CN103620829B - 层状氧化物阴极组合物的合成方法 - Google Patents

层状氧化物阴极组合物的合成方法 Download PDF

Info

Publication number
CN103620829B
CN103620829B CN201280030849.2A CN201280030849A CN103620829B CN 103620829 B CN103620829 B CN 103620829B CN 201280030849 A CN201280030849 A CN 201280030849A CN 103620829 B CN103620829 B CN 103620829B
Authority
CN
China
Prior art keywords
lithium
temperature
calcination
rotary calciner
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280030849.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN103620829A (zh
Inventor
I·佩特罗维克
A·瑟斯顿
S·舍尔戈德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of CN103620829A publication Critical patent/CN103620829A/zh
Application granted granted Critical
Publication of CN103620829B publication Critical patent/CN103620829B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compositions Of Oxide Ceramics (AREA)
CN201280030849.2A 2011-06-24 2012-06-21 层状氧化物阴极组合物的合成方法 Active CN103620829B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/168,516 2011-06-24
US13/168,516 US8992794B2 (en) 2011-06-24 2011-06-24 Process for synthesis of a layered oxide cathode composition
PCT/US2012/043479 WO2012177833A2 (en) 2011-06-24 2012-06-21 Process for synthesis of a layered oxide cathode composition

Publications (2)

Publication Number Publication Date
CN103620829A CN103620829A (zh) 2014-03-05
CN103620829B true CN103620829B (zh) 2017-03-15

Family

ID=47360973

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280030849.2A Active CN103620829B (zh) 2011-06-24 2012-06-21 层状氧化物阴极组合物的合成方法

Country Status (8)

Country Link
US (1) US8992794B2 (enExample)
EP (1) EP2724397B8 (enExample)
JP (2) JP6577188B2 (enExample)
KR (1) KR20140051184A (enExample)
CN (1) CN103620829B (enExample)
HU (1) HUE044067T2 (enExample)
PL (1) PL2724397T3 (enExample)
WO (1) WO2012177833A2 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102484029B1 (ko) 2014-11-26 2023-01-02 바스프 에스이 리튬화 전이 금속 산화물을 제조하는 방법
EP3362756B1 (de) 2015-10-14 2019-12-11 Basf Se Wärmedurchlässiges rohr beinhaltend faserverbundkeramik
US20180316004A1 (en) * 2016-06-09 2018-11-01 Hitachi Metals, Ltd. Method for producing cathode active material used for lithium secondary battery
JP6646129B1 (ja) * 2018-12-07 2020-02-14 住友化学株式会社 リチウム二次電池用正極活物質の製造方法
KR102565910B1 (ko) * 2019-01-21 2023-08-10 주식회사 엘지화학 이차전지용 양극 활물질의 제조방법
JP6936909B1 (ja) * 2020-08-07 2021-09-22 Ｂａｓｆ戸田バッテリーマテリアルズ合同会社 非水電解質二次電池用正極活物質及びそれを用いた非水電解質二次電池
WO2024249247A1 (en) * 2023-05-31 2024-12-05 Albemarle Corporation Process for producing lithium-containing mixed metal oxide material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6004526A (en) * 1997-09-30 1999-12-21 Mitsui & Mining Company, Ltd. Process for preparing cathode active material for lithium secondary battery
CN101521272A (zh) * 2009-03-20 2009-09-02 广州鸿森材料有限公司 一种高压煅烧制备锂镍锰氧锂离子电池正极材料的方法
WO2011072397A1 (en) * 2009-12-17 2011-06-23 Phostech Lithium Inc. Method for improving the electrochemical performances of an alkali metal oxyanion electrode material and alkali metal oxyanion electrode material obtained therefrom

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5874058A (en) * 1995-10-06 1999-02-23 Kerr-Mcgee Chemical Llc Method of preparing Li1+x MN2-x O4 for use as secondary battery electrode
US5728367A (en) 1996-06-17 1998-03-17 Motorola, Inc. Process for fabricating a lithiated transition metal oxide
AU744558B2 (en) 1998-02-09 2002-02-28 H.C. Starck Gmbh & Co. Kg Method for producing lithium-transition metal mixtures
US5908291A (en) * 1998-05-01 1999-06-01 Harper International Corp. Continuous cross-flow rotary kiln
US6267943B1 (en) 1998-10-15 2001-07-31 Fmc Corporation Lithium manganese oxide spinel compound and method of preparing same
JP3446639B2 (ja) * 1998-12-10 2003-09-16 松下電器産業株式会社 リチウム二次電池用正極活物質の製造方法およびリチウム二次電池
US6344366B1 (en) 1999-09-15 2002-02-05 Lockheed Martin Energy Research Corporation Fabrication of highly textured lithium cobalt oxide films by rapid thermal annealing
EP1142834A4 (en) 1999-11-15 2009-06-17 Mitsubishi Chem Corp LITHIUM MANGANESE COMPOSITE OXIDE, POSITIVE ELECTRODE MATERIAL FOR LITHIUM SECONDARY ACCUMULATOR, POSITIVE ELECTRODE AND LITHIUM SECONDARY ACCUMULATOR, AND PROCESS FOR THE PREPARATION OF LITHIUM MANGANESE COMPOSITE OXIDE
US6350543B2 (en) 1999-12-29 2002-02-26 Kimberly-Clark Worldwide, Inc. Manganese-rich quaternary metal oxide materials as cathodes for lithium-ion and lithium-ion polymer batteries
JP2002260655A (ja) * 2001-02-28 2002-09-13 Nichia Chem Ind Ltd リチウムイオン二次電池用正極活物質の製造方法
US7211237B2 (en) * 2003-11-26 2007-05-01 3M Innovative Properties Company Solid state synthesis of lithium ion battery cathode material
JP4797332B2 (ja) * 2004-03-24 2011-10-19 三菱化学株式会社 リチウム二次電池正極活物質用リチウム遷移金属複合酸化物粉体、リチウム二次電池正極及びリチウム二次電池
US7381496B2 (en) * 2004-05-21 2008-06-03 Tiax Llc Lithium metal oxide materials and methods of synthesis and use
JP5132308B2 (ja) * 2005-05-17 2013-01-30 Ａｇｃセイミケミカル株式会社 リチウム二次電池正極用のリチウム含有複合酸化物の製造方法
US8377412B2 (en) * 2005-06-28 2013-02-19 Toda Kogyo Europe Gmbh Methods for preparing inorganic compounds having a substantially single phase, hexagonal layered crystal structure that is substantially free from cubic-spinel like phases
JP4221448B1 (ja) 2007-07-19 2009-02-12 日鉱金属株式会社 リチウムイオン電池用リチウムマンガン複合酸化物及びその製造方法
KR101110922B1 (ko) * 2008-02-04 2012-03-13 파나소닉 주식회사 리튬 함유 천이금속 산화물의 제조방법
JP5006830B2 (ja) * 2008-04-30 2012-08-22 一般財団法人電力中央研究所 石炭ガス化スラグ発泡体の製造システム
JP5231171B2 (ja) * 2008-10-30 2013-07-10 パナソニック株式会社 非水電解質二次電池用正極活物質およびその製造方法
US8333950B2 (en) 2009-08-27 2012-12-18 Honeywell International Inc. Process for the preparation of lithium metal oxides involving fluidized bed techniques
US8980475B2 (en) * 2010-06-25 2015-03-17 Basf Se Process for preparing lithium mixed metal oxides and their use as cathode material
WO2012132072A1 (ja) * 2011-03-29 2012-10-04 Jx日鉱日石金属株式会社 リチウムイオン電池用正極活物質の製造方法及びリチウムイオン電池用正極活物質

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6004526A (en) * 1997-09-30 1999-12-21 Mitsui & Mining Company, Ltd. Process for preparing cathode active material for lithium secondary battery
CN101521272A (zh) * 2009-03-20 2009-09-02 广州鸿森材料有限公司 一种高压煅烧制备锂镍锰氧锂离子电池正极材料的方法
WO2011072397A1 (en) * 2009-12-17 2011-06-23 Phostech Lithium Inc. Method for improving the electrochemical performances of an alkali metal oxyanion electrode material and alkali metal oxyanion electrode material obtained therefrom

Also Published As

Publication number Publication date
HUE044067T2 (hu) 2019-09-30
PL2724397T3 (pl) 2019-09-30
EP2724397A2 (en) 2014-04-30
EP2724397B8 (en) 2019-06-12
EP2724397B1 (en) 2019-04-10
KR20140051184A (ko) 2014-04-30
JP6577188B2 (ja) 2019-09-18
EP2724397A4 (en) 2015-11-25
WO2012177833A3 (en) 2013-02-21
US20120326077A1 (en) 2012-12-27
US8992794B2 (en) 2015-03-31
WO2012177833A2 (en) 2012-12-27
JP2018150231A (ja) 2018-09-27
JP2014523070A (ja) 2014-09-08
CN103620829A (zh) 2014-03-05

Similar Documents

Publication Publication Date Title
CN103620829B (zh) 层状氧化物阴极组合物的合成方法
CN110662717B (zh) 用于制备针对可再充电锂离子电池的基于Ni的阴极材料的前体和方法
JP5809260B2 (ja) リチウム混合金属酸化物の製造方法とそのカソード材料としての使用法
JP5464348B2 (ja) 非水系電解質二次電池正極活物質用ニッケル−コバルト複合水酸化物およびその製造方法、ならびに該ニッケル−コバルト複合水酸化物を用いた非水系電解質二次電池正極活物質の製造方法
US8333950B2 (en) Process for the preparation of lithium metal oxides involving fluidized bed techniques
JP6673538B2 (ja) リチウムイオン二次電池用正極活物質の製造方法及び熱処理装置
WO2012132072A1 (ja) リチウムイオン電池用正極活物質の製造方法及びリチウムイオン電池用正極活物質
US11804599B2 (en) Precursor and method for preparing Ni based cathode material for rechargeable lithium ion batteries
JP2012505520A5 (enExample)
JP2014523070A5 (enExample)
JP2020528637A (ja) 電極活物質の製造方法
JP6117718B2 (ja) リチウム複合酸化物
US20230092675A1 (en) Cathode material and process
US20200274159A1 (en) Process for making an electrode active material
WO2018181967A1 (ja) マンガン酸化物、その製造方法、及びリチウム二次電池
JP7491659B2 (ja) 水酸化リチウム水和物、水酸化リチウム水和物の製造方法、リチウムニッケル複合酸化物の製造方法
JP7417675B1 (ja) 金属複合水酸化物粒子、金属複合化合物の製造方法、及びリチウム二次電池用正極活物質の製造方法
WO2024219262A1 (ja) リチウム金属複合酸化物の製造方法
WO2024111264A1 (ja) リチウム金属複合酸化物の製造方法
CN115667154A (zh) 用于制备锂过渡金属氧化物的方法
JP2024011936A (ja) 金属複合水酸化物粒子及びリチウム二次電池用正極活物質の製造方法
WO2024135203A1 (ja) リチウム金属複合酸化物、リチウム二次電池用正極活物質、リチウム二次電池用正極及びリチウム二次電池

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20181227

Address after: Rhine, Ludwigshafen, Germany

Patentee after: BASF SE

Address before: new jersey

Patentee before: BASF AG

TR01 Transfer of patent right