CN103645272A - 一种工业品中高沸点物质的检测方法 - Google Patents
一种工业品中高沸点物质的检测方法 Download PDFInfo
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- CN103645272A CN103645272A CN201310717154.8A CN201310717154A CN103645272A CN 103645272 A CN103645272 A CN 103645272A CN 201310717154 A CN201310717154 A CN 201310717154A CN 103645272 A CN103645272 A CN 103645272A
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- 238000002290 gas chromatography-mass spectrometry Methods 0.000 claims abstract description 12
- 150000002500 ions Chemical class 0.000 claims description 36
- 239000000523 sample Substances 0.000 claims description 26
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 22
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- 238000000197 pyrolysis Methods 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
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- 239000004014 plasticizer Substances 0.000 claims description 13
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- 229940106691 bisphenol a Drugs 0.000 claims description 11
- 238000004949 mass spectrometry Methods 0.000 claims description 11
- 230000005540 biological transmission Effects 0.000 claims description 9
- 239000012159 carrier gas Substances 0.000 claims description 9
- 239000001307 helium Substances 0.000 claims description 9
- 229910052734 helium Inorganic materials 0.000 claims description 9
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 9
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- 238000010494 dissociation reaction Methods 0.000 claims description 3
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- 239000000377 silicon dioxide Substances 0.000 claims description 3
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- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
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- 150000002989 phenols Chemical class 0.000 description 2
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CN201310717154.8A CN103645272B (zh) | 2013-12-23 | 2013-12-23 | 一种工业品中高沸点物质的检测方法 |
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CN201310717154.8A CN103645272B (zh) | 2013-12-23 | 2013-12-23 | 一种工业品中高沸点物质的检测方法 |
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CN103645272A true CN103645272A (zh) | 2014-03-19 |
CN103645272B CN103645272B (zh) | 2015-02-04 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109142608A (zh) * | 2018-10-22 | 2019-01-04 | 深圳出入境检验检疫局工业品检测技术中心 | 一种四类34种增塑剂的测定方法 |
CN110658278A (zh) * | 2019-10-12 | 2020-01-07 | 深圳海关工业品检测技术中心 | 一种纺织品中增塑剂的快速检测分析方法 |
CN111175412A (zh) * | 2020-03-02 | 2020-05-19 | 山东省产品质量检验研究院 | 一种检测儿童用品中16种邻苯二甲酸酯类塑化剂的方法 |
CN112881559A (zh) * | 2021-01-20 | 2021-06-01 | 广东产品质量监督检验研究院(国家质量技术监督局广州电气安全检验所、广东省试验认证研究院、华安实验室) | 邻苯二甲酸酯含量快速检测方法 |
CN112924575A (zh) * | 2021-01-25 | 2021-06-08 | 深圳海关工业品检测技术中心 | 一种用于有机包覆处理的无机粉体的鉴定方法 |
CN113189246A (zh) * | 2021-05-20 | 2021-07-30 | 山东省产品质量检验研究院 | 一种改进热裂解法检测儿童塑胶玩具中邻苯二甲酸酯类增塑剂的方法 |
Citations (3)
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CN101701944A (zh) * | 2009-11-05 | 2010-05-05 | 宁波中普检测技术服务有限公司 | 气相色谱-质谱联用测定产品中双酚a的方法 |
CN101999751A (zh) * | 2009-09-02 | 2011-04-06 | 湖北中烟工业有限责任公司 | 牛蒡根在烟草中综合利用的方法 |
RO129027A2 (ro) * | 2012-05-14 | 2013-11-29 | Incdo-Inoe 2000, Filiala Institutul De Cercetări Pentru Instrumentaţie Analitică | Metodă de determinare multireziduală a ftalaţilor în probe alimentare de lapte prin extracţie ultrasonică, microextracţie în fază solidă în headspace şi gaz cromatografie cuplată cu spectrometrie de masă () |
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2013
- 2013-12-23 CN CN201310717154.8A patent/CN103645272B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101999751A (zh) * | 2009-09-02 | 2011-04-06 | 湖北中烟工业有限责任公司 | 牛蒡根在烟草中综合利用的方法 |
CN101701944A (zh) * | 2009-11-05 | 2010-05-05 | 宁波中普检测技术服务有限公司 | 气相色谱-质谱联用测定产品中双酚a的方法 |
RO129027A2 (ro) * | 2012-05-14 | 2013-11-29 | Incdo-Inoe 2000, Filiala Institutul De Cercetări Pentru Instrumentaţie Analitică | Metodă de determinare multireziduală a ftalaţilor în probe alimentare de lapte prin extracţie ultrasonică, microextracţie în fază solidă în headspace şi gaz cromatografie cuplată cu spectrometrie de masă () |
Non-Patent Citations (8)
Title |
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ELKE FRIES ET AL: "Identification of polymer types and additives in marine microplastic particles using pyrolysis-GC/MS and scanning electron microscopy", 《ENVIRONMENTAL SCIENCE PROCESSES & IMPACTS》 * |
FRANK CHENG-YU WANG: "Polymer additive analysis by pyrolysis–gas chromatography II. Flame retardants", 《JOURNAL OF CHROMATOGRAPHY A》 * |
M. BLAZSO ET AL: "Pyrolysis and debromination of flame retarded polymers of electronic scrap studied by analytical pyrolysis", 《JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS》 * |
张颖: "TDI聚氨酯塑胶跑道的气相色谱-质谱分析", 《质谱学报》 * |
曹京宜 等: "涂料组成成分的快速分析方法-裂解气相色谱/质谱法", 《涂料工业》 * |
杨左军 等: "一种手机涂料的成分解析", 《光谱实验室》 * |
王丽丽 等: "Py-GC/MS技术快速鉴别和测定食品保鲜膜及其添加剂", 《浙江工业大学学报》 * |
邵敏 等: "人体血清中的多溴联苯醚、邻苯二甲酸酯和双酚A的连续在线分离及气相色谱-质谱测定", 《分析化学》 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109142608A (zh) * | 2018-10-22 | 2019-01-04 | 深圳出入境检验检疫局工业品检测技术中心 | 一种四类34种增塑剂的测定方法 |
CN110658278A (zh) * | 2019-10-12 | 2020-01-07 | 深圳海关工业品检测技术中心 | 一种纺织品中增塑剂的快速检测分析方法 |
CN111175412A (zh) * | 2020-03-02 | 2020-05-19 | 山东省产品质量检验研究院 | 一种检测儿童用品中16种邻苯二甲酸酯类塑化剂的方法 |
CN112881559A (zh) * | 2021-01-20 | 2021-06-01 | 广东产品质量监督检验研究院(国家质量技术监督局广州电气安全检验所、广东省试验认证研究院、华安实验室) | 邻苯二甲酸酯含量快速检测方法 |
CN112881559B (zh) * | 2021-01-20 | 2023-08-18 | 广东产品质量监督检验研究院(国家质量技术监督局广州电气安全检验所、广东省试验认证研究院、华安实验室) | 邻苯二甲酸酯含量快速检测方法 |
CN112924575A (zh) * | 2021-01-25 | 2021-06-08 | 深圳海关工业品检测技术中心 | 一种用于有机包覆处理的无机粉体的鉴定方法 |
CN113189246A (zh) * | 2021-05-20 | 2021-07-30 | 山东省产品质量检验研究院 | 一种改进热裂解法检测儿童塑胶玩具中邻苯二甲酸酯类增塑剂的方法 |
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Effective date of registration: 20150318 Address after: Eight inspection building, national inspection complex, Shekou Industrial Road, Shenzhen, Nanshan District 518000, Guangdong Patentee after: SHENZHEN ENTRY-EXIT INSPECTION AND QUARANTINE BUREAU INDUSTRIAL PRODUCT INSPECTION TECHNOLOGY CENTER Patentee after: SHENZHEN POLYTECHNIC Address before: Eight inspection building, national inspection complex, Shekou Industrial Road, Shenzhen, Nanshan District 518000, Guangdong Patentee before: Shenzhen Entry-Exit Inspection and Quarantine Bureau Industrial Product Inspection Technology Center |
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