CN101878766A - Pesticidal composition containing methoxyfenozide and biogenic pesticide - Google Patents
Pesticidal composition containing methoxyfenozide and biogenic pesticide Download PDFInfo
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Abstract
The invention relates to a pesticidal composition containing methoxyfenozide and a biogenic pesticide, in particular to a pesticidal composition containing the methoxyfenozide used as a first active ingredient and the abamectin or spinosyns biogenic pesticide used as a second active ingredient. The pesticidal composition can be prepared into various formulations, such as water dispersible granules, wettable powder, a suspending agent, a suspending emulsion, a dispersible oil suspending agent, emulsifiable concentrate, a microemulsion and a microcapsule suspension agent, and has reasonable compositions, good pesticidal effect and low drug using cost. The activity and the pesticidal effect of the pesticidal composition are not simple superposition of the activities of all the components, but have obvious synergistic action. The pesticidal composition can slow down generation of resistibility, has good safety for crops and is in compliance with safety requirement of a pesticide preparation. The pesticidal composition of the invention has better effects of preventing and treating lepidopterous pests, such as rice stem borer, scirpophaga incertulas, cnaphalocrocis medinalis guenee, cotton bollworm, apple leaf roller, spodoptera exigua and plutella xylostella.
Description
Technical field
The present invention relates to a kind of insecticides, particularly a kind of methoxyfenozide that comprises is as first active component, and Avermectin or multiple killing teichomycin biological source insecticide belong to technical field of compounded pesticide as the Pesticidal combination of second active component.
Background technology
Methoxyfenozide, english common name: methoxyfenozide, other English names: Intrepid, Runner, chemical name: the N-tert-butyl group-N '-(3-methyl-2-toluyl groups)-3,5-dimethyl benzene formylhydrazine.Methoxyfenozide belongs to the bishydrazide insecticide, it is a kind of insect growth regulator, IGR, moulting hormone for a kind of non-sterol type structure, simulate natural insect moulting hormones---20-HE, activation is also adhered to ecdysone receptor albumen, impel lepidopterous larvae before maturation, to enter the process of casting off a skin ahead of time and can not form healthy new epidermis, thereby cause larva to stop to get food, final death ahead of time.The reaction that lepidopterous larvae is ingested behind the methoxyfenozide is fast.Larva promptly stops to get food after generally ingesting 4～16 hours, poisoning symptom occurs.The methoxyfenozide of Xiao Shouing is the suspending agent of 240 grams per liters in the market, as a kind of bionical steroids insecticide, it has low dose, holds and imitate length, stable, efficient, characteristics such as environment friendly, be to meet people to the requirement of modern agricultural chemicals and development trend, but methoxyfenozide in use exists the use cost height, the defective of the risk that resistance increases.
Avermectin, english common name abamectin, chemical molecular formula C
48H
72O
14(B1a) C
47H
70O
14(B1b), it is a kind of macrolide disaccharide compounds, belong to the biogenic insecticidal/acaricidal agent, be the natural products that from edaphon, separates, insect and mite class had tag and stomach poison function and faint fumigation action is arranged, no systemic action, but it has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long, does not kill ovum.What its mechanism of action was different with general insecticide is that it disturbs the neurophysiology activity, stimulate and discharge the r-aminobutyric acid, and the r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, the mite class becomes, paralysis symptom promptly occurs as if mite, insect, larva and after medicament contacts, inertia is not got food, and is dead after 2-4 days.Because of not causing that insect dewaters rapidly, so its lethal effect is slower.But though predatism and parasite are had direct killing effect, because of plant surface is residual few, therefore little to the damage of beneficial insect.In actual application, because the single agent of long-term use Avermectin causes pest resistance to rise year by year, the risk of use cost increase etc.
Multiple killing teichomycin, English common name spinosad.Multiple killing teichomycin is a kind of a kind of macrolides Nuisanceless high-efficient biological source insecticide that extracts in thorn sugared many born of the same parents bacterium (Saccharopolysporaspinosa) zymotic fluid.Produce parent strain soil actinomycetes thorniness saccharopolyspora strain (the Saccharopolyspora spinosa Metrz ﹠amp of pleocidin; Yao) initial separation is from one of the Caribbean discarded wine brewing field.The product of practicability is the mixture of spinosynA and spinosynB, so be called spinosad.The mode of action novelty of pleocidin can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.Pleocidin also can influence the GABA acceptor, but mechanism of action is unclear.It can make insect benumb rapidly, paralyse, and causes death at last, and its desinsection speed can compare favourably with chemical pesticide.Safe, and do not have the biological insecticides that cross resistance is low toxicity, efficient, low-residual with present common insecticide, existing insecticidal properties efficiently has again the characteristic of beneficial insect and mammalian safe being arranged, the most suitable pollution-free vegetable, fruit production application.Multiple killing teichomycin is the insecticide of a kind of low toxicity, efficient, wide spectrum, insect is had tag fast and stomach poison function, and blade is had stronger osmosis, can kill subepidermal insect, and the longevity of residure is longer, and some insects are had certain ovicidal action.No systemic action.Can effectively preventing Lepidoptera, diptera and thrips insect, can prevent and treat well also that some measures the pest species of food blade greatly in coleoptera and the orthoptera, relatively poor to the control efficiency of sucking pest and mite class.Safer to the predator insect, unique because of insecticidal action mechanism, find as yet at present to have mutual drug-fast report with other insecticides, plant safety is not had poisoning, insecticidal effect be subjected to rain influence less.The multiple killing teichomycin of Xiao Shouing is 2.5% suspending agent and 48% suspending agent in the market, and multiple killing teichomycin in use exists the use cost height, the risk that resistance increases gradually, the defective that the lasting period is general.
At present, the pesticidal preparations that with the methoxyfenozide is effective ingredient is based on 240 grams per liter methoxyfenozide suspending agents, and in actual use, lasting effect is long, but quick-acting is general, the use cost height; Avermectin and multiple killing teichomycin are as a kind of biological source insecticide of brand-new mechanism of action, good disinsection effect, quick-acting is fast, but the use cost height, the risk that resistance increases, the defective that the lasting period is general, the inventor is unexpected to be found the use that is mixed of methoxyfenozide and Avermectin or multiple killing teichomycin, have significant synergistic effect, can reduce use cost, slow down the effect of the generation of pest resistance.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, significantly synergy, good disinsection effect, drug cost is low, the Pesticidal combination that contains methoxyfenozide and biological source insecticide that is difficult for developing immunity to drugs.
Another object of the present invention is to provide the application of the Pesticidal combination that contains methoxyfenozide and biological source insecticide.
In order to overcome the defective of existing unitary agent, technical scheme of the present invention is to solve like this:
Contain the Pesticidal combination of methoxyfenozide and biological source insecticide, comprising:
A) the first active component methoxyfenozide;
B) the second active component Avermectin or multiple killing teichomycin biological source insecticide;
The weight ratio of first active component and second active component is 1: 1～40: 1, is preferably 2: 1～20: 1.
The cumulant of first active component and second active component (weight add and) is 1%～80% of described composition total weight, be preferably 5%～50%, the size of active component cumulant is also closely related with formulation, but is no more than 50% as the active component cumulant of suspending agent dispersed oil suspending agent, suspended emulsion, microemulsion, microcapsule suspending agent.
But it is water dispersible granules, wetting powder, suspending agent, suspended emulsion dispersed oil suspending agent, missible oil, microemulsion, microcapsule suspending agent that the present invention contains the preparation formulation that the Pesticidal combination of methoxyfenozide can prepare according to the known method of those skilled in the art of the present technique.
For water dispersible granules, those skilled in the art are familiar with the use corresponding adjuvants and finish the present invention very much.Dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, alkylphenol polyoxyethylene, EO/PO block polyether; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate, sodium lignin sulfonate, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene; Disintegrant is selected from ammonium sulfate, sodium sulphate, sodium chloride, ammonium chloride, urea, sucrose, glucose, carboxymethyl cellulose, soluble starch, polyvinylpyrrolidone; Binding agent is selected from polyvinyl alcohol, soluble starch, dextrin, xanthans, carboxymethyl (ethyl) cellulose family; Filler is selected from diatomite, kaolin, white carbon, precipitated calcium carbonate, talcum powder, attapulgite, potter's clay.
To wetting powder, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Filler is selected from ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, talcum powder, attapulgite, potter's clay.
To suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE 2425 (U.S. Huntsman Corporation produces, the alkyl naphthalene sulfonic acid salt); Alkyl phenol formaldehyde resin polyoxyethylene ether), farming breast 2201, this dish-60# (common name: sorbitan monostearate), emulsifier T-60 (common name: the sorbitan monostearate APEO), agricultural newborn 1601# (common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), TERSPERSE 4894 (U.S. Huntsman Corporation product) emulsifier is selected from Nongru-700 # (common name:; Wetting agent is selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500 (U.S. Huntsman Corporation product); Thickener is selected from xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate; Preservative is selected from formaldehyde, benzoic acid, Sodium Benzoate; Defoamer is silicone based defoamer; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts (as sodium chloride).
To suspended emulsion, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), TERSPERSE 2425; Emulsifier is selected from Nongru-700 #, farming breast 2201, this dish-60#, Tween-60 #, agricultural newborn 1601#, triphen ethyl phenol polyoxyethylene groups ether phosphate, TERSPERSE 4894; Wetting agent is selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500; Solvent is selected from dimethylbenzene, toluene, cyclohexanone, solvent naphtha (S-150, S-180, S-200); Thickener is selected from xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate; Preservative is selected from formaldehyde, benzoic acid, Sodium Benzoate; Defoamer is silicone based defoamer; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts (as sodium chloride); Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane, aceticanhydride; Water is deionized water.
But to the dispersed oil suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), TERSPERSE 2425; Emulsifier is selected from the serial emulsifier of BY (castor oil polyoxyethylene ether) (BY-110, BY-125, BY-140) Nongru-700 #, farming breast 2201, this dish-60#, Tween-60 #, agricultural newborn 1601#, TERSPERSE 4894; Wetting agent is selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE2500; Thickener is selected from white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts (as sodium chloride); Stabilizing agent is selected from epoxidized soybean oil, epoxychloropropane, triphenyl phosphate; Dispersion medium is selected from soybean oil, rapeseed oil, corn oil, methyl oleate, diesel oil, machine oil, mineral oil.
Octyl phenol polyoxy ethene (10) ether), agricultural newborn 1601#, agricultural newborn 600#, agricultural newborn 400# for missible oil, spendable auxiliary agent has: emulsifier is selected from calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 #, agricultural newborn 2201#, this dish-60#, emulsifier T-60, TX-10 (common name:; Solvent is selected from dimethylbenzene, solvent naphtha (S-150, S-180, S-200), toluene, biodiesel, methylated vegetable oil; Cosolvent is selected from ethyl acetate, methyl alcohol, dimethyl formamide, cyclohexanone, acetone; Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane, aceticanhydride.
Octyl phenol polyoxy ethene (10) ether), farming breast 1601, agricultural newborn 600#, agricultural newborn 400# to microemulsion, spendable auxiliary agent has: emulsifier is selected from calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 #, agricultural newborn 2201#, this dish-60#, Tween-60 #, TX-10 (common name:; Assistant for emulsifying agent is selected from methyl alcohol, isopropyl alcohol, n-butanol, ethanol; Solvent is selected from cyclohexanone, N-Methyl pyrrolidone, dimethylbenzene, toluene, solvent naphtha (trade mark: S-150, S-180, S-200); Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane.
For microcapsule suspending agent, spendable auxiliary agent and filler have: solvent, emulsifier, encystation monomer, wetting dispersing agent, antifreezing agent, thickener and water.Solvent is selected from toluene, dimethylbenzene, dimethyl formamide, cyclohexanone, acetone, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone; Described emulsifier is selected from Nongru-700 #, farming breast 2201, this dish-60#, Tween-60 #, TX-10, farming breast 1601; Described encystation monomer is a PPG (specification is 6305 (GB12008.2-89)), (product specification is PMM-20 to polyalcohol modified MDI, NCO (free isocyanuric acid) content is 27.0-28.0%, acid part≤0.1%, viscosity 150 ± 50mPas/25 ℃) in a kind of; Wetting dispersing agent is selected from alkyl phenol formaldehyde resin polyoxyethylene ether sodium sulphate (SOPA), alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine; Thickener is selected from xanthans, polyvinyl alcohol, bentonite; Preservative is selected from formaldehyde, benzoic acid, Sodium Benzoate.Described water is deionized water.Preparation process: with first active component and second active component with dissolution with solvents after, add encystation monomer and emulsifier evenly as oil phase, be water with the deionized water.Oil phase is added aqueous phase, at the high-speed shearing machine down cut, make particle diameter to 1～3 micron of emulsion, then by control temperature and mixing speed, micro-capsule is solidified, the system particle diameter for the treatment of suits the requirements stops the encystation reaction when big or small, then dispersant, thickener, preservative, antifreezing agent is added, and stirs.
Component of the present invention is reasonable, good disinsection effect, and drug cost is low, and its active and insecticidal effect is not the simple superposition of each composition activity, but significant synergistic effect is arranged, and can slow down the generation of resistance, and is good to crop safety, meets the security requirement of pesticidal preparations.The present invention has the better prevention effect to rice-stem borer, paddy stem borer, rice leaf roller, cotton cotton bollworm, apple skin worm, vegetables beet armyworm, plutella maculipennis insect.
Embodiment
In order to prevent and treat rice-stem borer, paddy stem borer, rice leaf roller, cotton cotton bollworm, apple olethreutid, vegetables beet armyworm, the diamond-back moth insect in the agricultural production, the inventor has carried out mutual composite synergy research with compositions such as methoxyfenozide, Avermectin, multiple killing teichomycins, and concrete grammar is:
1) rice-stem borer formal name used at school (Chilo supperssalis) Lepidoptera, Pyralidae, another name borer; Paddy stem borer (Tryporyza incertulas (walker)) Lepidoptera, Pyralidae; Rice leaf roller (Cnaphalocrocis medialisGuenee), Lepidoptera, Pyralidae, medicament can be represented the paddy rice rice leaf roller rice-stem borer Toxicity Determination result, paddy stem borer indoor virulence result, therefore this test is Toxicity Determination test examination worm with the rice-stem borer, the former medicine that the former medicine of test medicine methoxyfenozide adopts the agricultural Co., Ltd of LG-DOW benefit to produce, the former medicine that the former medicine of Avermectin adopts Hebei Weiyuan biochemistry Co Co., Ltd to produce, the former medicine that the former medicine of multiple killing teichomycin adopts the agricultural Co., Ltd of LG-DOW benefit to produce, by technology department of Shanggezhilu Biosciences Co., Ltd., Shaanxi former medicine is mixed with the test medicine that needs, test method is with reference to " the agricultural industry criteria NY/T1154.2-2006 of the People's Republic of China (PRC) ".At first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, the rice-stem borer lethality is set by geometric progression in 5%～90% scope), the examination worm is the striped rice borer of picking up from the field, select the striped rice borer of uniformity in the length of time in the laboratory, hungry 4～8 hours, play skin leaf dish with the card punch of 1 centimetre of diameter, put into culture dish, and note preserving moisture, with the capillary dropper from low concentration, every leaf dish point 1 μ L～2 μ L soups that drip, treat after the solvent evaporates and another sheet scribbles the involutory malicious leaf dish of folder of making of leaf dish of gelatinized corn starch, making finishes and is put in the hole of 12 hole tissue culturing plates, every processing repeats for 4 times, every repeat to be no less than 12 the folder malicious leaf dish, and the processing of establishing the corresponding organic solvent that does not contain medicament in contrast, organize and connect 1 examination worm in each hole of superior consciousness plate, place under the normal condition and cultivate, connect worm after 2～4 hours, after worm to be tried is got and eaten pastille leaf dish, in cultivating plate hole, add the cleaning feed and continue to raise, eliminate the examination worm that has not eaten an intact leaves dish to investigation, check dead borer population in 24 hours, calculate lethality.
2) cotton cotton bollworm (Helibthis armigera Hiibner), test method is the malicious blade method of folder, with " the agricultural industry criteria NY/T1154.2-2006 of the People's Republic of China (PRC) " is reference, at first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, the cotton bollworm lethality is set by geometric progression in 5%～90% scope), the examination worm is the cotton bollworm of picking up from the field, select in the laboratory three the length of time uniformity cotton bollworm, hungry 4～8h, choose 50 larvas, use scales/electronic balance weighing, calculate every average quality.Insert in the tissue culturing plate, every empty 1 cephalont, every processing repeats 4 times, cultivates under normal condition, and 4d checks dead borer population, writes down total borer population and dead borer population.Blank is the processing that equivalent does not contain the corresponding organic solvent of medicament.
3) apple olethreutid (Adoxophyes orana), test method is with reference to " the agricultural industry criteria NY/T1154.2-2006 of the People's Republic of China (PRC) ".At first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, apple olethreutid lethality is set by geometric progression in 5%～90% scope), the examination worm is the olethreutid of picking up from the apple orchard, and test method is with aforementioned rice-stem borer.
4) cauliflower beet armyworm formal name used at school Laphygma exigua Hubner Lepidoptera, Noctuidae.Test method is with reference to " the agricultural industry criteria NY/T1154.2-2006 of the People's Republic of China (PRC) ".At first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, cauliflower beet armyworm lethality is set by geometric progression in 5%～90% scope), the examination worm is the beet armyworm of picking up from the field, and test method is with aforementioned rice-stem borer.
5) wild cabbage diamond-back moth formal name used at school (Plutella xylostella (L.)) Lepidoptera, diamond-back moth section.Another name diamond-back moth, square moth, pointed at both ends.Test method is with reference to " the agricultural industry criteria NY/T1154.2-2006 of the People's Republic of China (PRC) ".At first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, wild cabbage diamond-back moth lethality is set by geometric progression in 5%～90% scope), the examination worm is the diamond-back moth of picking up from the field, and test method is with aforementioned rice-stem borer.The co-toxicity coefficient of mixture (CTC value) calculates by following formula:
ATI---mixture actual measurement toxicity index;
S---standard insecticide LC
50, unit is every liter (mg/L) of milligram;
The LC of M---mixture
50, unit is every liter (mg/L) of milligram;
TTI=TI
A* P
A+ TI
B* P
B, in the formula:
The theoretical toxicity index of TTI---mixture;
TI
A---A medicament toxicity index;
P
A---the percentage composition of A medicament in mixture, unit are percentage (%);
TI
B---B medicament toxicity index;
P
B---the percentage composition of B medicament in mixture, unit are percentage (%);
CTC---co-toxicity coefficient; ATI---mixture actual measurement toxicity index; The theoretical toxicity index of TTI---mixture;
The co-toxicity coefficient of complex preparation (CTC) 〉=120 shows as synergistic effect; CTC≤80 show as antagonism; 80＜CTC＜120 show as summation action.
4) measurement result sees Table 1～5 respectively.
Table 1 methoxyfenozide and Avermectin, multiple killing teichomycin make up the Toxicity Determination to rice-stem borer
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| Methoxyfenozide (A) | ??Y＝3.3368+1.8587X | ??0.9967 | ??7.85 | ??5.7634～11.7602 | ??- |
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| Avermectin (B) | ??Y＝5.5919+1.9337X | ??0.9985 | ??0.494 | ??0.4319～0.5576 | ??- |
| Multiple killing teichomycin (C) | ??Y＝4.8769+2.0172X | ??0.9992 | ??1.15 | ??1.0677～1.2421 | ??- |
| ??A+B(40∶1) | ??Y＝3.9743+1.8023X | ??0.9851 | ??3.71 | ??2.3573～8.0259 | ??155.2 |
| ??A+B(20∶1) | ??Y＝4.2726+2.0098X | ??0.9993 | ??2.30 | ??2.1102～2.5278 | ??199.7 |
| ??A+B(10∶1) | ??Y＝4.7652+2.1029X | ??0.9993 | ??1.29 | ??1.2049～1.3909 | ??258.5 |
| ??A+B(5∶1) | ??Y＝4.8183+2.0452X | ??0.9969 | ??1.23 | ??1.0533～1.4415 | ??183.3 |
| ??A+B(2.5∶1) | ??Y＝5.0364+1.9716X | ??0.9975 | ??0.958 | ??0.8329～1.1013 | ??155.9 |
| ??A+B(1∶1) | ??Y＝5.4101+2.0311X | ??0.9996 | ??0.628 | ??0.5933～0.6637 | ??148.0 |
| ??A+B(1∶2.5) | ??Y＝5.5509+2.0452X | ??0.9983 | ??0.538 | ??0.4688～0.6086 | ??125.4 |
| ??A+B(1∶5) | ??Y＝5.6115+2.0267X | ??0.9979 | ??0.499 | ??0.4267～0.5755 | ??117.3 |
| ??A+B(1∶10) | ??Y＝5.5663+1.9813X | ??0.9987 | ??0.518 | ??0.4597～0.5771 | ??104.2 |
| ??A+C(40∶1) | ??Y＝3.6761+2.0858X | ??0.9992 | ??4.31 | ??3.8195～4.9411 | ??159.5 |
| ??A+C(20∶1) | ??Y＝3.9469+2.0248X | ??0.9993 | ??3.31 | ??2.9834～3.7182 | ??185.7 |
| ??A+C(10∶1) | ??Y＝4.2139+2.0209X | ??0.9989 | ??2.45 | ??2.1888～2.7753 | ??208.2 |
| ??A+C(5∶1) | ??Y＝4.5406+2.0441X | ??0.9982 | ??1.68 | ??1.4867～1.9156 | ??237.1 |
| ??A+C(2.5∶1) | ??Y＝4.6518+1.9992X | ??0.9994 | ??1.49 | ??1.3957～1.6024 | ??197.8 |
| ??A+C(1∶1) | ??Y＝4.8720+2.0405X | ??0.9994 | ??1.16 | ??1.0791～1.2386 | ??172.9 |
| ??A+C(1∶2.5) | ??Y＝5.0182+1.8711X | ??0.9943 | ??0.978 | ??0.7873～1.2124 | ??155.5 |
| ??A+C(1∶5) | ??Y＝4.9681+1.8772X | ??0.9938 | ??1.04 | ??0.8304～1.3069 | ??128.9 |
| ??A+C(1∶10) | ??Y＝4.9293+1.8615X | ??0.9965 | ??1.09 | ??0.9249～1.2931 | ??114.4 |
Table 2 methoxyfenozide and Avermectin, multiple killing teichomycin make up the Toxicity Determination to the cotton cotton bollworm
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| Methoxyfenozide (A) | ??Y＝2.8665+1.9022X | ??0.9953 | ??13.23 | ??8.5813～24.2644 | ??- |
| Avermectin (B) | ??Y＝5.1408+1.9985X | ??0.9994 | ??0.850 | ??0.7923～0.9112 | ??- |
| Multiple killing teichomycin (C) | ??Y＝4.4008+1.8298X | ??0.9943 | ??2.12 | ??1.6762～2.8685 | ??- |
| ??A+B(40∶1) | ??Y＝3.5316+1.9886X | ??0.9985 | ??5.48 | ??4.5654～6.7856 | ??178.4 |
| ??A+B(20∶1) | ??Y＝3.8639+2.1582X | ??0.9983 | ??3.36 | ??2.8754～4.0326 | ??232.7 |
| ??A+B(10∶1) | ??Y＝4.0945+1.9277X | ??0.9995 | ??2.95 | ??2.7197～3.2197 | ??193.1 |
| ??A+B(5∶1) | ??Y＝4.2171+1.9558X | ??0.9950 | ??2.51 | ??1.9954～3.3701 | ??153.8 |
| ??A+B(2.5∶1) | ??Y＝4.4870+1.9592X | ??0.9986 | ??1.83 | ??1.6304～2.0719 | ??140.1 |
| ??A+B(1∶1) | ??Y＝4.8012+1.7798X | ??0.9969 | ??1.29 | ??1.1017～1.5359 | ??123.8 |
| ??A+B(1∶2.5) | ??Y＝4.9805+1.8564X | ??0.9971 | ??1.02 | ??0.8802～1.1936 | ??113.8 |
| ??A+B(1∶5) | ??Y＝4.9829+1.8766X | ??0.9984 | ??1.02 | ??0.9121～1.1438 | ??117.3 |
| ??A+B(1∶10) | ??Y＝5.5663+1.9813X | ??0.9987 | ??0.518 | ??0.4597～0.5771 | ??98.7 |
| ??A+C(40∶1) | ??Y＝3.3802+1.9499X | ??0.9982 | ??6.77 | ??5.4340～8.8432 | ??173.5 |
| ??A+C(20∶1) | ??Y＝3.5396+1.9043X | ??0.9974 | ??5.85 | ??4.5713～7.9621 | ??181.2 |
| ??A+C(10∶1) | ??Y＝3.7525+1.8628X | ??0.9985 | ??4.67 | ??3.9136～5.7668 | ??192.0 |
| ??A+C(5∶1) | ??Y＝3.9296+1.9398X | ??0.9974 | ??3.56 | ??2.9142～4.5592 | ??198.5 |
| ??A+C(2.5∶1) | ??Y＝3.8310+2.1966X | ??0.9999 | ??3.40 | ??3.3088～3.5077 | ??155.9 |
| ??A+C(1∶1) | ??Y＝4.1856+1.9001X | ??0.9991 | ??2.68 | ??2.4106～3.0212 | ??136.4 |
| ??A+C(1∶2.5) | ??Y＝4.2396+2.0497X | ??0.9985 | ??2.35 | ??2.0738～2.7049 | ??118.7 |
| ??A+C(1∶5) | ??Y＝4.2719+2.0483X | ??0.9982 | ??2.27 | ??1.9783～2.6477 | ??108.6 |
| ??A+C(1∶10) | ??Y＝4.2492+2.0734X | ??0.9982 | ??2.30 | ??2.0121～2.6829 | ??99.8 |
Table 3 methoxyfenozide and Avermectin, multiple killing teichomycin make up the Toxicity Determination to the apple olethreutid
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| Methoxyfenozide (A) | ??Y＝3.9094+1.8401X | ??0.9944 | ??3.91 | ??2.9011～5.9063 | ??- |
| Avermectin (B) | ??Y＝6.0315+1.8569X | ??0.9966 | ??0.278 | ??0.2087～0.3495 | ??- |
| Multiple killing teichomycin (C) | ??Y＝5.6020+1.9238X | ??0.9973 | ??0.487 | ??0.4024～0.5727 | ??- |
| ??A+B(40∶1) | ??Y＝4.5410+1.9299X | ??0.9970 | ??1.73 | ??1.4718～2.0773 | ??171.3 |
| ??A+B(20∶1) | ??Y＝4.9409+1.9061X | ??0.9968 | ??1.07 | ??0.9177～1.2609 | ??225.2 |
| ??A+B(10∶1) | ??Y＝5.0035+1.9862X | ??0.9969 | ??0.996 | ??0.8536～1.1620 | ??179.4 |
| ??A+B(5∶1) | ??Y＝5.2277+1.8634X | ??0.9954 | ??0.755 | ??0.6109～0.9153 | ??163.0 |
| ??A+B(2.5∶1) | ??Y＝5.4082+1.7542X | ??0.9955 | ??0.585 | ??0.4621～0.7153 | ??141.2 |
| ??A+B(1∶1) | ??Y＝5.7572+1.8830X | ??0.9992 | ??0.396 | ??0.3561～0.4365 | ??131.1 |
| ??A+B(1∶2.5) | ??Y＝6.0268+2.0614X | ??0.9964 | ??0.318 | ??0.2436～0.3929 | ??119.0 |
| ??A+B(1∶5) | ??Y＝5.9621+2.0421X | ??0.9968 | ??0.338 | ??0.2642～0.4129 | ??97.3 |
| ??A+B(1∶10) | ??Y＝5.8703+1.9662X | ??0.9961 | ??0.361 | ??0.2760～0.4473 | ??84.1 |
| ??A+C(40∶1) | ??Y＝4.3988+1.9769X | ??0.9972 | ??2.01 | ??1.7126～2.4312 | ??165.9 |
| ??A+C(20∶1) | ??Y＝4.5579+1.9991X | ??0.9993 | ??1.66 | ??1.5109～1.8459 | ??176.7 |
| ??A+C(10∶1) | ??Y＝4.7930+2.0178X | ??0.9996 | ??1.27 | ??1.2013～1.3367 | ??188.0 |
| ??A+C(5∶1) | ??Y＝5.0636+2.0496X | ??0.9986 | ??0.931 | ??0.8410～1.0295 | ??193.7 |
| ??A+C(2.5∶1) | ??Y＝5.1059+2.0115X | ??0.9981 | ??0.886 | ??0.7846～0.9973 | ??146.6 |
| ??A+C(1∶1) | ??Y＝5.3976+1.8747X | ??0.9968 | ??0.614 | ??0.5086～0.7243 | ??141.1 |
| ??A+C(1∶2.5) | ??Y＝5.5799+1.9002X | ??0.9955 | ??0.495 | ??0.3849～0.6093 | ??131.2 |
| ??A+C(1∶5) | ??Y＝5.5653+1.7434X | ??0.9922 | ??0.474 | ??0.3280～0.6262 | ??120.3 |
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| ??A+C(1∶10) | ??Y＝5.5425+1.9217X | ??0.9957 | ??0.522 | ??0.4114～0.6369 | ??101.4 |
Table 4 methoxyfenozide and Avermectin, multiple killing teichomycin make up the Toxicity Determination to the cauliflower beet armyworm
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| Methoxyfenozide (A) | ??Y＝5.5158+1.9413X | ??0.9964 | ??0.542 | ??0.4393～0.6496 | ??- |
| Avermectin (B) | ??Y＝7.2388+2.0708X | ??0.9986 | ??0.083 | ??0.0625～0.1052 | ??- |
| Multiple killing teichomycin (C) | ??Y＝6.3150+2.0236X | ??0.9991 | ??0.224 | ??0.1926～0.2558 | ??- |
| ??A+B(40∶1) | ??Y＝6.0106+2.1076X | ??0.9991 | ??0.331 | ??0.2931～0.3702 | ??144.3 |
| ??A+B(20∶1) | ??Y＝6.2728+2.1070X | ??0.9993 | ??0.249 | ??0.2202～0.2778 | ??172.3 |
| ??A+B(10∶1) | ??Y＝6.6425+2.1478X | ??0.9989 | ??0.172 | ??0.1436～0.2010 | ??209.7 |
| ??A+B(5∶1) | ??Y＝6.6852+2.0423X | ??0.9997 | ??0.149 | ??0.1365～0.1629 | ??189.3 |
| ??A+B(2.5∶1) | ??Y＝6.6442+1.8691X | ??0.9949 | ??0.132 | ??0.0786～0.1911 | ??159.2 |
| ??A+B(1∶1) | ??Y＝6.8265+1.8503X | ??0.9943 | ??0.103 | ??0.0555～0.1581 | ??139.8 |
| ??A+B(1∶2.5) | ??Y＝6.9101+1.8625X | ??0.9971 | ??0.094 | ??0.0622～0.1301 | ??116.5 |
| ??A+B(1∶5) | ??Y＝6.8285+1.8316X | ??0.9967 | ??0.100 | ??0.0640～0.1411 | ??96.6 |
| ??A+B(1∶10) | ??Y＝6.8437+1.8694X | ??0.9977 | ??0.103 | ??0.0726～0.1367 | ??87.3 |
| ??A+C(40∶1) | ??Y＝5.7540+2.0246X | ??0.9976 | ??0.424 | ??0.3515～0.4981 | ??123.5 |
| ??A+C(20∶1) | ??Y＝5.9253+2.0519X | ??0.9984 | ??0.354 | ??0.3001～0.4086 | ??143.4 |
| ??A+C(10∶1) | ??Y＝6.0402+1.9509X | ??0.9971 | ??0.293 | ??0.2276～0.3596 | ??163.8 |
| ??A+C(5∶1) | ??Y＝6.2037+2.0220X | ??0.9981 | ??0.254 | ??0.2054～0.3034 | ??172.5 |
| ??A+C(2.5∶1) | ??Y＝6.2643+2.0314X | ??0.9971 | ??0.239 | ??0.1819～0.2967 | ??161.3 |
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| ??A+C(1∶1) | ??Y＝6.3115+2.0423X | ??0.9957 | ??0.228 | ??0.1610～0.2973 | ??139.0 |
| ??A+C(1∶2.5) | ??Y＝6.4001+2.0949X | ??0.9978 | ??0.215 | ??0.1683～0.2622 | ??125.2 |
| ??A+C(1∶5) | ??Y＝6.3562+2.0225X | ??0.9981 | ??0.213 | ??0.1698～0.2585 | ??116.6 |
| ??A+C(1∶10) | ??Y＝6.2599+1.9355X | ??0.9993 | ??0.223 | ??0.1949～0.2523 | ??106.1 |
Table 5 methoxyfenozide and Avermectin, multiple killing teichomycin make up the Toxicity Determination to the wild cabbage diamond-back moth
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| Methoxyfenozide (A) | ??Y＝4.9932+1.9639X | ??0.9969 | ??1.008 | ??0.8631～1.1776 | ??- |
| Avermectin (B) | ??Y＝6.3544+1.8754X | ??0.9982 | ??0.190 | ??0.1484～0.2322 | ??- |
| Multiple killing teichomycin (C) | ??Y＝5.8606+2.0043X | ??0.9987 | ??0.372 | ??0.3234～0.4212 | ??- |
| ??A+B(40∶1) | ??Y＝5.4388+1.8446X | ??0.9950 | ??0.578 | ??0.4509～0.7131 | ??157.7 |
| ??A+B(20∶1) | ??Y＝5.6270+1.9713X | ??0.9952 | ??0.481 | ??0.3698～0.5954 | ??174.2 |
| ??A+B(10∶1) | ??Y＝5.8496+1.9089X | ??0.9904 | ??0.359 | ??0.2230～0.4991 | ??202.0 |
| ??A+B(5∶1) | ??Y＝6.0323+1.9707X | ??0.9948 | ??0.299 | ??0.2097～0.3913 | ??196.2 |
| ??A+B(2.5∶1) | ??Y＝6.2002+2.0610X | ??0.9944 | ??0.262 | ??0.1782～0.3477 | ??172.5 |
| ??A+B(1∶1) | ??Y＝6.3367+1.9593X | ??0.9904 | ??0.208 | ??0.1107～0.3123 | ??153.6 |
| ??A+B(1∶2.5) | ??Y＝6.4215+1.9792X | ??0.9919 | ??0.191 | ??0.1072～0.2820 | ??129.5 |
| ??A+B(1∶5) | ??Y＝6.4424+1.9481X | ??0.9911 | ??0.182 | ??0.0963～0.2751 | ??120.7 |
| ??A+B(1∶10) | ??Y＝6.4688+2.0540X | ??0.9977 | ??0.193 | ??0.1474～0.2397 | ??106.3 |
| ??A+C(40∶1) | ??Y＝5.2952+2.0303X | ??0.9995 | ??0.715 | ??0.6712～0.7611 | ??135.5 |
| ??A+C(20∶1) | ??Y＝5.3859+1.9163X | ??0.9972 | ??0.629 | ??0.5306～0.7327 | ??148.2 |
| Medicament | Virulence regression equation | Correlation (r) | ??EC 50、??(μg/ml) | ??EC 5095% confidence interval | Co-toxicity coefficient (CTC) |
| ??A+C(10∶1) | ??Y＝5.4989+1.8680X | ??0.9981 | ??0.541 | ??0.4659～0.6175 | ??161.4 |
| ??A+C(5∶1) | ??Y＝5.7179+2.0018X | ??0.9994 | ??0.438 | ??0.4003～0.4759 | ??179.2 |
| ??A+C(2.5∶1) | ??Y＝5.8737+1.9187X | ??0.9969 | ??0.350 | ??0.2754～0.4267 | ??193.6 |
| ??A+C(1∶1) | ??Y＝5.9834+1.8613X | ??0.9961 | ??0.296 | ??0.2183～0.3758 | ??183.5 |
| ??A+C(1∶2.5) | ??Y＝6.0538+1.9600X | ??0.9984 | ??0.290 | ??0.2410～0.3395 | ??156.4 |
| ??A+C(1∶5) | ??Y＝6.0004+2.0140X | ??0.9971 | ??0.319 | ??0.2502～0.3881 | ??130.3 |
| ??A+C(1∶10) | ??Y＝5.9121+1.8899X | ??0.9966 | ??0.329 | ??0.2530～0.4066 | ??119.9 |
Toxicity Determination result shows: methoxyfenozide and biological source insecticide Avermectin or multiple killing teichomycin are used with has the better prevention effect to rice-stem borer, paddy stem borer, rice leaf roller, cotton cotton bollworm, apple olethreutid, vegetables beet armyworm, diamond-back moth, weight ratio is 1: 1～40: 1 o'clock, and it is remarkable to show as synergy.
Example of formulations 1:
Take by weighing 40% methoxyfenozide, 5% Avermectin, 3%TERSPERSE 2700 (polycarboxylate, U.S. Huntsman Corporation produces), 2% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 1% Nekal BX (nekal), 1%K-12 (lauryl sodium sulfate), 3% soluble starch, 3% glucose, kaolin adds to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is promptly mixed, ultra micro comminution by gas stream, mixing, granulation step are produced 45% methoxyfenozide Avermectin water dispersible granules.
Example of formulations 2
Take by weighing 60% methoxyfenozide, 3% Avermectin, 3%TERSPERSE 2700,4% sodium lignin sulfonate, 1% Nekal BX, 1%K-12,1% carboxymethyl cellulose, 3% urea, diatomite and add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is promptly mixed, ultra micro comminution by gas stream, mixing, granulation step are produced 63% methoxyfenozide Avermectin water dispersible granules.
Example of formulations 3:
Take by weighing 40% methoxyfenozide, 10% multiple killing teichomycin, 4%TERSPERSE 2700,1% Nekal BX, 1%K-12,0.8% dextrin, 5% ammonium sulfate, attapulgite and add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is promptly mixed, ultra micro comminution by gas stream, mixing, granulation step are produced 50% methoxyfenozide multiple killing teichomycin water dispersible granules.
Example of formulations 4:
Take by weighing 60% methoxyfenozide, 20% multiple killing teichomycin, 4%Morwet D-425 (alkylnaphthalene sulfonate, Akzo Nobel N.V. produces), 3% dispersing agent NNO, 2% Nekal BX, 2%K-12,2% polyvinylpyrrolidone, 0.5% xanthans, kaolin adds to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is promptly mixed, ultra micro comminution by gas stream, mixing, granulation step are produced 80% methoxyfenozide multiple killing teichomycin water dispersible granules.
Example of formulations 5
Take by weighing 40% methoxyfenozide, 1% Avermectin, 5% calcium lignosulfonate, 2% Nekal BX, 1%K-12,3% white carbon black, kaolin and add to 100% weight portion.Above-mentioned raw materials makes 41% methoxyfenozide Avermectin wetting powder through mixing behind the comminution by gas stream.
Example of formulations 6
Take by weighing 20% methoxyfenozide, 20% multiple killing teichomycin, 4% calcium lignosulfonate, 3%TERSPERSE 2700,2% Nekal BX, 1%K-12,3% white carbon black, precipitated calcium carbonate and add to 100% weight portion.Above-mentioned raw materials makes 40% methoxyfenozide multiple killing teichomycin wetting powder through mixing behind the comminution by gas stream.
Example of formulations 7
Take by weighing 4.5% methoxyfenozide, 0.5% Avermectin, 4% calcium lignosulfonate, 3% dispersing agent NNO, 1% Nekal BX, 1%K-12,5% white carbon black, attapulgite and add to 100% weight portion.Above-mentioned raw materials makes 5% methoxyfenozide Avermectin wetting powder through mixing behind the comminution by gas stream.
Example of formulations 8
Take by weighing 20% methoxyfenozide, 10% multiple killing teichomycin, 4% sodium lignin sulfonate, 2%TERSPERSE 2700,2%K-12,3% white carbon black, potter's clay and add to 100% weight portion.Above-mentioned raw materials makes 30% methoxyfenozide multiple killing teichomycin wetting powder through mixing behind the comminution by gas stream.
Example of formulations 9
Take by weighing 18% methoxyfenozide, 2% Avermectin, 3%TERSPERSE 4894,2%TERSPERSE 2500,1%TERSPERSE 2425 (U.S. Huntsman Corporation product), 0.2% xanthans, 5% ethylene glycol, 0.3% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces) deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 20% methoxyfenozide Avermectin suspending agent behind the sand mill sand milling.
Example of formulations 10:
Take by weighing 20% methoxyfenozide, 5% multiple killing teichomycin, 1.5%NNO, 1%TERSPERSE 2500,2% emulsifier T-60,3% Nongru-700 #, 0.1% xanthans, 5% propane diols, 0.5% formaldehyde, 0.3% silicone defoaming agent deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 25% methoxyfenozide multiple killing teichomycin suspending agent behind the sand mill sand milling.
Example of formulations 11:
Take by weighing 15% methoxyfenozide, 3% Avermectin, 3%TERSPERSE 4894,1%TERSPERSE 2500,1%TERSPERSE 2425,0.2% xanthans, 1% aluminium-magnesium silicate, 5% ethylene glycol, 0.3% Sodium Benzoate, 0.5% silicone defoaming agent deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 18% methoxyfenozide Avermectin suspending agent behind the sand mill sand milling.
Example of formulations 12:
Take by weighing 20% methoxyfenozide, 2.5% multiple killing teichomycin, 3% Nongru-700 #, 2% agricultural newborn 1601#, 1.5%TERSPERSE2500,0.5%TERSPERSE 2425,0.2% xanthans, 3% white carbon, 5% ethylene glycol, 0.3% benzoic acid, 0.5% silicone defoaming agent deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 22.5% methoxyfenozide multiple killing teichomycin suspending agent behind the sand mill sand milling.
Example of formulations 13
Take by weighing 15% methoxyfenozide, 1% Avermectin, 1.5% dispersing agent NNO, 4%TERSPERSE 4894,2.5% triphen ethyl phenol polyoxyethylene groups ether phosphates, 5.0% cyclohexanone, 5% toluene, 2.5% this dish-60#, 3.5% Tween-60 #, 1%TERSPERSE 2500,2% aluminium-magnesium silicates, 0.2% xanthans, 5% ethylene glycol, 1% epoxychloropropane, 0.3% benzoic acid, 0.5% silicone defoaming agent, deionized water adds to 100% weight portion.Operating procedure: 1, the complete back adding of Avermectin and dissolution with solvents emulsifier is even in the above-mentioned raw materials, 2, unclassified stores is through mixing, 3, drop in 2 in the material mixing material in 1, high speed shear is disperseed 30min, with making 16% methoxyfenozide Avermectin suspended emulsion behind the sand mill sand milling.
Example of formulations 14
Take by weighing 10% methoxyfenozide, 2% multiple killing teichomycin, 1.0%TERSPERSE 2700,4%TERSPERSE 4894,2.5% agricultural newborn 1601#, 6% dimethylbenzene, 3.5% farming breast 2201,1%TERSPERSE 2500,0.2% xanthans, 5% propane diols, 1% epoxychloropropane, 0.3% Sodium Benzoate, 0.3% silicone defoaming agent, deionized water adds to 100% weight portion.Operating procedure: 1, the complete back adding of multiple killing teichomycin and dissolution with solvents emulsifier is even in the above-mentioned raw materials, 2, unclassified stores is through mixing, 3, drop in 2 in the material mixing material in 1, high speed shear is disperseed 30min, with making 12% methoxyfenozide multiple killing teichomycin suspended emulsion behind the sand mill sand milling.
Example of formulations 15
Take by weighing 13% methoxyfenozide, 2% Avermectin, 2%TERSPERSE 2425,4% this dish-60#, 3% Tween-60 #, 2% Nongru-700 #, 1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, 1% epoxychloropropane, methyl oleate and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 15% methoxyfenozide Avermectin dispersed oil suspending agent behind the sand mill sand milling.
Example of formulations 16
Take by weighing 8% methoxyfenozide, 2% multiple killing teichomycin, 2% dispersing agent NNO, 3% agricultural newborn 2201#, 8%BY-110,1%TERSPERSE 2500,1% aluminium-magnesium silicate, 3% propane diols, 15% epoxidized soybean oil, soybean oil and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 10% methoxyfenozide multiple killing teichomycin dispersed oil suspending agent behind the sand mill sand milling.
Example of formulations 17
Take by weighing 10% methoxyfenozide, 1% Avermectin, 3%TERSPERSE 2425,3% this dish-60#, 3% Tween-60 #, 8%BY-110,1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, 20% epoxidized soybean oil, methyl oleate and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 11% methoxyfenozide Avermectin dispersed oil suspending agent behind the sand mill sand milling.
Example of formulations 18
Take by weighing 7.5% methoxyfenozide, 5% multiple killing teichomycin, 3% dispersing agent NNO, 5%BY-125,4% this dish-60#, 4% agricultural newborn 1601#, 1% phenethyl phenol polyethenoxy base ether phosphate, 0.5% bentonite, 5% glycerine, 3% triphenyl phosphate, rapeseed oil and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 12.5% methoxyfenozide multiple killing teichomycin dispersed oil suspending agent behind the sand mill sand milling.
Example of formulations 19
Take by weighing 14% methoxyfenozide, 1% Avermectin, 3%TERSPERSE 2425,4% agricultural newborn 2201#, 2% Nongru-700 #, 5%BY-110,1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, 20% epoxidized soybean oil, methyl oleate and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 15% methoxyfenozide Avermectin dispersed oil suspending agent behind the sand mill sand milling.
Example of formulations 20
Take by weighing 5% methoxyfenozide, 0.6% Avermectin, 4%TX-10,5% Nongru-700 #, 6% agricultural newborn 500#, 4% agricultural newborn 1601#, 15% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, 1% epoxychloropropane, through dissolving fully and mixing, deionized water adds to 100% weight portion, makes 5.6% methoxyfenozide avermectin micro-emulsion after the stirring.
Example of formulations 21
Take by weighing 9% methoxyfenozide, 3% multiple killing teichomycin, 5% agricultural newborn 400#, 4% agricultural newborn 500#, 6% agricultural newborn 1601#, 25% cyclohexanone, 5% dimethylbenzene, 5% isopropyl alcohol, 3% triphenyl phosphite, through dissolving fully and mixing, deionized water adds to 100% weight portion, makes 12% methoxyfenozide multiple killing teichomycin microemulsion after the stirring.
Example of formulations 22
Take by weighing 9% methoxyfenozide, 1% Avermectin, 6% agricultural newborn 2201#, 5% Nongru-700 #, 6% agricultural newborn 600#, 15% cyclohexanone, 5%N-methyl pyrrolidone, 5% toluene, 5% ethanol, 1% epoxychloropropane, through dissolving fully and mixing, deionized water adds to 100% weight portion, makes 10% methoxyfenozide avermectin micro-emulsion after the stirring.
Example of formulations 23
Take by weighing 8.5% methoxyfenozide, 1.5% multiple killing teichomycin, 4%TX-10,8% agricultural newborn 600#, 6% agricultural newborn 500#, 15% cyclohexanone, 5%N-methyl pyrrolidone, 5% toluene, 1% epoxychloropropane, through dissolving fully and mixing, deionized water adds to 100% weight portion, makes 10% methoxyfenozide multiple killing teichomycin microemulsion after the stirring.
Example of formulations 24
Take by weighing 8% methoxyfenozide, 0.5% Avermectin, 4% agricultural newborn 500#, 2% agricultural newborn 600#, 3% agricultural newborn 2201#, 3% triphenyl phosphite, 15% dimethyl formamide, 5% acetone, dimethylbenzene add to 100% weight portion.Above-mentioned raw materials makes 8.5% methoxyfenozide abamectin emulsifiable concentrate after mix, stirring and dissolving is complete.
Example of formulations 25
Take by weighing 8% methoxyfenozide, 2% multiple killing teichomycin, 4% agricultural newborn 500#, 3% agricultural newborn 400#, 5% agricultural newborn 1601#, 1% epoxychloropropane, 15% ethyl acetate, 10% acetone, S-150 and add to 100% weight portion.Above-mentioned raw materials makes 10% methoxyfenozide multiple killing teichomycin missible oil after mix, stirring and dissolving is complete.
Example of formulations 26
Take by weighing 5% methoxyfenozide, 3% multiple killing teichomycin, 4%Span-60#, 3% emulsifier T-60,3% agricultural newborn 2201#, 3% aceticanhydride, 5% acetone, 10% ethyl acetate, biodiesel add to 100% weight portion.Above-mentioned raw materials makes 8% methoxyfenozide multiple killing teichomycin missible oil after mix, stirring and dissolving is complete.
Example of formulations 27
Take by weighing 10% methoxyfenozide, 0.8% Avermectin, 3% agricultural newborn 500#, 3% agricultural newborn 1601#, 3% agricultural newborn 2201#, 3% triphenyl phosphite, 5% methyl alcohol, 15% dimethyl formamide, toluene add to 100% weight portion.Above-mentioned raw materials makes 10.8% methoxyfenozide abamectin emulsifiable concentrate after mix, stirring and dissolving is complete.
Example of formulations 28
Take by weighing 5% methoxyfenozide, 0.5% Avermectin, solvent toluene 5%, N-Methyl pyrrolidone 20%, encystation monomer PMM-20 3%, emulsifier TX-10 4%, emulsifier 2,201 2%, dispersant alkylphenol-polyethenoxy base ether phosphate 4%, the yellow first glue 0.3% of thickener, antifreeze glycol 4%, 0.5% benzoic acid, deionized water supply 100%.With two kinds of active components of methoxyfenozide and Avermectin with solvent toluene, N-Methyl pyrrolidone heating for dissolving after, add encystation monomer and emulsifier evenly as oil phase, be water with the excess water.Under 8000 rev/mins of speed of high-speed shearing machine, oil phase is joined the aqueous phase shearing obtained emulsion in 10-15 minute, the sampling and measuring emulsion particle diameter, average grain diameter gets final product at 3 microns.Emulsion is transferred in the reactor that has thermometer and agitator then, heating-up temperature to 45 ℃, 500 rev/mins of mixing speeds make the encystation monomer that interface polymerization reaction slowly take place on the emulsion particulate, form microcellular structure capsule skin on microparticle surfaces gradually.Treat the system reaction after 3-3.5 hour, the sampling and measuring particle diameter is measured average grain diameter about 5 microns, and the encystation stage of reaction finishes.Temperature is warmed up to 65 ℃ then, the system reaction changes capsule skin cure stage over to by the encystation stage of reaction, and the cure stage time is 1-1.5 hour.After capsule skin cure stage finished, system temperature returned to room temperature, then wetting dispersing agent, thickener, antifreezing agent, preservative was added, and stirred under 800 rev/mins speed and promptly obtained 5.5% methoxyfenozide avermectin microcapsule suspending agent in 30 minutes.
Example of formulations 29
Take by weighing 5% methoxyfenozide, 1% multiple killing teichomycin, solvent xylene 10%, 20%N-methyl pyrrolidone, encystation monomer PPG 6,305 4%, emulsifier Nongru-700 # 3%, emulsifier 2,201 2%, dispersant phenethyl phenol polyethenoxy base ether phosphate 4%, alkyl phenol formaldehyde resin polyoxyethylene ether sodium sulphate (SOPA) 2%, the yellow first glue 0.3% of thickener, antifreezing agent propane diols 4%, 0.5% Sodium Benzoate, deionized water supply 100%.After methoxyfenozide and two kinds of active components usefulness solvent xylenes of multiple killing teichomycin and N-Methyl pyrrolidone heating for dissolving, add encystation monomer and emulsifier evenly as oil phase, be water with the excess water.Under 8000 rev/mins of speed of high-speed shearing machine, oil phase is joined the aqueous phase shearing obtained emulsion in 10-15 minute, the sampling and measuring emulsion particle diameter, average grain diameter gets final product at 3 microns.Emulsion is transferred in the reactor that has thermometer and agitator then, heating-up temperature to 45 ℃, 500 rev/mins of mixing speeds make the encystation monomer that interface polymerization reaction slowly take place on the emulsion particulate, form microcellular structure capsule skin on microparticle surfaces gradually.Treat the system reaction after 3-3.5 hour, the sampling and measuring particle diameter is measured average grain diameter about 5 microns, and the encystation stage of reaction finishes.Temperature is warmed up to 65 ℃ then, the system reaction changes capsule skin cure stage over to by the encystation stage of reaction, and the cure stage time is 1-1.5 hour.After capsule skin cure stage finished, system temperature returned to room temperature, then wetting dispersing agent, thickener, antifreezing agent, preservative was added, and stirred under 800 rev/mins speed and promptly obtained 6% methoxyfenozide multiple killing teichomycin microcapsule suspending agent in 30 minutes.Biological Examples 1: control rice-stem borer field trial
The inventor carried out the field control effectiveness test of control rice-stem borer on May 20th, 2010 in Hubei Province's Shishou county, verified that this medicament is to the control efficiency of striped rice borer, effective dose and to the safety of paddy rice.Trial crops is a paddy rice, controlling object striped rice borer (Chilo supperssalis).Adopt conventional spray-on process, in rice plant of tillering stage, generation striped rice borer egg development is incubated the initial stage to ovum latter stage, adopts the conventional spraying of manual sprayer, and 45 liters of every mu of spouting liquids are investigated the control efficiency of each sub-district when generation striped rice borer borer pest is stablized.Take the random sampling of balance great-jump-forward, 25 clumps of rice of every sub-district investigation are added up withered heart rate and lethality.While is 2,7,14 days observation paddy growth situations behind medicine, and the visual test medicament has or not poisoning to produce to paddy rice.
Computational methods:
In the formula: Pt
0Withered heart rate behind-----chemicals treatment district medicine; CK
0Withered heart rate behind-----blank district medicine
Table 6 control rice-stem borer result of the test
| Handle numbering | Chemicals treatment | Dispenser dosage (amount of formulation) (gram/mu) | Seedling protecting effect (%) | Insecticidal effect (%) |
| ??1 | 20% methoxyfenozide+2% Avermectin SC | ??10 | ??71.15 | ??73.86 |
| ??2 | 20% methoxyfenozide+2% Avermectin SC | ??15 | ??86.42 | ??90.53 |
| ??3 | 20% methoxyfenozide+2% Avermectin SC | ??20 | ??90.31 | ??94.85 |
| ??4 | 20% methoxyfenozide+5% multiple killing teichomycin SC | ??10 | ??74.28 | ??78.08 |
| ??5 | 20% methoxyfenozide+5% multiple killing teichomycin SC | ??15 | ??87.23 | ??91.54 |
| ??6 | 20% methoxyfenozide+5% multiple killing teichomycin SC | ??20 | ??92.46 | ??95.32 |
| ??7 | 24% methoxyfenozide SC | ??25 | ??82.62 | ??84.98 |
| ??8 | 2% Avermectin EW | ??50 | ??83.21 | ??85.37 |
| ??9 | 2.5% multiple killing teichomycin SC | ??80 | ??76.54 | ??79.65 |
| ??10 | The clear water contrast | ??/ | ??/ | ??/ |
As can be seen from Table 6, methoxyfenozide and Avermectin or multiple killing teichomycin combination are composite, incubating the initial stage dispenser in striped rice borer egg development latter stage to ovum once can effectively control striped rice borer and cause harm, and dosage is less than the contrast dosing, tangible synergistic effect is arranged, can be used for the control of rice-stem borer, and to rice safety.
Biological Examples 2: control paddy rice rice leaf roller field trial
The inventor carried out the field control effectiveness test of control paddy rice rice leaf roller on July 26th, 2009 in Zhejiang Province's fairy house county, verified that this medicament is to the control efficiency of rice leaf roller, effective dose and to the safety of paddy rice.Trial crops is a paddy rice, controlling object rice leaf roller (Cnaphalocrocis medinalis).Adopt the conventional spraying of manual sprayer, 30 liters of every mu of spouting liquids, control paddy rice three generations rice leaf roller was investigated behind medicine in 3 days, 7 days, 10 days.Take the random sampling of balance great-jump-forward, 25 clumps of rice are looked in 5 samplings in every sub-district altogether, and statistics leaf roll rate compares with check plot leaf roll rate, calculates relative control effect, and investigating simultaneously has the worm rate in the leaf roll.While is 3,7,10 days observation paddy growth situations behind medicine, and the visual test medicament has or not poisoning to produce to paddy rice.
Computational methods:
In the formula: leaf roll rate behind the Pt-----chemicals treatment district medicine; Leaf roll rate behind the CK-----blank district medicine
Table 7 control paddy rice rice leaf roller result of the test
As can be seen from Table 7,40% methoxyfenozide+5% Avermectin WG, 60% methoxyfenozide+20% multiple killing teichomycin WG have preventive effect preferably to rice leaf roller under test dose, quick-acting and lasting period are better than contrasting single agent, can effectively reduce the consumption of each active ingredient, has tangible synergistic effect, to rice safety.
Biological Examples 3: control apple olethreutid field trial
The inventor carried out the field control effectiveness test of control apple rouleau leaf worm in April, 2010 in the Liquan County, Shaanxi Province, verified that this medicament is to the control efficiency of apple rouleau leaf worm, effective dose and to the safety of apple.Trial crops is an apple, controlling object apple rouleau leaf worm (Adoxophyes orana).Adopt the conventional spraying of power driven sprayer, in spending preceding medication, control apple rouleau leaf worm was investigated behind medicine in 3 days, 7 days, 10 days.Two strains are investigated in every sub-district, the worm bag number of record top tree crown 100～200 branches, before the medicine during radix investigation, in whole test block in addition stripping look into 100 worms bags the worm rate arranged, to proofread and correct worm bag radix.Investigation after the dispenser, what then 30～50 worms bag was looked in stripping in time corresponding and sub-district has worm (larva, a pupa and puparium) rate, and to proofread and correct corresponding worm bag number, last investigation also need be write down killed branch number.While is 3,7,10 days observation apple development situations behind medicine, and the visual test medicament has or not poisoning to produce to apple.
Computational methods:
In the formula: Pt-----chemicals treatment district borer population; CK-----blank district borer population.
Table 8 control apple olethreutid result of the test
As can be seen from Table 8,13% methoxyfenozide+2% Avermectin OF, 7.5% methoxyfenozide+5% multiple killing teichomycin OF have preventive effect preferably to the apple olethreutid under test dose, quick-acting and lasting period are better than contrasting single agent, can effectively reduce the consumption of each active ingredient, has tangible synergistic effect, to apple safety.
Biological example 4 control wild cabbage diamond-back moth field control effectiveness tests
Control wild cabbage diamond-back moth is handled with reference to the sub-district of " lepidopterous larvae of field control effectiveness test criterion () GB/T 17980.13-2000 insecticide control brassicaceous vegetable " test medicine, contrast medicament and blank and adopts district's group arrangement at random, sub-district area 30m
2, repeat investigation insect pest situation radix before the dispenser, 3,10 days investigation prevention effects before the dispenser and after the dispenser for 4 times.Every sub-district is got 5 investigation at random, looks into two strains at every, investigates the larva number all alive in the different length of times in every strain.
The drug effect computational methods:
In the formula: CK
0, CK
1Be respectively the forward and backward borer population of blank district dispenser; PT
0, PT
1Be respectively the forward and backward borer population of chemicals treatment district dispenser.
The result of the test of table 9 control wild cabbage diamond-back moth
Table 9 test shows: the high dose control efficiency obviously is better than contrasting the control efficiency of medicament among 5% methoxyfenozide+0.6% Avermectin ME and 9% methoxyfenozide+3% multiple killing teichomycin ME.After methoxyfenozide and Avermectin, multiple killing teichomycin are mixed, obviously improved quick-acting and lasting period, reduced dosage and drug cost, to wild cabbage growth safety the wild cabbage diamond-back moth.
Biological example 5 control cauliflower beet armyworm field control effectiveness tests
Control cauliflower beet armyworm is handled with reference to the sub-district of " lepidopterous larvae of field control effectiveness test criterion () GB/T 17980.13-2000 insecticide control brassicaceous vegetable " test medicine, contrast medicament and blank and adopts district's group arrangement at random, sub-district area 30m
2, repeat investigation insect pest situation radix before the dispenser, 3,10 days investigation prevention effects before the dispenser and after the dispenser for 4 times.Every sub-district is got 5 investigation at random, looks into two strains at every, investigates the larva number all alive in the different length of times in every strain.
The result of the test of table 10 control cauliflower beet armyworm
Table 10 field trial shows: 15% methoxyfenozide+3% Avermectin SC and 20% methoxyfenozide+2.5% multiple killing teichomycin SC C control efficiency, the control efficiency of high dose obviously is better than contrasting the control efficiency of medicament in its mu usefulness.Result of the test shows: after methoxyfenozide and Avermectin, multiple killing teichomycin are mixed, obviously improved quick-acting and lasting period to the cauliflower beet armyworm, reduced dosage and drug cost, to cauliflower growth safety.
Biological example 6 control cotton cotton bollworm field control effectiveness tests
Control cotton cotton bollworm is handled with reference to the sub-district of " field control effectiveness test criterion () GB/T 17980.5-2000 insecticide control cotton bollworm " test medicine, contrast medicament and blank and adopts district's group arrangement at random, sub-district area 50m
2, and guarantee the capable cotton plant of 5-6, and 4 repetitions, the mediant row random sampling of every sub-district is listed and is fixed 5 points, fixes the cotton plant that 5 strains have bollworm eggs and larva at every, totally 25 strains, record larva number and ovum number before the medicine, record larva number behind the medicine.Adopt at least 50 on ovum from investigation strain cotton plant in addition and take back the cultivation of at room temperature preserving moisture, measure the egg hatching rate of different time.Or be as the criterion with field blank district egg hatching rate rate.When investigating for the last time after the dispenser, need the statistics cotton buds and bolls count rate of damage and Bao Lei effect.Need statistics terminal bud rate of damage and protect the top effect if cotton buds and bolls are less, promptly decide total cotton buds and bolls number and killed cotton buds and bolls number in the strain, total strain number and the killed strain number of terminal bud.The radix investigation, larva number and ovum number in the strain are decided in investigation before the dispenser.Investigate for the first time behind the medicine 1 day, investigate behind the medicine 3 days for the second time, investigated medicine for the third time 7 days, investigate cotton buds and bolls rate of damage or terminal bud rate of damage simultaneously.
The drug effect computational methods:
Egg hatching rate (%)=(having hatched ovum number/total ovum number) * 100%
In the formula: the PT chemicals treatment district insect population rate that goes down; The CK blank district insect population rate that goes down.
Bud rate of damage (the %)=killed number of flowers of accumulative total * 100/ investigation bud sum
Protect flower bud effect (%)=(blank district bud rate of damage-chemicals treatment district bud rate of damage) * 100/ blank district bud rate of damage
The killed strain number of terminal bud rate of damage (%)=growing point * total strain number of 100/ investigation
Protect top effect (%)=(blank district terminal bud rate of damage-chemicals treatment district terminal bud rate of damage) * 100/ blank district terminal bud rate of damage
The result of the test of table 11 control cotton cotton bollworm
Table 11 field trial shows: 10% methoxyfenozide+0.8% Avermectin EC mu obviously is better than contrasting the control efficiency of medicament 24% methoxyfenozide SC mu usefulness 80g, 2% Avermectin EC mu 100g, 5% multiple killing teichomycin EC mu usefulness 50g with the control efficiency of 60g, 80g with 100g, 120g and 8% methoxyfenozide+2% multiple killing teichomycin EC mu.Result of the test shows: after methoxyfenozide and Avermectin, multiple killing teichomycin are mixed, obviously improved quick-acting and lasting period to the cotton cotton bollworm, reduced dosage and drug cost, to cotton growth safety.
In sum, composition of the present invention is to adopt two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compare with existing unitary agent, except paddy rice striped rice borer, yellow rice borer, rice leaf roller, cotton bollworm, apple leaf roller, vegetables beet noctuid, plutella maculipennis insect are had the significant insecticidal effect, and significant synergistic effect arranged, can slow down the generation of resistance, good to crop safety, drug cost is low, meets the security requirement of pesticidal preparations.
Claims (7)
1. Pesticidal combination that contains methoxyfenozide and biological source insecticide is characterized in that comprising:
A) the first active component methoxyfenozide;
B) the second active component Avermectin or multiple killing teichomycin biological source insecticide;
The weight ratio of first active component and second active component is (1: 1)～(40: 1).
2. the Pesticidal combination that contains methoxyfenozide and biological source insecticide according to claim 1 is characterized in that: the weight ratio of first active component and second active component is (2: 1)～(20: 1).
3. the Pesticidal combination that contains methoxyfenozide and biological source insecticide according to claim 1 and 2 is characterized in that: the cumulant of first active component and second active component is 1%～80% of a described composition total weight.
4. the Pesticidal combination that contains methoxyfenozide and biological source insecticide according to claim 3 is characterized in that: the cumulant of first active component and second active component is 5%～50% of a described composition total weight.
5. according to the described Pesticidal combination that contains methoxyfenozide and biological source insecticide of claim 1, it is characterized in that described composition can be mixed with agricultural and go up any formulation that allows.
6. the Pesticidal combination that contains methoxyfenozide and biological source insecticide according to claim 5 is characterized in that: but the preparation formulation that described composition can be prepared is water dispersible granules, wetting powder, suspending agent, suspended emulsion dispersed oil suspending agent, missible oil, microemulsion, microcapsule suspending agent.
7. the described application of Pesticidal combination in control rice-stem borer, paddy stem borer, rice leaf roller, cotton cotton bollworm, apple skin worm, vegetables beet armyworm, plutella maculipennis insect that contains methoxyfenozide and biological source insecticide of claim 1.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102165955A (en) * | 2011-03-11 | 2011-08-31 | 青岛海利尔药业有限公司 | High-efficiency environment-friendly pesticidal composition containing biological pesticide and diacylhydrazine pesticide |
| CN102302035A (en) * | 2011-03-17 | 2012-01-04 | 陕西汤普森生物科技有限公司 | Pesticide composition containing methoxyfenozide |
| CN102726396A (en) * | 2012-06-09 | 2012-10-17 | 广东中迅农科股份有限公司 | Spinosad microemulsion and preparation method thereof |
| CN103548821A (en) * | 2013-11-06 | 2014-02-05 | 南京南农农药科技发展有限公司 | Emamectin benzoate.methoxyfenozide oil suspension |
| CN103563900A (en) * | 2012-08-05 | 2014-02-12 | 南京华洲药业有限公司 | Composite insecticidal composition containing methoxyfenozide and spinosad and application thereof |
| CN103688933A (en) * | 2011-05-17 | 2014-04-02 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing fufenozide and antibiotic compounds |
| CN105685051A (en) * | 2016-04-20 | 2016-06-22 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension agent with methoxyfenozide |
| CN107318857A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN114982762A (en) * | 2022-07-07 | 2022-09-02 | 青岛凯源祥化工有限公司 | Insecticidal composition and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN101692819A (en) * | 2009-07-21 | 2010-04-14 | 深圳诺普信农化股份有限公司 | Pesticide composition with synergy effect and application thereof |
-
2010
- 2010-07-02 CN CN 201010216510 patent/CN101878766B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN101692819A (en) * | 2009-07-21 | 2010-04-14 | 深圳诺普信农化股份有限公司 | Pesticide composition with synergy effect and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102165955A (en) * | 2011-03-11 | 2011-08-31 | 青岛海利尔药业有限公司 | High-efficiency environment-friendly pesticidal composition containing biological pesticide and diacylhydrazine pesticide |
| CN102302035B (en) * | 2011-03-17 | 2013-11-27 | 陕西汤普森生物科技有限公司 | Pesticide composition containing methoxyfenozide |
| CN102302035A (en) * | 2011-03-17 | 2012-01-04 | 陕西汤普森生物科技有限公司 | Pesticide composition containing methoxyfenozide |
| CN103688933A (en) * | 2011-05-17 | 2014-04-02 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing fufenozide and antibiotic compounds |
| CN102726396A (en) * | 2012-06-09 | 2012-10-17 | 广东中迅农科股份有限公司 | Spinosad microemulsion and preparation method thereof |
| CN102726396B (en) * | 2012-06-09 | 2015-08-05 | 广东中迅农科股份有限公司 | A kind of spinosad microemulsion and preparation method thereof |
| CN103563900A (en) * | 2012-08-05 | 2014-02-12 | 南京华洲药业有限公司 | Composite insecticidal composition containing methoxyfenozide and spinosad and application thereof |
| CN103548821A (en) * | 2013-11-06 | 2014-02-05 | 南京南农农药科技发展有限公司 | Emamectin benzoate.methoxyfenozide oil suspension |
| CN103548821B (en) * | 2013-11-06 | 2015-11-18 | 南京南农农药科技发展有限公司 | A kind of emamectin-benzoate methoxyfenozide oil-suspending agent |
| CN105685051A (en) * | 2016-04-20 | 2016-06-22 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension agent with methoxyfenozide |
| CN107318857A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN114982762A (en) * | 2022-07-07 | 2022-09-02 | 青岛凯源祥化工有限公司 | Insecticidal composition and application thereof |
| CN114982762B (en) * | 2022-07-07 | 2023-10-27 | 青岛凯源祥化工有限公司 | Insecticidal composition and application thereof |
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