CN1632074A - Environmental protection type alcohol base liquid fuel - Google Patents
Environmental protection type alcohol base liquid fuel Download PDFInfo
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- CN1632074A CN1632074A CN 03104599 CN03104599A CN1632074A CN 1632074 A CN1632074 A CN 1632074A CN 03104599 CN03104599 CN 03104599 CN 03104599 A CN03104599 A CN 03104599A CN 1632074 A CN1632074 A CN 1632074A
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- China
- Prior art keywords
- ferrocene
- methyl alcohol
- mixed
- requirement
- potassium permanganate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
The invention relates to an environmental protective alcoholic group liquid fuel, belongs to a new product in energy development field, if use special burner to cracking the alcoholic group liquid fuel to be Co+H2, its heat value can be increased by 22%, without harmful gas, environmental protection and energy saving, it is an available way to use coal for saving oil.
Description
The environment-friendly type alcohol radical liquid fuel is an important invention of new forms of energy Application Areas.Methanol decomposition is that CO+H2 its calorific value that burns has improved 22% (promptly bringing up to 24500KJ/kg after the cracking by original methyl alcohol calorific value 20083KJ/kg), and it is the feasible way of coal clean utilization.Substituting diesel oil with methyl alcohol is a kind of effective ways that reduce the petroleum resources waste; It is the important measures of bringing back to life 400 little fertilizer enterprises.
1, reducing the petroleum resources waste is main contribution of the present invention
The petroleum resources shortage is global, for fighting for this resource, war takes place repeatedly, and the especially oil of that economic giant monopolization causes oily dust storm to rise, slump.This energy dilemma is the big problem of restriction Economic development after China enters the market, and therefore tapping a new source of energy and solving alternative fuel is a big problem that has strategic importance.
Show according to Hebei province's fuel main office statistic data.Year ten thousand tons of the diesel-fuel consumptions 4: 1 in eight tame power station.The stove in rural area is seen everywhere especially, to spray into diesel oil in order to light a fire convenient and to improve kiln temperature, the annual oil consumption of the stove of general scale is all wanted the hundreds of ton. according to another the Information Statistics of Tianjin industrial and commercial bureau, there is family more than 1000 in big-and-middle-sized hotel, the restaurant of this city registration, and a medium-sized hotel day: consumption diesel oil amount is all more than 250 kilograms, and only this item year is consumed tens0000 tons more than of diesel oil.Can be again how big statistical figure in the whole nation, this shows that the wasting of resources is very serious.The petroleum resources of China are not rich, and the explored amount of adopting is 23.26 hundred million tons, and a year produced quantity is 1.6 hundred million tons now, only enough exploits 20 years at this rate.Beginning in 93 years, we have become oil importers. after justing think 20 years what if? whether aircraft can also go up to the sky, and whether battleship can also oceangoing voyage, and much less the descendants how, and just we this generation people is too deep for tears probably.
In order to address the above problem the existing more than ten years history of domestic research, and the national standard of formulating alcohol-group fuel in 1997 to alcohol-group fuel.Don't you but see the big area popularization why so far? I think the location of application; Fuel and burning appliance exploitation; Three problems of policy and spin.I have developed alcohol radical liquid fuel and burner special at above problem, and first location is to solve the hotel to burn the diesel oil problem of cooking.Through repetition test, obtained mass data.And on probation among a small circle through 1 year, prove that this project is successful.
2, the present invention provides a kind of effective way for the clean utilization of coal
Along with people's Environmental awareness enhancing, all to control the toxic and harmful in the discharging, flue dust etc.Coal firing boiler is prohibited in Tianjin and many big and medium-sized cities.What burns so? the burning natural gas is not enough, and it is unfortunate to burn diesel oil.Coal resources in China is very abundant, reburns and also toos many or too much for use in 200 years.Therefore study the smart usefulness of rough coal, improve energy structure and be an important behave after the China's WTO.To this premier Zhu Rongji discuss very penetrating, be an important state basic policy.The methyl alcohol that the production liquid fuel is used is exactly the byproduct of producing coke.Because it has higher heat energy transformation efficiency, act as a fuel and use not only safety and environmental protection but also economical and practical.Therefore develop the feasible way that alcohol radical liquid fuel is the coal clean utilization.
3, producing alcohol-group fuel is the important measures of bringing back to life 400 tame little fertilizer enterprises
The seventies, domestic small fertilizer plant was thousands of, stop production now close down family more than 400 just arranged.Because methyl alcohol is the joint product of fertilizer plant, therefore develop alcohol-group fuel market and not only can save petroleum resources and can bring back to life these little fertilizer enterprises again simultaneously, create the chance of reemployment to the laid-off worker.
Claims (7)
1, the environment-friendly type alcohol radical liquid fuel that the present invention relates to is a series prescription, is according to the resource distribution situation design of different areas different industries.Formula range of the present invention (weight part %)
Inhibiter: phytic acid Viscotrol C 0.1-0.5
Main fuel: methyl alcohol (90%) 90-99
Gain of heat agent: potato spirit hydro carbons ester class coal tar 1-10
Catalyzer: ferrocene 0.002-0.005
Solubility promoter: isopropylcarbinol Virahol 0.1-1
Oxygenation agent: hydrogen peroxide 0.5-0.8
Potassium permanganate 0.0003-0.0005
Select following various prescription for use according to above-mentioned formula range and this area resources advantage.(input amount of high heating value raw material increases, and needs the input ratio of corresponding adjustment solubility promoter).
2, form example formulations one (weight %) according to the requirement of right 1
Methyl alcohol (90%) 95
Ferrocene 0.003
Isopropylcarbinol 0.5
Sherwood oil 5
Potassium permanganate 0.0004
3, form example formulations two (weight %) according to the requirement of right 1
Phytic acid 0.1-0.5
Methyl alcohol (90%) 95
Ferrocene 0.005
Virahol 0.5
Acetone 5
Potassium permanganate 0.0004
4, form example formulations three (weight %) according to the requirement of right 1
Viscotrol C 0.1-0.5
Methyl alcohol (90%) 95
Ferrocene 0.005
Acetone 0.4
No. 70 gasoline 5
Potassium permanganate 0.0005
5, form example formulations four (weight %) according to the requirement of right 1
Methyl alcohol (90%) 95
Ferrocene 0.005
Ethyl acetate 0.3
Potato spirit 5
Hydrogen peroxide (30%) 0.6
6, form example formulations five according to the requirement of right 1
Methyl alcohol (90%) 95
Ferrocene 0.005
Coal tar 0.5
Vegetables oil methyl esters 5
Potassium permanganate 0.0004
7, the prescription of the present invention technological process that is mixed is as follows
(1) first liquid adds ignition dope in the solubility promoter, be added in the gain of heat agent miscible stand-by after the dissolving again.
(2) second liquid is main fuel furnishing content methanol aqueous solution more than 90% in the jar that is mixed.
(3) in second liquid circulation is stirred, add first liquid slowly, add the oxygenation agent again after waiting to be mixed evenly, continue to stir 15 minutes, the levels survey proportion of taking a sample respectively, end is mixed when proportion is in full accord.The alcohol radical liquid fuel that has been mixed need be placed 2 hours after-filtration, packaging final prod.
(4) quality standard with the explained hereafter that originally is mixed is GB16663-1996.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03104599 CN1632074A (en) | 2002-04-15 | 2003-02-20 | Environmental protection type alcohol base liquid fuel |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN02117103 | 2002-04-15 | ||
| CN02117103.3 | 2002-04-15 | ||
| CN 03104599 CN1632074A (en) | 2002-04-15 | 2003-02-20 | Environmental protection type alcohol base liquid fuel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1632074A true CN1632074A (en) | 2005-06-29 |
Family
ID=34862411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03104599 Pending CN1632074A (en) | 2002-04-15 | 2003-02-20 | Environmental protection type alcohol base liquid fuel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1632074A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768476A (en) * | 2010-02-09 | 2010-07-07 | 上海舜天化工科技有限公司 | Clean alcohol-based fuel for industrial furnace |
| CN101921635A (en) * | 2010-09-30 | 2010-12-22 | 武汉大学 | High-oxygen-content active fuel and preparation method thereof |
| CN102382690A (en) * | 2011-09-22 | 2012-03-21 | 西北农林科技大学 | Production method of environment-friendly renewable fuel oil |
| CN102618337A (en) * | 2012-04-11 | 2012-08-01 | 韦唯 | Method for manufacturing civil fuel of biological alcohol oil |
| CN103031163A (en) * | 2011-09-30 | 2013-04-10 | 山西佳新能源化工实业有限公司 | Coal-based composite domestic fuel |
| CN104449886A (en) * | 2014-12-25 | 2015-03-25 | 山西华顿实业有限公司 | Methanol-based fuel oil with high calorific value |
| CN108034461A (en) * | 2017-12-13 | 2018-05-15 | 柳州市金升汽车配件有限公司 | Alcohols fuel oil additive and preparation method thereof |
| CN108998113A (en) * | 2018-06-14 | 2018-12-14 | 安徽大学 | A kind of monatomic cobalt-based methanol fuel and preparation method thereof |
-
2003
- 2003-02-20 CN CN 03104599 patent/CN1632074A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768476A (en) * | 2010-02-09 | 2010-07-07 | 上海舜天化工科技有限公司 | Clean alcohol-based fuel for industrial furnace |
| CN101921635A (en) * | 2010-09-30 | 2010-12-22 | 武汉大学 | High-oxygen-content active fuel and preparation method thereof |
| CN101921635B (en) * | 2010-09-30 | 2012-12-26 | 洛阳万山高新技术应用工程有限公司 | High-oxygen-content active fuel and preparation method thereof |
| CN102382690A (en) * | 2011-09-22 | 2012-03-21 | 西北农林科技大学 | Production method of environment-friendly renewable fuel oil |
| CN102382690B (en) * | 2011-09-22 | 2013-10-09 | 西北农林科技大学 | Production method of environment-friendly renewable fuel oil |
| CN103031163A (en) * | 2011-09-30 | 2013-04-10 | 山西佳新能源化工实业有限公司 | Coal-based composite domestic fuel |
| CN102618337A (en) * | 2012-04-11 | 2012-08-01 | 韦唯 | Method for manufacturing civil fuel of biological alcohol oil |
| CN104449886A (en) * | 2014-12-25 | 2015-03-25 | 山西华顿实业有限公司 | Methanol-based fuel oil with high calorific value |
| CN108034461A (en) * | 2017-12-13 | 2018-05-15 | 柳州市金升汽车配件有限公司 | Alcohols fuel oil additive and preparation method thereof |
| CN108998113A (en) * | 2018-06-14 | 2018-12-14 | 安徽大学 | A kind of monatomic cobalt-based methanol fuel and preparation method thereof |
| CN108998113B (en) * | 2018-06-14 | 2020-10-27 | 安徽大学 | Monoatomic cobalt-based methanol fuel and preparation method thereof |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |