CN103589023B - 一种阻燃耐候老化改性氯丁橡胶电缆料 - Google Patents
一种阻燃耐候老化改性氯丁橡胶电缆料 Download PDFInfo
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- CN103589023B CN103589023B CN201310517214.1A CN201310517214A CN103589023B CN 103589023 B CN103589023 B CN 103589023B CN 201310517214 A CN201310517214 A CN 201310517214A CN 103589023 B CN103589023 B CN 103589023B
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- cable materials
- chloroprene rubber
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- 239000000463 material Substances 0.000 title claims abstract description 34
- 229920001084 poly(chloroprene) Polymers 0.000 title claims abstract description 23
- 230000032683 aging Effects 0.000 title claims abstract description 15
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical class ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 title claims abstract description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000006229 carbon black Substances 0.000 claims abstract description 11
- 229920005558 epichlorohydrin rubber Polymers 0.000 claims abstract description 9
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 9
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 9
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 9
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- IMYZYCNQZDBZBQ-SJORKVTESA-N (9S,10R)-epoxyoctadecanoic acid Chemical compound CCCCCCCC[C@H]1O[C@H]1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-SJORKVTESA-N 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000001125 extrusion Methods 0.000 claims abstract description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 4
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 4
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000005456 glyceride group Chemical group 0.000 claims abstract description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000012545 processing Methods 0.000 claims abstract description 4
- 239000008117 stearic acid Substances 0.000 claims abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
- 239000011593 sulfur Substances 0.000 claims abstract description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 12
- 229910052923 celestite Inorganic materials 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 229910052624 sepiolite Inorganic materials 0.000 claims description 9
- 235000019355 sepiolite Nutrition 0.000 claims description 9
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 claims description 3
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 3
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000003063 flame retardant Substances 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005452 bending Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Abstract
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CN201310517214.1A CN103589023B (zh) | 2013-10-29 | 2013-10-29 | 一种阻燃耐候老化改性氯丁橡胶电缆料 |
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CN201310517214.1A CN103589023B (zh) | 2013-10-29 | 2013-10-29 | 一种阻燃耐候老化改性氯丁橡胶电缆料 |
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CN103589023B true CN103589023B (zh) | 2016-08-17 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104007523A (zh) * | 2014-04-23 | 2014-08-27 | 晶锋集团股份有限公司 | 加强型光纤电缆 |
CN104795147A (zh) * | 2014-05-28 | 2015-07-22 | 安徽天星光纤通信设备有限公司 | 一种高效阻燃耐撕裂煤矿用通讯电缆 |
CN104177806A (zh) * | 2014-08-19 | 2014-12-03 | 安徽蒙特尔电缆集团有限公司 | 一种低成本阻燃电缆护套材料 |
CN104448769A (zh) * | 2014-12-04 | 2015-03-25 | 侨健新能源科技(苏州)有限公司 | 一种环保高性能氯醇橡胶材料 |
CN107383557A (zh) * | 2017-08-30 | 2017-11-24 | 芜湖新农夫机械有限公司 | 一种聚乙烯抗老化电缆及其制造方法 |
CN108164774A (zh) * | 2017-12-29 | 2018-06-15 | 安徽天星电缆科技有限公司 | 一种低成本耐磨机器人手臂电缆料 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0171986A1 (en) * | 1984-08-06 | 1986-02-19 | Fujikura Ltd. | Silane-crosslinkable halogenated polymer composition and process of crosslinking the same |
CN1590451A (zh) * | 2003-07-31 | 2005-03-09 | 早川橡胶株式会社 | 抗辐射交联高分子组合物以及抗辐射高分子制品 |
CN101817952A (zh) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | 柔软型低烟无卤阻燃聚烯烃电缆料及其制备方法 |
CN103059386A (zh) * | 2013-01-31 | 2013-04-24 | 中原工学院 | 节能环保交联聚烯烃电缆料及其制备方法 |
CN103087373A (zh) * | 2012-06-11 | 2013-05-08 | 深圳市沃尔核材股份有限公司 | 辐射交联氯丁橡胶热缩管及其生产方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1990015841A1 (en) * | 1989-06-16 | 1990-12-27 | Lydall, Inc. | Composite for high temperature electrical insulating and method for manufacturing |
JP2013194133A (ja) * | 2012-03-19 | 2013-09-30 | Hitachi Cable Ltd | ポリクロロプレン組成物及びそれを用いた電線ケーブル |
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2013
- 2013-10-29 CN CN201310517214.1A patent/CN103589023B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0171986A1 (en) * | 1984-08-06 | 1986-02-19 | Fujikura Ltd. | Silane-crosslinkable halogenated polymer composition and process of crosslinking the same |
CN1590451A (zh) * | 2003-07-31 | 2005-03-09 | 早川橡胶株式会社 | 抗辐射交联高分子组合物以及抗辐射高分子制品 |
CN101817952A (zh) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | 柔软型低烟无卤阻燃聚烯烃电缆料及其制备方法 |
CN103087373A (zh) * | 2012-06-11 | 2013-05-08 | 深圳市沃尔核材股份有限公司 | 辐射交联氯丁橡胶热缩管及其生产方法 |
CN103059386A (zh) * | 2013-01-31 | 2013-04-24 | 中原工学院 | 节能环保交联聚烯烃电缆料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
俄罗斯生产橡胶制品用环氧橡胶;江畹兰;《世界橡胶工业》;20120630;第39卷(第6期);第5-9页 * |
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Inventor after: Chu Nianhong Inventor before: Xie Hua |
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Effective date of registration: 20170824 Address after: 300000, Tianjin, Wuqing District, Mei Yang Zhen town on the south side of the highway on the west side of Tian Jia Road, Tian Jia garden 14-1-801 Patentee after: Chu Nianhong Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei Patentee before: LVBAO CABLE (Group) Co.,Ltd. |
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Effective date of registration: 20181101 Address after: 233010 409 Wu Wan Road, Yuhui District, Bengbu, Anhui Patentee after: BENGBU JINSHI NEW MATERIAL Co.,Ltd. Address before: 230031 B-1014, 10 floor, business office building, Wo Ye garden, Shushan District, Hefei, Anhui. Patentee before: HEFEI WISDOM LOTUT INTELLECTUAL PROPERTY Co.,Ltd. Effective date of registration: 20181101 Address after: 230031 B-1014, 10 floor, business office building, Wo Ye garden, Shushan District, Hefei, Anhui. Patentee after: HEFEI WISDOM LOTUT INTELLECTUAL PROPERTY Co.,Ltd. Address before: 300000 Tianjin city Wuqing District Meishan Town, south side of Yang Bei Road, Jinan Road West Side Tianan Jiayuan 14-1-801 Patentee before: Chu Nianhong |
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Effective date of registration: 20181204 Address after: 225400 No. 288 North Second Ring Road, Taixing City, Taizhou City, Jiangsu Province Patentee after: TAIXING CITY XINGLONG SHIPS MACHINERY Co.,Ltd. Address before: 233010 409 Wu Wan Road, Yuhui District, Bengbu, Anhui Patentee before: BENGBU JINSHI NEW MATERIAL Co.,Ltd. |