CN103571415B - 双组份环氧胶粘剂及其制备方法 - Google Patents
双组份环氧胶粘剂及其制备方法 Download PDFInfo
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- CN103571415B CN103571415B CN201310016067.XA CN201310016067A CN103571415B CN 103571415 B CN103571415 B CN 103571415B CN 201310016067 A CN201310016067 A CN 201310016067A CN 103571415 B CN103571415 B CN 103571415B
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- epoxy adhesive
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- 229920006332 epoxy adhesive Polymers 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000003822 epoxy resin Substances 0.000 claims abstract description 25
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 25
- 239000000945 filler Substances 0.000 claims abstract description 17
- 150000001412 amines Chemical class 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 43
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 9
- 230000003014 reinforcing effect Effects 0.000 claims description 9
- ICGLPKIVTVWCFT-UHFFFAOYSA-N 4-methylbenzenesulfonohydrazide Chemical compound CC1=CC=C(S(=O)(=O)NN)C=C1 ICGLPKIVTVWCFT-UHFFFAOYSA-N 0.000 claims description 8
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 8
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 8
- 229960004217 benzyl alcohol Drugs 0.000 claims description 8
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 8
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 229920006295 polythiol Polymers 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229930185605 Bisphenol Natural products 0.000 claims description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 3
- FAMRKDQNMBBFBR-BQYQJAHWSA-N diethyl azodicarboxylate Chemical compound CCOC(=O)\N=N\C(=O)OCC FAMRKDQNMBBFBR-BQYQJAHWSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000004246 zinc acetate Substances 0.000 claims description 3
- 230000006378 damage Effects 0.000 abstract description 4
- 239000004088 foaming agent Substances 0.000 abstract description 3
- 238000007664 blowing Methods 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 17
- 239000010959 steel Substances 0.000 description 17
- 239000005357 flat glass Substances 0.000 description 14
- 238000004513 sizing Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 238000005520 cutting process Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004484 Briquette Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 208000014674 injury Diseases 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000007634 remodeling Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
样品 | 剪切强度(MPa) | 拉伸强度(MPa) | 水煮时间(Min) |
实施例1 | 17.1 | 18.5 | 15 |
实施例2 | 15.2 | 15.6 | 12 |
实施例3 | 17.9 | 18.1 | 16 |
实施例4 | 16.2 | 17.0 | 14 |
实施例5 | 16.8 | 16.1 | 14 |
对比实施例 | 16.7 | 17.9 | >120 |
Claims (2)
Priority Applications (1)
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CN201310016067.XA CN103571415B (zh) | 2013-01-16 | 2013-01-16 | 双组份环氧胶粘剂及其制备方法 |
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CN201310016067.XA CN103571415B (zh) | 2013-01-16 | 2013-01-16 | 双组份环氧胶粘剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN103571415A CN103571415A (zh) | 2014-02-12 |
CN103571415B true CN103571415B (zh) | 2015-05-27 |
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CN201310016067.XA Active CN103571415B (zh) | 2013-01-16 | 2013-01-16 | 双组份环氧胶粘剂及其制备方法 |
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Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103881638B (zh) * | 2014-03-12 | 2015-08-26 | 南京艾布纳密封技术有限公司 | 太阳能电池硅片切割工艺用胶 |
CN104559895A (zh) * | 2015-01-04 | 2015-04-29 | 上海都伟光伏科技有限公司 | 室温快速固化单组份水煮胶及其制备方法 |
CN105255425B (zh) * | 2015-11-19 | 2018-01-12 | 杭州得力科技股份有限公司 | 临时粘接用双组分环氧胶粘剂及其制备方法和应用 |
CN105485469B (zh) * | 2015-12-23 | 2018-01-02 | 中国石油天然气集团公司 | 一种碳纤维复合材料止裂器及其制作及安装方法 |
CN108676532B (zh) * | 2018-04-16 | 2021-06-01 | 杭州电子科技大学 | 一种环氧树脂粘结材料 |
CN109233719A (zh) * | 2018-10-12 | 2019-01-18 | 南宁珀源能源材料有限公司 | 可快速固化的双组份环氧树脂板胶及其制备方法 |
CN110885653B (zh) * | 2019-11-18 | 2022-07-05 | 北京航天控制仪器研究所 | 一种低温快速固化环氧绝缘胶及其制备方法与应用 |
CN110951431A (zh) * | 2019-12-11 | 2020-04-03 | 惠州市佳邦达复合材料有限公司 | 一种复合胶及其制备工艺 |
CN113025259A (zh) * | 2020-12-16 | 2021-06-25 | 江苏中科聚合新材料产业技术研究院有限公司 | 一种可拆卸双组分聚氨酯胶粘剂及其制备方法、可拆卸结构件 |
CN114558763A (zh) * | 2022-03-09 | 2022-05-31 | 福州环宇工艺品有限公司 | 一种仿搪瓷工艺品及其仿旧工艺 |
CN115353847B (zh) * | 2022-06-27 | 2023-07-14 | 韦尔通科技股份有限公司 | 一种双组分环氧胶黏剂及其制备方法和应用 |
CN117363290A (zh) * | 2023-10-31 | 2024-01-09 | 句容协鑫光伏科技有限公司 | 粘合组合物及其制备方法和应用、底板胶、底板胶层 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102120918A (zh) * | 2010-01-09 | 2011-07-13 | 爱克工业株式会社 | 粘着剂组成物 |
CN102120925A (zh) * | 2011-02-14 | 2011-07-13 | 上海康达化工新材料股份有限公司 | 一种单晶硅棒切割胶的改性环氧树脂及其制备方法 |
CN102627931A (zh) * | 2012-03-23 | 2012-08-08 | 烟台德邦科技有限公司 | 一种预催化型粘接胶及其制备方法 |
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2013
- 2013-01-16 CN CN201310016067.XA patent/CN103571415B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102120918A (zh) * | 2010-01-09 | 2011-07-13 | 爱克工业株式会社 | 粘着剂组成物 |
CN102120925A (zh) * | 2011-02-14 | 2011-07-13 | 上海康达化工新材料股份有限公司 | 一种单晶硅棒切割胶的改性环氧树脂及其制备方法 |
CN102627931A (zh) * | 2012-03-23 | 2012-08-08 | 烟台德邦科技有限公司 | 一种预催化型粘接胶及其制备方法 |
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C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
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ASS | Succession or assignment of patent right |
Owner name: SHANGHAI DUWEI PHOTOVOLTAIC TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANGHAI DUWEI ELECTRONICS CO., LTD. Effective date: 20150420 |
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C41 | Transfer of patent application or patent right or utility model | ||
C53 | Correction of patent for invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Xu Qibin Inventor after: Zhang Lifang Inventor after: Yang Liyan Inventor after: Wu Pingzhang Inventor before: Xu Qibin Inventor before: Zhang Lifang |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: XU QIBIN ZHANG LIFANG TO: XU QIBIN ZHANG LIFANG YANG LIYAN WU PINGZHANG |
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TA01 | Transfer of patent application right |
Effective date of registration: 20150420 Address after: West International Center 898 Shanghai City No. 201199 Minhang District Xiuwen Road 5 room 1205 Applicant after: Shanghai Dou Wei photovoltaic Science and Technology Ltd. Address before: 201199, room 4999, 1221 middle spring road, Shanghai, Minhang District Applicant before: Shanghai Dou Wei Electronics Co., Ltd. |
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Effective date of registration: 20180508 Address after: 201108 2 floor, 2 building, 1358 Xiangyang Road, Minhang District, Shanghai. Patentee after: Shanghai Yu Xin Mstar Technology Ltd Address before: 201199 room 1205, Xizi International Center, 898 Xiuwen Road, Minhang District, Shanghai, 5 Patentee before: Shanghai Dou Wei photovoltaic Science and Technology Ltd. |