CN1035432C - 提纯粗制对苯二酸、间苯二酸或萘二羧酸的催化剂和方法 - Google Patents
提纯粗制对苯二酸、间苯二酸或萘二羧酸的催化剂和方法 Download PDFInfo
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- CN1035432C CN1035432C CN93121625A CN93121625A CN1035432C CN 1035432 C CN1035432 C CN 1035432C CN 93121625 A CN93121625 A CN 93121625A CN 93121625 A CN93121625 A CN 93121625A CN 1035432 C CN1035432 C CN 1035432C
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- Prior art keywords
- acid
- catalyst
- oxidation
- naphthalene dicarboxylic
- catalyzer
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 239000003054 catalyst Substances 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 50
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 title claims abstract description 21
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000000746 purification Methods 0.000 claims abstract description 32
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000001721 carbon Chemical class 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
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- 229910052697 platinum Inorganic materials 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
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- 150000001875 compounds Chemical class 0.000 description 4
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- 239000002245 particle Substances 0.000 description 4
- RWQUWTMOHXGTNN-UHFFFAOYSA-N 9-n,10-n-bis(4-butylphenyl)-9-n,10-n-bis(4-methylphenyl)phenanthrene-9,10-diamine Chemical compound C1=CC(CCCC)=CC=C1N(C=1C2=CC=CC=C2C2=CC=CC=C2C=1N(C=1C=CC(C)=CC=1)C=1C=CC(CCCC)=CC=1)C1=CC=C(C)C=C1 RWQUWTMOHXGTNN-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
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- RVHSTXJKKZWWDQ-UHFFFAOYSA-N 1,1,1,2-tetrabromoethane Chemical compound BrCC(Br)(Br)Br RVHSTXJKKZWWDQ-UHFFFAOYSA-N 0.000 description 2
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
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- 150000002828 nitro derivatives Chemical class 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/029,037 US5362908A (en) | 1993-03-10 | 1993-03-10 | Catalyst and method for purifying crude terephthalic acid, isophthalic acid or naphthalene dicarboxylic acid |
| US08/029,037 | 1993-03-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1090792A CN1090792A (zh) | 1994-08-17 |
| CN1035432C true CN1035432C (zh) | 1997-07-16 |
Family
ID=21846884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93121625A Expired - Fee Related CN1035432C (zh) | 1993-03-10 | 1993-12-08 | 提纯粗制对苯二酸、间苯二酸或萘二羧酸的催化剂和方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5362908A (enExample) |
| EP (1) | EP0688310A1 (enExample) |
| JP (1) | JPH08507082A (enExample) |
| KR (1) | KR960700991A (enExample) |
| CN (1) | CN1035432C (enExample) |
| AU (1) | AU5730194A (enExample) |
| BR (1) | BR9307822A (enExample) |
| CA (1) | CA2157192A1 (enExample) |
| NZ (1) | NZ259126A (enExample) |
| PH (1) | PH29933A (enExample) |
| TW (1) | TW282453B (enExample) |
| WO (1) | WO1994020447A1 (enExample) |
| ZA (1) | ZA939094B (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5767311A (en) | 1995-06-07 | 1998-06-16 | Glitsch International, Inc. | Method and apparatus for preparing purified terephtalic acid |
| US5929274A (en) | 1995-06-07 | 1999-07-27 | Hfm International, Inc. | Method to reduce carboxybenzaldehyde isomers in terephthalic acid or isophthalic acid |
| US6054610A (en) | 1995-06-07 | 2000-04-25 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid and isophthalic acid from mixed xylenes |
| US6013835A (en) | 1995-06-07 | 2000-01-11 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid |
| DE69611430T2 (de) * | 1995-11-10 | 2001-06-07 | Mitsui Chemicals, Inc. | Verfahren zur reinigung von roher naphthalendicarbonsäure |
| US5756833A (en) * | 1996-02-01 | 1998-05-26 | Amoco Corporation | Catalytic purification and recovery of dicarboxylic aromatic acids |
| US5616792A (en) * | 1996-02-01 | 1997-04-01 | Amoco Corporation | Catalytic purification of dicarboxylic aromatic acid |
| JP3757995B2 (ja) * | 1996-07-12 | 2006-03-22 | 三菱瓦斯化学株式会社 | 高純度イソフタル酸の製造方法 |
| CN1230167A (zh) * | 1996-09-10 | 1999-09-29 | 三井化学株式会社 | 粗萘二甲酸的提纯方法和聚萘二甲酸乙二醇酯的制备方法 |
| US6121191A (en) * | 1996-09-20 | 2000-09-19 | Teruo Komatsu | Ultrafine metal particle carrying photocatalyst, highly function material loaded with the photocatalyst, and method of manufacturing them |
| US6265608B1 (en) | 1998-06-30 | 2001-07-24 | Eastman Chemical Company | Method of purifying aromatic dicarboxylic acids |
| EP1389609B1 (en) * | 2001-04-27 | 2013-09-11 | Mitsubishi Gas Chemical Company, Inc. | Method of purifying aromatic polycarboxylic acid |
| US6534677B1 (en) | 2001-06-04 | 2003-03-18 | Engelhard Corporation | Non-crushable, non-friable, non-breakable carbon catalyst supports |
| US7659225B2 (en) * | 2001-09-17 | 2010-02-09 | Basf Catalysts Llc | Precious metal catalyst for debenzylation |
| US6992037B2 (en) | 2001-09-17 | 2006-01-31 | Engelhard Corporation | Precious metal catalyst for debenzylation |
| US20030120109A1 (en) * | 2001-12-20 | 2003-06-26 | Rosen Bruce I. | Purification of a crude acid mixture |
| US6706658B2 (en) | 2001-12-21 | 2004-03-16 | Engelhard Corporation | Catalyst for purification of aromatic acids |
| US7135596B2 (en) * | 2002-04-23 | 2006-11-14 | Bp Corporation North America Inc. | Method of removing iron contaminants from liquid streams during the manufacture and/or purification of aromatic acids |
| US7547803B2 (en) * | 2003-06-20 | 2009-06-16 | Mitsubishi Gas Chemical Company, Inc. | Process for producing a high purity aromatic polycarboxylic acid |
| US20050249659A1 (en) * | 2004-05-04 | 2005-11-10 | Flynn Harry E | Scour media for titanium dioxide production |
| US7935834B2 (en) * | 2004-07-01 | 2011-05-03 | Isp Investments Inc. | Catalysts for maleic acid hydrogenation to 1,4-butanediol |
| CA2590371C (en) * | 2004-12-13 | 2013-04-02 | Bp Corporation North America Inc. | Process for purification of aromatic carboxylic acids |
| ES2346560T3 (es) * | 2005-03-21 | 2010-10-18 | Bp Corporation North America Inc. | Procedimiento y aparato para la fabricacion de acidos carboxilicos aromaticos que incluyen formas puras de los mismos. |
| US20070072783A1 (en) * | 2005-09-26 | 2007-03-29 | Tronox Llc | Scour medium for titanium dioxide production |
| JP5491033B2 (ja) * | 2005-12-29 | 2014-05-14 | ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド | Ｄｅｔを形成するためのｐｅｔのエタノリシス及びその酸化 |
| CA2774574A1 (en) | 2009-09-30 | 2011-04-07 | Bp Corporation North America Inc. | Catalyst, use thereof and process for hydrogenating aryl aldehydes |
| BR112016013885A2 (pt) | 2013-12-18 | 2020-09-24 | Bp Corporation North America Inc. | Aparelho e processo melhorado para fabricação de ácidos carboxílicos aromáticos |
| CN104826603A (zh) * | 2015-05-10 | 2015-08-12 | 江苏爱特恩东台新材料科技有限公司 | 一种制备对苯二甲酸盐气体吸附剂的方法 |
| US20170348671A1 (en) | 2016-06-06 | 2017-12-07 | Huntsman P&A Germany Gmbh | Process for reducing the sulphur content of anatase titania and the so-obtained product |
| BR112018073994A2 (pt) * | 2016-06-06 | 2019-02-26 | Venator Germany Gmbh | processo para reduzir o teor de enxofre de titânia anatase e o produto assim obtido |
| CN114425387B (zh) * | 2020-09-28 | 2023-10-31 | 中国石油化工股份有限公司 | 硼氮共掺杂二氧化钛载钯催化剂及其制备方法和应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52136208A (en) * | 1976-05-11 | 1977-11-14 | Mitsubishi Chem Ind | Manufacture of titanium oxide mold goods |
| EP0289061A1 (en) * | 1987-03-24 | 1988-11-02 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | Method for the preparation and application of rhodium catalysts for the hydrogenation of aromatic and other unsaturated compounds under mild conditions. |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3584039A (en) * | 1967-08-30 | 1971-06-08 | Standard Oil Co | Fiber-grade terephthalic acid by catalytic hydrogen treatment of dissolved impure terephthalic acid |
| US3639465A (en) * | 1968-06-18 | 1972-02-01 | Standard Oil Co | Purification of aromatic polycarboxylic acids by catalytic reduction using prehumidified hydrogen |
| DE3115032A1 (de) * | 1980-04-14 | 1982-02-18 | Showa Denko K.K., Tokyo | Rhodium-katalysator und verfahren zu seiner herstellung |
| FR2481145A1 (fr) * | 1980-04-23 | 1981-10-30 | Rhone Poulenc Ind | Procede de fabrication de catalyseurs ou de supports de catalyseurs faconnes a base d'oxyde de titane et leurs applications a la catalyse claus |
| US4405809A (en) * | 1981-12-04 | 1983-09-20 | Standard Oil Company (Indiana) | Process for the manufacture of aromatic polycarboxylic acids having delta Y values below ten |
| US4743577A (en) * | 1986-10-14 | 1988-05-10 | Amoco Corporation | Catalyst composition |
| FR2633605B1 (fr) * | 1988-07-01 | 1991-07-12 | Rhone Poulenc Chimie | Procede de preparation d'oxyde de titane et d'articles a base d'oxyde de titane |
| GB9213140D0 (en) * | 1992-06-20 | 1992-08-05 | Tioxide Specialties Ltd | Preparation of anatase titanium dioxide |
-
1993
- 1993-03-10 US US08/029,037 patent/US5362908A/en not_active Expired - Fee Related
- 1993-11-29 KR KR1019950703851A patent/KR960700991A/ko not_active Withdrawn
- 1993-11-29 JP JP6519949A patent/JPH08507082A/ja active Pending
- 1993-11-29 EP EP94903314A patent/EP0688310A1/en not_active Withdrawn
- 1993-11-29 CA CA002157192A patent/CA2157192A1/en not_active Abandoned
- 1993-11-29 AU AU57301/94A patent/AU5730194A/en not_active Abandoned
- 1993-11-29 BR BR9307822A patent/BR9307822A/pt not_active Application Discontinuation
- 1993-11-29 NZ NZ259126A patent/NZ259126A/en unknown
- 1993-11-29 WO PCT/US1993/011508 patent/WO1994020447A1/en not_active Ceased
- 1993-12-03 ZA ZA939094A patent/ZA939094B/xx unknown
- 1993-12-07 TW TW082110351A patent/TW282453B/zh active
- 1993-12-08 CN CN93121625A patent/CN1035432C/zh not_active Expired - Fee Related
- 1993-12-13 PH PH47435A patent/PH29933A/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52136208A (en) * | 1976-05-11 | 1977-11-14 | Mitsubishi Chem Ind | Manufacture of titanium oxide mold goods |
| EP0289061A1 (en) * | 1987-03-24 | 1988-11-02 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | Method for the preparation and application of rhodium catalysts for the hydrogenation of aromatic and other unsaturated compounds under mild conditions. |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2157192A1 (en) | 1994-09-15 |
| ZA939094B (en) | 1994-08-08 |
| TW282453B (enExample) | 1996-08-01 |
| CN1090792A (zh) | 1994-08-17 |
| JPH08507082A (ja) | 1996-07-30 |
| BR9307822A (pt) | 1995-11-14 |
| WO1994020447A1 (en) | 1994-09-15 |
| AU5730194A (en) | 1994-09-26 |
| US5362908A (en) | 1994-11-08 |
| EP0688310A1 (en) | 1995-12-27 |
| PH29933A (en) | 1996-09-16 |
| KR960700991A (ko) | 1996-02-24 |
| NZ259126A (en) | 1996-02-27 |
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