CN108034461A - Alcohols fuel oil additive and preparation method thereof - Google Patents
Alcohols fuel oil additive and preparation method thereof Download PDFInfo
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- CN108034461A CN108034461A CN201711330579.8A CN201711330579A CN108034461A CN 108034461 A CN108034461 A CN 108034461A CN 201711330579 A CN201711330579 A CN 201711330579A CN 108034461 A CN108034461 A CN 108034461A
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
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- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
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- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
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- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/14—Organic compounds
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- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/26—Organic compounds containing phosphorus
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- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/08—Inhibitors
- C10L2230/081—Anti-oxidants
Abstract
The invention discloses alcohols fuel oil additive and preparation method thereof, belongs to fuel oil additive technical field.The alcohols fuel oil additive of the present invention is made of the raw material of following weight parts：15 25 parts of fusel oil, 10 15 parts of combustion value reinforcing agent, 5 10 parts of stabilizer, 36 parts of neutralizer, 25 parts of solubilizer, anti-3 5 parts of sweller；26 parts of antioxidizing and antigum agent.The raw material of the present invention is stirred mixing by certain order of addition and condition, you can obtains alcohols fuel oil additive.The calorific value that can solve in existing alcohols motor vehicle fuel of the present invention is low, and each raw material mixes bad, and fuel chance water is easily layered, and alcohols has corrosivity, the problems such as easily producing colloid when having swelling, use to rubber.Preparation method of the present invention is simple, and cost is low, easy to use, environmental-friendly, economically feasible, as the substitute fuel of gasoline, can solve the problems, such as the petroleum-based energy of increasingly depleted.
Description
Technical field
The invention belongs to the technical field of fuel oil additive, and in particular to alcohols fuel oil additive and preparation method thereof.
Background technology
At present, the petroleum resources in the world are reduced increasingly, and oil-fired shortage phenomenon has occurred, and getting worse.
With the sustainable growth of car ownership, huge fuel consumption not only causes huge pressure to the petroleum-based energy of increasingly depleted
Power, meanwhile, the toxin gas of pollution environment is easily produced after fuel oil burning, improper the discharged pollutant of great amount of fuel oil burning is
As the principal element for threatening human survival.The Aalcohols fuels such as methanol, ethanol are with CH3OH、CH2H5OH and polyalcohol are main
Raw material, is aided with a kind of miscible liquid fuel of surfactant.Aalcohols fuel is a kind of regenerated raw material, it can from grain,
Refine or synthesize in the raw materials such as timber, coal, plant straw, natural gas, potato.Alcohols feedstock is produced with commercial run,
There is the technical foundation of maturation both at home and abroad.Aalcohols fuel is the mixture of hydrocarbon and hydroxyl composition, can be significantly from molecule composition
To find out, alcohols possesses the molecule identical with hydro carbons and forms, and no matter from raw material sources and cost, Aalcohols fuel and stone
Oily (hydro carbons) fuel is compared, and has great competitive advantage, therefore Aalcohols fuel is considered a kind of promising, clear of internal combustion engine
Clean substitute fuel.
And in the Aalcohols fuel developed at present, it is common to use method be to add a certain proportion of alcohols in the oil
It is made alcohol gasoline fuel, and this kind of alcohol gasoline fuel is also there are various problems, as fuel value is low, each raw material mixes not
Good, fuel is met water and is easily layered, and alcohols has corrosivity, there is swelling etc. to rubber.
In addition, alcohol gasoline fuel of the prior art also there are oxidation stability it is poor the problem of.Oxidation stability of fuel
It is poor then during storage and use easily occur oxidation reaction, it may appear that the phenomenon for the thick sediment that darkens, generates,
Colloid, carbon distribution are easily produced in combustion.This will cause automobile serious harm, such as：In fuel tank, strainer, vaporization
Sticky jelly is formed in device, atomizer can be blocked when serious, interrupts fuel feeding；It is deposited on colloid on spark plug at high temperature
Carbon deposit can be formed and cause short circuit；Meeting coking on inlet and outlet valve is deposited on, causes valve to be not closed completely, or even block valve
It is allowed to complete failure；Carbon deposit will be formed by being deposited on cylinder head and piston, be caused cylinder heat dissipation bad, temperature rise, be produced table
Face is burnt or phenomenon of detonation, reduces engine power, increases fuel consumption, engine abnormal noise, idling occurs in cold and hot car when serious
Shake, power wretched insufficiency, or even engine can not start.
Meanwhile Aalcohols fuel imperfect combustion easily forms unconventional pollutant effulent, such as aldehydes (formaldehyde) and acids (first
Acid etc.).The discharge of aldehydes is higher than the discharge of regular price gasoline car, be easy to cause automobile three-way catalysts poisoning solubilising；Acids is to rubber
Plastics also have corrosion colloidal sol effect, and many components of engine fuel system are all made of rubber, plastic or other material, the corruption of formic acid
Erosion colloidal sol has been easily reduced the service life of some components.After Aalcohols fuel is contacted with water, layering is easily produced, makes Aalcohols fuel
It is unable to normal combustion.Problem above fails to be solved very well in the prior art.
The content of the invention
The purpose of the present invention is for solve the above-mentioned problems in the prior art, there is provided a kind of alcohols fuel oil additive and
Its preparation method.Aalcohols fuel additive provided by the invention using when be directly added into fuel oil, application method is simple.
To reach above-mentioned purpose, the technical solution adopted by the present invention is as follows：
Alcohols fuel oil additive, is made of the raw material of following weight parts：15-25 parts of fusel oil, combustion value reinforcing agent 10-15
Part, 5-10 parts of stabilizer, 3-6 parts of neutralizer, 2-5 parts of solubilizer, anti-sweller 3-5 parts；2-6 parts of antioxidizing and antigum agent；
The combustion value reinforcing agent is made of the raw material of following weight parts：5~9 parts of trinitrophenol, 5~6 parts of potassium permanganate
Or trinitrophenol, potassium permanganate is any；
The stabilizer is dimethyl ether or isopropanol；
The neutralizer is alkaline amine：Aniline, methylamine, triphenylamine it is any；
The solubilizer is fatty glyceride, lecithin, triethanolamine oleate, any of castor oil polyoxyethylene ether
Kind；
The anti-sweller is lactic acid or tartaric acid；
The antioxidizing and antigum agent is alkyl phenol.
In above-mentioned technical proposal, preferably, being made of the raw material of following weight parts：16-20 parts of fusel oil, combustion value enhancing
10-12 parts of agent, 5-8 parts of stabilizer, 3-4 parts of neutralizer, 2-3 parts of solubilizer, anti-sweller 3-4 parts；3-5 parts of antioxidizing and antigum agent.
Preferably, the antioxidizing and antigum agent alkyl phenol is 2,6-di-tert-butyl p-cresol or 2,6- in above-mentioned technical proposal
Di-tert-butyl-4-methy phenol.
In above-mentioned technical proposal, preferably, being made of the raw material of following weight parts：18 parts of fusel oil, trinitrophenol
10 parts, 6 parts of dimethyl ether, 3 parts of methylamine, 3 parts of castor oil polyoxyethylene ether, 4 parts of tartaric acid；4 parts of 2,6-di-tert-butyl p-cresol.
The preparation method of above-mentioned alcohols fuel oil additive, it is characterised in that include the following steps：
(1) fusel oil and antioxidizing and antigum agent are weighed according to parts by weight, stirred evenly, obtain mixed solution A；
(2) stabilizer is added into the mixed solution A obtained by step (1), stirred evenly, obtain mixed solution B；
(3) anti-sweller and neutralizer are added into the mixed solution B obtained by step (2), is stirred evenly, obtains mixing molten
Liquid C；
(4) combustion value reinforcing agent is added into the mixed solution C obtained by step (3), stirs evenly, obtains mixed solution D；
(5) solubilizer is added into the mixed solution D obtained by step (4), stirred evenly, you can obtain the addition of alcohols fuel oil
Agent.
In above-mentioned technical proposal, preferably, in the step (1), the temperature in whipping process is 40~50 DEG C, stirring
Time is 15~20min.
In above-mentioned technical proposal, preferably, in the step (2), the temperature in whipping process is 40~50 DEG C, stirring
Time is 10~15min.
In above-mentioned technical proposal, preferably, in the step (3), the temperature in whipping process is 55~60 DEG C, stirring
Time is 30~40min.
In above-mentioned technical proposal, preferably, in the step (4), the temperature in whipping process is 30~40 DEG C, stirring
Time is 10~20min.
In above-mentioned technical proposal, preferably, in the step (5), the temperature in whipping process is 30~40 DEG C, stirring
Time is 15~20min.
The fusel oil added in the present invention, is the Main By product of the fermented ethanol production of cereal crops and beer, is come
Source is wide, cheap.Fusel oil can not only improve the calorific value of fuel oil, and can be being played each raw material when fuel oil is reconciled
The effect of solubilising, makes each raw material mix each other evenly, in stable condition after mixing, is not in layering or deposited phenomenon.
In the present invention, combustion value reinforcing agent selection trinitrophenol or potassium permanganate.Aalcohols fuel is generally by adding at present
Add combustion adjuvant to improve the calorific value of fuel, common combustion adjuvant is mainly ferrocene metallic addition, it can after adding in gasoline
The octane number of gasoline is improved, plays lifting engine combustion efficiency and ignition temperature, increase engine in-cylinder pressure and raising are sent out
The effect of motivation power.But the metallic addition such as ferrocene can produce engine larger harm, so not recommending
's.Trinitrophenol in the present invention as motor vehicle fuel combustion value reinforcing agent there is elevated oxygen level, excellent raising octane number to make
With, without phase separation, low toxicity and the property such as rapid biodegradability, the trinitro- for making motor vehicle fuel be used when reaching equal oxygen content
About 2 times fewer than common methyl tertiary butyl ether(MTBE) (MTBE) of the amount of phenol, so as to reduce car tail hydrocarbon in gas, an oxygen
The shortcomings that changing the total emission volumn of carbon and formaldehyde, also overcoming common gasoline additive soluble easily in water, polluted underground water source in addition.It is excellent
Trinitrophenol and potassium permanganate matching cooperation combustion value reinforcing agent are selected, more abundant, more environmentally friendly, the combustion-supporting effect of fuel oil burning can be made
Become apparent from, and the not over-emitting black exhaust that burns, and the reduction of the discharge capacity of nitrogen oxides and soot particle can be made.
In the present invention, stabilizer selection dimethyl ether and isopropanol, both be used cooperatively can make fuel continual and steady
Burning, makes engine working stability, is not in phenomenon of detonation, and work noise is small.
In the present invention, neutralizer selects alkaline amine such as aniline, methylamine or triphenylamine.It can be produced after alcohols automobile burning
A small amount of aldehydes (such as formaldehyde) or acids (formic acid), therefore there is certain corrosivity and swellability.The present invention is by a certain amount of
The addition of aniline, methylamine or triphenylamine uses, and can effectively neutralize the above-mentioned material that corrosion or swelling are produced to rubber, prevent
Automobile component is corroded, and ensures the normal use of automobile, extends the service life of automobile.
In the present invention, solubilizer selected fatty acid glyceride, lecithin, triethanolamine oleate or castor oil polyoxyethylene
Ether.Because of the easily water absorption character of Aalcohols fuel, when temperature reduction or lighter hydrocarbons solvent naphtha and other auxiliary agents necessarily refer to because moisture content exceedes
After mark, easily there is liquid phase separation, so as to cause the normal use for influencing fuel, above solubilizer can be in alcohols motor vehicle fuel
Water emulsified, make to wrap up in one layer of oil film outside each small water droplet, make ethanol petrol be not susceptible to be separated, there is significant solubilising
Effect, prevents fuel stratification, ensures normal combustion and the use of fuel.
In the present invention, anti-sweller selects lactic acid or tartaric acid, in alcohols motor vehicle fuel, aromatic hydrocarbon, alcohol ethers
Material has rubber stronger swelling action, can make various to touch the rubber containing such (aromatic hydrocarbons, alcohol ether) oil product over time
Product (sealing ring, pad, container) is swollen, and oil leak, clogging occur when serious.Organic acid more than addition trace binary-component is such as
Nicotinic acid, lactic acid and tartaric acid etc., can effectively improve anti-swelling and cold resistance at the same time.
In the present invention, antioxidizing and antigum agent is alkyl phenol, selects 2,6-di-tert-butyl p-cresol or 2,6- di-t-butyl -4-
Methylphenol.
Induction period is that one of index of Fuel Petroleum oxidation stability is evaluated under the conditions of accelerated oxidation, it represents automobile-used combustion
Oil oxidation and gumming tendency in storage.Generally, it is considered that the induction period of fuel oil is longer, its gumming tendency is got over
Small, anti-oxidative stability is better.But and not all fuel oil is all in this way, oxidation, which occurs, for the gasoline of different chemical compositions forms colloid
Process difference is very big.Some Fuel Petroleums form the process of colloid based on the oxidation reaction of oxygen uptake, its induction period can reflect oil
The storage stability of product.But some Fuel Petroleums form the process of colloid be condensed with polymerisation based on, its induction period is just not
It can truly reflect the storage stability of oil product.
The present invention in fuel oil by adding antioxidizing and antigum agent 2,6-di-tert-butyl p-cresol or 2,6- di-t-butyl -4- first
Base phenol prevents colloid from generating to extend breakdown time.This antioxidizing and antigum agent has excellent free radical and desulfurization performance,
It can not only control the generation of colloid, while can effectively extend induction period, can stablize the mixed antioxidant of fuel oil, and efficiency is remote
Super common T501 antioxidant.This antioxidizing and antigum agent can effectively prevent olefin oxidation be especially suitable for alcohols fuel oil additive
Gel is produced, so as to produce carbon deposit at positions such as combustion chamber, piston top, cylinder covers during avoiding oil product use.With other amine
Kind antioxidant is compared, this antioxidizing and antigum agent dosage is few, antioxidant effect is good, can not only effectively protect automobile component, extends vapour
The car service life, and environmental pollution can be greatly reduced.
Alcohols fuel oil additive provided by the invention is added directly into fuel oil especially suitable for alcohols vehicle fuel
Use, additive amount preferred mass ratio is alcohols fuel oil additive：Alcohols fuel oil=0.1~1:100.In addition, this alcohols fuel oil adds
Agent is added to be also applied for common gasoline.
Beneficial effect：Alcohols fuel oil additive provided by the invention specially to automobile Aalcohols fuel development, has following excellent
Point：
(1) alcohols fuel oil additive of the invention contains suitable solubilizer, and the resisting phase separation that can greatly improve fuel oil is made
With, and stability is good, and phase separation and deposited phenomenon also do not occur for storage for a long time, and what solution alcohols fuel oil was easily layered asks
Topic, present invention addition can fully ensure the burning using effect of fuel oil in alcohols fuel oil.
(2) present invention after lactic acid or tartaric acid add Aalcohols fuel, can make vapour by adding a certain amount of anti-sweller
The in-car extent of corrosion of metal parts and the corrosion degree of swelling of rubber member all drops to very low scope, and anti-swelling effect is good, energy
Effectively prevent the swelling of the rubber components in automobile, ensure the normal operation of automobile, extend motor live time.
(3) the combustion value reinforcing agent in the present invention can solve the problems, such as that the combustion heat value of alcohols fuel oil is low, and can directly make
With, it is not necessary to any change is done to engine, there is the characteristics of stability is good, dynamic property is strong, and oil consumption is few, with the addition of the present invention
Fuel contrast regular gasoline, oil consumption more than 10% can be reduced.
(4) alcohols fuel oil additive of the invention contains suitable antioxidizing and antigum agent, can effectively prevent fuel oil from oxygen occurs
Change reaction, avoid generating the phenomenon of thick sediment, substantially reduce situations such as producing colloid, carbon distribution, reduce colloid to vapour
Harm caused by car, extends motor live time.
(5) present invention provides specific components and proportioning, can make the more preferable of each raw material mixing by special technique and make
Co-operating effect is produced between each raw material, makes the various aspects of performance of alcohols fuel oil more excellent.The preparation method of the present invention is simple
Easy, special installation is not required in process, can reduce cost.The present invention can be added directly into fuel oil and use, convenient and simple,
Significant effect, the performance that fuel oil adds each side after this additive are obviously improved, can solve existing for current alcohols motor vehicle fuel
Various problems, and environmental-friendly, economically feasible, as the substitute fuel of gasoline, can solve the oil energy of increasingly depleted
Source problem.
Embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
Alcohols fuel oil additive, is made of the raw material of following weight parts：18 parts of fusel oil, 8 parts of trinitrophenol, permanganic acid
5 parts of potassium, 6 parts of dimethyl ether, 3 parts of methylamine, 3 parts of castor oil polyoxyethylene ether, 4 parts of 2,6-di-tert-butyl p-cresol, tartaric acid 4
Part.
The preparation method of above-mentioned alcohols fuel oil additive, includes the following steps：
(1) fusel oil and antioxidizing and antigum agent are weighed according to parts by weight, stirred evenly, the temperature in whipping process is 45
DEG C, mixing time 20min, obtains mixed solution A；
(2) stabilizer is added into the mixed solution A obtained by step (1), stirred evenly, the temperature in whipping process is 50
DEG C, mixing time 10min, obtains mixed solution B；
(3) anti-sweller and neutralizer are added into the mixed solution B obtained by step (2), is stirred evenly, in whipping process
Temperature be 55 DEG C, mixing time 30min, obtains mixed solution C；
(4) combustion value reinforcing agent is added into the mixed solution C obtained by step (3), is stirred evenly, the temperature in whipping process
For 35 DEG C, mixing time 15min, obtains mixed solution D；
(5) solubilizer is added into the mixed solution D obtained by step (4), stirred evenly, the temperature in whipping process is 40
DEG C, mixing time 15min, you can obtain alcohols fuel oil additive.
Alcohols fuel oil is tested after preparation-obtained alcohols fuel oil additive is added alcohols fuel oil, the ratio of addition
Example (weight) is alcohols fuel oil additive：Alcohols fuel oil=0.2：100, result of the test is shown in Table 1.
Table 1
As it can be seen from table 1 it with the addition of the alcohols fuel oil each side for the alcohols fuel oil additive that the present embodiment is prepared
Can preferably, alternative to gasoline uses.
Test to colloid retention amount：100g is taken to the addition of the alcohols fuel oil of this alcohols fuel oil additive and do not add respectively
Add the alcohols fuel oil of alcohols fuel oil additive to burn, take the material to burn incompletely to weigh after burning, obtain colloid retention amount, do
More than three times, it is averaged, obtaining colloid retention amount is：The alcohols fuel oil 1.0mg of this alcohols fuel oil additive is with the addition of, is not added
Add the alcohols fuel oil 5.3mg of alcohols fuel oil additive.And gum level is no more than 5 milligrams in 100 grams of gasoline of national regulation, because
This remaining colloid of part burning can become carbon deposit so as to influence the use of automobile component.The present embodiment is with the addition of to be prepared
The obtained colloid amount retained of fuel oil test of additive be far below the colloid amount retained of the fuel oil for being not added with this additive, it is and low
In national standard, therefore the significant effect of the anti-glue of this additive antioxygen.
Embodiment 2
Alcohols fuel oil additive, is made of the raw material of following weight parts：15 parts of fusel oil, 11 parts of trinitrophenol, isopropyl
8 parts of alcohol, 3 parts of triphenylamine, 4 parts of lecithin, 3 parts of tartaric acid；5 parts of 2,6-di-tert-butyl p-cresol.
The preparation method of above-mentioned alcohols fuel oil additive, includes the following steps：
(1) fusel oil and antioxidizing and antigum agent are weighed according to parts by weight, stirred evenly, the temperature in whipping process is 40
DEG C, mixing time 20min, obtains mixed solution A；
(2) stabilizer is added into the mixed solution A obtained by step (1), stirred evenly, the temperature in whipping process is 45
DEG C, mixing time 10min, obtains mixed solution B；
(3) anti-sweller and neutralizer are added into the mixed solution B obtained by step (2), is stirred evenly, in whipping process
Temperature be 60 DEG C, mixing time 30min, obtains mixed solution C；
(4) combustion value reinforcing agent is added into the mixed solution C obtained by step (3), is stirred evenly, the temperature in whipping process
For 38 DEG C, mixing time 12min, obtains mixed solution D；
(5) solubilizer is added into the mixed solution D obtained by step (4), stirred evenly, the temperature in whipping process is 35
DEG C, mixing time 20min, you can obtain alcohols fuel oil additive.
Alcohols fuel oil is tested after preparation-obtained alcohols fuel oil additive is added alcohols fuel oil, the ratio of addition
Example (weight) is alcohols fuel oil additive：Alcohols fuel oil=0.4：100, result of the test is shown in Table 2.
Table 2
From table 2 it can be seen that it with the addition of the alcohols fuel oil each side for the alcohols fuel oil additive that the present embodiment is prepared
Can preferably, alternative to gasoline uses.
Test to colloid retention amount：100g is taken to the addition of the alcohols fuel oil of this alcohols fuel oil additive and do not add respectively
Add the alcohols fuel oil of alcohols fuel oil additive to burn, take the material to burn incompletely to weigh after burning, obtain colloid retention amount, do
More than three times, it is averaged, obtaining colloid retention amount is：The alcohols fuel oil 1.5mg of this alcohols fuel oil additive is with the addition of, is not added
Add the alcohols fuel oil 5.2mg of alcohols fuel oil additive.The fuel oil test that with the addition of the additive that the present embodiment is prepared obtains
Colloid amount retained be far below the colloid amount retained of the fuel oil for being not added with this additive, and be less than national standard, therefore this addition
The significant effect of the anti-glue of agent antioxygen.
Embodiment 3
Alcohols fuel oil additive, is made of the raw material of following weight parts：20 parts of fusel oil, 10 parts of potassium permanganate, dimethyl
9 parts of ether, 3-6 parts of methylamine, 2-5 parts of triethanolamine oleate, 3-5 parts of lactic acid；2-6 parts of 2,6-di-tert-butyl p-cresol.
The preparation method of above-mentioned alcohols fuel oil additive, includes the following steps：
(1) fusel oil and antioxidizing and antigum agent are weighed according to parts by weight, stirred evenly, the temperature in whipping process is 50
DEG C, mixing time 15min, obtains mixed solution A；
(2) stabilizer is added into the mixed solution A obtained by step (1), stirred evenly, the temperature in whipping process is 40
DEG C, mixing time 12min, obtains mixed solution B；
(3) anti-sweller and neutralizer are added into the mixed solution B obtained by step (2), is stirred evenly, in whipping process
Temperature be 60 DEG C, mixing time 32min, obtains mixed solution C；
(4) combustion value reinforcing agent is added into the mixed solution C obtained by step (3), is stirred evenly, the temperature in whipping process
For 36 DEG C, mixing time 18min, obtains mixed solution D；
(5) solubilizer is added into the mixed solution D obtained by step (4), stirred evenly, the temperature in whipping process is 32
DEG C, mixing time 20min, you can obtain alcohols fuel oil additive.
Alcohols fuel oil is tested after preparation-obtained alcohols fuel oil additive is added alcohols fuel oil, the ratio of addition
Example (weight) is alcohols fuel oil additive：Alcohols fuel oil=0.5：100, result of the test is shown in Table 3.
Table 3
From table 3 it can be seen that it with the addition of the alcohols fuel oil each side for the alcohols fuel oil additive that the present embodiment is prepared
Can preferably, alternative to gasoline uses.
Test to colloid retention amount：100g is taken to the addition of the alcohols fuel oil of this alcohols fuel oil additive and do not add respectively
Add the alcohols fuel oil of alcohols fuel oil additive to burn, take the material to burn incompletely to weigh after burning, obtain colloid retention amount, do
More than three times, it is averaged, obtaining colloid retention amount is：The alcohols fuel oil 1.3mg of this alcohols fuel oil additive is with the addition of, is not added
Add the alcohols fuel oil 5.4mg of alcohols fuel oil additive.The fuel oil test that with the addition of the additive that the present embodiment is prepared obtains
Colloid amount retained be far below the colloid amount retained of the fuel oil for being not added with this additive, and be less than national standard, therefore antioxygen is prevented
The significant effect of glue.
Embodiment 4
Alcohols fuel oil additive, is made of the raw material of following weight parts：15 parts of fusel oil, 12 parts of trinitrophenol, isopropyl
5 parts of alcohol, 4 parts of aniline, 3 parts of fatty glyceride, 2,6- 6 parts of di-tert-butyl-4-methy phenols, 5 parts of tartaric acid.
The preparation method of above-mentioned alcohols fuel oil additive, includes the following steps：
(1) fusel oil and antioxidizing and antigum agent are weighed according to parts by weight, stirred evenly, the temperature in whipping process is 50
DEG C, mixing time 15min, obtains mixed solution A；
(2) stabilizer is added into the mixed solution A obtained by step (1), stirred evenly, the temperature in whipping process is 45
DEG C, mixing time 12min, obtains mixed solution B；
(3) anti-sweller and neutralizer are added into the mixed solution B obtained by step (2), is stirred evenly, in whipping process
Temperature be 55 DEG C, mixing time 35min, obtains mixed solution C；
(4) combustion value reinforcing agent is added into the mixed solution C obtained by step (3), is stirred evenly, the temperature in whipping process
For 40 DEG C, mixing time 10min, obtains mixed solution D；
(5) solubilizer is added into the mixed solution D obtained by step (4), stirred evenly, the temperature in whipping process is 30
DEG C, mixing time 20min, you can obtain alcohols fuel oil additive.
Alcohols fuel oil is tested after preparation-obtained alcohols fuel oil additive is added alcohols fuel oil, the ratio of addition
Example (weight) is alcohols fuel oil additive：Alcohols fuel oil=0.6：100, result of the test is shown in Table 4.
Table 4
From table 4, it can be seen that it with the addition of the alcohols fuel oil each side for the alcohols fuel oil additive that the present embodiment is prepared
Can preferably, alternative to gasoline uses.
Test to colloid retention amount：100g is taken to the addition of the alcohols fuel oil of this alcohols fuel oil additive and do not add respectively
Add the alcohols fuel oil of alcohols fuel oil additive to burn, take the material to burn incompletely to weigh after burning, obtain colloid retention amount, do
More than three times, it is averaged, obtaining colloid retention amount is：The alcohols fuel oil 1.2mg of this alcohols fuel oil additive is with the addition of, is not added
Add the alcohols fuel oil 5.5mg of alcohols fuel oil additive.
Colloid amount retained that the fuel oil test of the additive that the present embodiment is prepared obtains be with the addition of far below being not added with
The colloid amount retained of the fuel oil of this additive, and it is less than national standard, therefore the significant effect of the anti-glue of this additive antioxygen.
Embodiment 5
Alcohols fuel oil additive, is made of the raw material of following weight parts：25 parts of fusel oil, 9 parts of trinitrophenol, permanganic acid
6 parts of potassium, 10 parts of isopropanol, 6 parts of triphenylamine, 5 parts of castor oil polyoxyethylene ether, 5 parts of lactic acid；2,6- di-t-butyl -4- methylbenzenes
5 parts of phenol.
The preparation method of above-mentioned alcohols fuel oil additive, includes the following steps：
(1) fusel oil and antioxidizing and antigum agent are weighed according to parts by weight, stirred evenly, the temperature in whipping process is 42
DEG C, mixing time 16min, obtains mixed solution A；
(2) stabilizer is added into the mixed solution A obtained by step (1), stirred evenly, the temperature in whipping process is 47
DEG C, mixing time 14min, obtains mixed solution B；
(3) anti-sweller and neutralizer are added into the mixed solution B obtained by step (2), is stirred evenly, in whipping process
Temperature be 57 DEG C, mixing time 33min, obtains mixed solution C；
(4) combustion value reinforcing agent is added into the mixed solution C obtained by step (3), is stirred evenly, the temperature in whipping process
For 36 DEG C, mixing time 15min, obtains mixed solution D；
(5) solubilizer is added into the mixed solution D obtained by step (4), stirred evenly, the temperature in whipping process is 32
DEG C, mixing time 20min, you can obtain alcohols fuel oil additive.
Alcohols fuel oil is tested after preparation-obtained alcohols fuel oil additive is added alcohols fuel oil, the ratio of addition
Example (weight) is alcohols fuel oil additive：Alcohols fuel oil=0.3：100, result of the test is shown in Table 5.
Table 5
As can be seen from Table 5, it with the addition of the alcohols fuel oil each side for the alcohols fuel oil additive that the present embodiment is prepared
Can preferably, alternative to gasoline uses.
Test to colloid retention amount：100g is taken to the addition of the alcohols fuel oil of this alcohols fuel oil additive and do not add respectively
Add the alcohols fuel oil of alcohols fuel oil additive to burn, take the material to burn incompletely to weigh after burning, obtain colloid retention amount, do
More than three times, it is averaged, obtaining colloid retention amount is：The alcohols fuel oil 1.1mg of this alcohols fuel oil additive is with the addition of, is not added
Add the alcohols fuel oil 5.3mg of alcohols fuel oil additive.It with the addition of the fuel oil colloid retention amount for the additive that the present embodiment is prepared into
Low, antioxygen anti-glue property is good.
Although the present invention is disclosed as above with preferred embodiment, so it is not intended to limiting the invention, any this area skill
Art personnel, without departing from the spirit and scope of the present invention, when a little modification and perfect, therefore the protection model of the present invention can be made
Enclose to work as and be subject to what claims were defined.
Claims (10)
1. alcohols fuel oil additive, it is characterised in that be made of the raw material of following weight parts：15-25 parts of fusel oil, combustion value enhancing
10-15 parts of agent, 5-10 parts of stabilizer, 3-6 parts of neutralizer, 2-5 parts of solubilizer, anti-sweller 3-5 parts；2-6 parts of antioxidizing and antigum agent；
The combustion value reinforcing agent is made of the raw material of following weight parts：5~9 parts of trinitrophenol, 5~6 parts of potassium permanganate or three
Nitrophenol, potassium permanganate it is any；
The stabilizer is dimethyl ether or isopropanol；
The neutralizer is alkaline amine：Aniline, methylamine, triphenylamine it is any；
The solubilizer for fatty glyceride, lecithin, triethanolamine oleate, castor oil polyoxyethylene ether it is any；
The anti-sweller is lactic acid or tartaric acid；
The antioxidizing and antigum agent is alkyl phenol.
2. alcohols fuel oil additive as claimed in claim 1, it is characterised in that be made of the raw material of following weight parts：Fusel
It is 16-20 parts oily, 10-12 parts of combustion value reinforcing agent, 5-8 parts of stabilizer, 3-4 parts of neutralizer, 2-3 parts of solubilizer, anti-sweller 3-4
Part；3-5 parts of antioxidizing and antigum agent.
3. alcohols fuel oil additive as claimed in claim 2, it is characterised in that：The antioxidizing and antigum agent alkyl phenol is 2,6- bis-
Butylated Hydroxytoluene or 2,6- di-tert-butyl-4-methy phenol.
4. alcohols fuel oil additive as claimed in claim 3, it is characterised in that be made of the raw material of following weight parts：Fusel
18 parts of oil, 10 parts of trinitrophenol, 6 parts of dimethyl ether, 3 parts of methylamine, 3 parts of castor oil polyoxyethylene ether, 4 parts of tartaric acid；2,6-
4 parts of di-tert-butyl p-cresol.
5. the preparation method of the alcohols fuel oil additive described in a kind of claim 1, it is characterised in that include the following steps：
(1) fusel oil and antioxidizing and antigum agent are weighed according to parts by weight, stirred evenly, obtain mixed solution A；
(2) stabilizer is added into the mixed solution A obtained by step (1), stirred evenly, obtain mixed solution B；
(3) anti-sweller and neutralizer are added into the mixed solution B obtained by step (2), stirs evenly, obtains mixed solution C；
(4) combustion value reinforcing agent is added into the mixed solution C obtained by step (3), stirs evenly, obtains mixed solution D；
(5) solubilizer is added into the mixed solution D obtained by step (4), stirred evenly, you can obtain alcohols fuel oil additive.
6. the preparation method of Aalcohols fuel additive as claimed in claim 5, it is characterised in that：In the step (1), stirring
During temperature be 40~50 DEG C, mixing time is 15~20min.
7. the preparation method of alcohols fuel oil additive as claimed in claim 5, it is characterised in that：In the step (2), stirring
During temperature be 40~50 DEG C, mixing time is 10~15min.
8. the preparation method of alcohols fuel oil additive as claimed in claim 5, it is characterised in that：In the step (3), stirring
During temperature be 55~60 DEG C, mixing time is 30~40min.
9. the preparation method of alcohols fuel oil additive as claimed in claim 5, it is characterised in that：In the step (4), stirring
During temperature be 30~40 DEG C, mixing time is 10~20min.
10. the preparation method of alcohols fuel oil additive as claimed in claim 5, it is characterised in that：In the step (5), stir
Temperature during mixing is 30~40 DEG C, and mixing time is 15~20min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111534336A (en) * | 2020-05-13 | 2020-08-14 | 大容新能源科技(深圳)有限公司 | Alcohol-based liquid fuel |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632074A (en) * | 2002-04-15 | 2005-06-29 | 张鹏飞 | Environmental protection type alcohol base liquid fuel |
| CN101119890A (en) * | 2005-02-11 | 2008-02-06 | 贝尔直升机泰克斯特龙公司 | Dual motor dual concentric valve |
| CN101323800A (en) * | 2008-07-25 | 2008-12-17 | 西安祺祥能源科技发展有限公司 | Stable synergistic of methanol gasoline for vehicle |
| CN101392203A (en) * | 2008-09-28 | 2009-03-25 | 梁千豪 | High efficiency environment friendly fuel for vehicle |
| CN101880554A (en) * | 2010-07-30 | 2010-11-10 | 郑德明 | Alcohol liquid fuel and preparation method thereof |
| CN102061198A (en) * | 2010-12-26 | 2011-05-18 | 西安市尚华科技开发有限责任公司 | Clean gasoline |
| CN102604694A (en) * | 2012-03-23 | 2012-07-25 | 田强 | Methanol gasoline additive and methanol gasoline containing additive thereof |
| CN107267228A (en) * | 2017-07-08 | 2017-10-20 | 湖北文理学院 | A kind of composite gasoline |
-
2017
- 2017-12-13 CN CN201711330579.8A patent/CN108034461A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632074A (en) * | 2002-04-15 | 2005-06-29 | 张鹏飞 | Environmental protection type alcohol base liquid fuel |
| CN101119890A (en) * | 2005-02-11 | 2008-02-06 | 贝尔直升机泰克斯特龙公司 | Dual motor dual concentric valve |
| CN101323800A (en) * | 2008-07-25 | 2008-12-17 | 西安祺祥能源科技发展有限公司 | Stable synergistic of methanol gasoline for vehicle |
| CN101392203A (en) * | 2008-09-28 | 2009-03-25 | 梁千豪 | High efficiency environment friendly fuel for vehicle |
| CN101880554A (en) * | 2010-07-30 | 2010-11-10 | 郑德明 | Alcohol liquid fuel and preparation method thereof |
| CN102061198A (en) * | 2010-12-26 | 2011-05-18 | 西安市尚华科技开发有限责任公司 | Clean gasoline |
| CN102604694A (en) * | 2012-03-23 | 2012-07-25 | 田强 | Methanol gasoline additive and methanol gasoline containing additive thereof |
| CN107267228A (en) * | 2017-07-08 | 2017-10-20 | 湖北文理学院 | A kind of composite gasoline |
Non-Patent Citations (2)
| Title |
|---|
| 刘友平: "《实验室管理与安全》", 30 September 2014, 中国医药科技出版社 * |
| 王九等: "《石油产品添加剂基础知识》", 31 October 2009, 中国石化出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111534336A (en) * | 2020-05-13 | 2020-08-14 | 大容新能源科技(深圳)有限公司 | Alcohol-based liquid fuel |
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Application publication date: 20180515 |