrylic ester emulsion |
| CN104629525A (en) * | 2015-01-15 | 2015-05-20 | 长兴艾飞特塑料科技有限公司 | Preparation method of inorganic material and water-based amino resin composite water-based printing ink connecting material |
| CN104629532A (en) * | 2015-01-15 | 2015-05-20 | 长兴艾飞特塑料科技有限公司 | Nano titanium dioxide-modified composite water-based ink and preparation method thereof |
| CN104672365A (en) * | 2014-12-03 | 2015-06-03 | 桐乡嘉力丰实业股份有限公司 | Wallpaper base film and preparation method thereof |
| CN105085785A (en) * | 2015-08-13 | 2015-11-25 | 新东方油墨有限公司 | Environmentally-friendly cross-linked acrylate polymer emulsion and preparation method thereof |
| CN105400285A (en) * | 2015-12-29 | 2016-03-16 | 广东天龙油墨集团股份有限公司 | High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof |
| CN106905465A (en) * | 2015-12-22 | 2017-06-30 | 北京奥托米特电子有限公司 | A kind of manufacture method of resin, the resin and the aqueous ink using the resin |
| CN107200807A (en) * | 2017-06-09 | 2017-09-26 | 封开县嘉诚纸业有限公司 | A kind of paper nano color paste dispersant and preparation method and application |
| CN107384014A (en) * | 2017-09-11 | 2017-11-24 | 杭州海维特化工科技有限公司 | A kind of PVC furniture film water foam ink and preparation method thereof |
| CN107964280A (en) * | 2017-12-06 | 2018-04-27 | 安徽鸿宾医药包装有限公司 | A kind of yellowing-resistant printed label and preparation method thereof |
| CN108484823A (en) * | 2018-03-09 | 2018-09-04 | 陕西理工大学 | A kind of acrylic emulsion and preparation method thereof |
| CN108794928A (en) * | 2018-06-22 | 2018-11-13 | 安徽索亚装饰材料有限公司 | A kind of anti-mildew PVC foam Wallpaper paste material |
| CN109021666A (en) * | 2018-08-01 | 2018-12-18 | 佛山市高明绿色德化工有限公司 | A kind of aqueous self-drying glass ink and preparation method thereof |
| CN109266098A (en) * | 2018-08-21 | 2019-01-25 | 广东天龙油墨有限公司 | A kind of waterborne preprinting lotion and preparation method thereof and the application in ink |
| CN109337440A (en) * | 2018-09-26 | 2019-02-15 | 浙江美浓世纪集团有限公司 | A kind of environment-friendly water-based gravure printing ink and preparation method thereof |
| CN109957063A (en) * | 2019-03-22 | 2019-07-02 | 泰兴市华盛银洋新材料科技有限公司 | A kind of acrylic acid ester emulsion and preparation method thereof with ultra-dispersed effect |
| CN110643224A (en) * | 2019-11-12 | 2020-01-03 | 廊坊市安鼎新材料科技有限公司 | Water-based white ink for surface treatment of base material before code spraying and preparation method thereof |
| CN111019435A (en) * | 2019-12-26 | 2020-04-17 | 李辉 | Printing ink binder |
| CN111269350A (en) * | 2020-03-30 | 2020-06-12 | 上海保立佳新材料有限公司 | Environment-friendly water-based plastic-plastic composite adhesive and preparation method thereof |
| CN112778834A (en) * | 2021-02-22 | 2021-05-11 | 昆明凌润科技有限公司 | Nanoscale weak cation acrylate emulsion for water-based transparent ink and preparation method thereof |
| CN114231086A (en) * | 2021-12-01 | 2022-03-25 | 肇庆新广利化工实业有限公司 | Gravure printing ink emulsion, preparation method and preparation device thereof |
| CN114573869A (en) * | 2022-03-17 | 2022-06-03 | 浙江传化华洋化工有限公司 | Barium-zinc liquid stabilizer and application thereof |
| CN116041606A (en) * | 2022-12-30 | 2023-05-02 | 东华大学 | Fluorine-containing acrylate polymer adhesive and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1644795A (en) * | 2004-12-03 | 2005-07-27 | 华南理工大学 | Acrylic acid emulsion gloss, oil, its production and use |
-
2013
- 2013-07-05 CN CN201310281992.5A patent/CN103304719B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1644795A (en) * | 2004-12-03 | 2005-07-27 | 华南理工大学 | Acrylic acid emulsion gloss, oil, its production and use |
Cited By (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694789A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Water-based ink with mosquito repelling effect for wallpaper and preparation method thereof |
| CN103694790A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Water-based inflaming retarding printing ink special for inflaming retarding wallpaper and preparation method thereof |
| CN103709864A (en) * | 2013-12-20 | 2014-04-09 | 吴江华尔美特装饰材料有限公司 | Emulsion for preparing metal slurry |
| CN104277512A (en) * | 2014-09-05 | 2015-01-14 | 天长市巨龙车船涂料有限公司 | High-viscosity rosin paint |
| CN104672365B (en) * | 2014-12-03 | 2017-06-16 | 嘉力丰科技股份有限公司 | A kind of wallpaper basement membrane and preparation method thereof |
| CN104672365A (en) * | 2014-12-03 | 2015-06-03 | 桐乡嘉力丰实业股份有限公司 | Wallpaper base film and preparation method thereof |
| CN104530302B (en) * | 2014-12-11 | 2016-10-05 | 华南理工大学 | A kind of Ludox/polyacrylate dispersion of high silicon content and preparation method thereof |
| CN104530302A (en) * | 2014-12-11 | 2015-04-22 | 华南理工大学 | Silica sol/polyacrylic ester emulsion with high silicon content and preparation method of silica sol/polyacrylic ester emulsion |
| CN104530870A (en) * | 2014-12-24 | 2015-04-22 | 宁波高佳环保涂料有限公司 | Special water-based printing crack pulp for wallpaper and preparation method and application thereof |
| CN104629525A (en) * | 2015-01-15 | 2015-05-20 | 长兴艾飞特塑料科技有限公司 | Preparation method of inorganic material and water-based amino resin composite water-based printing ink connecting material |
| CN104629525B (en) * | 2015-01-15 | 2016-09-21 | 长兴艾飞特科技股份有限公司 | The preparation method of the water color ink binder that a kind of inorganic material is compound with water-compatible amino resin |
| CN104629532A (en) * | 2015-01-15 | 2015-05-20 | 长兴艾飞特塑料科技有限公司 | Nano titanium dioxide-modified composite water-based ink and preparation method thereof |
| CN105085785A (en) * | 2015-08-13 | 2015-11-25 | 新东方油墨有限公司 | Environmentally-friendly cross-linked acrylate polymer emulsion and preparation method thereof |
| CN106905465A (en) * | 2015-12-22 | 2017-06-30 | 北京奥托米特电子有限公司 | A kind of manufacture method of resin, the resin and the aqueous ink using the resin |
| CN105400285A (en) * | 2015-12-29 | 2016-03-16 | 广东天龙油墨集团股份有限公司 | High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof |
| CN107200807B (en) * | 2017-06-09 | 2019-08-06 | 封开县嘉诚纸业有限公司 | A kind of paper nano color paste dispersing agent and preparation method and application |
| CN107200807A (en) * | 2017-06-09 | 2017-09-26 | 封开县嘉诚纸业有限公司 | A kind of paper nano color paste dispersant and preparation method and application |
| CN107384014A (en) * | 2017-09-11 | 2017-11-24 | 杭州海维特化工科技有限公司 | A kind of PVC furniture film water foam ink and preparation method thereof |
| CN107384014B (en) * | 2017-09-11 | 2020-02-21 | 杭州海维特化工科技有限公司 | PVC furniture film water-based foaming ink and preparation method thereof |
| CN107964280A (en) * | 2017-12-06 | 2018-04-27 | 安徽鸿宾医药包装有限公司 | A kind of yellowing-resistant printed label and preparation method thereof |
| CN108484823A (en) * | 2018-03-09 | 2018-09-04 | 陕西理工大学 | A kind of acrylic emulsion and preparation method thereof |
| CN108794928A (en) * | 2018-06-22 | 2018-11-13 | 安徽索亚装饰材料有限公司 | A kind of anti-mildew PVC foam Wallpaper paste material |
| CN109021666A (en) * | 2018-08-01 | 2018-12-18 | 佛山市高明绿色德化工有限公司 | A kind of aqueous self-drying glass ink and preparation method thereof |
| CN109266098A (en) * | 2018-08-21 | 2019-01-25 | 广东天龙油墨有限公司 | A kind of waterborne preprinting lotion and preparation method thereof and the application in ink |
| CN109337440A (en) * | 2018-09-26 | 2019-02-15 | 浙江美浓世纪集团有限公司 | A kind of environment-friendly water-based gravure printing ink and preparation method thereof |
| CN109957063A (en) * | 2019-03-22 | 2019-07-02 | 泰兴市华盛银洋新材料科技有限公司 | A kind of acrylic acid ester emulsion and preparation method thereof with ultra-dispersed effect |
| CN110643224A (en) * | 2019-11-12 | 2020-01-03 | 廊坊市安鼎新材料科技有限公司 | Water-based white ink for surface treatment of base material before code spraying and preparation method thereof |
| CN111019435A (en) * | 2019-12-26 | 2020-04-17 | 李辉 | Printing ink binder |
| CN111269350A (en) * | 2020-03-30 | 2020-06-12 | 上海保立佳新材料有限公司 | Environment-friendly water-based plastic-plastic composite adhesive and preparation method thereof |
| CN112778834A (en) * | 2021-02-22 | 2021-05-11 | 昆明凌润科技有限公司 | Nanoscale weak cation acrylate emulsion for water-based transparent ink and preparation method thereof |
| CN114231086A (en) * | 2021-12-01 | 2022-03-25 | 肇庆新广利化工实业有限公司 | Gravure printing ink emulsion, preparation method and preparation device thereof |
| CN114573869A (en) * | 2022-03-17 | 2022-06-03 | 浙江传化华洋化工有限公司 | Barium-zinc liquid stabilizer and application thereof |
| CN114573869B (en) * | 2022-03-17 | 2023-10-13 | 浙江传化华洋化工有限公司 | Barium zinc liquid stabilizer and application thereof |
| CN116041606A (en) * | 2022-12-30 | 2023-05-02 | 东华大学 | Fluorine-containing acrylate polymer adhesive and preparation method and application thereof |
| CN116041606B (en) * | 2022-12-30 | 2024-02-27 | 东华大学 | Fluorine-containing acrylate polymer adhesive and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103304719B (en) | 2015-06-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103304719B (en) | Acrylic emulsion and preparation method and application in waterborne polyvinyl chloride (PVC) wallpaper ink thereof | |
| CN102731735B (en) | Organosilicon modified silica sol/polyacrylate composite emulsion and its preparation method | |
| CN102649835B (en) | Organic-inorganic hybrid high-silicon-content acrylic ester emulsion and preparation method thereof | |
| CN101649152B (en) | Environmentally-friendly organic inorganic hybridized paint and preparation method and application thereof | |
| CN102617771B (en) | Aqueous printing ink binding agent and ink as well as preparation methods thereof | |
| CN102337704B (en) | Temperature-resisting printing paper water base varnish and preparation method thereof | |
| CN104356320B (en) | Waterborne epoxy ester-acrylic hybrid resin and preparation method thereof | |
| JPS5989313A (en) | Tackifying alkylacrylamide-containing emulsion copolymer | |
| CN103756601B (en) | Metal(lic)powder tackiness agent and preparation method thereof and wallpaper, textiles | |
| CN104672403A (en) | Environment-friendly silicon-acrylate emulsion and preparation method thereof | |
| CN102838953A (en) | Aqueous acrylate emulsion adhesive for paper pearl powder, and preparation method thereof | |
| CN101831230A (en) | Method for preparing polyacrylate/nano-SiO2 compound coating agent by using reactive emulsifier | |
| CN103709885A (en) | Water-based environment-friendly modified alkyd wood paint | |
| CN103711033A (en) | Waterproof waterborne glazing oil and preparation method thereof | |
| CN107384011A (en) | A kind of PVC floor film intaglio printing water-based ink and preparation method thereof | |
| CN102101947A (en) | Gloss oil of aqueous ink fountain for offset printing press and preparation method thereof | |
| CN101798776A (en) | Water-based paper polishing oil and preparation method thereof | |
| CN107266625A (en) | A kind of PVC furniture film water inkwood fat and preparation method thereof | |
| CN105085771A (en) | Waterborne acrylic resin and preparation method therefor | |
| CN103709303A (en) | Preparation method of water-based acrylate emulsion for coating | |
| CN102286229B (en) | Environment-friendly aqueous aluminum foil ink and preparation method thereof | |
| CN106988134A (en) | A kind of printing adhesive and preparation method thereof, print paste and clothes | |
| CN103936916B (en) | PET film precoating heat is mounted aqueous binder emulsion and preparation method | |
| CN102587203B (en) | High-gloss water-borne coating and preparation method as well as application thereof | |
| CN107141945A (en) | Wear-resisting high glaze water lustering oil and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170713 Address after: 526108 Guangdong city of Zhaoqing Province Gaoyao district town of clay highway entrance Patentee after: Guangdong Tianlong Printing Ink Co., Ltd. Address before: 526108 Industrial Park, Zhaoqing, Guangdong Patentee before: Guangdong Sky Dragon Printing Ink Group Co., Ltd. |