CN103570469A - Pollution-free nano fertilizer for controlling powdery mildew of lonicera tragophylla and preparation method thereof - Google Patents

Abstract

The invention relates to a pollution-free nano fertilizer for controlling powdery mildew of lonicera tragophylla and a preparation method thereof. The pollution-free nano fertilizer is prepared from the following raw materials in parts by weight: 45 to 55 parts of strontium carbonate, 20 to 30 parts of wild pepper, 20 to 30 parts of ginkgo biloba sarcotesta, 20 to 30 parts of fructus cnidii, 10 to 20 parts of organic solvent, 25 to 30 parts of silicon hydroxyl apatite, 25 to 30 parts of silicon hydroxyl apatite, 10 to 15 parts of capsule wall material, and 1 to 3 parts of colloid, etc. Compared with the prior art, the pollution-free nano fertilizer of such a dosage form has good weeding effect and is friendly to the environment; weeds hardly generate resistance to the pollution-free nano fertilizer; and the application prospect of the pollution-free nano fertilizer is broad.

Description

Nuisanceless nanometer fertilizer of a kind of control flower bud of Chinese Honeysuckle Powdery Mildew and preparation method thereof

Technical field

The invention belongs to nuisanceless fertilizer technical field, relate to nuisanceless nanometer fertilizer of a kind of control flower bud of Chinese Honeysuckle Powdery Mildew and preparation method thereof.

Background technology

Flower bud of Chinese Honeysuckle ( lonicera tragophyllaHemasl) belong to Caprifoliaceae Lonicera winding-type climbing vine plant, be mainly distributed in Central China and western part, along Qinling Mountain, all there is distribution.Our province is distributed in county, the cities such as the sky and water, Wushan, Kang County, health and happiness, Zhouqu County, Cheng County, Hui County, Wen County, Huating, Pingliang, grow in the hillside shrubbery of height above sea level 1 000-2 000 m more, flower bud of Chinese Honeysuckle is not only of many uses, or the fastest plant of growth, and 1 budlet 1 a can grow more than 2 m, 1 rattan can separate a plurality of forks, only inquire for bud with regard to bifurcated, be radial growth, and see that bud joint takes root, start new 1 and take turns growth and climb up by holding on to, in northern China, start mid-March to germinate.Flower bud of Chinese Honeysuckle can be wound in hedge wall, flower stand, flower corridor, withered tree, lamppost, balcony or be attached on the stone of mountain, plants in limes marginis, climbs in hillside, as ground quilt, is rich in natural taste.Plant body is light, is the good material that beautifies roof garden; Potted landscape is made in old stake, and attitude is quaint.Except the purposes of gardens, the bud of flower bud of Chinese Honeysuckle and band leaf spray can be used as medicine, and are again good nectariferous plants.

At present, about the fertilizer technology of preparing of honeysuckle, not yet someone studies, and popularizing not yet of improved seeds completes, and nursery stock disparities between supply and demand are increasingly sharpened, and have had a strong impact on Landscape Application and the popularization of flower bud of Chinese Honeysuckle.Powdery Mildew harm blade and tender stem., there is circular white velvet-like mildew in blade their early stage, rear continuous expansion, connects in flakes, forms white amyloid plaque not of uniform size.Finally cause fallen flowers, the leaf that withers, make branch withered; At present single for the method for preventing and treating of Powdery Mildew, generally only by spraying chemical agent, prevent and treat, yet only Agro-chemicals control to be cured the symptoms, not the disease, effect is undesirable.

The fertilizer of currently available technology only has the trophic function of fertilizer, does not have the effect of killing plant insect.Market in urgent need is a kind of is conducive to environment protection, effectively sterilization, and weeding, and can be applicable to the large nuisanceless bactericidal and herbicidal Chemical Mixed Fertilizer of plant of producing.

The fertilizer of currently available technology only has the trophic function of fertilizer, does not have the effect of killing plant insect.Market in urgent need is a kind of is conducive to environment protection, effectively sterilization, and weeding, and can be applicable to the large nuisanceless bactericidal and herbicidal Chemical Mixed Fertilizer of plant of producing.

Summary of the invention

The nuisanceless nanometer of a kind of control flower bud of Chinese Honeysuckle Powdery Mildew is fertile, and it is prepared by the raw material of following parts by weight: furfural dregs 10-15 part, bean cake powder 20-30 part, peanut cake 15-20 part, maize straw 15-20 part, chicken slaughterhouse waste 10-20 part, kongpo monkshood root 45-55 part, Semen Momordicae 40-50 part, Stellera chamaejasme L. 1-15 part, hops 5-10 part, matrine 5-10 part, Golden Larch Bark 10-15 part, Chinese prickly ash 20-30 part, ginkgo kind skin 20-30 part, Fructus Cnidii 20-30 part, Cortex Meliae 10-30 part, Rangooncreeper Fruit 15-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, Seed of Chinese Soapberry exosper 55-60 part, fructus ulmi 10-15 part, camphor 5-15 part, Strontium carbonate powder 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, manganous sulfate 5-10 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20, , ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part, 10 ~ 20 parts of organic solvents, silicon hydroxyapatite 25-30 part, 10 ~ 15 parts of cyst materials, 1 ~ 3 part, colloid.

Its preparation method comprises the steps: above-mentioned furfural dregs 10-15 part, bean cake powder 20-30 part, peanut cake 15-20 part, maize straw 15-20 part, chicken slaughterhouse waste 10-20 part heap heap in echelon, from top, down punch, 10～15 of every square metre of hole counts, material surface covers with gunnysack or straw screen or mat, start to carry out aerobic fermentation, temperature rise to 50 to be piled ℃ starts timing, ferments 5～7 days; When stockpile temperature starts to decline, carry out turning, then ferment 5～7 days, turning in later every 5～7 days once, is fermented 35～45 days altogether, and fermenting process completes; The above-mentioned humus organic material moisture content fermenting is dried or dried in the air to 25～35%(wt);

(2) fermenting agent fermented liquid l～5 part are joined in 95～99 parts of humus organic materials, regulate moisture content 60～70%(wt), pH 6.5～7.5, fully mix, pile the long strip shape stockpile of high 0.4-0.6 meter, cover gunnysack or straw screen or mat, 25～30 ℃ of the temperature of control stockpile, turning every day once, fermentation culture is 5～8 days altogether, after it covers with spore, stop, drying in the air to moisture content 20～22%(wt), then according to mushroom residue, 6%-10% straw ash and the 600-1000g/T arbuscular mycorrhiza microbial inoculum of mass percent interpolation 5%-10%, obtain biological organic fertilizer;

(3) get kongpo monkshood root, Semen Momordicae, Stellera chamaejasme L., hops, matrine, Golden Larch Bark, Chinese prickly ash, ginkgo kind skin, Fructus Cnidii, Cortex Meliae, Rangooncreeper Fruit, Turkey-galls, Root of Pubescent Holly, Seed of Chinese Soapberry exosper, fructus ulmi, camphor according to described parts by weight, in water, soak after 2.5 hours, being warmed to 50 ℃ keeps 30 minutes, then add the cellulase of (unit of activity of 10 parts is 100U) to carry out enzymolysis, enzyme digestion reaction temperature is 30-50 ℃, the enzyme digestion reaction time is 1.5 hours, filters and obtains Chinese herbal medicine fluid; The 75% alcohol immersion 80min that 300 parts of the described herbal liquid medicines making is added to 10 times of weight, is heated to 70 ℃ times and heats up in a steamer 45min, filters, and collects extracting solution; Filter residue adds 70% ethanol of 5 times of weight again, is heated to 80 ℃ times and heats up in a steamer 45min, filters, and collects extracting solution; The extracting solution obtaining is obtained to inorganic fertilizer by above-mentioned formula interpolation Strontium carbonate powder, carbon ammonium, diammonium phosphate, Repone K, zinc sulfate, boric acid, manganous sulfate, medical stone powder, calcium stone flour, wilkinite, thiocarbamide, diatomite, ground phosphate rock, Sodium salts humic acids;

(4) ratio that in the biological organic fertilizer in step (2) and step (3), inorganic fertilizer is 3-4:1-2 according to mass ratio is mixed, the silicon hydroxyapatite, the cyst material that add described weight part, add again the colloid of described weight part to stir with per minute 2500 rotating speeds, form oil-in-water emulsion; Reduce revolution to 1500 and turn, stir and within 25 minutes, then add dilute hydrochloric acid to regulate pH value to 3.0, then stir after 1 hour rotating speed is dropped to 100 revs/min, be warmed up to 50 ~ 55 ℃, continue to stir, after 2 hours, add sodium hydroxide to regulate pH value to 7.0.

Described agricultural wastes comprise stalk, bran, rice husk, oil cake, dregs of beans, wood powder, pericarp, weeds, and fermenting agent is bacstearothermophilus, mucormycosis, plant lactobacillus, saccharomycetic mixture, and mass ratio is 1: 0.8: 1.2: 1.4.

Described bacterial classification is the commercially available bacterial classification of business, by conventional commercial channel, all can buy.

Bactericidal and herbicidal agent of the present invention can be used for broadcasting the front soil treatment of rear seedling, prevents and kill off the sterilization idiocratic of farmland weed and wide spectrum.Compared with prior art, it is good that formulation of the present invention has herbicidal effect, environmentally safe, and the weeds feature such as be difficult for developing immunity to drugs, has a extensive future.Bactericidal and herbicidal agent of the present invention is little on the impact of farmland natural enemy, contributes to keep ecotope, more friendly to environment, meets the production requirement of crop; The second main group element strontium, not only has promoter action to plant growth, and the harmful bacteria in soil is had to killing action, effectively prevents and treats soil-borne disease; The present invention on average reaches 89.1% to the prevention effect of Powdery Mildew, and soil contains and enriches organic matter and humic acid, can improve Soil structure, and vegetable soil promotes soil to build up fertility; Utilize hydroxyapatite itself to there is the character of vesicular structure, Drug absorbability, in the inner mesh of carrier, is reached to the object of slow release.Hydroxyapatite also has biodegradable characteristic, gained degraded product is phosphate anion and calcium ion, and these elements can be absorbed by crop again, can not produce destruction to crop and environment, can also improve soil, so the product quality that the hydroxyapatite of usining obtains as agricultural chemicals, chemical fertilizer carrier is reliable, stability is strong, uses safety, drug loading and adsorptive capacity all improve a lot, fertilizer efficiency time lengthening is more than 4 months, and utilization rate of fertilizer improves 18%, improves the producer's benefit.

Embodiment

The present invention is described in further detail by the following examples, but should be appreciated that the present invention is not in following examples.

Embodiment 1: the nuisanceless nanometer of a kind of control flower bud of Chinese Honeysuckle Powdery Mildew is fertile, and it is prepared by the raw material of following parts by weight: furfural dregs 10-15 part, bean cake powder 20-30 part, peanut cake 15-20 part, maize straw 15-20 part, chicken slaughterhouse waste 10-20 part, kongpo monkshood root 45-55 part, Semen Momordicae 40-50 part, Stellera chamaejasme L. 1-15 part, hops 5-10 part, matrine 5-10 part, Golden Larch Bark 10-15 part, Chinese prickly ash 20-30 part, ginkgo kind skin 20-30 part, Fructus Cnidii 20-30 part, Cortex Meliae 10-30 part, Rangooncreeper Fruit 15-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, Seed of Chinese Soapberry exosper 55-60 part, fructus ulmi 10-15 part, camphor 5-15 part, Strontium carbonate powder 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, manganous sulfate 5-10 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20, , ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part, 10 ~ 20 parts of organic solvents, silicon hydroxyapatite 25-30 part, 10 ~ 15 parts of cyst materials, 1 ~ 3 part, colloid.

Its preparation method comprises the steps: above-mentioned furfural dregs 10-15 part, bean cake powder 20-30 part, peanut cake 15-20 part, maize straw 15-20 part, chicken slaughterhouse waste 10-20 part heap heap in echelon, from top, down punch, 10～15 of every square metre of hole counts, material surface covers with gunnysack or straw screen or mat, start to carry out aerobic fermentation, temperature rise to 50 to be piled ℃ starts timing, ferments 5～7 days; When stockpile temperature starts to decline, carry out turning, then ferment 5～7 days, turning in later every 5～7 days once, is fermented 35～45 days altogether, and fermenting process completes; The above-mentioned humus organic material moisture content fermenting is dried or dried in the air to 25～35%(wt);

(2) fermenting agent fermented liquid l～5 part are joined in 95～99 parts of humus organic materials, regulate moisture content 60～70%(wt), pH 6.5～7.5, fully mix, pile the long strip shape stockpile of high 0.4-0.6 meter, cover gunnysack or straw screen or mat, 25～30 ℃ of the temperature of control stockpile, turning every day once, fermentation culture is 5～8 days altogether, after it covers with spore, stop, drying in the air to moisture content 20～22%(wt), then according to mushroom residue, 6%-10% straw ash and the 600-1000g/T arbuscular mycorrhiza microbial inoculum of mass percent interpolation 5%-10%, obtain biological organic fertilizer;

(3) get kongpo monkshood root, Semen Momordicae, Stellera chamaejasme L., hops, matrine, Golden Larch Bark, Chinese prickly ash, ginkgo kind skin, Fructus Cnidii, Cortex Meliae, Rangooncreeper Fruit, Turkey-galls, Root of Pubescent Holly, Seed of Chinese Soapberry exosper, fructus ulmi, camphor according to described parts by weight, in water, soak after 2.5 hours, being warmed to 50 ℃ keeps 30 minutes, then add the cellulase of (unit of activity of 10 parts is 100U) to carry out enzymolysis, enzyme digestion reaction temperature is 30-50 ℃, the enzyme digestion reaction time is 1.5 hours, filters and obtains Chinese herbal medicine fluid; The 75% alcohol immersion 80min that 300 parts of the described herbal liquid medicines making is added to 10 times of weight, is heated to 70 ℃ times and heats up in a steamer 45min, filters, and collects extracting solution; Filter residue adds 70% ethanol of 5 times of weight again, is heated to 80 ℃ times and heats up in a steamer 45min, filters, and collects extracting solution; The extracting solution obtaining is obtained to inorganic fertilizer by above-mentioned formula interpolation Strontium carbonate powder, carbon ammonium, diammonium phosphate, Repone K, zinc sulfate, boric acid, manganous sulfate, medical stone powder, calcium stone flour, wilkinite, thiocarbamide, diatomite, ground phosphate rock, Sodium salts humic acids;

(4) ratio that in the biological organic fertilizer in step (2) and step (3), inorganic fertilizer is 3-4:1-2 according to mass ratio is mixed, the silicon hydroxyapatite, the cyst material that add described weight part, add again the colloid of described weight part to stir with per minute 2500 rotating speeds, form oil-in-water emulsion; Reduce revolution to 1500 and turn, stir and within 25 minutes, then add dilute hydrochloric acid to regulate pH value to 3.0, then stir after 1 hour rotating speed is dropped to 100 revs/min, be warmed up to 50 ~ 55 ℃, continue to stir, after 2 hours, add sodium hydroxide to regulate pH value to 7.0.

Described agricultural wastes comprise stalk, bran, rice husk, oil cake, dregs of beans, wood powder, pericarp, weeds, and fermenting agent is bacstearothermophilus, mucormycosis, plant lactobacillus, saccharomycetic mixture, and mass ratio is 1: 0.8: 1.2: 1.4.

The present invention on average reaches 89.1% to the prevention effect of Powdery Mildew, and soil contains and enriches organic matter and humic acid, can improve Soil structure, and vegetable soil promotes soil to build up fertility.Formulate and coordinate farm crop absorption nutrition, stimulating and regulation and control plant growth, reduce or reduce crop pest, affecting crop quality.Need not or reduce fertilizer amount, be beneficial to protection of the environment; Utilize hydroxyapatite itself to there is the character of vesicular structure, Drug absorbability, in the inner mesh of carrier, is reached to the object of slow release.Hydroxyapatite also has biodegradable characteristic, gained degraded product is phosphate anion and calcium ion, and these elements can be absorbed by crop again, can not produce destruction to crop and environment, can also improve soil, so the product quality that the hydroxyapatite of usining obtains as agricultural chemicals, chemical fertilizer carrier is reliable, stability is strong, uses safety, drug loading and adsorptive capacity all improve a lot, fertilizer efficiency time lengthening is more than 4 months, and utilization rate of fertilizer improves 18%, improves the producer's benefit.

Claims (3)

1. the nuisanceless nanometer of control flower bud of Chinese Honeysuckle Powdery Mildew is fertile, it is characterized in that, it is prepared by the raw material of following parts by weight: furfural dregs 10-15 part, bean cake powder 20-30 part, peanut cake 15-20 part, maize straw 15-20 part, chicken slaughterhouse waste 10-20 part, kongpo monkshood root 45-55 part, Semen Momordicae 40-50 part, Stellera chamaejasme L. 1-15 part, hops 5-10 part, matrine 5-10 part, Golden Larch Bark 10-15 part, Chinese prickly ash 20-30 part, ginkgo kind skin 20-30 part, Fructus Cnidii 20-30 part, Cortex Meliae 10-30 part, Rangooncreeper Fruit 15-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, Seed of Chinese Soapberry exosper 55-60 part, fructus ulmi 10-15 part, camphor 5-15 part, Strontium carbonate powder 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, manganous sulfate 5-10 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20, , ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part, 10 ~ 20 parts of organic solvents, silicon hydroxyapatite 25-30 part, silicon hydroxyapatite 25-30 part, 10 ~ 15 parts of cyst materials, 1 ~ 3 part, colloid.

2. mixed organic manure according to claim 1, it is characterized in that, it comprises the steps: above-mentioned furfural dregs 10-15 part, bean cake powder 20-30 part, peanut cake 15-20 part, maize straw 15-20 part, chicken slaughterhouse waste 10-20 part heap to pile in echelon, from top, down punch, 10～15 of every square metre of hole counts, gunnysack or straw screen or mat cover for material surface, start to carry out aerobic fermentation, temperature rise to 50 to be piled ℃ starts timing, ferments 5～7 days; When stockpile temperature starts to decline, carry out turning, then ferment 5～7 days, turning in later every 5～7 days once, is fermented 35～45 days altogether, and fermenting process completes; The above-mentioned humus organic material moisture content fermenting is dried or dried in the air to 25～35%(wt);

(2) fermenting agent fermented liquid l～5 part are joined in 95～99 parts of humus organic materials, regulate moisture content 60～70%(wt), pH 6.5～7.5, fully mix, pile the long strip shape stockpile of high 0.4-0.6 meter, cover gunnysack or straw screen or mat, 25～30 ℃ of the temperature of control stockpile, turning every day once, fermentation culture is 5～8 days altogether, after it covers with spore, stop, drying in the air to moisture content 20～22%(wt), then according to mushroom residue, 6%-10% straw ash and the 600-1000g/T arbuscular mycorrhiza microbial inoculum of mass percent interpolation 5%-10%, obtain biological organic fertilizer;

(3) get kongpo monkshood root, Semen Momordicae, Stellera chamaejasme L., hops, matrine, Golden Larch Bark, Chinese prickly ash, ginkgo kind skin, Fructus Cnidii, Cortex Meliae, Rangooncreeper Fruit, Turkey-galls, Root of Pubescent Holly, Seed of Chinese Soapberry exosper, fructus ulmi, camphor according to described parts by weight, in water, soak after 2.5 hours, being warmed to 50 ℃ keeps 30 minutes, then add the cellulase of (unit of activity of 10 parts is 100U) to carry out enzymolysis, enzyme digestion reaction temperature is 30-50 ℃, the enzyme digestion reaction time is 1.5 hours, filters and obtains Chinese herbal medicine fluid; The 75% alcohol immersion 80min that 300 parts of the described herbal liquid medicines making is added to 10 times of weight, is heated to 70 ℃ times and heats up in a steamer 45min, filters, and collects extracting solution; Filter residue adds 70% ethanol of 5 times of weight again, is heated to 80 ℃ times and heats up in a steamer 45min, filters, and collects extracting solution; The extracting solution obtaining is obtained to inorganic fertilizer by above-mentioned formula interpolation Strontium carbonate powder, carbon ammonium, diammonium phosphate, Repone K, zinc sulfate, boric acid, manganous sulfate, medical stone powder, calcium stone flour, wilkinite, thiocarbamide, diatomite, ground phosphate rock, Sodium salts humic acids;

(4) ratio that in the biological organic fertilizer in step (2) and step (3), inorganic fertilizer is 3-4:1-2 according to mass ratio is mixed, the silicon hydroxyapatite, the cyst material that add described weight part, add again the colloid of described weight part to stir with per minute 2500 rotating speeds, form oil-in-water emulsion; Reduce revolution to 1500 and turn, stir and within 25 minutes, then add dilute hydrochloric acid to regulate pH value to 3.0, then stir after 1 hour rotating speed is dropped to 100 revs/min, be warmed up to 50 ~ 55 ℃, continue to stir, after 2 hours, add sodium hydroxide to regulate pH value to 7.0.

3. multi-component composite fertilizer according to claim 1, it is characterized in that: described agricultural wastes comprise stalk, bran, rice husk, oil cake, dregs of beans, wood powder, pericarp, weeds, fermenting agent is bacstearothermophilus, mucormycosis, plant lactobacillus, saccharomycetic mixture, and mass ratio is 1: 0.8: 1.2: 1.4.