CN103666587B - Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof - Google Patents
Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof Download PDFInfo
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- CN103666587B CN103666587B CN201210327214.0A CN201210327214A CN103666587B CN 103666587 B CN103666587 B CN 103666587B CN 201210327214 A CN201210327214 A CN 201210327214A CN 103666587 B CN103666587 B CN 103666587B
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- alcohol
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- oil fuel
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Abstract
The present invention discloses a kind of novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof, is made up by mass percentage of following raw material：Methanol 78~90%；Water 8~20%；Silver powder 0.058~0.178%；Red phosphorus powder 0.058~0.178%；Ethyl acetate 0.058~0.178%；Strontium carbonate 0.024~0.144%；Acetone 0.058~0.178%；Industry glycerol 0.179~0.479%；Ferrocene 0.058~0.178%；Nitromethane 0.058~0.178%；Absolute ethyl alcohol 0.179~0.479%；The mass percent sum of above raw material is equal to 100%；Preparation method is, at normal temperatures, first silver powder, red phosphorus powder and acetic acid ethyl ester are put into container and stirred 5~10 minutes, then toward adding strontium carbonate, acetone, industry glycerol and ferrocene in container and continuing stirring 5~10 minutes, hot gas can be now produced, absolute ethyl alcohol and part water is subsequently added into, then methanol and remaining water are added, with this so that novel environment friendly clean biometric alcohol-oil fuel, it has calorific value high, and burning is abundant：Without black smoke, no carbon distribution, no blacking pan bottom, no residue, the exhaust gases after combustion discharge low advantage of proportion.
Description
Technical field
The present invention relates to fuel area technology, a kind of novel environment friendly clean biometric alcohol-oil fuel and its preparation side are referred in particular to
Method.
Background technology
Fuel is widely used in industrial and agricultural production and people's lives, can be by chemically or physically reacting (comprising reaction) release
Go out the material of energy.Fuel has many kinds, most common such as coal, coke, liquefied gas, diesel oil.With the development of science and technology,
The mankind's more reasonably development and utilization fuel, and pursue environmental protection concept as far as possible.Fuel is also that study is needed in physics
A part of content, its inhale heat release formula be q=Q/m.
Because world petroleum resource day is becoming tight and price rises steadily, oil station in all parts of the country is the anxiety of valuable oil-free
State.To alleviate diesel oil situation in short supply and pollution problem, combined hereafter by Ministry of Energy, environment general bureau within 07 year, it is following several
Year enters kitchen by diesel oil is completely forbidden, and urban is had at present and has been forbidden.The tense situation of fuel oil supply, huge city
Demand, the support energetically of national environmental protection policy, this is a series of to be not difficult to find out, exploitation is cheap, cleaning alternative energy source has been compeled
The eyebrows and eyelashes！
The primary raw material of biological alcohol oil is just to contain substantial amounts of methanol in methanol, industrial alcohol, belongs to moderate toxicity product
It is suitable with alcohol, but produce the alcohol radical liquid fuel for meeting national standard through scientific technology, burning and exhausting be it is safe and clean,
Meet environmental protection requirement.At present, alcohol has increasingly obtained generally acknowledging for the whole world as new energy product.The substantial amounts of alcohol energy
Automobile, industrial combustion machine, kitchen burner, have been one of important developing direction in Future New Energy Source field.However, current biology
Alcohol oil firing value is low, and stability is poor, and the combustion value that there is fire is not high, and burning midway spontaneous combustion is not fiery, has readily volatilized consumption big, in city
It is difficult sale on field.
The content of the invention
In view of this, in view of the existing deficiencies of the prior art, it is clear that its main purpose is to provide a kind of novel environment friendly to the present invention
Clean bio-alcohol oil fuel and preparation method thereof, it has the characteristics of calorific value is high, burning is substantially stabilized, safe and reliable.
To achieve the above object, the present invention is using following technical scheme：
A kind of novel environment friendly clean biometric alcohol-oil fuel, is made up of following raw material by mass percentage：
The mass percent sum of above raw material is equal to 100%.
As a kind of preferred scheme, it is made up by mass percentage of following raw material：
A kind of preparation method of novel environment friendly clean biometric alcohol-oil fuel, at normal temperatures, first by silver powder, red phosphorus powder and acetic acid
Ethyl ester, which is put into container, stirs 5~10 minutes, then toward add in container strontium carbonate, acetone, industry glycerol and ferrocene and after
Continuous stirring 5~10 minutes, can now produce hot gas, be subsequently added into absolute ethyl alcohol and part water, detectable concentration fills small point with small bowl
Amount solution simultaneously whether caught fire with open firing point, it is unsafe to catch fire, can only add water until point not untill, then, addition
Nitromethane and after continuing stirring 5~20 minutes, whether foregoing inspect catches fire for another example, then adds methanol, adds the ratio of methanol
Example is identical with the ratio of foregoing added water, and observation in brewed 2~3 hours is to produce hot gas, and can produce nature if any hot gas rises
Fire, it can only add water until being produced without hot gas, then, by solution obtained above with plastic cement barreled stock, there is safety
It is all non-ignitable with fire, it can be prepared by novel environment friendly in use, remaining first alcohol and water is added to stir in solution obtained above
Clean biometric alcohol-oil fuel.
After such scheme, novel environment friendly clean biometric alcohol-oil fuel prepared by the present invention has the characteristics that：
1st, sanitation and hygiene, environmental protection：
The fuel value is high, and burning is abundant：Without black smoke, no carbon distribution, no blacking pan bottom, no residue, exhaust gases after combustion discharge ratio
Amount is low.
2nd, it is safe and reliable, applied widely：
Easy to use without explosion danger, catching fire can be put out with water, will not also be revealed and be triggered poisoning, completely may be used
To replace diesel oil and liquefied gas, kitchen fuel is used as, it is adaptable to the large enterprise such as hotel, hotel, school, office and unit group
Kitchen is used, and diesel range that dining room is used, gas-cooker are to change stove core to can be used, and installs and uses very convenient, and it is operated
Simply, operated with diesel range as gas-cooker.
3rd, energy-conservation, material benefit：
Material benefit is in diesel oil and liquefied gas, by the price ups and downs of in the market diesel oil and liquefied gas, and contrast saving economy is minimum can
Between profit 15~30%.
Embodiment
Embodiment 1
(1) novel environment friendly clean biometric alcohol-oil fuel formula one
(2) preparation method
At normal temperatures, first silver powder, red phosphorus powder and ethyl acetate are put into container and stirred 5~10 minutes, then toward container
Middle addition strontium carbonate, acetone, industry glycerol and ferrocene simultaneously continue stirring 5~10 minutes, can now produce hot gas, be subsequently added into
Whether absolute ethyl alcohol and part water, detectable concentration fill small component solution with small bowl and are caught fire with open firing point, it is dangerous to catch fire
, can only add water until point not untill, then, add nitromethane and after continuing stirring 5~20 minutes, it is foregoing for another example
Inspect and whether catch fire, then add methanol, the ratio of addition methanol and the ratio of foregoing added water are identical, and brewed 2~3 is small
When observation be to produce hot gas, it is on fire to produce nature if any hot gas, can only add water until produced without hot gas, then, will
Solution obtained above has safety fire all non-ignitable with plastic cement barreled stock, in use, remaining first alcohol and water is added above-mentioned
Stirred in obtained solution and can be prepared by novel environment friendly clean biometric alcohol-oil fuel.
Embodiment 2
(1) novel environment friendly clean biometric alcohol-oil fuel formula two
(2) preparation method is same as Example 1, therefore does not repeat.
Embodiment 3
(1) novel environment friendly clean biometric alcohol-oil fuel formula three
(2) preparation method is same as Example 1, therefore does not repeat.
Embodiment 4
(1) novel environment friendly clean biometric alcohol-oil fuel formula four
(2) preparation method is same as Example 1, therefore does not repeat.
Embodiment 5
(1) novel environment friendly clean biometric alcohol-oil fuel formula five
(2) preparation method is same as Example 1, therefore does not repeat.
Embodiment 6
(1) novel environment friendly clean biometric alcohol-oil fuel formula six
(2) preparation method is same as Example 1, therefore does not repeat.
Using above-mentioned each implementation explanation
After tested, novel environment friendly clean biometric alcohol-oil fuel of the present invention is free from extraneous odour, colourless transparent liquid.The fuel alcohol contains
Amount is more than 70%, and density at 20 DEG C is no more than 0.83g/ cubic centimetres；Mechanical admixture is no more than 0.3 ‰, and condensation point is less than -30
℃；Ignition temperature is more than 230 DEG C；PH value is 6~8；50% gold-plating goes out temperature no more than 75 DEG C；Total sulfur content is no more than 0.15%；
And be also not in lamination at -20 DEG C；Through aldehyde test, pinkish red is not in blue, through calculating air excess system number
Position 1.2 or so, thermal efficiency of stoves is up to 85~90%；Low heat value is more than 26000KJ/kg.
Take novel environment friendly clean biometric alcohol-oil fuel produced by the present invention, test each formula calorific value and with methanol, liquefaction
Gas, the calorific value of diesel oil are compared, and test result is as shown in table 1 below：
Table 1
| Fuel classification | Methanol | Liquefied gas | Diesel oil | Formula one | Formula two | Formula three | Formula four | Formula five | Formula six |
| Calorific value (kcal/kg) | 4650 | 8650 | 8500 | 8600 | 8550 | 8580 | 8560 | 8540 | 8500 |
Learnt by upper table, calorific value of the invention may be up to 8600kcal/kg, this hair suitable with the calorific value of oil liquefied gas
It is bright to contrast economic data sale by royalty with going up using liquefied gas, diesel oil market, falling, it is specifically shown in table 2 below：
Table 2
From above table, novel environment friendly clean biometric alcohol-oil fuel prepared by the present invention has the characteristics that：
1st, sanitation and hygiene, environmental protection：
The fuel value is high, and burning is abundant：Without black smoke, no carbon distribution, no blacking pan bottom, no residue, exhaust gases after combustion discharge ratio
Amount is low.
2nd, it is safe and reliable, applied widely：
Easy to use without explosion danger, catching fire can be put out with water, will not also be revealed and be triggered poisoning completely can be with
Instead of diesel oil and liquefied gas, kitchen fuel is used as, it is adaptable to the large enterprise such as hotel, hotel, school, office and unit group kitchen
Room is used, and diesel range that dining room is used, gas-cooker are to change stove core to can be used, and installs and uses very convenient, and it operates letter
It is single, operated with diesel range as gas-cooker.
3rd, energy-conservation, material benefit：
Material benefit is in diesel oil and liquefied gas, by the price ups and downs of in the market diesel oil and liquefied gas, and contrast saving economy is minimum can
Between profit 15~30%.
The above described is only a preferred embodiment of the present invention, be not intended to limit the scope of the present invention,
Therefore any subtle modifications, equivalent variations and modifications that every technical spirit according to the present invention is made to above example, still
Belong in the range of technical solution of the present invention.
Claims (2)
1. a kind of preparation method of novel environment friendly clean biometric alcohol-oil fuel, it is characterised in that：Novel environment friendly clean biometric alcohol oil
Fuel is made up of following raw material by mass percentage：
Include following steps：
(1) at normal temperatures, first silver powder, red phosphorus powder and ethyl acetate are put into container and stirred 5~10 minutes, then toward in container
Add strontium carbonate, acetone, industry glycerol and ferrocene and continue stirring 5~10 minutes, can now produce hot gas, be subsequently added into nothing
Water-ethanol and part water；
(2) whether detectable concentration, fill the solution of small component step (1) with small bowl and caught fire with open firing point, it is unsafe to catch fire,
Can only add water until point not untill；
(3) after adding nitromethane and continuing stirring 5~20 minutes, whether foregoing inspect catches fire for another example, if can not light, then
Methanol is added, the ratio for adding the water that ratio and step (1) and the step (2) of methanol are added is identical, sight in brewed 2~3 hours
It is to produce hot gas to examine, and it is that meeting nature is on fire to be produced if any hot gas, can only be added water until being produced without hot gas；
(4) solution obtained above there is into the place of safety fire all without spontaneous combustion, in use, will with plastic cement barreled stock
Remaining first alcohol and water, which adds to stir in solution obtained above, can be prepared by novel environment friendly clean biometric alcohol-oil fuel.
2. the preparation method of novel environment friendly clean biometric alcohol-oil fuel according to claim 1, it is characterised in that：Novel ring
Clean biometric alcohol-oil fuel is protected to be made up of following raw material by mass percentage：
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210327214.0A CN103666587B (en) | 2012-09-06 | 2012-09-06 | Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210327214.0A CN103666587B (en) | 2012-09-06 | 2012-09-06 | Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103666587A CN103666587A (en) | 2014-03-26 |
| CN103666587B true CN103666587B (en) | 2017-07-21 |
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| CN201210327214.0A Expired - Fee Related CN103666587B (en) | 2012-09-06 | 2012-09-06 | Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104388134B (en) * | 2014-12-12 | 2016-05-25 | 李可文 | Fuel oil additive, preparation method, the fuel oil of applying and containing this fuel oil additive |
| CN107937057A (en) * | 2017-12-04 | 2018-04-20 | 宁波高新区敦和科技有限公司 | A kind of gasoline additive and its production method comprising nanoparticle complexes |
| CN107987903A (en) * | 2017-12-30 | 2018-05-04 | 宁波高新区州致科技有限公司 | A kind of gasoline additive and its production method |
| CN110157499A (en) * | 2019-05-23 | 2019-08-23 | 贵州定北科技有限公司 | A kind of high heating value synthol oil and preparation method thereof |
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| CN1688677A (en) * | 2002-08-22 | 2005-10-26 | (株)火林Tech | A fuel composition and a device for colored flames |
| CN1718699A (en) * | 2005-04-06 | 2006-01-11 | 尹小林 | Catalytic combustion adjuvant for coal |
| CN1861763A (en) * | 2006-06-07 | 2006-11-15 | 广州市波鑫环保科技有限公司 | Water-soluble ol group liquid fuel |
| CN101270306A (en) * | 2008-05-14 | 2008-09-24 | 上海安投新能源科技有限公司 | General fuel for vehicle |
| CN102260548A (en) * | 2010-11-09 | 2011-11-30 | 永州锦溁新能源开发有限公司 | Methanol gasoline and preparation method thereof |
| CN102358853A (en) * | 2011-09-16 | 2012-02-22 | 邓群英 | Novel environmental protection and energy saving biological alcohol oil |
-
2012
- 2012-09-06 CN CN201210327214.0A patent/CN103666587B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1688677A (en) * | 2002-08-22 | 2005-10-26 | (株)火林Tech | A fuel composition and a device for colored flames |
| CN1718699A (en) * | 2005-04-06 | 2006-01-11 | 尹小林 | Catalytic combustion adjuvant for coal |
| CN1861763A (en) * | 2006-06-07 | 2006-11-15 | 广州市波鑫环保科技有限公司 | Water-soluble ol group liquid fuel |
| CN101270306A (en) * | 2008-05-14 | 2008-09-24 | 上海安投新能源科技有限公司 | General fuel for vehicle |
| CN102260548A (en) * | 2010-11-09 | 2011-11-30 | 永州锦溁新能源开发有限公司 | Methanol gasoline and preparation method thereof |
| CN102358853A (en) * | 2011-09-16 | 2012-02-22 | 邓群英 | Novel environmental protection and energy saving biological alcohol oil |
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| CN103666587A (en) | 2014-03-26 |
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Effective date of registration: 20180930 Address after: 417600 022 villager group second, Bing Tian Village, Cha Xi Town, Xinhua, Loudi, Hunan Patentee after: Ye Yongxing Address before: 523000 A102, A, Huaxing Industrial Park, Bu Xin Road, Yan Tian Village, Fenggang Town, Dongguan, Guangdong Patentee before: DONGGUAN RONGNENG ELECTRONIC SCIENCE AND TECHNOLOGY CO., LTD. |
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Granted publication date: 20170721 Termination date: 20180906 |