CN103688933A - Insecticidal composition containing fufenozide and antibiotic compounds - Google Patents
Insecticidal composition containing fufenozide and antibiotic compounds Download PDFInfo
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- CN103688933A CN103688933A CN201310637124.6A CN201310637124A CN103688933A CN 103688933 A CN103688933 A CN 103688933A CN 201310637124 A CN201310637124 A CN 201310637124A CN 103688933 A CN103688933 A CN 103688933A
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Abstract
The invention discloses an insecticidal composition containing fufenozide and antibiotic compounds. The insecticidal composition contains an active component A and an active component B, wherein the active component A is selected from fufenozide; the active component B is any one selected from the following compounds: ivermectin, abamectin, emamectin benzoate and spinosad; and the weight ratio of the active component A to the active component B ranges from 1:40 to 60:1. The composition disclosed by the invention can be used for preventing and controlling various pests and expanding the bacteriocidal spectrum and is remarkable in synergistic effect and higher in activity for diseases such as rice leaf folders, diamond back moths, beet armyworms, cabbage caterpillars, cotton bollworms and the like on rice, fruit trees, eggplants, vegetables and cottons; in addition, the dosage of pesticide is reduced, the quantity of residue pesticide on crops is reduced, and environment pollution is reduced; and the insecticidal composition is safe to both people and livestock, good in environmental compatibility and not easy to generate pest resistance to the pesticide.
Description
The application is for dividing an application; original application is the patent application " a kind of Pesticidal combination containing furan tebufenozide and antibiotic compound " of Shaanxi Welch Crop Protection Co., Ltd.; the application number of original application is ︰ 201110126112.8, and original application day is 2011.05.17.
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination containing furan tebufenozide and antibiotic compound.
Background technology
Furan tebufenozide is the insecticide that China has independent intellectual property right; chemical name: N-(2; 3-7-hydrogen-2; 7-dimethyl. benzofuran .6-formoxyl)-N '-tertiary butyl .N '. (3; 5 dimethylbenzoyls) hydrazine; furan tebufenozide, as the N-tertiary butyl bishydrazide compounds that contains benzofuran ring, has the moulting hormone regulating and controlling effect that bishydrazide compounds generally has.The Main Ingredients and Appearance of insect moulting hormones is steroid hormone 20-hydroxyl ecdysone, and this is peculiar a kind of somatotropin in arthropods body.When 20-hydroxyl ecdysone concentration raises, larva enters the stage of casting off a skin, now larva stops feed, epidermal cell is recombinated, by combining closely with ecdysone receptor albumen, activated receptor albumen, the ecdysial fluid that contains multiple protein hydrolase enters the space of casting off a skin, it is synthetic that epidermal cell increases protein, generates new epicuticle and cuticula.When 20-hydroxyl ecdysone concentration reduces, insect grows and to enter next stage, comprises the activation of enzyme in ecdysial fluid, the absorbing again of the digestion of procuticle and ecdysial fluid.Along with the further reduction of its concentration, complete needed other hormone of the process of casting off a skin and be released, insect recovers feed thereupon.
Ivermectin (Ivermectin) chemical name: 5-O-demethyl-22, the two hydrogen Avermectin A1 of 23-, molecular formula: C
48h
74o
14, ivermectin is to take Avermectin as lead compound, by two key hydrogenation, and structure optimization and the novel synthetic pesticide succeeded in developing.Structure optimization product as agricultural antibiotic, compare with parent Avermectin, its expelling parasite and acaricidal activity have not only been retained, and safety is higher, be difficult for to produce resistance, for the production of vegetables, fruit, cotton etc. provides efficient a, high security and the biological source insecticide good with Environmental compatibility.
Avermectin (abamectin) molecular formula: C48H72O14 (B1a) C47H70O14 (B1b), it is a kind of macrolide disaccharide compounds for Avermectin.Be natural products separated from edaphon, insects and mites had and tags with stomach poison function and have faint fumigation action, without systemic action.It has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long.It is ovicidal not.What its mechanism of action was different from general insecticide is that it disturbs neurophysiology movable, stimulate and discharge r-aminobutyric acid, and r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, if become mite mite, insect, larva to occur paralysis symptom after contacting with medicament, inertia does not take food, dead after 2-4 days.Because not causing that insect dewaters rapidly, so its lethal effect is slower.But though predatism and parasite are had to direct killing effect, because plant surface is residual few, therefore little to the damage of beneficial insect.
Emamectin-benzoate (emamectinbenzoate) chemical name: 4'-table-methylamino-4'-deoxidation abamectin benzoate, emamectin-benzoate is that a kind of efficient, wide spectrum, the longevity of residure are long, for good insecticidal/acaricidal agent, its mechanism of action hinders pest movements nerve information transmission and makes health paralysis dead.The mode of action be take stomach toxicity as main, has action of contace poison concurrently, and to crop, without interior absorption energy, but active ingredient infiltrates and to use crop epidermal tissue, thereby has the longer longevity of residure.To control cotton boll, Lepidoptera, mite class, coleoptera and homoptera pest have high activity, and do not produce and intersect with other crops, easily degraded noresidue in soil, free from environmental pollution, within the scope of routine dose to useful insect and natural enemy, people, animal safety, can with most of combined use of pesticides.The abbreviation that first dimension salt of the present invention is emamectin-benzoate.
Multiple killing teichomycin (spinosad) mechanism of action is considered to the acting body of nicotinic acid acetylcholinergic receptor, can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.Pleocidin also can affect GABA acceptor, but mechanism of action is unclear.Can make insect benumb rapidly, paralyse, finally cause death.Its desinsection speed can compare favourably with chemical pesticide.Safe, and with current common insecticide without cross resistance, be the biological insecticides of low toxicity, efficient, low-residual.Multiple killing teichomycin has and tags fast and stomach poison function insect, and blade is had to stronger osmosis, can kill subepidermal insect, and the longevity of residure is longer, and some insects are had to certain ovicidal action.Without systemic action.Can effectively preventing Lepidoptera, diptera and thrips insect, also can well prevent and treat that in coleoptera and orthoptera, some takes food the pest species of blade in a large number, poor to the control efficiency of sucking pest and mite class.Safer to predatory natural enemy insect, unique because of insecticidal action mechanism, not yet find at present to have mutual drug-fast report with other insecticides.Safe without poisoning to plant.Be suitable for using on vegetables, fruit tree, gardening, crops.Insecticidal effect be subject to rain affect less.
Yet in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's research, after discovery is composite by furan tebufenozide and ivermectin, Avermectin, emamectin-benzoate, multiple killing teichomycin, can produce good synergistic effect, and not yet open about the composite relevant report of furan tebufenozide and ivermectin, Avermectin, emamectin-benzoate, multiple killing teichomycin.
Summary of the invention
Degradation problem under the resistance generation that the long-term use of furan tebufenozide single dose may bring, drug effect, the composition pesticide that the present invention proposes contains A, two kinds of active components of B, and appropriate surfactant and carrier.
A kind of Pesticidal combination containing furan tebufenozide and antibiotic compound, comprise effective active component, auxiliary agent and filler, it is characterized in that: active components A, B ratio of weight and number are 1 ︰ 40～60 ︰ 1, described active components A is selected from furan tebufenozide, and active component B is selected from a kind of in ivermectin, Avermectin, emamectin-benzoate, multiple killing teichomycin.
Described Pesticidal combination, is characterized in that: the ratio of weight and number of A, two kinds of active components of B is 1 ︰ 20～40 ︰ 1.
Described Pesticidal combination, is characterized in that: the ratio of weight and number of furan tebufenozide and ivermectin is 30 ︰ 1～1 ︰ 1.
Described Pesticidal combination, is characterized in that: the ratio of weight and number of furan tebufenozide and Avermectin is 20 ︰ 1～1 ︰ 1.
Described Pesticidal combination, is characterized in that: the ratio of weight and number of furan tebufenozide and emamectin-benzoate is 30 ︰ 1～1 ︰ 1.
Described Pesticidal combination, is characterized in that: the ratio of weight and number of furan tebufenozide and multiple killing teichomycin is 16 ︰ 1～1 ︰ 4.
The ratio of weight and number of A, two kinds of active components of B is 1 ︰ 40～60 ︰ 1.Conventionally in composition, the weight percentage of active component is gross weight 0.5～90%, is preferably 5%～85%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1～70% active substance by weight, is preferably 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, is preferably 10～80%.
In composition pesticide of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of composition pesticide of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, binding agent or defoamer.According to different dosage form, in preparation, can also contain disintegrant known in those skilled in the art, antifreeze etc.
Composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, after being about to active substance and mixing with liquid flux or solid carrier, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer etc.
Composition pesticide of the present invention, can be processed into acceptable formulation on any agricultural chemicals on demand, and wherein the excellent formulation of selecting is: wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
When making wetting powder, composition comprises following constituent content: active components A 1～60%, active component B1～40%, dispersant 2～10%, wetting agent 2～10%, filler 8～94%.
Active components A, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, can be made into wetting powder product of the present invention.
When making water dispersible granules, composition comprises following constituent content: active components A 1～60%, active component B1～40%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～92%.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent, obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, make water dispersible granules product of the present invention.
When making suspending agent, composition comprises following constituent content: active components A 1～50%, active component B1～30%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in above-mentioned formulation material are mixed through high speed shear, add active components A, active component B, in ball mill, ball milling is 2～3 hours, makes diameter of particle all below 5 μ m, makes suspending agent product of the present invention.
When making suspension emulsion, composition comprises following constituent content: active components A 1～50%, active component B1～30%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material are mixed through high speed shear, add active component B, in ball mill, ball milling is 2～3 hours, make diameter of particle all below 5 μ m, make active component B suspending agent, then by active components A, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
When making aqueous emulsion, composition comprises following constituent content: active components A 1～50%, active component B1～30%, solvent 0～30%, emulsifier 1～15%, co-emulsifier 0～8%, antifreeze 0～10%, thickener 0.1～2%, defoamer 0.01～2%, deionized water are supplied surplus.
Above-mentioned formulation material is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make to be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, make aqueous emulsion product of the present invention.
When making microemulsion, composition comprises following constituent content: active components A 1～50%, active component B1～30%, solvent 0～30%, emulsifier 3～20%, co-emulsifier 0～12%, antifreeze 0～10%, thickener 0.1～2%, defoamer 0.01～2%, stabilizing agent 0～4%, deionized water is supplied surplus.
Active components A and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; After emulsifier, stabilizing agent and antifreeze, water being joined in the homogenizer that above-mentioned solution is housed, give strong mixing and homogenize, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, glucose, aluminium chloride.
Described emulsifier is selected from: agriculture breast 500#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400#(benzyl dimethyl phenol polyoxy ethyl ether), agriculture breast 600#(phenyl phenol polyoxy ethyl ether), Nongru-700 #(alkylphenol-formaldehyde resin polyoxy ethyl ether), agriculture breast 36#(phenethyl fluosite polyoxy ethyl ether), agriculture breast 1600#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34#(alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), one or more in AEO series (fat alcohol alcohol APEO).
Described co-emulsifier is one or more in butanols, isobutanol, dodecanol-1, tetradecanol-1, octadecanol-1;
Described solvent is selected from one or more in toluene, dimethylbenzene, methyl alcohol, ethanol, acetone, ether, cyclohexanone, vegetable oil, dimethyl formamide, acetonitrile, polyethylene glycol, pyrrolidones, solvent N-chain alkyl pyrrolidones;
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10aliphatic alcohols, C
10～20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described preservative is selected from one or more in formaldehyde, sodium salicylate, Sodium Benzoate, dichlorophen;
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
The invention has the advantages that:
(1) furan tebufenozide and Avermectin, ivermectin, first dimension salt, multiple killing teichomycin composite after, there is notable synergistic and lasting effect;
(2) expanded insecticidal spectrum, the diamond-back moth on brassicaceous vegetable, paddy rice, apple, cotton, pear tree, mandarin tree, eggplant, beet armyworm, cabbage caterpillar, aphid, rice fulgorid, rice leaf roller, blister mite, leaf miner, two spotted spider mite, Americal rice leaf miner, striped rice borer, cotton bollworm, pear sucker, thrips etc. have all been had to greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to person poultry safety, Environmental compatibility is good, and insect is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is ratio of weight and number, but the present invention is not limited thereto.
Application Example one
Example 140% furan tebufenozide ivermectin wetting powder
Furan tebufenozide 35%, ivermectin 5%, alkyl benzene sulfonate calcium salt 5%, wetting and penetrating agent F6%, white carbon 6%, diatomite add to 100%, and mixture carries out air-flow crushing, make 40% furan tebufenozide ivermectin wetting powder.
Example 232% furan tebufenozide ivermectin water dispersible granules
Furan tebufenozide 30%, ivermectin 2%, alkylphenol-polyethenoxy are phonetic 5%, lauryl sodium sulfate 4%, sodium carbonate 2%, white carbon 6%, bentonite add to 100%, mix and make 32% furan tebufenozide ivermectin water dispersible granules.
Example 315% furan tebufenozide ivermectin suspending agent
Furan tebufenozide 10%, ivermectin 5%, octylphenol polyethylene oxyethylene group ether sulfate 3%, DBSA 5%, C
8～10aliphatic alcohols 0.5%, methylcellulose 1.5%, ethylene glycol 1%, deionized water add to 100%, mix and make 15% furan tebufenozide ivermectin suspending agent.
Example 410% furan tebufenozide ivermectin suspension emulsion
Furan tebufenozide 8%, ivermectin 2%, aryl phenol polyoxyethylene succinate sulfonate 4%, soapberry powder 5%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, silicone compound 0.2%, polyvinylpyrrolidone 1.5%, propane diols 1.8%, deionized water add to 100%, mix and make 10% furan tebufenozide ivermectin suspension emulsion.
Example 515% furan tebufenozide ivermectin micro emulsion
Furan tebufenozide 12%, ivermectin 3%, alkylphenol polyoxyethylene phosphate 3%, N-pyrrolidones 5%, castor oil polyoxyethylene ether 5%, gelatin 2%, glycerine 3%, C
8～10aliphatic alcohols 0.4%, deionized water is supplied 100%, 15% furan tebufenozide ivermectin micro emulsion.
Example 66% furan tebufenozide ivermectin aqueous emulsion
Furan tebufenozide 4%, ivermectin 2%, fatty alcohol-polyoxyethylene ether 6%, alkylbenzenesulfonate 4%, agriculture breast 33#5%, polyethylene glycol 2%, gelatin 2%, silicone oil 0.4%, deionized water supplies 100%, makes 6% furan tebufenozide ivermectin aqueous emulsion.
Example 730% furan tebufenozide Avermectin wetting powder
Furan tebufenozide 25%, Avermectin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea are withered 4%, attapulgite adds to 100%, and mixture carries out air-flow crushing, makes 30% furan tebufenozide Avermectin wetting powder.
Example 855% furan tebufenozide Avermectin wetting powder
Furan tebufenozide 53%, Avermectin 2%, polyoxyethylene carboxylate 4%, spaonin powder 5%, kaolin add to 100%, and mixture carries out air-flow crushing, make 55% furan tebufenozide Avermectin wetting powder.
Example 920% furan tebufenozide Avermectin water dispersible granules
Furan tebufenozide 15%, Avermectin 5%, polycarboxylate 6%, lauryl sodium sulfate 6%, ammonium sulfate 3%, bentonite add to 100%, mix and make 20% furan tebufenozide Avermectin water dispersible granules.
Example 1040% furan tebufenozide Avermectin water dispersible granules
Furan tebufenozide 38%, Avermectin 2%, aliphatic amine polyoxyethylene are phonetic 6%, silkworm excrement 4%, aluminium chloride 2.5%, diatomite add to 100%, mix and make 40% furan tebufenozide Avermectin water dispersible granules.
Example 1110% furan tebufenozide Avermectin suspending agent
Furan tebufenozide 5%, Avermectin 5%, octylphenol polyethylene oxyethylene group ether sulfate 6%, DBSA 5%, C
8～10aliphatic alcohols 0.5%, methylcellulose 1.4%, deionized water add to 100%, mix and make 10% furan tebufenozide Avermectin suspending agent.
Example 1230% furan tebufenozide Avermectin suspending agent
Furan tebufenozide 27%, Avermectin 3%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 7%, wetting and penetrating agent F6%, silicone compound 0.2%, sodium phosphate trimer 1.5%, glycerine 1.2%, deionized water add to 100%, mix and make 30% furan tebufenozide Avermectin suspending agent.
Example 1310% furan tebufenozide Avermectin suspension emulsion
Furan tebufenozide 6%, Avermectin 4%, aryl phenol polyoxyethylene succinate sulfonate 5%, soapberry powder 5%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, silicone compound 0.1%, polyvinylpyrrolidone 1.5%, propane diols 1.8%, deionized water add to 100%, mix and make 10% furan tebufenozide Avermectin suspension emulsion.
Example 1418% furan tebufenozide Avermectin suspension emulsion
Furan tebufenozide 16%, Avermectin 2%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, Nekal BX 6%, castor oil polyoxyethylene ether 5%, C
10～20saturated fat acids 0.2%, gum Arabic 1.2%, triethylene glycol 1.6%, deionized water add to 100%, mix and make 18% furan tebufenozide Avermectin suspension emulsion.
Example 1514% furan tebufenozide avermectin micro-emulsion
By furan tebufenozide 12%, Avermectin 2%, tween 4%, alkylbenzenesulfonate 3%, phenethyl phenol polyethenoxy ether phosphate 5%, xanthans 2%, propane diols 3%, C
8～10aliphatic alcohols 0.4%, deionized water is supplied 100%, 14% furan tebufenozide avermectin micro-emulsion.
Example 1622% furan tebufenozide avermectin micro-emulsion
By furan tebufenozide 20%, Avermectin 2%, ethylene glycol monomethyl ether 5%, ethylene glycol 4%, polyvinyl alcohol 2%, tween series 8%, alkylbenzenesulfonate 3%, silicone oil 0.4%, deionized water supplies 100%, makes 22% furan tebufenozide avermectin micro-emulsion.
Example 1710% furan tebufenozide abamectin aqueous emulsion
By furan tebufenozide 4%, Avermectin 6%, phenethyl phenol polyethenoxy ether 5%, alkylbenzenesulfonate 5%, OP series 5%, glycerine 4%, gum Arabic 1%, C
8～10aliphatic alcohols 0.4%, deionized water supplies 100%, makes 10% furan tebufenozide abamectin aqueous emulsion.
Example 1818% furan tebufenozide abamectin aqueous emulsion
By furan tebufenozide 15%, Avermectin 3%, castor oil polyoxyethylene ether 4%, OP series 5%, gelatin 0.5%, glycerine 4%, N-pyrrolidones 2%, silicone oil 0.4%, deionized water supplies 100%, makes 18% furan tebufenozide abamectin aqueous emulsion.
Example 1940% furan tebufenozide first dimension salt wetting powder
Furan tebufenozide 35%, first dimension salt 5%, polycarboxylate 7.6%, white carbon 8%, bentonite adds to 100%, and mixture carries out air-flow crushing, makes 40% furan tebufenozide first dimension salt wetting powder.
Example 2050% furan tebufenozide first dimension salt wetting powder
Furan tebufenozide 48%, first dimension salt 2%, lignosulfonates 7.6%, soapberry powder 5.4%, white carbon add to 100%, and mixture carries out air-flow crushing, make 50% furan tebufenozide first dimension salt wetting powder.
Example 2139% furan tebufenozide emamectin benzoate water dispersible granule
Furan tebufenozide 36%, first dimension salt 3%, alkyl benzene sulfonate calcium salt 6.5%, Nekal BX 5%, aluminium chloride 2.5%, kaolin add to 100%, mix and make 39% furan tebufenozide emamectin benzoate water dispersible granule.
Example 2252% furan tebufenozide emamectin benzoate water dispersible granule
Furan tebufenozide 48%, first dimension salt 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, spaonin powder 4%, bentonite add to 100%, mix and make 52% furan tebufenozide emamectin benzoate water dispersible granule.
Example 2325% furan tebufenozide first dimension salt suspension agent
Furan tebufenozide 20%, first dimension salt 5%, lignosulfonates 4%, wetting and penetrating agent F5%, C
8～10aliphatic alcohols 0.5%, gum Arabic 2.5%, deionized water add to 100%, mix and make 25% furan tebufenozide first dimension salt suspension agent.
Example 2442% furan tebufenozide first dimension salt suspension agent
Furan tebufenozide 40%, first dimension salt 2%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, lauryl sodium sulfate 6%, C
10～20saturated fat acids 0.4%, sodium phosphate trimer 1.5%, deionized water add to 100%, mix and make 42% furan tebufenozide first dimension salt suspension agent.
Example 2518% furan tebufenozide first dimension salt suspension emulsion
Furan tebufenozide 15%, first dimension salt 3%, naphthalene sulfonic acid-formaldehyde condensation product 6%, tea are withered 5%, polyvinylpyrrolidone 1.6%, agriculture breast 1600#7%, glycerine 2.2%, C
8～10aliphatic alcohols 0.3%, water add to 100%, through mixing, make 18% furan tebufenozide first dimension salt suspension emulsion.
Example 2624% furan tebufenozide first dimension salt suspension emulsion
Furan tebufenozide 20%, first dimension salt 4%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, wetting and penetrating agent F4%, methylcellulose 1%, By series 4%, ethylene glycol 1.6%, silicone oil 0.5%, water add to 100%, through mixing, make 24% furan tebufenozide first dimension salt suspension emulsion.
Example 2716% furan tebufenozide first dimension salt microemulsion
Furan tebufenozide 14%, first dimension salt 2%, styrene polyoxyethylene ether ammonium sulfate salt 9%, cyclohexanone 3%, glycerine 8%, silicone 1.2%, deionized water adds to 100%, through mixing, makes 16% furan tebufenozide first dimension salt microemulsion.
Example 2826% furan tebufenozide first dimension salt microemulsion
Furan tebufenozide 24%, first dimension salt 2%, By series 10%, ethylene glycol monomethyl ether 2%, polyethylene glycol 8%, C
8～10aliphatic alcohols 1%, deionized water adds to 100%, through mixing, makes 26% furan tebufenozide first dimension salt microemulsion.
Example 298% furan tebufenozide emamectin benzoate water emulsion
Furan tebufenozide 4%, first dimension salt 4%, DMF 5%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, butanols 3%, ethylene glycol 5%, C
8～10aliphatic alcohols 0.8%, deionized water adds to 100%, through mixing, makes 8% furan tebufenozide emamectin benzoate water emulsion.
Example 3015% furan tebufenozide emamectin benzoate water emulsion
Furan tebufenozide 12%, first dimension salt 3%, ethylene glycol monomethyl ether 6%, agriculture breast 1600#7%, calcium chloride 5%, glycerine 4%, silicone 1.2%, deionized water adds to 100%, through mixing, makes 15% furan tebufenozide emamectin benzoate water emulsion.
Example 3120% furan tebufenozide multiple killing teichomycin wetting powder
Furan tebufenozide 15%, multiple killing teichomycin 5%, lignosulfonates 4%, soapberry powder 5%, white carbon 8%, kaolin add to 100%, and mixture carries out air-flow crushing, make 20% furan tebufenozide multiple killing teichomycin wetting powder.
Example 3245% furan tebufenozide multiple killing teichomycin wetting powder
Furan tebufenozide 40%, multiple killing teichomycin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea are withered 4%, attapulgite adds to 100%, and mixture carries out air-flow crushing, makes 45% furan tebufenozide multiple killing teichomycin wetting powder.
Example 3316% furan tebufenozide multiple killing teichomycin water dispersible granules
Furan tebufenozide 12%, multiple killing teichomycin 4%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 4%, spaonin powder 4%, urea 2%, white carbon 12%, kaolin add to 100%, mix and make 16% furan tebufenozide multiple killing teichomycin water dispersible granules.
Example 3460% furan tebufenozide multiple killing teichomycin water dispersible granules
Furan tebufenozide 58%, multiple killing teichomycin 2%, alkylphenol-polyethenoxy are phonetic 5%, lauryl sodium sulfate 4%, sodium carbonate 2%, white carbon 12%, bentonite add to 100%, mix and make 60% furan tebufenozide multiple killing teichomycin water dispersible granules.
Example 3525% furan tebufenozide multiple killing teichomycin suspending agent
Furan tebufenozide 20%, multiple killing teichomycin 5%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, wetting and penetrating agent F4%, silicone compound 0.2%, sodium phosphate trimer 1.5%, deionized water add to 100%, mix and make 25% furan tebufenozide multiple killing teichomycin suspending agent.
Example 3635% furan tebufenozide multiple killing teichomycin suspending agent
Furan tebufenozide 28%, multiple killing teichomycin 7%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, silkworm excrement 5%, C
10～20saturated fat acids 1.2%, xanthans 1.5%, propane diols 1.2%, deionized water add to 100%, mix and make 35% furan tebufenozide multiple killing teichomycin suspending agent.
Example 3710% furan tebufenozide multiple killing teichomycin suspension emulsion
Furan tebufenozide 6%, multiple killing teichomycin 4%, alkylphenol-polyethenoxy are phonetic 4.5%, neopelex 3.5%, silicone oil 0.7%, polyvinylpyrrolidone 1.3%, tween series 6%, polyethylene glycol 3%, water add to 100%, aforementioned formula material is mixed, make 10% furan tebufenozide multiple killing teichomycin suspension emulsion.
Example 3822% furan tebufenozide multiple killing teichomycin suspension emulsion
Furan tebufenozide 18%, multiple killing teichomycin 4%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, Nekal BX 6%, castor oil polyoxyethylene ether 5%, C
10～20saturated fat acids 0.2%, gum Arabic 1.2%, triethylene glycol 1.5%, deionized water add to 100%, mix and make 22% furan tebufenozide multiple killing teichomycin suspension emulsion.
Example 398% furan tebufenozide multiple killing teichomycin microemulsion
Furan tebufenozide 6%, multiple killing teichomycin 2%, sapn series 8%, methyl alcohol 5%, aliphatic alcohol polyoxyvinethene phosphate 7%, propane diols 3%, gelatin 1%, C
8～10aliphatic alcohols 0.4%, deionized water is supplied 100%, 8% furan tebufenozide multiple killing teichomycin microemulsion.
Example 4020% furan tebufenozide multiple killing teichomycin microemulsion
Furan tebufenozide 15%, multiple killing teichomycin 5%, alkylphenol polyoxyethylene phosphate 3%, castor oil polyoxyethylene ether 5%, gelatin 2%, glycerine 3%, silicone oil 0.4%, deionized water supplies 100%, mixes and makes 20% furan tebufenozide multiple killing teichomycin microemulsion.
Example 4110% furan tebufenozide spinosad aqueous emulsion
Furan tebufenozide 5%, multiple killing teichomycin 5%, alkylbenzenesulfonate 4%, alkylphenol polyoxyethylene 5%, OP series 7%, propane diols 4%, polyvinyl alcohol 1%, C
8～10aliphatic alcohols 0.4%, deionized water supplies 100%, makes 10% furan tebufenozide spinosad aqueous emulsion.
Example 4218% furan tebufenozide spinosad aqueous emulsion
By furan tebufenozide 16%, multiple killing teichomycin 2%, phenethyl phenol polyethenoxy ether 5%, alkylbenzenesulfonate 5%, C
3-C
6alcohol 5%, glycerine 4%, gum Arabic 1%, silicone oil 0.4%, deionized water supplies 100%, mixes and makes 18% furan tebufenozide spinosad aqueous emulsion.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in respectively beaker standby.Adopt and first to soak the method that connects worm after leaf, after the blade of the same size that does not contact any medicament is soaked to 5s in the liquid configuring, take out, naturally dry, put into insect box, then connect for examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat examination borer population used be 50, establishes blank simultaneously, in 72h, checks dead borer population, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC50 value.If contrast lethality is greater than 10%, be considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value to (x), with method of least squares, draws virulence regression equation, and calculates thus the value of every kind of medicament.According to the abundant equation of Sun Yun, calculate co-toxicity coefficient CTC.Computing formula following (take furan tebufenozide as standard medicament, its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=furan tebufenozide of M
furan tebufenozidetI * P of+effective active composition B
effective active compositionb
In formula: the mixture that M is different proportionings
P
effective active compositionb is effective active composition B shared ratio in composition
P
furan tebufenozidefor furan tebufenozide shared ratio in composition
A is selected from furan tebufenozide;
B is selected from following any one compound: a kind of in ivermectin, Avermectin, first dimension salt, multiple killing teichomycin.
Application Example two:
For trying insect: diamond-back moth.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining furan tebufenozide, the former medicine of ivermectin and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
The toxicity test of table 1 furan tebufenozide proportionings different from ivermectin to diamond-back moth
As shown in Table 1, the proportioning of the composite control of furan tebufenozide and ivermectin diamond-back moth is when 60 ︰ 1 to 1:40, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 60:1 to 1 ︰ 40 scopes, especially when furan tebufenozide and ivermectin obtain proportioning at 30:1 to 1:1, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when furan tebufenozide and ivermectin weight ratio are 15 ︰ 1 wherein, and synergistic effect is the most obvious.
Application Example three:
For trying insect: rice leaf roller.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining furan tebufenozide, the former medicine of Avermectin and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
The toxicity test of table 2 furan tebufenozide proportionings different from Avermectin to rice leaf roller
As shown in Table 2, the proportioning of furan tebufenozide and abamectin compounded control rice leaf roller is when 60 ︰ 1 to 1:40, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 60:1 to 1 ︰ 40 scopes, especially when the proportioning of furan tebufenozide and Avermectin is during at 20:1 to 1:1, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when furan tebufenozide and Avermectin weight ratio are 8 ︰ 1 wherein, and synergistic effect is the most obvious.
Application Example four:
For trying insect: beet armyworm.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining furan tebufenozide, the first dimension former medicine of salt and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
Table 3 furan tebufenozide and the toxicity test of the different proportionings of first dimension salt to beet armyworm
As shown in Table 3, the proportioning of the composite control of furan tebufenozide and first dimension salt beet armyworm is when 60 ︰ 1 to 1:40, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 60:1 to 1 ︰ 40 scopes, especially when furan tebufenozide and first dimension salt obtains proportioning at 30:1 to 1:1, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when furan tebufenozide and first are tieed up salt weight ratio and be 12 ︰ 1 wherein, and synergistic effect is the most obvious.
Application Example five:
For trying insect: cotton bollworm.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining furan tebufenozide, the former medicine of multiple killing teichomycin and the two different proportioning mixture through preliminary experiment.
Toxicity test result four
The toxicity test of table 4 furan tebufenozide proportionings different from multiple killing teichomycin to cotton bollworm
As shown in Table 4, the proportioning of the composite control of furan tebufenozide and multiple killing teichomycin cotton bollworm is when 60 ︰ 1 to 1:40, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 60:1 to 1 ︰ 40 scopes, especially when furan tebufenozide and multiple killing teichomycin obtain proportioning at 16:1 to 1:4, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when furan tebufenozide and multiple killing teichomycin weight ratio are 4 ︰ 1 wherein, and synergistic effect is the most obvious.
Application Example six furan tebufenozides and ivermectin and the composite control Chinese cabbage diamond-back moth test of pesticide effectiveness thereof
This experimental establishment is in Sanyuan County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% furan tebufenozide suspending agent (commercial), 0.5% ivermectin missible oil (commercial).
Before medicine, investigation Chinese cabbage diamond-back moth insect pest index, in their early stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 3 days, 7 days.Experimental result is as follows:
Table 5 furan tebufenozide, ivermectin and the composite control Chinese cabbage diamond-back moth test of pesticide effectiveness thereof
As can be seen from Table 5, after furan tebufenozide and ivermectin are composite, can effectively prevent and treat Chinese cabbage diamond-back moth, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example seven furan tebufenozides and Avermectin and the composite control paddy rice rice leaf roller test of pesticide effectiveness thereof
This experimental establishment is in suburb, Jingzhou City, Hubei Province, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% furan tebufenozide suspending agent (commercial), 18 grams per liter abamectin emulsifiable concentrates (commercial).
Before medicine, investigation paddy rice rice leaf roller insect pest index, in their early stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 3 days, 7 days.Experimental result is as follows:
Table 6 furan tebufenozide, Avermectin and the composite control paddy rice rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 6, furan tebufenozide and abamectin compounded after can effectively prevent and treat paddy rice rice leaf roller, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example eight furan tebufenozides and first dimension salt and the composite control eggplant beet armyworm test of pesticide effectiveness thereof
This experimental establishment is in Chengwu County, Shandong, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% furan tebufenozide suspending agent (commercial), 0.5% first dimension salt microemulsion (commercial).
Before medicine, investigation eggplant beet armyworm insect pest index, in their early stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 3 days, 7 days.Experimental result is as follows:
Table 7 furan tebufenozide, first dimension salt and the composite control eggplant beet armyworm test of pesticide effectiveness thereof
As can be seen from Table 7, after furan tebufenozide and first dimension salt are composite, can effectively prevent and treat eggplant beet armyworm, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine furan tebufenozides and multiple killing teichomycin and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
This experimental establishment is in Hami City great Quan gulf, Xinjiang Uygur Autonomous Regions, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% furan tebufenozide suspending agent (commercial), 25 grams per liter multiple killing teichomycin suspending agents (commercial).
Before medicine, investigation cotton cotton bollworm insect pest index, in their early stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 3 days, 7 days.Experimental result is as follows:
Table 8 furan tebufenozide, multiple killing teichomycin and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 8, after furan tebufenozide and multiple killing teichomycin are composite, can effectively prevent and treat cotton cotton bollworm, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Claims (6)
1. the Pesticidal combination containing furan tebufenozide and antibiotic compound, by effective active composition, auxiliary agent and media assemblage, it is characterized in that: active components A, B ratio of weight and number are 1 ︰ 40～60 ︰ 1, and described active components A is furan tebufenozide, and active component B is multiple killing teichomycin.
2. the Pesticidal combination containing furan tebufenozide and antibiotic compound according to claim 1, is characterized in that: the ratio of weight and number of furan tebufenozide and multiple killing teichomycin is 1 ︰ 20～40 ︰ 1.
3. the Pesticidal combination containing furan tebufenozide and antibiotic compound according to claim 2, is characterized in that: the ratio of weight and number of furan tebufenozide and multiple killing teichomycin is 16 ︰ 1～1 ︰ 4.
4. the Pesticidal combination containing furan tebufenozide and antibiotic compound according to claim 1, is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
5. the Pesticidal combination containing furan tebufenozide and antibiotic compound according to claim 1 is for preventing and treating the application of the insect on brassicaceous vegetable, paddy rice, apple, cotton, pear tree, mandarin tree, eggplant.
6. the Pesticidal combination containing furan tebufenozide and antibiotic compound according to claim 5 is for preventing and treating the application of diamond-back moth, beet armyworm, cabbage caterpillar, aphid, rice fulgorid, rice leaf roller, blister mite, leaf miner, two spotted spider mite, Americal rice leaf miner, striped rice borer, cotton bollworm, pear sucker, thrips.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1471822A (en) * | 2003-07-15 | 2004-02-04 | 江苏省农药研究所有限公司 | Composition with insect killing activity |
| CN101878766A (en) * | 2010-07-02 | 2010-11-10 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing methoxyfenozide and biogenic pesticide |
-
2011
- 2011-05-17 CN CN201310637124.6A patent/CN103688933A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1471822A (en) * | 2003-07-15 | 2004-02-04 | 江苏省农药研究所有限公司 | Composition with insect killing activity |
| CN101878766A (en) * | 2010-07-02 | 2010-11-10 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing methoxyfenozide and biogenic pesticide |
Non-Patent Citations (1)
| Title |
|---|
| 何翠娟等: "几种新型高效低毒农药对小菜蛾的防治效果及抗性筛选研究", 《上海交通大学学报(农业科学版)》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109769841A (en) * | 2017-11-15 | 2019-05-21 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
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