CN103635086B - 农业园艺用杀虫剂组合物及其使用方法 - Google Patents
农业园艺用杀虫剂组合物及其使用方法 Download PDFInfo
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- CN103635086B CN103635086B CN201280032497.4A CN201280032497A CN103635086B CN 103635086 B CN103635086 B CN 103635086B CN 201280032497 A CN201280032497 A CN 201280032497A CN 103635086 B CN103635086 B CN 103635086B
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- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 description 1
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- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- RSOBJVBYZCMJOS-CYBMUJFWSA-N tolprocarb Chemical compound FC(F)(F)COC(=O)N[C@@H](C(C)C)CNC(=O)C1=CC=C(C)C=C1 RSOBJVBYZCMJOS-CYBMUJFWSA-N 0.000 description 1
- IYMLUHWAJFXAQP-UHFFFAOYSA-N topramezone Chemical compound CC1=C(C(=O)C2=C(N(C)N=C2)O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 IYMLUHWAJFXAQP-UHFFFAOYSA-N 0.000 description 1
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- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- PIHCREFCPDWIPY-UHFFFAOYSA-N tris[2-(2,4-dichlorophenoxy)ethyl] phosphite Chemical compound ClC1=CC(Cl)=CC=C1OCCOP(OCCOC=1C(=CC(Cl)=CC=1)Cl)OCCOC1=CC=C(Cl)C=C1Cl PIHCREFCPDWIPY-UHFFFAOYSA-N 0.000 description 1
- 239000002753 trypsin inhibitor Substances 0.000 description 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
- DBXFMOWZRXXBRN-LWKPJOBUSA-N valifenalate Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)NC(CC(=O)OC)C1=CC=C(Cl)C=C1 DBXFMOWZRXXBRN-LWKPJOBUSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
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- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
Abstract
一种含有氟虫双酰胺和唑虫酰胺作为有效成分的农业园艺用杀虫剂组合物以及该农业园艺用杀虫剂组合物的使用方法,所述使用方法的特征在于,使用有效量的该农业园艺用杀虫剂组合物直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理。
Description
技术领域
本发明涉及含有氟虫双酰胺和唑虫酰胺作为有效成分的农业园艺用杀虫剂组合物及其使用方法。
背景技术
氟虫双酰胺是作为农业园艺用杀虫剂市售的化合物,已知组合氟虫双酰胺或其近缘化合物与各种农业园艺用杀虫剂,对于杀虫谱的补充或特定组合具有协同效果(例如参考专利文献1~5以及非专利文献1)。另外,唑虫酰胺也是作为农业园艺用杀虫剂市售的化合物,已知组合唑虫酰胺与各种农业园艺用杀虫剂组合,对于杀虫谱的补充或特定组合具有协同效果(例如参考专利文献6、7以及非专利文献1)。然而,组合氟虫双酰胺与唑虫酰胺而得的组合物是未知的,而且与单独使用各化合物相比将它们组合而成的组合物具有协同的优良杀虫效果也是完全未知的。
现有技术文献
专利文献
专利文献1:日本特开2001-131141号公报
专利文献2:国际公开第2002/087334号小册子
专利文献3:国际公开第2004/034786号小册子
专利文献4:国际公开第2005/004603号小册子
专利文献5:国际公开第2005/004604号小册子
专利文献6:日本特开平3-81266号公报
专利文献7:日本特开2006-131516号公报
非专利文献
非专利文献1:ThePesticideManual14thEdition(BritishCropProductionCouncil)
发明内容
发明所要解决的问题
在农作物的生产中,遭受的来自各种害虫的灾害仍然很大,为了对其进行防除,需要使用各种杀虫剂进行处理,该处理操作对农业从事者而言成为特别大的负担。从降低农业从事者的劳动负担的劳动卫生方面、从降低农作物生产成本的经济性方面均强烈要求减少上述处理操作,开发了各种农业园艺用杀虫剂组合物。但是,对于现有技术而言,根据防除对象害虫的种类、栖息特性、耐药性的发展等有时无法有效防除,期望开发出用于有效地防除难以防除或不能防除的害虫的新技术。
用于解决问题的方法
本发明人为了解决上述课题而进行了深入的研究,结果发现,通过组合作为农业园艺用杀虫剂已知的氟虫双酰胺(通用名:Flubendiamide、化学名:3-iodo-N'-(2-mesyl-1,1-dimethylethyl)-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-o-tolyl}phthalamide(3-碘-N'-(2-甲磺酰基-1,1-二甲基乙烷基-N-{4-[1,2,2,2-四氟-1-(三氟甲基)乙基]-邻甲苯基}邻苯二酰胺))与同样作为农业园艺用杀虫剂已知的唑虫酰胺(通用名:Tolfenpyrad、化学名:4-chloro-3-ethyl-1-methyl-N-[4-(p-tolyloxy)benzyl]pyrazole-5-carboxamide(4-氯-3-乙基-1-甲基-N-[4-(对甲基苯氧基)苄基]吡唑-5-甲酰胺)),与单独使用各化合物的情况相比,具有显著的协同效果、对象害虫种类的扩大、使用药量的降低、药剂处理次数的降低等效果,从而完成了本发明。
即,本发明涉及以下[1]~[6]:
一种农业园艺用杀虫剂组合物,含有氟虫双酰胺和唑虫酰胺作为有效成分;
如上述[1]所述的农业园艺用杀虫剂组合物,其中,相对于氟虫双酰胺1质量份,以0.1~10质量份的比例含有唑虫酰胺;
一种农业园艺用杀虫剂组合物的使用方法,其特征在于,使用有效量的含有氟虫双酰胺和唑虫酰胺作为有效成分的农业园艺用杀虫剂组合物直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理;
一种农业园艺害虫的防除方法,其特征在于,分别使用有效量的以氟虫双酰胺作为有效成分的制剂和含有唑虫酰胺作为有效成分的制剂,以其原状态或对其进行稀释后,于同时期直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理;
一种农业园艺害虫的防除方法,其特征在于,分别使用有效量的以氟虫双酰胺作为有效成分的制剂和含有唑虫酰胺作为有效成分的制剂,以其原状态或对其进行稀释后,空出处理时期的间隔地直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理;
一种农业园艺害虫的防除方法,其特征在于,混合使用有效量的以氟虫双酰胺作为有效成分的制剂和含有唑虫酰胺作为有效成分的制剂,以其原状态或对其进行稀释后,直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理。
发明效果
本发明涉及以氟虫双酰胺及唑虫酰胺作为有效成分的农业园艺用杀虫剂组合物及其使用方法,与单独使用各化合物的情况相比,发挥出显著的协同效果、对象害虫种类的扩大、使用药量的降低、药剂处理次数的降低等效果,提供用于有效地防除以现有技术难以防除或不能防除的害虫的新技术。
具体实施方式
作为本发明的农业园艺用杀虫剂组合物的有效成分之一的氟虫双酰胺可以通过上述专利文献1中公开的制造方法等来制造,也可以购入市售制剂。作为另一个有效成分的唑虫酰胺也可以通过上述专利文献6中公开的制造方法来制造,也可以购入市售制剂。将这些化合物与表面活性剂以及根据需要的助剂一起以适当的比例配合后,溶解、分离、悬浮、混合、含浸、吸附或附着于适当的惰性载体,制成各种剂型、例如悬浮剂(流动剂)、乳液悬浮剂、乳剂、液剂、可湿性粉剂、可湿性颗粒剂、颗粒剂、粉剂、微囊剂、胶囊剂、片剂、大粒剂或袋剂(パック剤)等后使用即可。
相对于本发明的农业园艺用杀虫剂组合物整体的有效成分的配合比例可以根据需要进行调节,没有特别限定,通常为约0.01~约90质量份,在形成例如粉剂或颗粒剂的情况下,优选为约0.1~约30质量份,在乳剂、可湿性粉剂、流动剂或可湿性颗粒剂等的情况下,优选为约0.1~约60质量份。关于作为本发明的农业园艺用杀虫剂组合物的有效成分的氟虫双酰胺与唑虫酰胺的配合比例,相对于氟虫双酰胺1质量份,唑虫酰胺可以适当选自0.1~10质量份的比例。
这些各有效成分可以直接使用市售制剂,也可以将有效成分彼此单独进行制剂化或一起制剂化后使用。进行制剂化时,使有效成分溶解、分离、悬浮、混合、含浸、吸附或附着于适当的惰性载体、或根据需要使有效成分与助剂一起以适当的比例配合后溶解、分离、悬浮、混合、含浸、吸附或附着于适当的惰性载体,制成适当的剂型、例如悬浮剂(流动剂)、乳液悬浮剂、乳剂、液剂、可湿性粉剂、可湿性颗粒剂、颗粒剂、粉剂、微囊剂、胶囊剂、片剂、大粒剂或袋剂等即可。
作为上述惰性载体,可以列举固体载体和液体载体,作为固体载体,例如可以列举石英、粘土、高岭土(kaolin)、叶蜡石、绢云母、滑石、膨润土、酸性白土、硅镁土、沸石、硅藻土等天然矿物类;碳酸钙、硫酸铵、硫酸钠、氯化钾等无机盐类;合成硅酸、合成硅酸盐、淀粉、纤维素、植物粉末(例如锯屑、椰子壳、玉米棒芯、烟草茎等)等有机固体载体;聚乙烯、聚丙烯、聚偏氯乙烯等塑料载体;尿素;无机中空体;塑料中空体;气相二氧化硅(fumedsilica,白炭黑)等。它们可以单独使用,并且还可以将2种以上组合使用。
作为液体载体,例如可以列举甲醇、乙醇、丙醇、异丙醇、丁醇等一元醇类;以及乙二醇、二乙二醇、丙二醇、己二醇、聚乙二醇、聚丙二醇、丙三醇等多元醇类等醇类;丙二醇醚等多元醇化合物类;丙酮、甲乙酮、甲基异丁酮、二异丁酮、环己酮等酮类;乙醚、二氧杂环己烷、乙二醇单乙醚、二丙醚、四氢呋喃等醚类;正链烷烃、环烷烃、异链烷烃、煤油、矿物油等脂肪族烃类;苯、甲苯、二甲苯、溶剂石脑油、烷基萘等芳香族烃类;二氯甲烷、氯仿、四氯化碳等卤代烃类;乙酸乙酯、邻苯二甲酸二异丙酯、邻苯二甲酸二丁酯、邻苯二甲酸二辛脂、己二酸二甲酯等酯类;γ-丁内酯等内酯类;二甲基甲酰胺、二乙基甲酰胺、二甲基乙酰胺、N-烷基吡咯烷酮(N-甲基吡咯烷酮等)等酰胺类;乙腈等腈类;二甲基亚砜等硫化合物类;大豆油、油菜籽油、棉籽油、蓖麻油等植物油;以及水等。它们可以单独使用,并且还可以将2种以上组合使用。
作为助剂,可以列举用作分散剂/润湿剂/扩展剂/展着剂等的表面活性剂、粘合剂、增粘剂、增稠剂、着色剂、防冻剂、抗结块剂、崩解剂和防分解剂等。除此之外,还可以根据需要将防腐剂、植物片用于添加成分。这些添加成分可以单独使用,并且还可以将2种以上组合使用。
作为用作分散剂/润湿剂/扩展剂/展着剂等的表面活性剂,例如可以列举:脱水山梨醇脂肪酸酯、聚氧乙烯脱水山梨醇脂肪酸酯、蔗糖脂肪酸酯、聚氧乙烯脂肪酸酯、聚氧乙烯树脂酸酯、聚氧乙烯脂肪酸二酯、聚氧乙烯烷基醚、聚氧乙烯烷基芳基醚、聚氧乙烯烷基苯基醚、聚氧乙烯二烷基苯基醚、聚氧乙烯烷基苯基醚福尔马林缩合物、聚氧乙烯聚氧丙烯嵌段共聚物、聚苯乙烯聚氧乙烯嵌段聚合物、烷基聚氧乙烯聚丙烯嵌段共聚物醚、聚氧乙烯烷基胺、聚氧乙烯脂肪酸酰胺、聚氧乙烯脂肪酸二苯基醚、聚亚烷基苄基苯基醚、聚氧化烯苯乙烯基苯基醚、乙炔二醇、聚氧化烯加成乙炔二醇、聚氧乙烯醚型聚硅氧烷、酯型聚硅氧烷、氟系表面活性剂、聚氧乙烯蓖麻油、聚氧乙烯硬化蓖麻油等非离子型表面活性剂;
烷基硫酸盐、聚氧乙烯烷基醚硫酸盐、聚氧乙烯烷基苯基醚硫酸盐、聚氧乙烯苯乙烯基苯基醚硫酸盐、烷基苯磺酸盐、烷基芳基磺酸盐、木质素磺酸盐、烷基磺基琥珀酸盐、萘磺酸盐、烷基萘磺酸盐、萘磺酸的福尔马林缩合物的盐、烷基萘磺酸的福尔马林缩合物的盐、脂肪酸盐、聚羧酸盐、聚丙烯酸盐、N-甲基-脂肪酸肌氨酸酯、树脂酸盐、聚氧乙烯烷基醚磷酸盐、聚氧乙烯烷基苯基醚磷酸盐等阴离子型表面活性剂;
十二胺盐酸盐、硬脂胺盐酸盐、油烯胺盐酸盐、硬脂胺乙酸盐、十八氨基丙胺乙酸盐、氯化烷基三甲基铵、烷基二甲基苯扎氯铵等烷基胺盐等阳离子表面活性剂;氨基酸型或甜菜碱型等两性表面活性剂等。这些表面活性剂可以单独使用,并且可以将2种以上组合使用。
作为粘合剂或增粘剂,例如可以列举羧甲基纤维素及其盐、糊精、水溶性淀粉、黄原胶、瓜尔胶、蔗糖、聚乙烯基吡咯烷酮、阿拉伯胶、聚乙烯醇、聚醋酸乙烯酯、聚丙烯酸钠、平均分子量为6000~20000的聚乙二醇、平均分子量为10万~500万的聚环氧乙烷、磷脂(例如脑磷脂、卵磷脂等)、纤维素粉末、糊精、加工淀粉、聚氨基羧酸螯合化合物、交联聚乙烯基吡咯烷酮、马来酸与苯乙烯类的共聚物、(甲基)丙烯酸系共聚物、由多元醇形成的聚合物与二酸酐的半酯、聚苯乙烯磺酸的水溶性盐、石蜡、萜烯、聚酰胺树脂、聚丙烯酸盐、聚氧乙烯、蜡、聚乙烯基烷基醚、烷基酚福尔马林缩合物、合成树脂乳液等。
作为增稠剂,例如可以列举黄原胶、瓜尔胶、迪特胶、羧甲基纤维素、聚乙烯基吡咯烷酮、羧乙烯聚合物、丙烯酸系聚合物、淀粉衍生物、多糖类等水溶性高分子;高纯度膨润土、气相二氧化硅(fumedsilica,白炭黑)等无机微粉等。
作为着色剂,例如可以列举氧化铁、氧化钛、普鲁士蓝等无机颜料;茜素染料、偶氮染料、金属酞菁染料等有机染料等。
作为防冻剂,例如可以列举乙二醇、二乙二醇、丙二醇、丙三醇等多元醇类。
作为抗结块或促进崩解的助剂,例如可以列举淀粉、海藻酸、甘露糖、半乳糖等多糖类、聚乙烯基吡咯烷酮、气相二氧化硅(fumedsilica,白炭黑)、酯胶、石油树脂、三聚磷酸钠、六偏磷酸钠、硬脂酸金属盐、纤维素粉末、糊精、甲基丙烯酸酯的共聚物、聚乙烯基吡咯烷酮、聚氨基羧酸螯合化合物、磺化苯乙烯-异丁烯-马来酸酐共聚物、淀粉-聚丙烯腈接枝共聚物等。
作为防分解剂,例如可以列举沸石、生石灰、氧化镁等干燥剂;酚化合物、胺化合物、硫化合物、磷酸化合物等抗氧化剂;水杨酸化合物、二苯甲酮化合物等紫外线吸收剂等。作为防腐剂,例如可以列举山梨酸钾、1,2-苯并噻唑啉-3-酮等。
此外,根据需要,还可以使用功能性展着剂、胡椒基丁醚等代谢分解抑制剂等活性增强剂、BHT等抗氧化剂、紫外线吸收剂等其它助剂。
可以使用本发明的农业园艺用杀虫剂组合物的“作物”没有特别限定,例如可以列举水稻、大麦、小麦、黑麦、燕麦、玉米、高粱等谷类;大豆、小豆、蚕豆、豌豆、花生等豆类;苹果、桔子、橙子、柠檬、酸橙、葡萄柚、木瓜、柑橘、梨、西洋梨、日本梨、葡萄、蓝莓、蔓越莓、黑莓、树莓、草莓、桃、梅、油桃、李子、樱桃、杏、黑枣、核桃仁、榛子、杏仁、开心果、腰果、澳洲坚果、香蕉、柿子、橄榄、枇杷、枣、椰子、油棕等果树/果实类;圆白菜、番茄、菠菜、西兰花、莴苣、洋葱、葱、青椒、茄子、甘蓝、白菜、芥菜、菜花、茼蒿、朝鲜蓟、芦笋、胡萝卜、香菜、芹菜、欧洲防风草、瑞士甜菜等蔬菜类;胡萝卜、牛蒡、马铃薯、红薯、山药、芋头、萝卜、莲藕、白萝卜等根菜类;棉、麻、桑、三桠、菜籽、棕榈、麻疯树、荞麦、甜菜根、啤酒花、甘蔗、甜菜、橄榄、橡胶、咖啡、烟草、蚕桑、茶等加工用作物类;南瓜、黄瓜、西葫芦、西瓜、甜瓜等瓜类;野茅、高粱、梯牧草、三叶草、紫花苜蓿等牧草类;
结缕草、细叶结缕草、狗牙根草、梗草、匍匐翦股颖、毛状剪股颖、草地早熟禾、粗茎早熟禾、高羊茅、字节羊茅、高羊茅、稗子、黑麦草、鸭茅、猫尾草等芝类;薰衣草、迷迭香、百里香、香菜、辣椒、红辣椒、芥末、姜、蒜、日本罗勒、薄荷、罗勒等香料用作物类;玫瑰、康乃馨、菊花、洋桔梗、满天星、向日葵、非洲菊、万寿菊、鼠尾草、矮牵牛、马鞭草、郁金香、阿斯特、龙胆、百合、三色堇、仙客来、兰花、铃兰、薰衣草、紫罗兰、羽衣甘蓝、报春花、一品红、剑兰、卡特兰、菊花、马鞭草、大花蕙兰、海棠等花卉类;水曲柳、桦木、山茱萸、桉树、银杏、丁香、枫树、橡树、杨树、紫荆花、枫香、悬铃木、榉黑份、冷杉、铁杉、杜松、松树、云杉、紫杉、榆树、七叶树、珊瑚树、罗汉松、雪松、扁柏、巴豆、卫矛、石楠等树木类。
另外,上述“作物”也包含:通过经典培育法或近年的基因重组技术的进步赋予了有用的性状的基因重组作物(除草剂抗性作物、整合入了产生杀虫性蛋白的基因的害虫抗性作物、整合入了对病害的抗性诱导物质的基因的病害抗性作物、改善了口味的作物、改善了保存性的作物、提高了产量的作物等)。
作为通过经典培育法赋予了除草剂抗性的“作物”的例子,有咪草烟等咪唑啉酮系ALS抑制型除草剂抗性的油菜、小麦、向日葵、水稻、玉米,已经以Clearfield<注册商标>的商品名在销售。同样还有通过经典培育法获得的甲基噻吩磺隆等磺酰脲系ALS抑制型除草剂抗性的大豆,已经以STS大豆的商品名在销售。同样地,作为赋予了三酮肟系、芳氧苯氧基丙酸系除草剂等乙酰辅酶A羧化酶抑制剂抗性的作物的例子,有SR玉米等。
作为通过基因重组技术赋予了抗性的作物的例子,有草甘膦抗性的玉米、大豆、棉花、油菜、甜菜品种,已经以ラウンドアップレディ(RoundupReady<注册商标>)、AgrisureGT等商品名在销售。同样还有利用基因重组技术获得的草铵膦抗性的玉米、大豆、棉花、油菜品种,已经以リバティーリンク(LibertyLink<注册商标>)等商品名在销售。同样地,利用基因重组技术获得的溴苯腈抗性的棉花已经以BXN的商品名在销售。
赋予了乙酰辅酶A羧化酶抑制剂抗性的作物在プロシーディングズ·オブ·ザ·ナショナル·アカデミー·オブ·サイエンシーズ·オブ·ザ·ユナイテッド·ステーツ·オブ·アメリカ(Proc.Natl.Acad.Sci.USA)87卷、7175~7179页(1990年)等中有记载。另外,乙酰辅酶A羧化酶抑制剂抗性的突变的乙酰辅酶A羧化酶在ウィード·サイエンス(WeedScience)53卷、728~746页(2005年)等中进行了报道,通过利用基因重组技术将上述突变乙酰辅酶A羧化酶基因导入作物或将与赋予抗性相关的突变导入作物乙酰辅酶A羧化酶,能够制作乙酰辅酶A羧化酶抑制剂抗性的作物。另外,通过以嵌合修复技术(GuraT.1999.RepairingtheGenome'sSpellingMistakes.Science285:316-318.)为代表的将导入有碱基置换突变的核酸导入作物细胞内,从而在作物{乙酰辅酶A羧化酶}基因上引起位点特异的氨基酸置换突变,由此能够制作{乙酰辅酶A羧化酶抑制剂}抗性的作物。
另外,也包含使用了基因重组技术的能够合成杀虫性毒素等的基因重组作物。作为在这种基因重组植物中表达的杀虫性毒素,例如可以列举:来自蜡样芽胞杆菌(Bacilluscereus)、日本金龟甲芽孢杆菌(Bacilluspopilliae)的杀虫性蛋白;来自苏云金杆菌(Bacillusthuringiensis)的Cry1Ab、Cry1Ac、Cry1F、Cry1Fa2、Cry2Ab、Cry3A、Cry3Bb1或Cry9C等δ-内毒素、VIP1、VIP2、VIP3或VIP3A等杀虫性蛋白;来自线虫的杀虫性蛋白;蝎毒素、蜘蛛毒素、蜂毒素或昆虫特异的神经毒素等由动物产生的毒素;糸条菌类毒素;植物凝血素;凝集素;胰蛋白酶抑制剂、丝氨酸蛋白酶抑制剂、马铃薯糖蛋白、半胱氨酸蛋白酶抑制剂、木瓜蛋白酶抑制剂等蛋白酶抑制剂;赖氨酸、玉米-RIP、相思豆毒素、皂草毒蛋白、异株腹泻毒蛋白(bryodin)等核糖体失活蛋白(RIP);3-羟基类固醇氧化酶、蜕化类固醇-UDP-葡糖基转移酶、胆固醇氧化酶等类固醇代谢酶;蜕皮素抑制剂;HMG-CoA还原酶;钠通道抑制剂、钙通道抑制剂等离子通道抑制剂;保幼激素酯酶;利尿激素受体;芪合酶;联苄合酶;壳多糖酶;葡聚糖酶等。这些毒素的例子以及能够合成这些毒素的重组作物例如记载在EP-A-0374753、WO93/07278、WO95/34656、EP-A-0427529、EP-A-451878、WO03/052073等中。这些重组作物中包含的毒素特别适于防除鞘翅目害虫、双翅目害虫、鳞翅目害虫,赋予作物对这些害虫的抗性性状。
已知表达这些杀虫性毒素中的一种或多种毒素的基因重组作物,几种已经市售。作为这些基因重组作物的例子,可以列举:表达Cry1Ab毒素的玉米品种、例如イールドガード(YieldGard)<注册商标>等、表达Cry3Bb1毒素的玉米品种、例如イールドガードルートワーム(YieldGardRootworm)等、表达Cry1Ab和Cry3Bb1毒素的玉米品种、例如イールドガードプラス(YieldGardPlus)<注册商标>等、表达Cry1Fa2毒素和用于赋予草铵膦抗性的草丁膦N-乙酰基转移酶(PAT)的玉米品种、例如ハーキュレックスI(HerculexI)<注册商标>等、表达Cry1Ac毒素的棉花品种、例如NuCOTN33B<注册商标>、ボルガードI(BollgardI)<注册商标>等、表达Cry1Ac和Cry2Ab毒素的棉花品种、例如ボルガードII(BollgardII)<注册商标>等、表达VIP毒素的棉花品种、例如VIPCOT<注册商标>等、表达Cry3A毒素的马铃薯品种、例如ニューリーフ(NewLeaf)<注册商标>等、GA21草甘膦抗性性状ネイチャーガードアグリシュアーGTアドバンテージ(NatureGard<注册商标>Agrisure<注册商标>GTAdvantage)等、Bt11玉米螟(CB)性状、例如アグリシュアーCBアドバンテージ(Agrisure<注册商标>CBAdvantage)等、プロテクタ(Protecta)<注册商标>等。
另外,也包含使用基因重组技术赋予产生具有选择性作用的抗病原性物质的性状的作物。作为抗病原性物质,例如可以列举PR蛋白(PRPs、在EP-A-0392225中记载);钠通道抑制剂、钙通道抑制剂(已知病毒产生的KP1、KP4、KP6毒素等)等离子通道抑制剂;芪合酶;联苄合酶;壳多糖酶;葡聚糖酶;肽抗生素、具有杂环的抗生素、与植物病害抗性有关的蛋白因子(称为植物病害抗性基因,在WO03/000906中记载)等微生物产生的物质等。这样的抗病原性物质和产生其的基因重组作物在EP-A-0392225、WO95/33818、EP-A-0353191等中记载。
另外,也包含使用基因重组技术赋予油料成分改质、氨基酸含量增强性状等有用性状的作物。作为例子,可以列举:VISTIVE<注册商标>(使亚麻酸含量降低的低亚麻酸大豆)或高赖氨酸(或高油)玉米(使赖氨酸或油含量增量的玉米)等。
另外,对于上述经典除草剂性状或除草剂抗性基因、杀虫性害虫抗性基因、抗病原性物质产生基因、油料成分改质或氨基酸含量增强性状等有用性状,也包含将这些多种组合而成的复合性状转基因品种。对除草剂抗性的作物使用本发明的农业园艺用杀虫剂组合物时,通过该作物形成了抗性的除草剂(例如草甘膦或其盐、草铵膦或其盐、麦草畏或其盐、咪草烟或其盐、异恶唑草酮等)与本发明的农业园艺用杀虫剂组合物的系统处理和/或混合处理,能够综合地防除杂草以及害虫。
在本发明的农业园艺用杀虫剂组合物的使用中,将对各种害虫防除有效量的上述预先含有各成分的制剂,以原状态或用水等适当稀释或使其悬浮的形式,直接对害虫、或者对预测到该害虫的发生的对象作物、或者对其种子或用于播种的土壤或栽培载体等进行通常的处理即可。作为处理方法,例如可以列举:向茎叶等的散布处理、水稻育苗箱处理、拌种/浸种/种子消毒等种子处理、栽植穴处理、根部处理、垄沟处理、灌注处理、土壤混合处理等处理方法,也可以对水耕栽培中的水耕液进行处理。
作为种子处理的方法,可以列举根据通常的方法例如将液状或固体状的制剂进行稀释或不进行稀释而以液体状态浸渍种子,浸透药剂的方法;将固体制剂或液状制剂与种子混合,进行拌种处理等,使其附着到种子表面的方法;与树脂、聚合物等附着性高的载体混合,对种子进行单层或多层包覆的方法;在进行种植的同时在种子附近进行散布的方法等。进行该种子处理的“种子”广义上与本发明的“繁殖用植物体”为相同含义,除了所谓的种子之外,也包括球根、块茎、种薯、鳞茎、或用于插枝栽培的茎等用于营养繁殖的植物体。
实施本发明的方法时的“土壤”或“栽培载体”是指用于栽培植物的支撑体,材质没有特别限定,只要是植物能够生长的材质即可,包括例如所谓的各种土壤、育苗垫、水等,也可以包括砂、蛭石、棉、纸、硅藻土、琼脂、凝胶状物质、高分子物质、岩棉、玻璃棉、木屑、树皮、浮石等。
作为对土壤的施用方法,可以列举例如:将液体或固体制剂以用水稀释或不进行稀释的方式施用于植物体的设置位置附近或用于育苗的苗床等的方法;将颗粒剂散布于植物体的设置位置附近或苗床的方法;在播种前或移植前散布粉剂、可湿性粉剂、可湿性颗粒剂、颗粒剂等,与土壤整体混合的方法;在播种前或种植植物体前在栽植穴、垄沟等中散布粉剂、可湿性粉剂、可湿性颗粒剂、颗粒剂等的方法等。
作为对水稻的育苗箱的施用方法,剂型可能根据例如播种时施用、绿化期施用、移植时施用等施用时期而不同,以粉剂、可湿性颗粒剂、颗粒剂等剂型施用即可。也可以通过与培土的混合来施用,可以进行培土与粉剂、可湿性颗粒剂或颗粒剂等的混合、例如床土混合、覆土混合、向培土整体的混合等。也可以仅仅将培土和各种制剂交替形成层状来施用。播种时的施用的时期可以为播种前、同时、播种后的任意一种,也可以在覆土后施用。另外,在水稻领域中,还可以使用颗粒剂等对水田进行水面施用。
在大田作物、例如马铃薯、番薯、大豆等的情况下,在从播种开始的育苗期中,优选为对与种子或植物体接近的栽培载体等的处理。对大田直接播种的植物中,除了对种子的直接处理之外,优选为对与栽培中的植物接近的栽培载体等的处理。可以使用颗粒剂进行散布处理或将用水稀释或未稀释的药剂以液状进行灌注处理。
作为进行移植的栽培植物的播种、育苗期的处理,除了对种子的直接处理之外,可以对育苗用苗床进行形成为液状的药剂的灌注处理或颗粒剂的散布处理。另外,可以在定植时使用颗粒剂对栽植穴进行处理,或者也可以与移植位置附近的栽培载体混合。
将各个单独的制剂在现场混合使用,通过上述处理方法进行处理,能够显示出期望的杀虫效果。另外,将各个单独的制剂于同时期通过上述处理方法进行处理,也能够显示出期望的杀虫效果。在此,同时期不是指完全同时进行处理的含义,只要是在约一周的期间内则可以视为同时期,也可以采用各自不同的处理方法。另外,将各个单独的制剂空出间隔地通过上述处理方法进行处理,也能够显示出期望的杀虫效果。此时的处理间隔只要在能够发挥本发明效果的范围,则没有特别限定,通常优选为距各个单独制剂的处理在3个月以内,特别优选为2个月以内。此时,可以将任意有效成分先进行处理,也可以采用各自不同的处理方法。
此外,近年来使用昆虫性信息素(卷叶蛾类、甘蓝夜蛾类的通信干扰剂等)、天敌昆虫等的IPM(害虫综合治理)技术已经进步,本发明的药剂可以与这些技术并用,或系统化使用。
本发明的农业园艺用杀虫剂组合物的处理量根据各种因素、例如目的、对象害虫、作物的生长状况、天气、环境条件、剂型、施用方法、施用位置、或施用时期等发生变动,作为有效成分化合物,在散布处理的情况下,以氟虫双酰胺1g~200g/公顷、唑虫酰胺10g~500g/公顷的范围适当地对对象作物进行处理即可,在土壤或灌注处理的情况下,以氟虫双酰胺1g~100g/公顷、唑虫酰胺5g~300g/公顷的范围对对象作物生长的周边土壤进行散布或灌注处理即可。
本发明的农业园艺用杀虫剂组合物适于以下的水稻、蔬菜、果树、其他的花卉等各种农林、园艺储粮害虫、卫生害虫或线虫等的防除。
作为鳞翅目(鳞翅目),例如可以列举:绿刺蛾(Parasaconsocia)、桥夜蛾(Anomismesogona)、柑橘凤蝶(Papilioxuthus)、日豆小卷蛾(Matsumuraesesazukivora)、麻田豆秆野螟(Ostriniascapulalis)、莎草粘虫(Spodopteraexempta)、美国白蛾(Hyphantriacunea)、亚洲玉米螟(Ostriniafurnacalis)、东方粘虫(Pseudaletiaseparata)、蠹虫(Tineatranslucens)、尖翅小卷蛾(Bactrafurfurana)、直纹稻弄蝶(Parnaraguttata)、稻显纹刷须野螟(Marasmiaexigua)、直纹稻弄蝶(Parnaraguttata)、大螟(Sesamiainferens)、甘薯麦蛾(Brachmiatriannulella)、黄刺蛾(Monemaflavescens)、粉纹夜蛾(Trichoplusiani)、苧麻肋野螟蛾(Pleuroptyaruralis)、小蜻蜓尺蛾(Cystidiacouaggaria)、亮灰蝶(Lampidesboeticus)、透翅天蛾(Cephonodeshylas)、棉铃虫(Helicoverpaarmigera)、曼蚕舟蛾(Phalerodontamanleyi)、大避债蛾(Eumetajaponica)、大菜粉蝶(Pierisbrassicae)、天幕毛虫(Malacosomaneustriatestacea)、柿举肢蛾(Stathmopodamasinissa)、柿细蛾(Cuphodesdiospyrosella)、角纹卷叶虫(Archipsxylosteanus)、黄地老虎(Agrotissegetum)、甘蔗黄螟(Tetramoeraschistaceana)、黄凤蝶(Papiliomachaonhippocrates)、黃斑蝙蝠蛾(Endoclytasinensis)、银纹潜蛾(Lyonetiaprunifoliella)、金纹小潜细蛾(Phyllonorycterringoneella)、栗白小卷蛾(Cydiakurokoi)、栗绿小卷蛾(Eucoenogenesaestuosa)、葡萄花翅小卷蛾(Lobesiabotrana)、中国绿刺蛾(Latoiasinica)、皮暗斑螟(Euzopherabatangensis)、慈姑褐纹蛾(Phalonidiamesotypa)、桑斑灯蛾(Spilosomaimparilis)、桑绢野螟(Glyphodespyloalis)、桑卷叶蛾(Olethreutesmori)、幕谷蛾(Tineolabisselliella)、蝙蝠蛾(Endoclytaexcrescens)、谷蛾(Nemapogongranellus)、苹果透翅蛾(Synanthedonhector)、苹果蠹蛾(Cydiapomonella)、小菜蛾(Plutellaxylostella)、稻纵卷叶野螟(Cnaphalocrocismedinalis)、蛀茎夜蛾(Sesamiacalamistis)、三化螟(Scirpophagaincertulas)、兰草螟蛾(Pediasiateterrellus)、马铃薯块茎蛾(Phthorimaeaoperculella)、苹蚁舟蛾(Stauropusfagipersimilis)、豆荚螟(Etiellazinckenella)、甜菜夜蛾(Spodopteraexigua)、白斑蝙蝠蛾(Palpifersexnotata)、灰翅夜蛾(Spodopteramanuritia)、稻白螟(Scirpophagainnotata)、八字地老(Xestiac-nigrum)、淡剑纹灰翅夜蛾(Spodopteradepravata)、地中海斑螟(Ephestiakuehniella)、李尺蛾(Angeronaprunaria)、分月扇舟蛾(Closteraanastomosis)、大豆夜蛾(Pseudoplusiaincludens)、松村氏捲蛾(Matsumuraesesfalcana)、烟夜蛾(Helicoverpaassulta)、黑点丫纹夜蛾(Autographanigrisigna)、球菜夜蛾(Agrotisipsilon)、茶毒蛾(Euproctispseudoconspersa)、棉褐带卷蛾(Adoxophyesorana)、茶细蛾(Caloptiliatheivora)、茶长卷蛾(Homonamagnanima)、烟草粉斑螟(Ephestiaelutella)、茶避债蛾(Eumetaminuscula)、杨扇舟蛾(Closteraanachoreta)、苜蓿夜蛾(Heliothismaritima)、葡萄长须卷蛾(Sparganothispilleriana)、玉米茎夜蛾(Busseolafusca)、折带黄毒蛾(Euproctissubflava)、褐纹大尺蛾(Bistonrobustum)、美洲棉铃虫(Heliothiszea)、甘薯烦夜蛾(Aedialeucomelas)、梨娜刺蛾(Narosoideusflavidorsalis)、梨剑纹夜蛾(Viminiarumicis)、潜蛾(Bucculatrixpyrivorella)、梨小食心虫(Grapholitamolesta)、梨潜皮蛾(Spulerinaastaurota)、梨云翅斑螟(Ectomyeloispyrivorella)、二化螟(Chilosuppressalis)、葱菜蛾(Acrolepiopsissapporensis)、印度谷螟(Plodiainterpunctella)、菜心野螟蛾(Hellulaundalis)、麦蛾(Sitotrogaceralella)、斜纹夜蛾(Spodopteralitura)、绿豆芽蛾(Eucosmaaporema)、草莓长翅卷蛾(Acleriscomariana)、球须刺蛾(Scopelodescontracus)、旋古毒蛾(Orgyiathyellina)、草地夜蛾(Spodopterafrugiperda)、Ostriniazaguliaevi、双带夜蛾(Narangaaenescens)、茶蚕(Andracabipunctata)、葡萄透翅蛾(Paranthreneregalis)、缺角天蛾(Acosmeryxcastanea)、葡萄潜叶蛾(Phyllocnististoparcha)、葡萄浆果蛾(Endopizaviteana)、环针单纹蛾(Eupoecilliaambiguella)、大豆夜蛾(Anticarsiagemmatalis)、Cnephasiacinereipalpana、舞毒蛾(Lymantriadispar)、赤松毛虫(Dendrolimusspectabilis)、大豆食心虫(Leguminivoraglycinivorella)、豆荚野螟(Marucatestulalis)、豆小卷蛾(Matsumuraesesphaseoli)、大豆丽细蛾(Caloptiliasoyella)、柑桔叶潜蛾(Phyllocnistiscitrella)、Hadyleptaindicata、杏黄卷蛾(Archipsfuscocupreanus)、银纹夜蛾(Acanthoplusiaagnata)、桑蓑蛾(Bambalinasp.)、桃蛀果蛾(Carposinaniponensis)、桃蛀螟(Conogethespunctiferalis)、樟兴透翅蛾(Synanthedonsp.)、桃潜蛾(Lyonetiaclerkella)、小黄斑粉蝶(Papiliohelenus)、斑缘豆粉蝶(Coliaseratepoliographus)、苹掌舟蛾(Phaleraflavescens)、小菜蛾(Pierisrapae)等粉蝶类、桑毛虫(Euproctissimilis)、Acrolepiopsissuzukiella、欧洲玉米螟(Ostrinianubilalis)、甘蓝夜蛾(Mamestrabrassicae)、大造桥虫(Ascotisselenaria)、艾草大细卷叶蛾(Phtheochroidesclandestina)、北川卷蛾(Hoshinoaadumbratana)、圆斑黄枯叶蝶(Odonestisprunijaponensis)、苹剑纹夜蛾(Triaenaintermedia)、苹小卷叶蛾(Adoxophyesoranafasciata)、苹小食心虫(Grapholitainopinata)、苹白小卷蛾(Spilonotaocellana)、顶梢卷叶蛾(Spilonotalechriaspis)、梨星毛虫(Illiberispruni)、苹果银蛾(Argyresthiaconjugella)、猛花细蛾(Caloptiliazachrysa)、梨黄卷蛾(Archipsbreviplicanus)、小造桥夜蛾(Anomisflava)、棉红铃虫(Pectinophoragossypiella)、棉大卷叶野螟(Notarchaderogata)、瓜绢野螟(Diaphaniaindica)、烟芽夜蛾(Heliothisvirescens)及鼎点钻夜蛾(Eariascupreoviridis)等,
作为半翅目(Hemiptera),例如可以列举:稻绿椿(Nezaraantennata)、赤条纤盲蝽(Stenotusrubrovittatus)、黑条红椿象(Graphosomarubrolineatum)、条赤须盲蝽(Trigonotyluscoelestialium)等、黄伊缘蝽(Aeschyntelesmaculatus)、Creontiadespallidifer、赤星椿象(Dysdercuscingulatus)、褐圆介壳虫(Chrysomphalusficus)、枳壳圆蹄盾蚧(Aonidiellaaurantii)、油蝉(Graptopsaltrianigrofuscata)、麦长蝽(Blissusleucopterus)、吹绵蚧(Iceryapurchasi)、壁椿(Piezodorushybneri)、稻褐蝽(Lagynotomuselongatus)、白翅叶蝉(Thaiasubrufa)、稻黑蝽(Scotinopharalurida)、玫瑰蚜(Sitobionibarae)、Stariodesiwasakii、椰圆盾蚧(Aspidiotusdestructor)、苍白泰盲蝽(Taylorilyguspallidulus)、杏瘤蚜(Myzusmumecola)、梅白蚧(Pseudaulacaspisprunicola)、豌豆蚜(Acyrthosiphonpisum)、纹须同缘椿象(Anacanthocorisstriicornis)、跃盲蝽(Ectometopterusmicantulus)、日本二星棒(Eysarcorislewisi)、巨叶足虫(Molipteryxfulginosa)、大青叶蝉(Cicadellaviridis)、红腹缢管蚜(Rhopalosophumrufiabdominalis)、黑蜡蚧(Saissetiaoleae)、温室粉虱(Trialeurodesvaporariorum)、橡木叶蝉(Aguriahanaquercus)、草盲蝽属(Lygussp.)、桦绵斑蚜(Euceraphispunctipennis)、柑橘介壳虫(Andaspiskashicola)、橘软蜡蚧(Coccuspseudomagnoliarum)、甘蔗异背长蝽(Caveleriussaccharivorus)、长贝脊网蝽(Galeatusspinifrons)、菊小长管蚜(Macrosiphoniellasanborni)、黄圆蹄盾蚧(Aonidiellacitrina)、茶翅蝽(Halyomorphamista)、樟网蝽(Stephanitisfasciicarina)、樟木虱(Triozacamphorae)、中华稻缘蝽(Leptocorisachinensis)、Triozaquercicola、黄角肩网蝽(Uhleriteslatius)、葡萄伴斑叶蝉(Erythroneuracomes)、长蝽(Paromiusexguus)、柘柳重圆盾蚧(Duplaspidiotusclaviger)、二条斑黑尾叶蝉(Nephotettixnigropictus)、庭园盲蝽(Halticiellusinsularis)、甘蔗扁角飞虱(Perkinsiellasaccharicida)、苹果木虱(Psyllamalivorella)、桑木虱(Anomomeuramori)、长尾粉蚧(Pseudococcuslongispinis)、桑白盾蚧(Pseudaulacaspispentagona)、桑绵蜡蚧(Pulvinariakuwacola)、绿盲蝽(Apolyguslucorum)、葫芦长蝽(Togohemipterus)、桔二叉蚜(Toxopteraaurantii)、糖粉蚧(Saccharicoccussacchari)、蔗根蚜(Geoicalucifuga)、瓶额飞虱(Numatamuiri)、梨圆介壳虫(Comstockaspisperniciosa)、桔矢尖盾蚧(Unaspiscitri)、茄沟无网蚜(Aulacorthumsolani)、广二星蝽(Eysarcorisventralis)、银叶粉虱(Bemisiaargentifolii)、大白叶蝉(Cicadellaspectra)、春藤圆盾蚧(Aspidiotushederae)、粟缘蝽(Liorhyssushyalinus)、黑背丽木虱(Calophyanigridorsalis)、白背稻虱(Sogatellafurcifera)、空豆髭长油虫(Megouracrassicauda)、甘蓝蚜(Brevicorynebrassicae)、大豆蚜(Aphisglycines)、稻斑腹蛛缘蝽(Leptocorisaoratorius)、二点黑尾叶蝉(Nephotettixvirescens)、莴苣指管蚜(Uroeuconformosanum)、烟盲蝽(Cyrtopeltistennuis)、烟粉虱(Bemisiatabaci)、桃蜡蚧(Lecaniumpersicae)、茶糠蚧(Parlatoriatheae)、牡丹网纹盾蚧(Pseudaonidiapaeoniae)、大贯小绿叶蝉(Empoascaonukii)、褐翅绿椿象(Plautiastali)、百合西圆尾蚜(Dysaphistulipae)、大戟长管蚜(Macrosiphumeuphorbiae)、杜鹃冠网蝽(Stephanitispyrioides)、角蜡蚧(Ceroplastesceriferus)、山茶糠蚧(Parlatoriacamelliae)、淡娇异蝽(Apolygusspinolai)、黑尾叶蝉(Nephotettixcincticeps)、青蝽(Glauciassubpunctatus)、杂毛合垫盲蝽(Orthotylusflavosparsus)、玉米蚜(Rhopalosiphummaidis)、玉米蜡蝉(Peregrinusmaidis)、二星蝽(Eysarcorisparvus)、温带臭虫(Cimexlectularius)、冷杉木虱(Psyllaabieti)、褐飞虱(Nilaparvatalugens)、海桐木虱(Psyllatobirae)、皱纹菜蝽(Eurydemarugosum)、梨二叉蚜(Schizaphispiricola)、梨黄木虱(Psyllapyricola)、梨星片盾蚧(Parlatoreopsispyri)、梨冠网蝽(Stephanitissashi)、水松粉蚧(Dysmicoccuswistariae)、梨蚧(Lepholeucaspisjaponica)、梨园尾蚜(Sappaphispiri)、萝卜蚜(Lipaphiserysimi)、台湾韭蚜(Neotoxopteraformosana)、莲缢管蚜(Rhopalosophumnymphaeae)、蔷薇小叶蝉(Edwardsianarosae)、苏铁褐点盾蚧(Pinnaspisaspidistrae)、赤杨木虱(Psyllaalni)、叶蝉(Speusotettixsubfusculus)、杂食性叶蝉(Alnetoidiaalneti)、稗飞虱(Sogatellapanicicola)、苜蓿盲蝽(Adelphocorislineolatus)、联斑棉红蝽(Dysdercuspoecilus)、黑片盾蚧(Parlatoriaziziphi)、褐角肩网蝽(Uhleritesdebile)、灰飞虱(Laodelphaxstriatellus)、六斑菜蝽(Eurydemapulchrum)、长肩棘缘椿象(Cletustrigonus)、一点铲头沫蝉(Cloviapunctata)、小绿叶蝉(Empoascasp.)、褐软蜡蚧(Coccushesperidum)、草鼓胸长蝽(Pachybrachiusluridus)、藤臀纹粉蚧(Planococcuskraunhiae)、双斑盲蝽(Stenotusbinotatus)、葡萄阿小叶蝉(Arboridiaapicaris)、二点叶蝉(Macrostelesfascifrons)、斑须蝽(Dolycorisbaccarum)、三环苜蓿盲蝽(Adelphocoristriannulatus)、葡萄根瘤蚜(Viteusvitifolii)、瘤缘椿象(Acanthocorissordidus)、大稻缘蝽(Leptocorisaacuta)、瘤腹巨股长蝽(Macropesobnubilus)、稻棘缘蝽(Cletuspunctiger)、点蜂缘椿象(Riptortusclavatus)、番茄木虱(Paratriozacockerelli)、柳尖胸沫蝉(Aphrophoracostalis)、日本草盲蝽(Lygusdisponsi)、东亚草盲蝽(Lygussaundersi)、松白粉蚧(Crisicoccuspini)、松小叶蝉(Empoascaabietis)、松粉蚧(Crisicoccusmatsumotoi)、豆蚜(Aphiscraccivora)、臭蝽(Megacoptapunctatissimum)、圆白星椿象(Eysarcorisguttiger)、紫疤蛎盾蚧(Lepidosaphesbeckii)、柑桔木虱(Diaphorinacitri)、桔蚜(Toxopteracitricidus)、柑桔粉蚧(Planococcuscitri)、柑橘粉虱(Dialeurodescitri)、黑刺粉虱(Aleurocanthusspiniferus)、桔小粉蚧(Pseudococcuscitriculus)、Zyginellacitri、桔绵蜡蚧(Pulvinariacitricola)、偏软蜡蚧(Coccusdiscrepans)、蛇眼臀网盾蚧(Pseudaonidiaduplex)、柑橘绵蚧(Pulvinariaaurantii)、东方球蜡蚧(Lecaniumcorni)、稻绿蝽(Nezaraviridula)、二刺狭盲蝽(Stenodemacalcaratum)、禾谷缢管蚜(Rhopalosiphumpadi)、麦长管蚜(Sitobionakebiae)、麦二叉蚜(Schizaphisgraminum)、麦叶蝉(Sorhoanustritici)、光管舌尾蚜(Brachycaudushelichrysi)、紫翅果蝽(Carpocorispurpureipennis)、桃蚜(Myzuspersicae)、桃大尾蚜(Hyalopteruspruni)、柳蚜(Aphisfarinoseyanagicola)、杨柳网蝽(Metasalispopuli)、矢尖盾蚧(Unaspisyanonensis)、芙蓉木虱(Mesohomotomacamphorae)、绣线菊蚜(Aphisspiraecola)、苹果蚜(Aphispomi)、榆蛎盾蚧(Lepidosaphesulmi)、苹木虱(Psyllamali)、苹叶盲蝽(Heterocordylusflavipes)、苹果瘤蚜(Myzusmalisuctus)、苹果蚜虫(Aphidonuguismali)、苹果叶蝉(Orientusishidai)、苹果蚜(Ovatusmalicolens)、苹绵蚜(Eriosomalanigerum)、红蜡蚧(Ceroplastesrubens)、棉蚜(Aphisgossypii)等。
作为鞘翅目(Coleoptera),例如可以列举:合欢双条天牛(Xystroceraglobosa)、毒隐翅虫(Paederusfuscipes)、金边青花金龟(Eucetoniaroelofsi)、绿豆象(Callosobruchuschinensis)、甘薯小象(Cylasformicarius)、紫苜蓿叶象(Hyperapostica)、稻象甲(Echinocnemussquameus)、水稻负泥虫(Oulemaoryzae)、长腿水叶甲(Donaciaprovosti)、稻水象甲(Lissorhoptrusoryzophilus)、甘薯叶甲(Colasposomadauricum)、西印度甘薯象甲(Euscepespostfasciatus)、墨西哥豆瓢虫(Epilachnavarivestis)、菜豆象(Acanthoscelidesobtectus)、玉米根叶甲(Diabroticavirgiferavirgifera)、李蓝卷象(Involvuluscupreus)、黄守瓜(Aulacophorafemoralis)、豌豆象(Bruchuspisorum)、马铃薯瓢虫(Epilachnavigintioctomaculata)、脊胸露尾甲(Carpophilusdimidiatus)、甜菜大龟甲(Cassidanebulosa)、粗背寡毛跳甲(Luperomorphatunebrosa)、黄曲条菜跳甲(Phyllotretastriolata)、黄星天牛(Psacotheahilaris)、黄斑天牛(Aeolestheschrysothrix)、蒙栎象(Curculiosikkimensis)、酱曲露尾甲(Carpophilushemipterus)、小青花金龟(Oxycetoniajucunda)、根萤叶甲(Diabroticasp.)、亮绿彩丽金龟(Mimelasplendens)、玉米象(Sitophiluszeamais)、赤拟谷盗(Triboliumcastaneum)、米象(Sitophilusoryzae)、亚扁粉盗(Palorussubdepressus)、日本豆金龟(Melolonthajaponica)、星天牛(Anoplophoramalasiaca)、大点拟粉虫(Neatuspicipes)、马铃薯叶甲(Leptinotarsadecemlineata)、黄瓜十一星叶甲食根亚种(Diabroticaundecimpunctatahowardi)、猎象(sphenophorusvenatus)、十四点负泥虫(Criocerisquatuordecimpunctata)、梅球颈象(Conotrachelusnenuphar)、大根猿象虫(Ceuthorhynchidiusalbosuturalis)、小猿叶虫(Phaedonbrassicae)、烟草甲(Lasiodermaserricorne)、日本根瘤象(Sitonajaponicus)、斑喙丽金龟(Adoretustenuimaculatus)、面粉甲虫(Tenebriomolitor)、黄粉虫猴子甲虫(Basileptabalyi)、小车轴草叶象甲(Hyperanigrirostris)、甜菜跳甲(Chaetocnemaconcinna)、大绿丽金龟(Anomalacuprea)、黑七鳃金龟(Heptophyllapicea)、茄二十八星瓢虫(Epilachnavigintioctopunctata)、长角叶甲(Diabroticalongicornis)、花甲虫(ucetoniapilifera)、叩甲(Agriotesspp.)、黑毛皮蠹(Attagenusunicolorjaponicus)、斑鞘豆叶甲(Pagriasignata)、红铜丽金龟(Anomalarufocuprea)、姬帕谷甲(Palorusratzeburgii)、褐菌虫(Alphitobiuslaevigatus)、地毯甲虫(Anthrenusverbasci)、褐粉蠹(Lyctusbrunneus)、杂拟谷盗(Triboliumconfusum)、黑条麦萤叶甲(Medythianigrobilineata)、葡萄脊虎天牛(Xylotrechuspyrrhoderus)、黄瓜跳甲(Epitrixcucumeris)、纵坑切梢小蠹(Tomicuspiniperda)、松墨天牛(Monochamusalternatus)、日本豆金龟(Popilliajaponica)、豆芫青(Epicautagorhami)、玉米象(Sitophiluszeamais)、日本苹虎象(Rhynchitesheros)、蔬菜叶象甲(Listroderescostirostris)、四纹豆象(Callosobruchusmaculatus)、苹霜绿切叶象(Phyllobiusarmatus)、苹果开花象鼻虫(Anthonomuspomorum)、铜绿里叶甲(Linaeideaaenea)、墨西哥棉铃象(Anthonomusgrandis)等。
作为双翅目(Diptera),例如可以列举:淡色库蚊(Culexpipienspallens)、甜菜潜叶蝇(Pegomyahyoscyami)、南美斑潜蝇(Liriomyzahuidobrensis)、家蝇(Muscadomestica)、稻秆蝇(Chloropsoryzae)、稻心蝇(Hydrelliasasakii)、日本稻潜蝇(Agromyzaoryzae)、姬稻潜叶蝇(Hydrelliagriseola)、麦叶毛眼水蝇(Hydrelliagriseola)、菜豆蛇潜蝇(Ophiomyiaphaseoli)、瓜实蝇(Dacuscucurbitae)、樱桃果蝇(Drosophilasuzukii)、日本樱桃实蝇(Rhacochlaenajaponica)、厩腐蝇(Muscinastabulans)、东亚异蚤蝇(Megaseliaspiracularis)等蚤蝇科类、毛蠓(Clogmiaalbipunctata)、稻大蚊(Tipulaaino)、伏蝇(Phormiaregina)、三带喙库蚊(Culextritaeniorhynchus)、中华按蚊(Anophelessinensis)、甘蓝地种蝇(Hylemyabrassicae)、大豆荚瘿蝇(Asphondyliasp.)、灰地种蝇(Deliaplatura)、葱地种蝇(Deliaantiqua)、樱桃绕实绳(Rhagoletiscerasi)、地下家蚊(CulexpipiensmolestusForskal)、地中海实蝇(Ceratitiscapitata)、黑翅蕈蝇(Bradysiaagrestis)、肖藜泉蝇(Pegomyacunicularia)、美洲斑潜蝇(Liriomyzasativae)、番茄斑潜蝇(Liriomyzabryoniae)、豌豆彩潜蝇(Chromatomyiahorticola)、葱斑潜蝇(Liriomyzachinensis)、致倦库蚊(Culexquinquefasciatus)、埃及伊蚊(Aedesaegypti)、白纹伊蚊(Aedesalbopictus)、三叶斑潜蝇(Liriomyzatrifolii)、东方果实蝇(Dacusdorsalis)、蜜柑大实蝇(Dacustsuneonis)、麦红吸浆虫(Sitodiplosismosellana)、黑腹麦秆蝇(Meromuzanigriventris)、墨西哥按实蝇(Anastrephaludens)、苹果实蝇(Phagoletispomonella)等。
作为膜翅目(Hymenoptera),例如,可以列举:短刺棱胸切叶蚁(Pristomyrmexpungens)、肿腿蜂科类、法老蚁(Monomoriumpharaosis)、宽节大头蚁(Pheidolenoda)、菜叶蜂(Athaliarosae)、栗瘿蜂(Dryocosmuskuriphilus)等、日本黑褐蚁(Formicafuscajaponica)、胡蜂亚科类、黑背白萝卜叶蜂(Athaliainfumatainfumata)、月季叶蜂(Argepagana)、日本芜菁叶蜂(Athaliajaponica)、切叶蚁(Acromyrmexspp.)、火蚁(Solenopsisspp.)、苹果三节叶蜂(Argemali)和光滑管琉璃蚁(Ochetellusglaber)等。
作为直翅目(Acrididae),例如可以列举:南方稻草螽(Homorocoryphuslineosus)、蝼蛄(Gryllotalpasp.)、小稻蝗(Oxyahylaintricata)、小翅稻蝗(Oxyayezoensis)、飞蝗(Locustamigratoria)、短翅稻蝗(Oxyajaponica)、北方水稻螽斯(Homorocoryphusjezoensis)、黄脸油葫芦(Teleogryllusemma)等。
作为缨翅目,例如,可以列举:红带滑胸针蓟马(Selenothripsrubrocinctus)、稻蓟马(Stenchaetothripsbiformis)、稻管蓟马(Haplothripsaculeatus)、Ponticulothripsdiospyrosi等、黄蓟马(Thripsflavus)、玉米黄呆蓟马(Anaphothripsobscurus)、佛州樟蓟马(Liothripsfloridensis)、唐菖蒲简蓟马(Thripssimplex)、菊黑毛蓟马(Thripsnigropilosus)、温室蓟马(Heliothripshaemorrhoidalis)、桑蓟马(Pseudodendrothripsmori)、腹小头蓟马(Microcephalothripsabdominalis)、帕氏毛管蓟马(Leeuweniapasanii)、Litotetothripspasaniae、柑桔硬蓟马(Scirtothripscitri)、华简管蓟马(Haplothripschinensis)、豆喙蓟马(Mycterothripsglycines)、毛蓟马(Thripssetosus)、茶黄蓟马(Scirtothripsdorsalis)、茶棍蓟马(Dendrothripsminowai)、黑角简管蓟马(Haplothripsniger)、烟蓟马(Thripstabaci)、葱蓟马(Thripsalliorum)、黄胸蓟马(Thripshawaiiensis)、豆简管蓟马(Haplothripskurdjumovi)、袖指蓟马(Chirothripsmanicatus)、花蓟马(Fankliniellaintonsa)、日本蓟马(Thripscoloratus)、西花蓟马(Franklinellaoccidentalis)、棕榈蓟马(Thripspalmi)、百合蓟马(Frankliniellalilivora)、百合滑管蓟马(Liothripsvaneeckei)等。
作为蜱螨目,例如,可以列举:红纤沙螨(Leptotrombidiumakamushi)、卢氏叶螨(Tetranychusludeni)、变异革蜱(Dermacentorvariabilis)、截形叶螨(Tetranychustruncatus)、柏氏禽刺螨(Ornithonyssusbacoti)、犬蠕形螨(Demodexcanis)、山楂叶螨(Tetranychusviennensis)、神泽氏叶螨(Tetranychuskanzawai)、血红扇头蜱(Rhipicephalussanguineus)等硬蜱科类、马六甲肉食螨(Cheyletusmalaccensis)、腐食酪螨(Tyrophagusputrescentiae)、粉剂螨(Dermatophagoidesfarinae)、红背蜘蛛(Latrodectushasseltii)、台湾革蜱(Dermacentortaiwanicus)、茶尖叶节蜱(Acaphyllatheavagrans)、侧多食跗线螨(Polyphagotarsonemuslatus)、番茄刺皮瘿螨(Aculopslycopersici)、Ornithonyssussylvairum、二斑叶螨(Tetranychusurticae)、中国瘿螨(Eriophyeschibaensis)、人疥螨(Sacroptesscabiei)、长角血蜱(Haemaphysalislongicornis)、有胛硬蜱(Ixodesscapularis)、似食酪螨(Tyrophagussimilis)、普通肉食螨(Cheyletuseruditus)、柑桔全爪螨(Panonychuscitri)、莫氏肉食螨(Cheyletusmoorei)、紫红短须螨(Brevipalpusphoenicis)、犬猫耳螨(Octodectescynotis)、欧洲室尘螨(Dermatophagoidesptrenyssnus)、褐黄血蜱(Haemaphysalisflava)、卵形硬蜱(Ixodesovatus)、琉球柑橘锈螨(Phyllocoptrutacitri)、苹刺瘿螨(Aculusschlechtendali)、苹果全爪螨(Panonychusulmi)、美洲花蜱(Amblyommaamericanum)和鸡皮刺螨(Dermanyssusgallinae)等。
作为等翅目,例如,可以列举:奄美大白蚁(Reticulitermesmiyatakei)、小楹白蚁(Incisitermesminor)、家白蚁(Coptotermesformosanus)、日本湿木蚁(Hodotermopsisjaponica)、散白蚁(Reticulitermessp.)、黄胸散白蚁(Reticulitermesflavicepsamamianus)、Glyptotermeskushimensis、广州乳白蚁(Coptotermesguangzhoensis)、恒春新白蚁(Neotermeskoshunensis)、儿玉白蚁(Glyptotermeskodamai)、赤树白蚁(Glyptotermessatsumensis)、截头堆砂白蚁(Cryptotermesdomesticus)、黑翅土白蚁(Odontotermesformosanus)、中岛白蚁(Glyptotermesnakajimai)、近扭白蚁(Pericapritermesnitobei)和栖北散白蚁(Reticulitermessperatus)等。
作为蜚蠊目,例如,可以列举:黑胸大蠊(Periplanetafuliginosa)、德国小蠊(Blattellagermanica)、东方蠊(Blattaorientalis)、密西西比黑蠊(Periplanetabrunnea)、拟德国小蠊(Blattellalituricollis)、日本大蠊(Periplanetajaponica)和美洲大蠊(PeriplanetaAmericana)等。
作为隐翅目,例如,可以列举:人蚤(Pulexirritans)、猫蚤(Ctenocephalidesfelis)和鸡蚤(Ceratophyllusgallinae)等。
作为线虫门类,例如,可以列举:草莓芽线虫(Nothotylenchusacris)、水稻干尖线虫(Aphelenchoidesbesseyi)、穿刺短体线虫(Pratylenchuspenetrans)、北方根结线虫(Meloidogynehapla)、南方根瘤线虫(Meloidogyneincognita)、罗斯托克异皮线虫(Globoderarostochiensis)、爪哇根结线虫(Meloidogynejavanica)、大豆胞囊线虫(Heteroderaglycines)、咖啡短体线虫(Pratylenchuscoffeae)、落选短体线虫(Pratylenchusneglectus)、柑桔半穿剌线虫(Tylenchussemipenetrans)等。
作为软体动物门类,例如,可以列举:福寿螺(Pomaceacanaliculata)、非洲大蜗牛(Achatinafulica)、双线蛞蝓(Meghimatiumbilineatum)、查科蛞蝓(Lehmanninavalentiana)、黄蛞蝓(Limacusflavus)、螺蛳(Acustadespectasieboldiana)。此外,还可以例示斑潜蝇(Tutaabsoluta)等农业园艺害虫。
在使用本发明的农业园艺用杀虫剂组合物的情况下,为了防除同时产生的病害虫及杂草等、效果的增强、减轻作物的药害,可以同时使用农业园艺用杀菌剂、农业园艺用杀虫剂、农业园艺用除草剂、增效剂及安全剂等。以下例示出该农业园艺用杀菌剂、农业园艺用杀虫剂、农业园艺用除草剂、增效剂或安全剂的代表化合物,但不限于这些。
作为农业园艺用杀菌剂,可以列举:金色制霉素(aureofungin)、阿扎康唑(azaconazole)、氧化福美双杀菌剂(azithiram)、acypetacs、活化酯(acibenzolar)、苯并噻二唑(acibenzolar-S-methyl)、嘧菌酯(azoxystrobin)、敌菌灵(anilazine)、吲唑磺菌胺(amisulbrom)、1-氨基丙基磷酸(ampropylfos)、唑嘧菌胺(ametoctradin)、烯丙醇(allylalcohol)、杀螟丹(aldimorph)、代森铵(amobam)、异噻菌胺(isotianil)、异酰菌酮(isovaledione)、萘吡菌胺(isopyrazam)、isofetamid、稻瘟灵(isoprothiolane)、种菌唑(ipconazole)、异菌脲(iprodione)、丙森辛(iprovalicarb)、异稻瘟净(iprobenfos)、抑霉唑(imazalil)、双胍辛胺(iminoctadine)、双胍辛胺-烷苯磺酸盐(iminoctadine-albesilate)、双胍辛胺-三乙酸盐(iminoctadine-triacetate)、酰胺唑(imibenconazole)、烯效唑(uniconazole)、烯效唑-P(uniconazole-P)、氯唑灵(echlomezole)、克瘟散(edifenphos)、乙环唑(etaconazole)、噻唑菌胺(ethaboxam)、乙菌定(ethirimol)、伊特姆(etem)、乙氧喹(ethoxyquin)、土菌灵(etridiazole)、烯肟菌酯(enestroburin)、氟环唑(epoxiconazole)、恶霜灵(oxadixyl)、氧化萎锈灵(oxycarboxin)、8-羟基喹啉铜(copper-8-quinolinolate)、土霉素(oxytetracycline)、喹啉铜(copper-oxinate)、恶咪唑(oxpoconazole)、恶咪唑富马酸盐(oxpoconazole-fumarate)、恶喹酸(oxolinicacid)、辛噻酮(octhilinone)、呋酰胺(ofurace)、肟醚菌胺(orysastrobin)、威百亩(metam-sodium)、春雷霉素(kasugamycin)、吗菌威(carbamorph)、环丙酰菌胺(carpropamid)、多菌灵(carbendazim)、萎锈灵(carboxin)、香芹酮(carvone)、醌菌腙(quinazamid)、羟基喹啉基乙酮(quinacetol)、喹氧灵(quinoxyfen)、灭螨猛(chinomethionat)、灭螨猛(quinomethionate)、敌菌丹(captafol)、克菌丹(captan)、精苯霜灵(kiralaxyl)、氯苯喹唑(quinconazole)、五氯硝基苯(quintozene)、双胍盐(guazatine)、硫杂灵(cufraneb)、福美铜氯(cuprobam)、果绿定(glyodin)、灰黄霉素(griseofulvin)、甘宝素(climbazole)、甲酚(cresol)、醚菌酯(kresoxim-methyl)、乙菌利(chlozolinate)、克霉唑(clotrimazole)、灭瘟唑(chlobenthiazone)、双胺灵(chloraniformethan)、氯醌(chloranil)、四氯喹恶啉(chlorquinox)、氯化苦(chloropicrin)、氯芬唑(chlorfenazole)、氯二硝基萘(chlorodinitronaphthalene)、百菌清(chlorothalonil)、地茂散(chloroneb)、水杨酰苯胺(salicylanilide)、氰菌胺(zarilamid)、氰霜唑(cyazofamid)、焦碳酸二乙酯(diethylpyrocarbonate)、乙霉威(diethofencarb)、环菌胺(cyclafuramid)、双氯氰菌胺(diclocymet)、菌核利杀菌剂(dichlozoline)、苄氯三唑醇(diclobutrazol)、抑菌灵(dichlofluanid)、放线菌酮(cycloheximide)、哒菌清(diclomezine)、氯硝胺(dicloran)、双氯酚(dichlorophen)、二氯萘醌(dichlone)、双硫仑(disulfiram)、灭菌磷(ditalimfos)、二噻农(dithianon)、烯唑醇(diniconazole)、烯唑醇-M(diniconazole-M)、代森锌(zineb)、敌螨普(dinocap)、邻敌螨消(dinocton)、硝辛酯(dinosulfon)、硝丁酯(dinoterbon)、敌螨通(dinobuton)、硝戊酯(dinopenton)、双硫氧吡啶(dipyrithione)、二苯胺(diphenylamine)、苯醚甲环唑(difenoconazole)、环氟菌胺(cyflufenamid)、二氟林(diflumetorim)、环唑醇(cyproconazole)、嘧菌环胺(cyprodinil)、酯菌胺(cyprofuram)、氰菌灵(cypendazole)、硅氟唑(simeconazole)、甲菌定(dimethirimol)、烯酰吗啉(dimethomorph)、霜脲氰(cymoxanil)、醚菌胺(dimoxystrobin)、甲基溴(methylbromide)、福美锌(ziram)、硅噻菌胺(silthiofam)、链霉素(streptomycin)、螺环菌胺(spiroxamine)、戊苯砜(sultropen)、环苯吡菌胺(sedaxane)、苯酰菌胺(zoxamide)、棉隆(dazomet)、代森环(thiadiazin)、噻酰菌胺(tiadinil)、巯基乙醇(thiadifluor)、噻菌灵(thiabendazole)、硫氰苯甲酰胺(tioxymid)、克杀螨(thioquinox)、硫氯苯亚胺(thiochlorfenphim)、硫菌灵(thiophanate)、甲基硫菌灵(thiophanate-methyl)、噻菌腈(thicyofen)、噻呋酰胺(thifluzamide)、福美双(thiram)、癸磷锡(decafentin)、四氧硝基苯(tecnazene)、叶枯酞(tecloftalam)、福美双联(tecoram)、氟醚唑(tetraconazole)、咪菌威(debacarb)、脱氢乙酸(dehydroaceticacid)、戊唑醇(tebuconazole)、异丁乙氧喹啉(tebufloquin)、多地辛(dodicin)、多果定(dodine)、十二烷基苯磺酸双乙二胺铜络盐(II)(DBEDC)、吗菌灵(dodemorph)、敌菌酮(drazoxolon)、三唑醇(triadimenol)、三唑酮(triadimefon)、丁三唑(triazbutil)、唑菌嗪(triazoxide)、威菌磷(triamiphos)、嘧菌醇(triarimol)、水杨菌胺(trichlamide)、三环唑(tricyclazole)、灭菌唑(triticonazole)、十三吗啉(tridemorph)、三丁基氧化锡(tributyltinoxide)、氟菌唑(triflumizole)、肟菌酯(trifloxystrobin)、嗪氨灵(triforine)、对甲抑菌灵(tolylfluanid)、甲基立枯磷(tolclofos-methyl)、氨基甲酸酯类杀菌剂(tolprocarb)、游霉素(natamycin)、代森钠(nabam)、硝基苯乙烯(nitrostyrene)、酞菌酯(nitrothal-isopropyl)、氟苯嘧啶醇(nuarimol)、壬基苯酚磺酸铜(coppernonylphenolsulfonate)、丙烯酸喹啉酯(halacrinate)、有效霉素(validamycin)、valifenalate、超敏蛋白(harpinprotein)、联苯吡菌胺(bixafen)、啶氧菌酯(picoxystrobin)、氟吡菌胺(picobenzamide)、硫双二氯酚(bithionol)、双苯三唑醇(bitertanol)、羟基异恶唑(hydroxyisoxazole)、羟基异恶唑钾(hydroxyisoxazole-potassium)、乐杀螨(binapacryl)、联苯(biphenyl)、粉病灵(piperalin)、恶霉灵(hymexazol)、唑菌酯(pyraoxystrobin)、比锈灵(pyracarbolid)、吡唑醚菌酯(pyraclostrobin)、定菌磷(pyrazophos)、唑胺菌酯(pyrametostrobin)、甲氧苯啶菌(pyriofenone)、啶菌腈(pyridinitril)、啶斑肟(pyrifenox)、吡菌苯威(pyribencarb)、嘧霉胺(pyrimethanil)、甲氧氯吡啶(pyroxychlor)、吡氧呋(pyroxyfur)、咯喹酮(pyroquilon)、乙烯菌核利(vinclozolin)、福美铁(ferbam)、恶唑菌酮(famoxadone)、咪菌腈(fenapanil)、咪唑菌酮(fenamidone)、地克松(fenaminosulf)、氯苯嘧啶醇(fenarimol)、种衣酯(fenitropan)、稻瘟酰胺(fenoxanil)、嘧菌腙(ferimzone)、三苯锡(fentin)、拌种咯(fenpiclonil)、胺苯吡菌酮(fenpyrazamine)、腈苯唑(fenbuconazole)、甲呋酰胺(fenfuram)、苯锈啶(fenpropidin)、丁苯吗啉(fenpropimorph)、环酰菌胺(fenhexamid)、四氯苯酞(phthalide)、丁硫啶(buthiobate)、丁胺(butylamine)、磺酸丁嘧啶(bupirimate)、麦穗宁(fuberidazole)、杀稻瘟素S(blasticidin-S)、呋吡菌胺(furametpyr)、呋霜灵(furalaxyl)、嘧螨酯(fluacrypyrin)、氟啶胺(fluazinam)、氟嘧菌酯(fluoxastrobin)、氟苯三唑(fluotrimazole)、氟吡菌胺(fluopicolide)、氟吡菌酰胺(fluopyram)、氟酰亚胺(fluoroimide)、二甲呋酰胺(furcarbanil)、氟唑菌酰胺(fluxapyroxad)、氟喹唑(fluquinconazole)、呋菌唑(furconazole)、呋醚唑(furconazole-cis)、咯菌腈(fludioxonil)、氟硅唑(flusilazole)、磺菌胺(flusulfamide)、噻唑烷杀菌剂(flutianil)、氟酰胺(flutolanil)、粉唑醇(flutriafol)、糠醛(furfural)、拌种胺(furmecyclox)、氟联苯菌(flumetover)、氟吗啉(flumorph)、碘喹唑酮(proquinazid)、咪鲜胺(prochloraz)、腐霉利(procymidone)、胺丙威(prothiocarb)、丙硫菌唑(prothioconazole)、霜霉威(propamocarb)、丙环唑(propiconazole)、甲基代森锌(propineb)、呋菌隆(furophanate)、噻菌灵(probenazole)、糠菌唑(bromuconazole)、六氯丁二烯(hexachlorobutadiene)、己唑醇(hexaconazole)、hexylthiofos、bethoxazin、苯霜灵(benalaxyl)、苯霜灵M(benalaxyl-M)、麦锈灵(benodanil)、苯菌灵(benomyl)、稻瘟酯(pefurazoate)、敌菌腙(benquinox)、戊菌唑(penconazole)、benzamorf、戊菌隆(pencycuron)、苯甲羟肟酸(benzohydroxamicacid)、丙唑草隆(bentaluron)、苯噻硫氰(benthiazole)、苯噻菌胺(benthiavalicarb)、苯噻菌胺酯(benthiavalicarb-isopropyl)、吡噻菌胺(penthiopyrad)、戊苯吡菌胺(penflufen)、啶酰菌胺(boscalid)、氯瘟磷(phosdiphen)、藻菌磷(fosetyl)、藻菌磷铝(fosetyl‐Al)、多氧霉素(polyoxins)、保粒霉素(polyoxorim)、福代锌(polycarbamate)、灭菌丹(folpet)、甲醛(formaldehyde)、机油(machineoil)、代森锰(maneb)、代森锰锌(mancozeb)、双炔酰菌胺(mandipropamid)、甲菌利(myclozolin)、腈菌唑(myclobutanil)、
米多霉素(mildiomycin)、代森环(milneb)、咪卡病西(mecarbinzid)、磺菌威(methasulfocarb)、间氯敌菌酮(metazoxolon)、威百亩(metam)、威百亩钠(metam‐sodium)、甲霜灵(metalaxyl)、精甲霜灵(metalaxyl-M)、代森联(metiram)、异硫氰酸甲酯(methylisothiocyanate)、甲基敌螨普(meptyldinocap)、叶菌唑(metconazole)、噻菌胺(metsulfovax)、呋菌胺(methfuroxam)、苯氧菌胺(metominostrobin)、苯菌酮(metrafenone)、嘧菌胺(mepanipyrim)、甲霜灵(mefenoxam)、消螨多(meptyldinocap)、担菌宁(mepronil)、灭锈胺(mebenil)、碘代甲烷(iodomethane)、吡咪唑(rabenzazole)、苯扎氯铵(benzalkoniumchloride)、碱性氯化铜(basiccopperchloride)、碱性硫酸铜(basiccoppersulfate)、金属银(silver)等无机杀菌剂、次氯酸钠(sodiumhypochlorite)、氢氧化铜(cuprichydroxide)、可湿性硫粉剂(wettablesulfur)、石硫合剂(calciumpolysulfide)、碳酸氢钾(potassiumhydrogencarbonate)、碳酸氢钠(sodiumhydrogencarbonate)、无机硫(sulfur)、无水硫酸铜(coppersulfateanhydride)、有机镍(nickeldimethyldithiocarbamate)、有机铜(oxinecopper)、硫酸锌(zincsulfate)及五水硫酸铜(coppersulfate)等。
作为农业园艺用杀虫剂,可以列举:3,5-二甲苯基甲基氨基甲酸酯(XMC)、苏云金杆菌aizawai亚种(Bacillusthuringiensesaizawai)、苏云金杆菌以色列亚种(Bacillusthuringiensesisraelensis)、苏云金杆菌日本亚种(Bacillusthuringiensesjaponensis)、苏云金杆菌kurstaki亚种(Bacillusthuringienseskurstaki)、苏云金杆菌拟步甲亚种(Bacillusthuringiensestenebrionis)、苏云金杆菌(Bacillusthuringienses)生成的结晶蛋白毒素、BPMC、Bt毒素系杀虫性化合物、CPCBS(杀螨酯,chlorfenson)、DCIP(二氯二异丙醚,dichlorodiisopropylether)、D-D(1,3-二氯丙烯,1,3-Dichloropropene)、DDT、NAC、O-4-二甲基苯磺酰胺O,O-二乙基硫代磷酸酯(O-4-dimethylsulfamoylphenylO,O-diethylphosphorothioate)(DSP)、O-乙基O-4-硝基苯基苯基硫代磷酸酯(O-ethylO-4-nitrophenylphenylphosphonothioate)(EPN)、异氰脲酸三丙酯(TPIC)、氟酯菊酯(acrinathrin)、印楝素(azadirachtin)、甲基谷硫磷(azinphos-methyl)、灭螨醌(acequinocyl)、啶虫脒(acetamiprid)、乙酰虫腈(acetoprole)、乙酰甲胺磷(acephate)、阿福丁(abamectin)、afidopyropen、阿维菌素(avermectin-B)、磺胺螨酯(amidoflumet)、双甲脒(amitraz)、棉铃威(alanycarb)、涕灭威(aldicarb)、涕灭砜威(aldoxycarb)、艾氏剂(aldrin)、α-硫丹(alpha-endosulfan)、α-氯氰菊酯(alpha-cypermethrin)、阿苯达唑(albendazole)、丙烯菊酯(allethrin)、氯唑磷(isazofos)、isamidofos、加福松(isoxathion)、异柳磷(isofenphos)、异丙威(isoprocarb:MIPC)、伊维菌素(ivermectin)、imicyafos、吡虫啉(imidacloprid)、炔咪菊酯(imiprothrin)、茚虫威(indoxacarb)、高氰戊菊酯(esfenvalerate)、乙硫苯威(ethiofencarb)、乙硫磷(ethion)、乙虫腈(ethiprole)、乙螨唑(etoxazole)、醚菊酯(ethofenprox)、丙线磷(ethoprophos)、乙嘧硫磷(etrimfos)、埃玛菌素(emamectin)、甲氨基阿维菌素(emamectin-benzoate)、硫丹(endosulfan)、烯炔菊酯(empenthrin)、杀线威(oxamyl)、砜吸磷(oxydemeton-methyl)、异亚砜磷(oxydeprofos:ESP)、奥苯达唑(oxibendazole)、奥芬达唑(oxfendazole)、油酸钾(Potassiumoleate)、油酸钠(sodiumoleate)、硫线磷(cadusafos)、巴丹(cartap)、西维因(carbaryl)、丁硫克百威(carbosulfan)、克百威(carbofuran)、γ-氯氟氰菊酯(gamma-cyhalothrin)、灭杀威(xylylcarb)、喹硫磷(quinalphos)、烯虫炔酯(kinoprene)、灭螨猛(chinomethionat)、除线威(cloethocarb)、噻虫胺(clothianidin)、四螨嗪(clofentezine)、环虫酰肼(chromafenozide)、氯虫苯甲酰胺(chlorantraniliprole)、氯氧磷(chlorethoxyfos)、杀虫脒(chlordimeform)、氯丹(chlordane)、毒死蜱(chlorpyrifos)、甲基毒死蜱(chlorpyrifos-methyl)、溴虫腈(chlorphenapyr)、杀螨酯(chlorfenson)、毒虫畏(chlorfenvinphos)、定虫隆(chlorfluazuron)、乙酯杀螨醇(chlorobenzilate)、氯苯甲酸酯(chlorobenzoate)、三氯杀螨醇(ジコホル:dicofol)、杀力松(salithion)、杀螟腈(cyanophos:CYAP)、杀螨隆(diafenthiuron)、除线特(diamidafos)、溴氰虫酰胺(cyantraniliprole)、θ-氯氰菊酯(theta-cypermethrin)、除螨灵(dienochlor)、腈吡螨酯(cyenopyrafen)、蔬果磷(dioxabenzofos)、苯虫醚(diofenolan)、σ-氯氰菊酯(sigma-cypermethrin)、除线磷(dichlofenthion:ECP)、乙氰菊酯(cycloprothrin)、乙拌磷(disulfoton)、呋虫胺(dinotefuran)、氯氟氰菊酯(cyhalothrin)、苯醚氰菊酯(cyphenothrin)、氟氯氰菊酯(cyfluthrin)、除虫脲(diflubenzuron)、丁氟螨酯(cyflumetofen)、氟螨嗪(diflovidazin)、三环锡(cyhexatin)、氯氰菊酯(cypermethrin)、甲基毒虫畏(dimethylvinphos)、乐果(dimethoate)、四氟甲醚菊酯(dimefluthrin)、氟硅菊酯(silafluofen)、灭蝇胺(cyromazine)、乙基多杀菌素(spinetoram)、多杀菌素(spinosad)、螺螨酯(spirodiclofen)、螺虫乙酯(spirotetramat)、螺甲螨酯(spiromesifen)、氟虫胺(sulfluramid)、硫丙磷(sulprofos)、氟啶虫胺腈(sulfoxaflor)、ζ-氯氰菊酯(zeta-cypermethrin)、二嗪农(diazinon)、氟胺氰菊酯(tau-fluvalinate)、棉隆(dazomet)、噻虫啉(thiacloprid)、噻虫嗪(thiamethoxam)、硫双灭多威(thiodicarb)、硫环杀(thiocyclam)、杀虫双(thiosultap)、杀虫双(thiosultap-sodium)、硫磷嗪(thionazin)、甲基乙拌磷(thiometon)、避蚊胺(deet)、狄氏剂(dieldrin)、杀虫畏(tetrachlorvinphos)、三氯杀螨砜(tetradifon)、四氟醚菊酯(tetramethylfluthrin)、胺菊酯(tetramethrin)、嘧丙磷(tebupirimfos)、双苯酰肼(tebufenozide)、吡螨胺(tebufenpyrad)、七氟菊酯(tefluthrin)、伏虫隆(teflubenzuron)、甲基内吸磷(demeton-S-methyl)、双硫磷(temephos)、溴氰菊酯(deltamethrin)、特丁磷(terbufos)、溴代吡咯腈(tralopyril)、四溴菊酯(tralomethrin)、四氟苯菊酯(transfluthrin)、唑蚜威(triazamate)、唑呀威(triazuron)、水杨菌胺(trichlamide)、敌百虫(trichlorphon:DEP)、杀虫隆(triflumuron)、唑虫酰胺(tolfenpyrad)、二溴磷(naled:BRP)、硝虫噻嗪(nithiazine)、烯啶虫胺(nitenpyram)、双苯氟脲(novaluron)、多氟脲(noviflumuron)、烯虫乙酯(hydroprene)、氟吡唑虫(vaniliprole)、蚜灭多(vamidothion)、对硫磷(parathion)、甲基对硫磷(parathion-methyl)、苄螨醚(halfenprox)、氯虫酰肼(halofenozide)、双三氟虫脲(bistrifluron)、杀虫双(bisultap)、氟蚁腙(hydramethylnon)、羟丙基淀粉(hydroxypropylstarch)、乐杀螨(binapacryl)、联苯肼酯(bifenazate)、氟氯菊酯(bifenthrin)、pyflubumide、吡蚜酮(pymetrozine)、吡唑硫磷(pyraclorfos)、嘧啶威(pyrafluprole)、哒嗪硫磷(pyridafenthion)、哒螨酮(pyridaben)、啶虫丙醚(pyridalyl)、pyrifluquinazon、吡啶醇(pyriprole)、蚊蝇醚(pyriproxyfen)、抗蚜威(pirimicarb)、嘧螨醚(Pyrimidifen)、甲基嘧啶磷(pirimiphos-methyl)、除虫菊酯(pyrethrins)、氟虫腈(fipronil)、喹螨醚(fenazaquin)、苯线磷(fenamiphos)、溴螨酯(phenisobromolate)、杀螟硫磷(fenitrothion:MEP)、苯氧威(fenoxycarb)、苯硫威(fenothiocarb)、苯醚菊酯(phenothrin)、仲丁威(fenobucarb)、丰索磷(fensulfothion)、倍硫磷(fenthion:MPP)、稻丰散(phenthoate:PAP)、氰戊菊酯(fenvalerate)、唑螨酯(fenpyroximate)、甲氰菊酯(fenpropathrin)、芬苯达唑(fenbendazole)、丁硫松(butathiofos)、噻嗪酮(buprofezin)、呋线威(furathiocarb)、炔丙菊酯(prallethrin)、嘧螨酯(fluacrypyrim)、氟啶胺(fluazinam)、氟啶蜱脲(fluazuron)、氟噻虫砜(fluensulfone)、氟螨脲(flucycloxuron)、氟氰戊菊酯(flucythrinate)、氟氰胺菊酯(fluvalinate)、flupyradifurone、吡氟硫磷(flupyrazofos)、丁虫腈(flufiprole)、嘧虫胺(flufenerim)、氟虫脲(flufenoxuron)、氟螨嗪(flufenzine)、flufenoprox、苄螨醚(fluproxyfen)、溴氟菊酯(flubrocythrinate)、氟氯苯菊酯(flumethrin)、flurimfen、丙硫磷(prothiofos)、氟虫清(protrifenbute)、氟啶虫酰胺(flonicamid)、丙虫磷(propaphos)、炔螨特(propargite:BPPS)、丙溴磷(profenofos)、丙氟菊酯(profluthrin)、残杀威(propoxur:PHC)、flometoquin、溴螨酯(bromopropylate)、β-氟氯氰菊酯(beta-cyfluthrin)、氟铃脲(hexaflumuron)、噻螨酮(hexythiazox)、庚虫磷(heptenophos)、氯菊酯(permethrin)、苯菌灵(benclothiaz)、恶虫威(bendiocarb)、杀虫磺(bensultap)、苯螨特(benzoximate)、丙硫克百威(benfuracarb)、腈肟磷(phoxim)、伏杀磷(phosalone)、噻唑磷(fosthiazate)、丁环硫磷(fosthietan)、磷胺(phosphamidon)、磷虫威(phosphocarb)、亚胺硫磷(phosmet:PMP)、浏阳霉素复合物(polynactins)、伐虫脒(formetanate)、安果(formothion)、甲拌磷(phorate)、机油(machineoil)、马拉硫磷(malathion)、米尔倍霉素(milbemycin)、米尔倍霉素A(milbemycin-A)、弥拜菌素(milbemectin)、灭蚜磷(mecarbam)、倍硫磷亚砜(mesulfenfos)、灭多虫(methomyl)、蜗牛敌(metaldehyde)、氰氟虫腙(metaflumizone)、甲胺磷(methamidophos)、安百亩(metam-ammonium)、威百亩(metam-sodium)、灭虫威(methiocarb)、杀扑磷(methidathion:DMTP)、异硫氰酸甲酯(methyisothiocyanate)、甲基新癸酰胺(methylneodecanamide)、甲基对硫磷(methylparathion)、恶虫酮(metoxadiazone)、甲氧滴滴涕(methoxychlor)、甲氧虫酰肼(methoxyfenozide)、甲氧苄氟菊酯(metofluthrin)、烯虫酯(methoprene)、速灭威(metolcarb)、氯氟醚菊酯(meperfluthrin)、速灭磷(mevinphos)、久效磷(monocrotophos)、杀虫单(monosultap)、λ-氯氟氰菊酯(lambda-cyhalothrin)、利阿诺定(ryanodine)、虱螨脲(lufenuron)、苄呋菊酯(resmethrin)、雷皮菌素(lepimectin)、鱼藤酮(rotenone)、左旋咪唑(levamisol)、氧化苯丁锡(fenbutatinoxide)、甲噻嘧啶酒石酸酯(moranteltartarate)、溴化甲烷(Methylbromide)、氢氧化三环锡(cyhexatin)、氰氨化钙(Calciumcyanamide)、石硫合剂(Calciumpolysulfide)、硫(Sulfur)和硫酸烟碱(nicotine-sulfate)等。
作为农业园艺用除草剂,可以列举:1-萘乙酰胺(1-naphthylacetamide)、2,4-PA、2,3,6-TBA、2,4,5-T、2,4,5-TB、2,4-D、2,4-DB、2,4-DEB、2,4-DEP、3,4-DA、3,4-DB、3,4-DP、4-CPA(4-chlorophenoxyaceticacid)、4-CPB、4-CPP、MCP、MCPA、2甲4氯硫代乙酯(MCPA-thioethyl)、MCPB、碘苯腈(ioxynil)、苯草醚(aclonifen)、唑啶草酮(azafenidin)、三氟羧草醚(acifluorfen)、叠氮津(aziprotryne)、四唑嘧磺隆(azimsulfuron)、磺草灵(asulam)、乙草胺(acetochlor)、莠去津(atrazine)、莠去通(atraton)、疏草隆(anisuron)、莎稗磷(anilofos)、四烯雌酮(aviglycine)、脱落酸(abscisicacid)、胺唑草酮(amicarbazone)、酰嘧磺隆(amidosulfuron)、杀草强(amitrole)、环丙嘧啶酸(aminocyclopyrachlor)、氯氨吡啶酸(aminopyralid)、特草嗪酮(amibuzin)、甲基胺草磷(amiprophos-methyl)、特津酮(ametridione)、莠灭净(ametryn)、甲草胺(alachlor)、草毒死(allidochlor)、枯杀达(alloxydim)、五氯戊酮酸(alorac)、iofensulfuron、异恶隆(isouron)、草特灵(isocarbamid)、异恶氯草酮(isoxachlortole)、异恶草醚(isoxapyrifop)、异恶唑草酮(isoxaflutole)、异恶草胺(isoxaben)、异草定(isocil)、异草完隆(isonoruron)、异丙隆(isoproturon)、异乐灵(isopropalin)、氮萆草(isopolinate)、丁嗪草酮(isomethiozin)、抗倒胺(inabenfide)、抑草津(ipazine)、三唑酰草胺(ipfencarbazone)、丙草定(iprymidam)、灭草喹(imazaquin)、甲基咪草烟(imazapic)、灭草烟(imazapyr)、甲基咪草烟(imazamethapyr)、咪草酯(imazamethabenz)、咪草酸(imazamethabenz-methyl)、甲氧咪草烟(imazamox)、咪草烟(imazethapyr)、唑吡嘧磺隆(imazosulfuron)、三嗪茚草胺(indaziflam)、茚草酮(indanofan)、吲哚丁酸(indolebutyricacid)、烯效唑-P(uniconazole-P)、甘草津(eglinazine)、禾草畏(esprocarb)、胺苯磺隆(ethametsulfuron)、胺苯磺隆(ethametsulfuron-methyl)、丁氟消草(ethalfluralin)、抑草威(ethiolate)、吲熟酯(ethychlozateethyl)、噻二唑隆(ethidimuron)、硝草酚(etinofen)、乙烯利(ethephon)、乙氧嘧磺隆(ethoxysulfuron)、氟乳醚(ethoxyfen)、乙胺草醚(etnipromid)、乙呋草磺(ethofumesate)、乙氧苯草胺(etobenzanid)、磺唑草(epronaz)、抑草蓬(erbon)、草藻灭(endothal)、恶草酮(oxadiazon)、丙炔恶草酮(oxadiargyl)、氯恶嗪草(oxaziclomefone)、环丙氧磺隆(oxasulfuron)、草哒松恶杀草敏(oxapyrazon)、乙氧氟草醚(oxyfluorfen)、氨磺乐灵(oryzalin)、嘧苯胺磺隆(orthosulfamuron)、坪草丹(orbencarb)、唑草胺(cafenstrole)、克草胺酯(cambendichlor)、除草隆(carbasulam)、唑草酮(carfentrazone)、唑酮草酯(carfentrazone-ethyl)、卡灵草(karbutilate)、长杀草(carbetamide)、特恶唑威(carboxazole)、喹禾灵(quizalofop)、精喹禾灵(quizalofop-P)、喹禾灵(quizalofop-ethyl)、二甲苯草胺(xylachlor)、灭藻醌(quinoclamine)、氯藻胺(quinonamid)、二氯喹啉酸(quinclorac)、氯甲喹啉酸(quinmerac)、苄草隆(cumyluron)、氯酰草膦(clacyfos)、碘氯啶酯(cliodinate)、草甘膦(glyphosate)、草铵膦(glufosinate)、草铵膦-P(glufosinate-P)、醚草敏(credazine)、烯草酮(clethodim)、坐果酸(cloxyfonac)、游离炔草酸(clodinafop)、炔草酯(clodinafop-propargyl)、二氯吡啶酸(clopyralid)、环丁烯草酮(cloproxydim)、调果酸(cloprop)、氯丁草(clofop)、异恶草酮(clomazone)、氯硝醚(chlomethoxynil)、甲氧除草醚(chlomethoxyfen)、稗草胺(clomeprop)、炔禾灵(chlorazifop)、可乐津(chlorazine)、丁酰草胺(chloranocryl)、草灭平(chloramben)、氯酯磺草胺酸(cloransulam)、氯酯磺草胺(cloransulam-methyl)、氯草敏(chloridazon)、氯嘧磺隆(chlorimuron)、氯嘧磺隆(chlorimuron-ethyl)、氯磺隆(chlorsulfuron)、氯酞酸(chlorthal)、草克乐(chlorthiamid)、绿麦隆(chlortoluron)、草枯醚(chlornitrofen)、伐草克(chlorfenac)、燕麦酯(chlorfenprop)、氯炔灵(chlorbufam)、氟咪杀(chlorflurazole)、氯甲丹(chlorflurenol)、草败死(chlorprocarb)、氯苯胺灵(chlorpropham)、氯溴隆(chlorbromuron)、矮壮素(chlormequat)、乙氧苯隆(chloreturon)、羟敌草腈(chloroxynil)、枯草隆(chloroxuron)、绿麦隆(chlorotoluron)、三氯丙酸(chloropon)、苯嘧磺草胺(saflufenacil)、草净津(cyanazine)、氰草净(cyanatryn)、燕麦敌(di-allate)、敌草隆(diuron)、二乙除草双(diethamquat)、麦草畏(dicamba)、环莠隆(cycluron)、草灭特(cycloate)、噻草酮(cycloxydim)、双氯磺草胺(diclosulam)、环丙嘧磺隆(cyclosulfamuron)、2,4-滴丙酸(dichlorprop)、精2,4-滴丙酸(dichlorprop-P)、敌草腈(dichlobenil)、二氯苯氧基丙酸(diclofop)、禾草灵(diclofop-methyl)、苄胺灵(dichlormate)、氯双脲(dichloralurea)、敌草快(diquat)、咯草隆(cisanilide)、2,4-滴硫钠(disul)、环草隆(siduron)、氟硫草定(dithiopyr)、敌乐胺(dinitramine)、吲哚酮草酯(cinidon-ethyl)、戊硝酚(dinosam)、醚磺隆(cinosulfuron)、地乐酚(dinoseb)、特乐酚(dinoterb)、地乐特(dinofenate)、硝丙酚(dinoprop)、氰氟草酯(cyhalofop-butyl)、草乃敌(diphenamid)、枯莠隆(difenoxuron)、戊味禾草灵(difenopenten)、野燕枯(difenzoquat)、洒布净(cybutryne)、环丙津(cyprazine)、三环噻草胺(cyprazole)、吡氟草胺(diflufenican)、氟吡草腙(diflufenzopyr)、杀草净(dipropetryn)、环酰草胺(cypromid)、牧草快(cyperquat)、赤霉素(gibberellin)、西玛津(simazine)、草哒酮(dimidazon)、敌灭生(dimexano)、克草胺(dimethachlor)、异戊乙净(dimethametryn)、二甲吩草胺(dimethenamid)、西草净(simetryn)、西玛通(simeton)、哌草丹(dimepiperate)、恶唑隆(dimefuron)、环庚草醚(cinmethylin)、灭草灵(swep)、吖庚磺酯(sulglycapin)、磺草酮(sulcotrione)、草克死(sulfallate)、甲磺草胺(sulfentrazone)、磺酰磺隆(sulfosulfuron)、甲嘧磺隆(sulfometuron)、甲嘧磺隆甲酯(sulfometuron-methyl)、密草通(secbumeton)、稀禾定(sethoxydim)、另丁津(sebuthylazine)、特草定(terbacil)、香草隆(daimuron)、棉隆(dazomet)、茅草枯(dalapon)、噻氟隆(thiazafluron)、噻草啶(thiazopyr)、噻酮磺隆(thiencarbazone)、噻酮磺隆(thiencarbazone-methyl)、仲草丹(tiocarbazil)、嘧草胺(tioclorim)、禾草丹(thiobencarb)、噻二唑草胺(thidiazimin)、噻苯隆(thidiazuron)、噻磺隆(thifensulfuron)、噻吩磺隆(thifensulfuron-methyl)、甜菜安(desmedipham)、敌草净(desmetryn)、四氟隆(tetrafluron)、噻吩草胺(thenylchlor)、牧草胺(tebutam)、丁唑隆(tebuthiuron)、甲氧去草净(terbumeton)、吡喃草酮(tepraloxydim)、特糠酯酮(tefuryltrione)、环磺酮(tembotrione)、异丁草胺(delachlor)、特草定(terbacil)、芽根灵(terbucarb)、特丁草胺(terbuchlor)、特丁津(terbuthylazine)、去草净(terbutryn)、苯吡唑草酮(topramezone)、三甲苯草酮(tralkoxydim)、三嗪氟草胺(triaziflam)、醚苯磺隆(triasulfuron)、氟酮磺草胺(triafamone)、野麦畏(tri-allate)、草达津(trietazine)、杀草畏(tricamba)、绿草定(triclopyr)、灭草环(tridiphane)、草达克(tritac)、三氟甲磺隆(tritosulfuron)、氟胺磺隆(triflusulfuron)、氟胺磺隆(triflusulfuron-methyl)、氟乐灵(trifluralin)、三氟啶磺隆(trifloxysulfuron)、茚草酮(tripropindan)、苯磺隆(tribenuron)、苯磺隆(tribenuron-methyl)、三氟苯氧丙酸(trifop)、三氟禾草肟(trifopsime)、三甲隆(trimeturon)、萘草胺(naptalam)、萘丙胺(naproanilide)、敌草胺(napropamide)、烟嘧磺隆(nicosulfuron)、甲磺乐灵(nitralin)、除草醚(nitrofen)、三氟甲草醚(nitrofluorfen)、吡氯草胺(nipyraclofen)、草不隆(neburon)、达草灭(norflurazon)、草完隆(noruron)、燕麦灵(barban)、多效唑(paclobutrazol)、百草枯(paraquat)、对氟隆(parafluron)、卤草定(haloxydine)、氟吡禾灵(haloxyfop)、高效氟吡禾灵(haloxyfop-P)、氟吡甲禾灵(haloxyfop-methyl)、氟硝磺酰胺(halosafen)、氯吡嘧磺隆(halosulfuron)、氯吡嘧磺隆(halosulfuron-methyl)、双丙氨酰膦(bilanafos)、氨氯吡啶酸(picloram)、氟吡草胺(picolinafen)、双环吡喃酮(bicyclopyrone)、双草醚(bispyribac)、双草醚(bispyribac-sodium)、比达农(pydanon)、唑啉草酯(pinoxaden)、甲羧除草醚(bifenox)、哌草磷(piperophos)、恶霉灵(hymexazol)、双唑草腈(pyraclonil)、磺酰草吡唑(pyrasulfotole)、苄草唑(pyrazoxyfen)、吡嘧磺隆(pyrazosulfuron)、吡嘧磺隆(pyrazosulfuron-ethyl)、吡唑特(pyrazolate)、双丙氨酰膦(bilanafos)、吡草醚(pyraflufen-ethyl)、氯草定(pyriclor)、pyridafol、嘧硫草醚(pyrithiobac)、嘧硫草醚钠(pyrithiobac-sodium)、达草止(pyridate)、环酯草醚(pyriftalid)、稗草丹(pyributicarb)、嘧啶肟草醚(pyribenzoxim)、嘧啶硫蕃(pyrimisulfan)、氟嘧磺隆(primisulfuron)、嘧草醚(pyriminobac-methyl)、pyroxasulfone、甲氧磺草胺(pyroxsulam)、酰苯磺威(fenasulam)、棉胺宁(phenisopham)、非草隆(fenuron)、fenoxasulfone、恶唑禾草灵(fenoxaprop)、精恶唑禾草灵(fenoxaprop-P)、恶唑禾草灵(fenoxaprop-ethyl)、酚硫杀(phenothiol)、2,4,5-涕丙酸(fenoprop)、稀草隆(phenobenzuron)、噻唑禾草灵(fenthiaprop)、氯苯氧乙醇(fenteracol)、四唑草胺(fentrazamide)、甜菜宁(phenmedipham)、乙基甜菜宁(phenmedipham-ethyl)、丁草胺(butachlor)、氟丙嘧草酯(butafenacil)、抑草膦(butamifos)、丁噻隆(buthiuron)、特咪唑草(buthidazole)、苏达灭(butylate)、炔草隆(buturon)、丁烯草胺(butenachlor)、丁苯草酮(butroxydim)、地乐胺(butralin)、丁苯草酮(butroxydim)、啶嘧磺隆(flazasulfuron)、氟燕酯(flamprop)、氟呋草醚(furyloxyfen)、广草胺(prynachlor)、氟嘧磺隆(primisulfuron-methyl)、吡氟禾草灵(fluazifop)、精吡氟禾草灵(fluazifop-P)、吡氟禾草灵(fluazifop-butyl)、异丙吡草酯(fluazolate)、氟草烟(fluroxypyr)、氟硫隆(fluothiuron)、伏草隆(fluometuron)、乙羧氟草醚(fluoroglycofen)、氟咯草酮(flurochloridone)、三氟硝草醚(fluorodifen)、氟除草醚(fluoronitrofen)、唑啶草(fluoromidine)、氟唑磺隆(flucarbazone)、氟唑磺隆钠(flucarbazone-sodium)、氟消草(fluchloralin)、氟吡磺隆(flucetosulfuron)、嗪草酸(fluthiacet)、嗪草酸甲酯(fluthiacet-methyl)、氟啶磺隆(flupyrsulfuron)、氟噻草胺(flufenacet)、氟苯吡草(flufenican)、氟哒嗪草酯(flufenpyr)、flupropacil、四氟丙酸(flupropanate)、氟胺草唑(flupoxam)、丙炔氟草胺(flumioxazin)、氟烯草酸(flumiclorac)、氟亚胺草酯(flumiclorac-pentyl)、炔草胺(flumipropyn)、三氟恶嗪(flumezin)、唑嘧磺草胺(flumetsulam)、氟草酮(fluridone)、呋草酮(flurtamone)、氟草烟(fluroxypyr)、丙草胺(pretilachlor)、扑灭生(proxan)、甘扑津(proglinazine)、环丙腈津(procyazine)、氨氟乐灵(prodiamine)、草硫亚胺(prosulfalin)、氟丙磺隆(prosulfuron)、苄草丹(prosulfocarb)、喔草酯(propaquizafop)、毒草安(propachlor)、扑灭津(propazine)、敌稗(propanil)、炔苯酰草胺(propyzamide)、异丙草胺(propisochlor)、茉莉酮(prohydrojasmon)、嗪咪唑嘧磺隆(propyrisulfuron)、苯胺灵(propham)、氟唑草胺(profluazol)、环丙氟灵(profluralin)、调环酸钙(prohexadione-calcium)、丙苯磺隆(propoxycarbazone)、丙苯磺隆(propoxycarbazone-sodium)、环苯草酮(profoxydim)、除草定(bromacil)、溴杀莠敏(brompyrazon)、扑草净(prometryn)、扑灭通(prometon)、溴苯腈(bromoxynil)、杀草全(bromofenoxim)、溴丁酰草胺(bromobutide)、溴草腈(bromobonil)、双氟磺草胺(florasulam)、六氯丙酮(hexachloroacetone)、六嗪酮(hexazinone)、烯草胺(pethoxamid)、草除灵(benazolin)、五氟磺草胺(penoxsulam)、克草猛(pebulate)、氟丁酰草胺(beflubutamid)、灭草猛(vernolate)、氟草磺胺(perfluidone)、bencarbazone、胺酸杀(benzadox)、苄草胺(benzipram)、苄氨基嘌呤(benzylaminopurine)、噻草隆(benzthiazuron)、双苯嘧草酮(benzfendizone)、地散磷(bensulide)、苄嘧磺隆(bensulfuron-methyl)、新燕灵(benzoylprop)、苯并双环酮(benzobicyclon)、吡草酮(benzofenap)、氟草黄(benzofluor)、灭草松(bentazone)、甲氯酰草胺(pentanochlor)、杀草丹(benthiocarb)、二甲戊乐灵(pendimethalin)、环戊恶草酮(pentoxazone)、氟草胺(benfluralin)、呋草黄(benfuresate)、杀木膦(fosamine)、氟磺胺草醚(fomesafen)、甲酰氨磺隆(foramsulfuron)、吡效隆(forchlorfenuron)、抑芽丹(maleichydrazide)、2甲4氯丙酸(mecoprop)、精2甲4氯丙酸(mecoprop-P)、地乐施(medinoterb)、甲基二磺隆(mesosulfuron)、甲基二磺隆(mesosulfuron-methyl)、硝草酮(mesotrione)、灭莠津(mesoprazine)、盖草津(methoprotryne)、吡草胺(metazachlor)、灭草定(methazole)、双醚氯吡嘧磺隆(metazosulfuron)、噻唑隆(methabenzthiazuron)、苯嗪草酮(metamitron)、恶唑酰草胺(metamifop)、威百亩(metam)、氟烯硝草(methalpropalin)、灭草恒(methiuron)、methiozolin、甲疏苯威(methiobencarb)、甲基杀草隆(methyldymron)、甲氧隆(metoxuron)、磺草唑胺(metosulam)、甲磺隆(metsulfuron)、甲磺隆(metsu1furon-methyl)、二甲哒草伏(metflurazon)、秀谷隆(metobromuron)、吡喃隆(metobenzuron)、醚草通(methometon)、异丙甲草胺(metolachlor)、赛克津(metribuzin)、缩节胺(mepiquat-chloride)、苯噻草胺(mefenacet)、氟草磺(mefluidide)、杀草利(monalide)、特恶唑隆(monisouron)、灭草隆(monuron)、一氯醋酸(monochloroaceticacid)、绿谷隆(monolinuron)、草达灭(molinate)、伐草快(morfamquat)、碘甲磺隆(iodosulfuron)、碘甲磺隆钠(iodosulfuron-methyl-sodium)、碘草腈(iodobonil)、碘甲烷(iodomethane)、乳氟禾草灵(lactofen)、利谷隆(linuron)、玉嘧磺隆(rimsulfuron)、环草定(lenacil)、硫氰苯胺(rhodethanil)、过氧化钙(calciumperoxide)和溴化甲烷(methylbromide)等。
作为增效剂,可以列举胡椒基丁醚(piperonylbutoxide)、增效散(sesamex)、亚砜(sulfoxide)、N-(2-乙基己基)-8,9,10-三降冰片-5-烯-2,3-二羧基酰亚胺(MGK264)、N-癸基咪唑(N-declyimidazole)、WARF-antiresistant(WARF-antiresistant)、TBPT、TPP、IBP、PSCP、碘甲烷、t-苯基丁酮(t-phenylbutenone)、马来酸二乙酯(diethylmaleate)、DMC、FDMC、ETP和ETN等。
作为安全剂,可以列举:解草嗪(benoxacor)、解草酯(cloquintocet-mexyl)、解草胺腈(cyometrinil)、杀草隆(daimuron)、烯丙酰草胺(dichlormid)、环丙磺酰胺(cyprosulfamide)、解草唑(fenchlorazole-ethyl)、解草啶(fenclorim)、解草胺(flurazole)、氟草肟(fluxofenim)、解草恶唑(furilazole)、吡唑解草酯(mefenpyr-diethyl)、MG191、解草腈(oxabetrinil)、草毒死(allidochlor)、双苯恶唑酸乙酯(isoxadifen-ethyl)、环丙磺酰胺(cyprosulfamide)、氟草肟(fluxofenim)和1,8-萘二酸酐(1,8-naphthalicanhydride)等。
实施例
以下,示出本发明的代表实施例及试验例,但本发明并不限于这些。需要说明的是,实施例中、“份”表示“质量份”。
制剂例1.乳剂
将以上物质均匀地混合溶解而得到乳剂。
制剂例2.粉剂
将以上物质均匀地混合粉碎而得到粉剂。
制剂例3.颗粒剂
将以上物质均匀地混合,加入适量的水进行混炼,并进行造粒、干燥,得到颗粒剂。
制剂例4.可湿性粉剂
将以上物质均匀地混合粉碎而得到可湿性粉剂。
制剂例5.流动剂
将以上物质均匀地混合,使其分散在水中,得到流动剂。
试验例1.对小菜蛾、甜菜夜蛾及斜纹夜蛾的杀虫效果试验
在芥兰(绿叶甘蓝)的试验区(4m×5m、1区栽植800株)中,将氟虫双酰胺20%可湿性颗粒剂及唑虫酰胺15%乳剂的规定药量的药剂用水稀释(相当于750L/公顷),每隔4日进行茎叶散布8次。在小菜蛾及斜纹夜蛾区,每1区随机提取20株,在药剂散布处理前调查生存虫数,在第5次药剂处理4日后和第6次药剂处理后4日后调查各自寄生的幼虫数,与药剂处理前的幼虫数比较,根据下述计算出防除效果。另外,通过下述コルビー(Colby)计算式,求出混合使用的期待值。在混合使用的防除效果比期待值大的情况下,判断为不是简单的相加效果而是具有混合使用产生的协同效果。需要说明的是,在甜菜夜蛾区,在第7次药剂处理4日后和第8次药剂处理4日后同样地进行计算。
防除效果=100-{(Ta×Cb)/(Tb×Ca)}×100
Ta=处理区的药剂处理后的幼虫数
Tb=处理区的药剂处理前的幼虫数
Ca=无处理区的药剂处理后的幼虫数
Cb=无处理区的药剂处理前的幼虫数
コルビー计算式E(期待值)=(X+Y)-(X×Y/100)
X=氟虫双酰胺单独的防除效果
Y=唑虫酰胺单独的防除效果
将结果示于表1至表3。需要说明的是,各表中,4DAT5、4DAT6、4DAT7及4DAT8表示以下含义,a.i.表示activeingredient(有效成分)。
4DAT5:第5次药剂处理的4日后调查
4DAT6:第6次药剂处理的4日后调查
4DAT7:第7次药剂处理的4日后调查
4DAT8:第8次药剂处理的4日后调查
表1
对小菜蛾的防除效果
表2
对甜菜夜蛾的防除效果
表3
对斜纹夜蛾的防除效果
在任意试验中,在混合使用区观察到超过由氟虫双酰胺及唑虫酰胺单剂区的效果期待的混合使用时的效果(期待值)的防除效果。
Claims (5)
1.一种农业园艺用杀虫剂组合物,含有氟虫双酰胺和唑虫酰胺作为有效成分,相对于氟虫双酰胺1质量份,以0.1~10质量份的比例含有唑虫酰胺。
2.一种农业园艺用杀虫剂组合物的使用方法,其特征在于,使用有效量的含有氟虫双酰胺和唑虫酰胺作为有效成分、且相对于氟虫双酰胺1质量份以0.1~10质量份的比例含有唑虫酰胺的农业园艺用杀虫剂组合物直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理。
3.一种农业园艺害虫的防除方法,其特征在于,以相对于氟虫双酰胺1质量份唑虫酰胺为0.1~10质量份的比例,分别使用有效量的以氟虫双酰胺作为有效成分的制剂和含有唑虫酰胺作为有效成分的制剂,以其原状态或对其进行稀释后,于同时期直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理。
4.一种农业园艺害虫的防除方法,其特征在于,以相对于氟虫双酰胺1质量份唑虫酰胺为0.1~10质量份的比例,分别使用有效量的以氟虫双酰胺作为有效成分的制剂和含有唑虫酰胺作为有效成分的制剂,以其原状态或对其进行稀释后,空出处理时期的间隔地直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理。
5.一种农业园艺害虫的防除方法,其特征在于,以相对于氟虫双酰胺1质量份唑虫酰胺为0.1~10质量份的比例,混合使用有效量的以氟虫双酰胺作为有效成分的制剂和含有唑虫酰胺作为有效成分的制剂,以其原状态或对其进行稀释后,直接对害虫、或者对害虫栖息的作物、或者对作物生长的周边土壤或栽培载体进行处理。
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- 2012-06-28 BR BR112013031678A patent/BR112013031678A2/pt not_active Application Discontinuation
- 2012-06-28 WO PCT/JP2012/066473 patent/WO2013002299A1/ja active Application Filing
- 2012-06-28 US US14/125,517 patent/US20140148493A1/en not_active Abandoned
- 2012-06-28 EP EP12804251.2A patent/EP2727466A4/en not_active Withdrawn
- 2012-06-28 PE PE2013002890A patent/PE20141383A1/es not_active Application Discontinuation
- 2012-06-28 CN CN201280032497.4A patent/CN103635086B/zh active Active
- 2012-06-28 KR KR1020137034138A patent/KR20140031950A/ko not_active Application Discontinuation
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JP2006131516A (ja) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | 有害生物防除剤組成物及びその使用方法 |
Also Published As
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KR20140031950A (ko) | 2014-03-13 |
US20140148493A1 (en) | 2014-05-29 |
EP2727466A1 (en) | 2014-05-07 |
CN103635086A (zh) | 2014-03-12 |
EP2727466A4 (en) | 2015-01-21 |
BR112013031678A2 (pt) | 2016-08-16 |
WO2013002299A1 (ja) | 2013-01-03 |
PE20141383A1 (es) | 2014-10-21 |
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