CN103666587A - Novel environment-friendly and clean biological alcohol-oil fuel and preparation method thereof - Google Patents
Novel environment-friendly and clean biological alcohol-oil fuel and preparation method thereof Download PDFInfo
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- CN103666587A CN103666587A CN201210327214.0A CN201210327214A CN103666587A CN 103666587 A CN103666587 A CN 103666587A CN 201210327214 A CN201210327214 A CN 201210327214A CN 103666587 A CN103666587 A CN 103666587A
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Abstract
The invention discloses a novel environment-friendly and clean biological alcohol-oil fuel and a preparation method thereof. The novel environment-friendly and clean biological alcohol-oil fuel is prepared from the following raw materials by mass percent: 78 to 90% of methanol, 8 to 20% of water, 0.058 to 0.178% of silver powder, 0.058 to 0.178% of red phosphorus powder, 0.058 to 0.178% of ethyl acetate, 0.024 to 0.144% of strontium carbonate, 0.058 to 0.178% of acetone, 0.179 to 0.479% of technical glycerine, 0.058 to 0.178% of ferrocene, 0.058 to 0.178% of nitromethane, 0.179 to 0.479% of absolute ethyl alcohol; the sum of the raw materials in mass percent reaches 100%. The preparation method comprises the following steps: adding the silver powder, the red phosphorus powder and ethyl acetate to a vessel and agitating for 5 to 10 minutes at normal temperature; adding strontium carbonate, acetone, technical glycerine and ferrocene to the vessel; continuously agitating for 5 to 10 minutes, wherein hot gas is produced at the same time; adding absolute ethyl alcohol and partial water; then adding methanol and the rest water to obtain the novel environment-friendly and clean biological alcohol-oil fuel. The novel environment-friendly and clean biological alcohol-oil fuel has the advantages of being high in calorific value, sufficient in combustion, free from black smoke, carbon deposit and residue, low in exhaust emission specific flow after combustion, in capable of blackening the bottom of a pot, and the like.
Description
Technical field
The present invention relates to fuel art, refer in particular to a kind of novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof.
Background technology
Fuel is widely used in industrial and agricultural production and people's lives, the material that can give off energy by chemistry or physical reaction (comprising reaction).Fuel has many kinds, modal as coal, coke, liquefied gas, diesel oil etc.Along with scientific and technological development, the mankind are development and utilization fuel more reasonably, and pursue environmental protection concept as far as possible.Fuel is also a part of content that needs study in physics, and its formula of inhaling heat release is q=Q/m.
Owing to being becoming tight world petroleum resource day and price rises steadily, oil in all parts of the country station is to have valency without oily Stress.For alleviating diesel oil situation and pollution problem in short supply, 07Nian You Ministry of Energy, environment general bureau combine below, and enter kitchen by complete prohibition diesel oil the coming years, and forbid existing urban at present.The tense situation of fuel supply, huge market demand, the support energetically of national environmental protection policy, this series of being not difficult to find out, develops cheap, clean substitute energy extremely urgent!
The main raw material of biological alcohol oil is methyl alcohol; in industrial spirit, just contain a large amount of methyl alcohol; belong to moderate toxicity product and alcohol suitable, but produce through scientific technology the alcohol radical liquid fuel that meets national standard, burning and exhausting is safely, clean, meet environmental protection requirement.At present, alcohol, as new forms of energy product, more and more obtains generally acknowledging of the whole world.A large amount of alcohol energy automobiles, industrial combustion machine, kitchen burner have been one of important developing direction in Future New Energy Source field.Yet current biological alcohol oil fuel value is low, poor stability, exists fiery combustion value not high, and the spontaneous combustion midway of burning is not fiery, has easy volatilization consumption large, is difficult to sell on market.
Summary of the invention
In view of this, the present invention is directed to the disappearance of prior art existence, its main purpose is to provide a kind of novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof, and it has, and calorific value is high, sufficient combustion is stable, safe and reliable feature.
For achieving the above object, the present invention adopts following technical scheme:
A novel environment friendly clean biometric alcohol-oil fuel, by following raw material, made by mass percentage:
Methyl alcohol 78～90%;
Water 8～20%;
Silver powder 0.058～0.178%;
Red phosphorus powder 0.058～0.178%;
Ethyl acetate 0.058～0.178%;
Strontium carbonate powder 0.024～0.144%;
Acetone 0.058～0.178%;
Industry glycerol 0.179～0.479%;
Ferrocene 0.058～0.178%;
Nitromethane 99Min. 0.058～0.178%;
Dehydrated alcohol 0.179～0.479%;
The mass percent sum of above raw material equals 100%.
As a kind of preferred version, by following raw material, made by mass percentage:
Methyl alcohol 85%;
Water 14%;
Silver powder 0.068%;
Red phosphorus powder 0.068%;
Ethyl acetate 0.068%;
Strontium carbonate powder 0.034%;
Acetone 0.068%;
Industry glycerol 0.279%;
Ferrocene 0.068%;
Nitromethane 99Min. 0.068%;
Dehydrated alcohol 0.279%.
A kind of preparation method of novel environment friendly clean biometric alcohol-oil fuel, at normal temperatures, first by silver powder, red phosphorus powder and acetic acid ethyl ester are put into container and are stirred 5～10 minutes, then in container, add Strontium carbonate powder, acetone, industry glycerol and ferrocene also continue to stir 5～10 minutes, now can produce hot gas, then add dehydrated alcohol and part water, detectable level, with little bowl, fill small component solution and whether catch fire with open firing point, it is unsafe catching fire, can only add water again until point not, then, add Nitromethane 99Min. and continue to stir after 5～20 minutes, for another example whether aforementioned inspecting catches fire, then add methyl alcohol, add the ratio of methyl alcohol identical with the ratio of aforementioned added water, within brewed 2～3 hours, observe is to produce hot gas, if any hot gas, nature can be produced on fire, can only add water again until do not have hot gas to produce, then, the above-mentioned solution making is used to plastic cement barreled stock processed, there is safety not fire with fire, during use, residue first alcohol and water is added in the above-mentioned solution making and stirs and can make novel environment friendly clean biometric alcohol-oil fuel.
Adopt after such scheme, novel environment friendly clean biometric alcohol-oil fuel prepared by the present invention has following characteristics:
1, sanitation and hygiene, environmental protection:
This fuel value is high, sufficient combustion: without black smoke, without carbon distribution, at the bottom of no blacking pan, without residue, after burning, exhaust gas emission is made a gesture of measuring low.
2, safe and reliable, applied widely:
Without explosion hazard, easy to use, the water that catches fire can put out, and also can not reveal and cause poisoning, can replace diesel oil and liquefied gas completely, as kitchen fuel, be applicable to the large-lot producer such as hotel, hotel, school, office and the kitchen use of group of unit, diesel range, gas-cooker that dining room is used are just changed kitchen range core and can be used, and install and use very convenient, it is simple to operate, with diesel range is the same with gas-cooker, operates.
3, energy-conservation, economical:
Material benefit is in diesel oil and liquefied gas, and by the price ups and downs of diesel oil on market and liquefied gas, economic minimum profit between 15～30% saved in contrast.
Embodiment
Embodiment 1
(1) novel environment friendly clean biometric alcohol-oil fuel formula one
Methyl alcohol 85%;
Water 14%;
Silver powder 0.068%;
Red phosphorus powder 0.068%;
Ethyl acetate 0.068%;
Strontium carbonate powder 0.034%;
Acetone 0.068%;
Industry glycerol 0.279%;
Ferrocene 0.068%;
Nitromethane 99Min. 0.068%;
Dehydrated alcohol 0.279%.
(2) preparation method
At normal temperatures, first by silver powder, red phosphorus powder and acetic acid ethyl ester are put into container and are stirred 5～10 minutes, then in container, add Strontium carbonate powder, acetone, industry glycerol and ferrocene also continue to stir 5～10 minutes, now can produce hot gas, then add dehydrated alcohol and part water, detectable level, with little bowl, fill small component solution and whether catch fire with open firing point, it is unsafe catching fire, can only add water again until point not, then, add Nitromethane 99Min. and continue to stir after 5～20 minutes, for another example whether aforementioned inspecting catches fire, then add methyl alcohol, add the ratio of methyl alcohol identical with the ratio of aforementioned added water, within brewed 2～3 hours, observe is to produce hot gas, if any hot gas, nature can be produced on fire, can only add water again until do not have hot gas to produce, then, the above-mentioned solution making is used to plastic cement barreled stock processed, there is safety not fire with fire, during use, residue first alcohol and water is added in the above-mentioned solution making and stirs and can make novel environment friendly clean biometric alcohol-oil fuel.
Embodiment 2
(1) novel environment friendly clean biometric alcohol-oil fuel formula two
Methyl alcohol 80%;
Water 18.5%;
Silver powder 0.058%;
Red phosphorus powder 0.058%;
Ethyl acetate 0.178%;
Strontium carbonate powder 0.144%;
Acetone 0.178%;
Industry glycerol 0.324%;
Ferrocene 0.058%;
Nitromethane 99Min. 0.178%;
Dehydrated alcohol 0.324%.
(2) preparation method is identical with embodiment 1, therefore do not repeat.
Embodiment 3
(1) novel environment friendly clean biometric alcohol-oil fuel formula three
Methyl alcohol 90%;
Water 8.61%;
Silver powder 0.178%;
Red phosphorus powder 0.178%;
Ethyl acetate 0.058%;
Strontium carbonate powder 0.024%;
Acetone 0.058%;
Industry glycerol 0.179%;
Ferrocene 0.178%;
Nitromethane 99Min. 0.058%;
Dehydrated alcohol 0.479%.
(2) preparation method is identical with embodiment 1, therefore do not repeat.
Embodiment 4
(1) novel environment friendly clean biometric alcohol-oil fuel formula four
Methyl alcohol 89%;
Water 9.41%;
Silver powder 0.178%;
Red phosphorus powder 0.178%;
Ethyl acetate 0.158%;
Strontium carbonate powder 0.124%;
Acetone 0.058%;
Industry glycerol 0.479%;
Ferrocene 0.178%;
Nitromethane 99Min. 0.058%;
Dehydrated alcohol 0.179%.
(2) preparation method is identical with embodiment 1, therefore do not repeat.
Embodiment 5
(1) novel environment friendly clean biometric alcohol-oil fuel formula five
Methyl alcohol 90%;
Water 8%;
Silver powder 0.178%;
Red phosphorus powder 0.144%;
Ethyl acetate 0.142%;
Strontium carbonate powder 0.142%;
Acetone 0.178%;
Industry glycerol 0.436%;
Ferrocene 0.172%;
Nitromethane 99Min. 0.172%;
Dehydrated alcohol 0.436%.
(2) preparation method is identical with embodiment 1, therefore do not repeat.
Embodiment 6
(1) novel environment friendly clean biometric alcohol-oil fuel formula six
Methyl alcohol 78%;
Water 20%;
Silver powder 0.178%;
Red phosphorus powder 0.144%;
Ethyl acetate 0.142%;
Strontium carbonate powder 0.142%;
Acetone 0.178%;
Industry glycerol 0.436%;
Ferrocene 0.172%;
Nitromethane 99Min. 0.172%;
Dehydrated alcohol 0.436%.
(2) preparation method is identical with embodiment 1, therefore do not repeat.
Apply above-mentioned each implementation
After tested, novel environment friendly clean biometric alcohol-oil fuel of the present invention is free from extraneous odour, colourless transparent liquid.Density when this fuel alcohol content is greater than 70%, 20 ℃ is no more than 0.83g/ cubic centimetre; Mechanical impurity is no more than 0.3 ‰, and condensation point is lower than-30 ℃; Ignition temperature is greater than 230 ℃; PH value is 6～8; 50% gold-plating goes out temperature and is no more than 75 ℃; Total sulfur content is no more than 0.15%; And in the time of-20 ℃, also there will not be demixing phenomenon; Through formolite test, magenta is not blue look, and through measuring and calculating air excess system numerical digit 1.2 left and right, thermal efficiency of stoves reaches 85～90%; Low heat value surpasses 26000KJ/kg.
Get the novel environment friendly clean biometric alcohol-oil fuel that the present invention makes, the calorific value of each formula of test also compares with the calorific value of methyl alcohol, liquefied gas, diesel oil, and test result is as shown in table 1 below:
Table 1
| Fuel classification | Methyl alcohol | Liquefied gas | Diesel oil | Formula one | Formula two | Formula three | Formula four | Formula five | Formula six |
| Calorific value (kcal/kg) | 4650 | 8650 | 8500 | 8600 | 8550 | 8580 | 8560 | 8540 | 8500 |
By upper table, learnt, calorific value of the present invention can be up to 8600kcal/kg, and suitable with the calorific value of oil liquefied gas, the present invention goes up, falls contrast economic data sale by royalty with using liquefied gas, diesel oil market, specifically sees the following form 2:
Table 2
From above table, novel environment friendly clean biometric alcohol-oil fuel prepared by the present invention has following characteristics:
1, sanitation and hygiene, environmental protection:
This fuel value is high, sufficient combustion: without black smoke, without carbon distribution, at the bottom of no blacking pan, without residue, after burning, exhaust gas emission is made a gesture of measuring low.
2, safe and reliable, applied widely:
Without explosion hazard, easy to use, the water that catches fire can put out, also can not reveal and cause poisoning and can replace diesel oil and liquefied gas completely, as kitchen fuel, being applicable to the large-lot producer such as hotel, hotel, school, office and group of unit kitchen is used, diesel range, gas-cooker that dining room is used are just changed kitchen range core and can be used, install and use very conveniently, it is simple to operate, with diesel range is the same with gas-cooker, operates.
3, energy-conservation, economical:
Material benefit is in diesel oil and liquefied gas, and by the price ups and downs of diesel oil on market and liquefied gas, economic minimum profit between 15～30% saved in contrast.
The above, it is only preferred embodiment of the present invention, not technical scope of the present invention is imposed any restrictions, therefore any trickle modification, equivalent variations and modification that every foundation technical spirit of the present invention is done above embodiment all still belong in the scope of technical solution of the present invention.
Claims (3)
1. a novel environment friendly clean biometric alcohol-oil fuel, is characterized in that: by following raw material, made by mass percentage:
Methyl alcohol 78～90%;
Water 8～20%;
Silver powder 0.058～0.178%;
Red phosphorus powder 0.058～0.178%;
Ethyl acetate 0.058～0.178%;
Strontium carbonate powder 0.024～0.144%;
Acetone 0.058～0.178%;
Industry glycerol 0.179～0.479%;
Ferrocene 0.058～0.178%;
Nitromethane 99Min. 0.058～0.178%;
Dehydrated alcohol 0.179～0.479%;
The mass percent sum of above raw material equals 100%.
2. novel environment friendly clean biometric alcohol-oil fuel according to claim 1, is characterized in that: by following raw material, made by mass percentage:
Methyl alcohol 85%;
Water 14%;
Silver powder 0.068%;
Red phosphorus powder 0.068%;
Ethyl acetate 0.068%;
Strontium carbonate powder 0.034%;
Acetone 0.068%;
Industry glycerol 0.279%;
Ferrocene 0.068%;
Nitromethane 99Min. 0.068%;
Dehydrated alcohol 0.279%.
3. the preparation method of a novel environment friendly clean biometric alcohol-oil fuel, it is characterized in that: at normal temperatures, first by silver powder, red phosphorus powder and acetic acid ethyl ester are put into container and are stirred 5～10 minutes, then in container, add Strontium carbonate powder, acetone, industry glycerol and ferrocene also continue to stir 5～10 minutes, now can produce hot gas, then add dehydrated alcohol and part water, detectable level, with little bowl, fill small component solution and whether catch fire with open firing point, it is unsafe catching fire, can only add water again until point not, then, add Nitromethane 99Min. and continue to stir after 5～20 minutes, for another example whether aforementioned inspecting catches fire, then add methyl alcohol, add the ratio of methyl alcohol identical with the ratio of aforementioned added water, within brewed 2～3 hours, observe is to produce hot gas, if any hot gas, nature can be produced on fire, can only add water again until do not have hot gas to produce, then, the above-mentioned solution making is used to plastic cement barreled stock processed, there is safety not fire with fire, during use, residue first alcohol and water is added in the above-mentioned solution making and stirs and can make novel environment friendly clean biometric alcohol-oil fuel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210327214.0A CN103666587B (en) | 2012-09-06 | 2012-09-06 | Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof |
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| CN201210327214.0A CN103666587B (en) | 2012-09-06 | 2012-09-06 | Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof |
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| CN103666587A true CN103666587A (en) | 2014-03-26 |
| CN103666587B CN103666587B (en) | 2017-07-21 |
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| CN201210327214.0A Expired - Fee Related CN103666587B (en) | 2012-09-06 | 2012-09-06 | Novel environment friendly clean biometric alcohol-oil fuel and preparation method thereof |
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Cited By (4)
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| CN104388134A (en) * | 2014-12-12 | 2015-03-04 | 李可文 | Fuel additive, preparation method, application and fuel containing fuel additive |
| CN107937057A (en) * | 2017-12-04 | 2018-04-20 | 宁波高新区敦和科技有限公司 | A kind of gasoline additive and its production method comprising nanoparticle complexes |
| CN107987903A (en) * | 2017-12-30 | 2018-05-04 | 宁波高新区州致科技有限公司 | A kind of gasoline additive and its production method |
| CN110157499A (en) * | 2019-05-23 | 2019-08-23 | 贵州定北科技有限公司 | A kind of high heating value synthol oil and preparation method thereof |
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| CN1688677A (en) * | 2002-08-22 | 2005-10-26 | (株)火林Tech | A fuel composition and a device for colored flames |
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| CN104388134A (en) * | 2014-12-12 | 2015-03-04 | 李可文 | Fuel additive, preparation method, application and fuel containing fuel additive |
| CN104388134B (en) * | 2014-12-12 | 2016-05-25 | 李可文 | Fuel oil additive, preparation method, the fuel oil of applying and containing this fuel oil additive |
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| CN110157499A (en) * | 2019-05-23 | 2019-08-23 | 贵州定北科技有限公司 | A kind of high heating value synthol oil and preparation method thereof |
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| CN103666587B (en) | 2017-07-21 |
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Effective date of registration: 20180930 Address after: 417600 022 villager group second, Bing Tian Village, Cha Xi Town, Xinhua, Loudi, Hunan Patentee after: Ye Yongxing Address before: 523000 A102, A, Huaxing Industrial Park, Bu Xin Road, Yan Tian Village, Fenggang Town, Dongguan, Guangdong Patentee before: DONGGUAN RONGNENG ELECTRONIC SCIENCE AND TECHNOLOGY CO., LTD. |
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Granted publication date: 20170721 Termination date: 20180906 |