CN102533351A - Alcohol ether fuel - Google Patents

Alcohol ether fuel Download PDF

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CN102533351A
CN102533351A CN2011103977359A CN201110397735A CN102533351A CN 102533351 A CN102533351 A CN 102533351A CN 2011103977359 A CN2011103977359 A CN 2011103977359A CN 201110397735 A CN201110397735 A CN 201110397735A CN 102533351 A CN102533351 A CN 102533351A
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alcohol
ether
fuel
ether fuel
gasoline
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CN102533351B (en
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胡显坤
王鹏
陈洪超
李志梁
杨跃华
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Abstract

The invention discloses an alcohol ether fuel. The alcohol ether fuel comprises the following raw material components in percentage by weight: 86-91 % of methanol, 5-10 % of ethyl ether-dimethyl ether, 0.1-0.6 % of isopropanol, 0.4-0.9 % of n-butyl alcohol or isobutyl alcohol, 0.35-0.9 % of diethyl carbonate, 0.3-0.6 % of ethyl acetate and 0.4-1.0 % of methyl tert-butyl ether. The alcohol ether fuel disclosed by the invention can be singly used as gasoline alternative fuel; and compared with the traditional 93# vehicle gasoline, the alcohol ether fuel disclosed by the invention has the advantages of excellent dynamic performance, capability of keeping stability under the low temperature condition of -40 DEG C and super-strong water resistance.

Description

A kind of alcohol-ether fuel
Technical field
The present invention relates to alcohol-ether fuel and preparation method thereof
Background technology
The data presentation that Ministry of Industry and Information announces on August in this year 2, the external interdependency of crude oil in China reaches 55.2%, has surmounted the U.S., and this is after the external interdependency of crude oil in China is broken historical record year after year, surpasses the U.S. first.China's oil consumption speedup has surpassed the GDP speedup at present, and the energy expenditure speedup is too fast, all brings immense pressure for Energy production and energy-saving and emission-reduction.Improve China's energy structure, it is very urgent to seek new cleaning substitute energy.
Current, can substitute the product of oil, at first to measure big, one-tenth scale, secondly be that raw material is wanted fully to weigh from this point, the most qualified is exactly alcohol-ether fuel (methanol fuel and dimethyl ether fuel).It is the economical liquid fuel that can do the scale operation of raw material with coal and Sweet natural gas etc., and mature production technology stores easy to use.U.S. Nobel chemistry Prize winner, famous organic chemist George A Aura is said, " cross over the oil gas epoch, methyl alcohol economy will promote the world energy sources revolution ".Member of Chinese Academy of Engineering professor Ni Weidou points out, " dme economy is the great key that solves Chinese energy and environmental problem ".
Alcohol-ether fuel has lot of advantages as substitute energy: the one, and the wide material sources of methyl alcohol, wherein coal system methyl alcohol has more significant meaning, especially to high, the unsuitable civilian or industrial coal of sulphur content, does not also influence production methyl alcohol.From coal system methyl alcohol, also can in the multiple material of lighting, extract alcohol mixture, again with the methyl alcohol gasoline replacing that acts as a fuel, equal automobile and burn coal.The 2nd, the alcohol ether gasoline oxygen level is high, and sufficient combustion can effectively reduce and reduce discharge of harmful gases; According to national standard, oxycarbide descends 98.9%, and hydrocarbon polymer descends 88.11%; Reach EUROIII Emission Standard; Part reaches Europe IV standard, helps environment protection, the title of intrinsic environmental protection fuel.The 3rd, because of having good burning performance of alcohol-ether fuel; Can effectively eliminate the carbon deposit at each position of firing system; Avoided causing phenomenons such as power descends, burning is insufficient because of the formation of carbon deposit; And can reduce each operating mode exhaust temperature, help reducing part heat load, prolong the work-ing life of engine parts.The 4th, because methyl alcohol is a kind of solvent of excellent property in the alcohol ether gasoline; Can eliminate fuel tank and oil piping system contamination precipitation effectively and condense; Good oil circuit mediation effect is arranged, reduce cleaning mediation oil piping system and the expenses of the additives such as, fuel oil essence logical bought like oil circuit.The 5th, because use no matter alcohol ether gasoline is any a petrol engine of EFI formula and carburettor, need not do any transformation and can normally use.The 6th because the alcohol ether gasoline octane value is high, and power is strong, is applicable to high compression engine, can improve the efficient of mover, reduces oil consumption.
Fast development of Chinese economy is for alcohol-ether fuel provides great demand.China is oil consumption big country, greatly develops alcohol-ether fuel, fundamentally solves the energy problem of China, creates more social benefit, meets current socio-economic development needs, and strategic importance is great.The alcohol-ether fuel novel energy is listed " national medium-to long-range program for scientific and technological development " in, becomes the focus of people's research and development.
The kind of vehicle alcohol ether fuel of the prior art is a lot, and the standard of national alcohol-ether fuel gasoline is issued and implemented, but still has following situation:
One of which, low-temperature condition or chance regimen condition issue looks separates, and influences quality product.
Two, the vp of methyl alcohol sharply rises with the rising of temperature, is prone to cause in automobile oil transportation Lu Zhonghui appearance " gas is stifled " phenomenon.
" mix burning " three, at high proportion and have the phenomenon that is short of power.
Summary of the invention
The objective of the invention is to overcome the deficiency that exists in the existing alcohol-ether fuel technology, a kind of novel vehicle alcohol ether fuel is provided.Utilize vehicle alcohol ether fuel of the present invention to reach the reduction noxious gas emission, change combustionproperty and object of energy saving.
The technical scheme that the alcohol-ether fuel invention is provided is: a kind of alcohol-ether fuel comprises the composition that weight fraction is following respectively:
Figure BSA00000628199600021
Wherein the weight percent of methyl alcohol is 88%;
Wherein the weight percent of ether or dme is 7%-8%;
The preparation method: above-mentioned raw materials in proportion in pressurized vessel uniform mixing be pressed into that slaking promptly got in 24 hours in the normal temperature and pressure oil tank.
Beneficial effect (product technology advantage):
This alcohol ether gasoline: alternative to gasoline uses separately as motor spirit.
Below further set forth the present invention in detail, but do not constitute restriction protection domain of the present invention through embodiment and test.
Embodiment
Embodiment 1
A kind of alcohol-ether fuel comprises the composition that weight fraction is following respectively:
Figure BSA00000628199600022
Figure BSA00000628199600031
The preparation method: above-mentioned raw materials in proportion in pressurized vessel uniform mixing be pressed into that slaking promptly got in 24 hours in the normal temperature and pressure oil tank.
Embodiment 2
A kind of alcohol-ether fuel comprises the composition that weight fraction is following respectively:
Figure BSA00000628199600032
The preparation method: above-mentioned raw materials in proportion in pressurized vessel uniform mixing be pressed into that slaking promptly got in 24 hours in the normal temperature and pressure oil tank.
Embodiment 3
A kind of alcohol-ether fuel comprises the composition that weight fraction is following respectively:
Figure BSA00000628199600033
The preparation method: above-mentioned raw materials in proportion in pressurized vessel uniform mixing be pressed into that slaking promptly got in 24 hours in the normal temperature and pressure oil tank.
Embodiment 4
A kind of alcohol-ether fuel comprises the composition that weight fraction is following respectively:
Figure BSA00000628199600041
The preparation method: above-mentioned raw materials in proportion in pressurized vessel uniform mixing be pressed into that slaking promptly got in 24 hours in the normal temperature and pressure oil tank.
Embodiment 5
A kind of alcohol-ether fuel comprises the composition that weight fraction is following respectively:
The preparation method: above-mentioned raw materials in proportion in pressurized vessel uniform mixing be pressed into that slaking promptly got in 24 hours in the normal temperature and pressure oil tank.
Get the said alcohol ether gasoline of 200mL and place 250mL tool plug graduated cylinder, add 3mL zero(ppm) water and shake 5min, behind the room temperature held 48h, said alcohol ether gasoline is still limpid transparent, is not separated, and explains that said alcohol ether gasoline has the anti-performance that is separated of good chance water;
Get the said alcohol ether gasoline of 200mL and place 250mL tool plug graduated cylinder; Said graduated cylinder vertically is positioned in 0 ℃ the refrigerator, takes out behind the 48h, said alcohol ether gasoline is still limpid transparent; Be not separated, explain that said alcohol ether gasoline has the anti-performance that is separated of good low temperature;
When said alcohol ether gasoline is placed 1 month, 3 months and 6 months respectively under room temperature, observe said methanol gasoline, the result is referring to table 1, and table 1 is the stability test result of the alcohol ether gasoline of the embodiment of the invention.
Table 1 stability test result
Figure BSA00000628199600051
The resulting product of the foregoing description 1-5 is carried out sampling Detection, and each item index all meets the 93# gasoline standard, and related detection result sees table 2:
Table 2 embodiment alcohol-ether fuel and standard 93# gasoline detected result are relatively
Figure BSA00000628199600052
Figure BSA00000628199600061
The useful technique effect of alcohol-ether fuel of the present invention is embodied in following several aspect:
1) octane value high (>=93);
2) can use separately as the gasoline alternative fuel, and compare with the 93# motor spirit at present, have outstanding dynamic performance;
3) oil product stability is stronger, ensures alcohol and organic the mixing of oil, infinitely dissolves each other with GB gasoline, ethanol petrol, places layering, not emulsification never naturally, and still can keep stable at-40 ℃ of coldcondition.
4) good corrosion resistance.
5) superpower water repelling property.Be inhaled into airborne moisture in the time of resisting because of transportation, storage, filling.

Claims (4)

1. alcohol-ether fuel comprises the material composition that weight fraction is following respectively:
Figure FSA00000628199500011
2. alcohol-ether fuel according to claim 1, wherein the weight percent of methyl alcohol is 88%.
3. alcohol-ether fuel according to claim 1 and 2, wherein the weight percent of ether or dme is 7%-8%.
4. according to the preparation method of one of claim 1-3 described alcohol-ether fuel, it is with each raw material uniform mixing in pressurized vessel in proportion, is pressed into that slaking promptly got in 24 hours in the normal temperature and pressure oil tank.
CN 201110397735 2011-11-30 2011-11-30 Alcohol ether fuel Expired - Fee Related CN102533351B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102732332A (en) * 2012-07-11 2012-10-17 温志明 Preparation method of methanol/butanol mixed vehicle fuel
CN102732335A (en) * 2012-07-20 2012-10-17 天津林苑科技有限公司 Novel environment-friendly energy-saving biological alcohol oil
CN103289757A (en) * 2013-06-04 2013-09-11 朱钱洪 Automobile low-oil-consumption alcohol ether fuel
CN103820173A (en) * 2012-11-19 2014-05-28 东莞市久能二甲醚应用技术专利有限公司 Biomass alcohol ether engine fuel
CN106221834A (en) * 2016-08-22 2016-12-14 天津市苏同兴盛环保科技有限公司 Low-temperature methanol starts additive

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101012397A (en) * 2007-01-26 2007-08-08 杨娴 Alcohol ether household fuel
CN101100619A (en) * 2007-08-08 2008-01-09 鲁家政 High content environmental protection alcohol ether fuel additive for vehicle
JP2008024822A (en) * 2006-07-21 2008-02-07 Reiketsu Kichi Additive for alcohol-containing fuel oil, fuel oil containing the additive for alcohol-containing fuel oil, and method for producing fuel oil containing the additive for alcohol-containing fuel oil
CN102127475A (en) * 2010-01-15 2011-07-20 北京兰凯博能源科技有限公司 Ether-based fuel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008024822A (en) * 2006-07-21 2008-02-07 Reiketsu Kichi Additive for alcohol-containing fuel oil, fuel oil containing the additive for alcohol-containing fuel oil, and method for producing fuel oil containing the additive for alcohol-containing fuel oil
CN101012397A (en) * 2007-01-26 2007-08-08 杨娴 Alcohol ether household fuel
CN101100619A (en) * 2007-08-08 2008-01-09 鲁家政 High content environmental protection alcohol ether fuel additive for vehicle
CN102127475A (en) * 2010-01-15 2011-07-20 北京兰凯博能源科技有限公司 Ether-based fuel

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102732332A (en) * 2012-07-11 2012-10-17 温志明 Preparation method of methanol/butanol mixed vehicle fuel
CN102732335A (en) * 2012-07-20 2012-10-17 天津林苑科技有限公司 Novel environment-friendly energy-saving biological alcohol oil
CN103820173A (en) * 2012-11-19 2014-05-28 东莞市久能二甲醚应用技术专利有限公司 Biomass alcohol ether engine fuel
CN103289757A (en) * 2013-06-04 2013-09-11 朱钱洪 Automobile low-oil-consumption alcohol ether fuel
CN106221834A (en) * 2016-08-22 2016-12-14 天津市苏同兴盛环保科技有限公司 Low-temperature methanol starts additive
CN106221834B (en) * 2016-08-22 2018-01-26 天津市苏同兴盛环保科技有限公司 Low-temperature methanol starts additive

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