CN1035007C - 齐格勒-纳塔催化剂及其制备方法 - Google Patents

齐格勒-纳塔催化剂及其制备方法 Download PDF

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Publication number
CN1035007C
CN1035007C CN89102807A CN89102807A CN1035007C CN 1035007 C CN1035007 C CN 1035007C CN 89102807 A CN89102807 A CN 89102807A CN 89102807 A CN89102807 A CN 89102807A CN 1035007 C CN1035007 C CN 1035007C
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CN
China
Prior art keywords
propylene
support
carrier
donor compound
catalyzer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN89102807A
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English (en)
Chinese (zh)
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CN1037346A (zh
Inventor
基恩·克劳德·拜利
路易斯·伯德
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BP Chemicals Ltd
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BP Chemicals Ltd
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Publication of CN1037346A publication Critical patent/CN1037346A/zh
Application granted granted Critical
Publication of CN1035007C publication Critical patent/CN1035007C/zh
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN89102807A 1988-03-31 1989-03-24 齐格勒-纳塔催化剂及其制备方法 Expired - Fee Related CN1035007C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR8804573A FR2629461B1 (fr) 1988-03-31 1988-03-31 Catalyseur de (co)polymerisation du propylene, supporte sur des particules spheriques de chlorure de magnesium et enrobe par du polypropylene, et procedes de preparation
FR8804573 1988-03-31
IN260DE1989 IN174772B (cg-RX-API-DMAC7.html) 1988-03-31 1989-03-21

Publications (2)

Publication Number Publication Date
CN1037346A CN1037346A (zh) 1989-11-22
CN1035007C true CN1035007C (zh) 1997-05-28

Family

ID=26226597

Family Applications (1)

Application Number Title Priority Date Filing Date
CN89102807A Expired - Fee Related CN1035007C (zh) 1988-03-31 1989-03-24 齐格勒-纳塔催化剂及其制备方法

Country Status (17)

Country Link
US (1) US5032560A (cg-RX-API-DMAC7.html)
EP (1) EP0338676B1 (cg-RX-API-DMAC7.html)
JP (1) JP2755669B2 (cg-RX-API-DMAC7.html)
KR (1) KR0137773B1 (cg-RX-API-DMAC7.html)
CN (1) CN1035007C (cg-RX-API-DMAC7.html)
AU (1) AU621349B2 (cg-RX-API-DMAC7.html)
CA (1) CA1331377C (cg-RX-API-DMAC7.html)
CS (1) CS401391A3 (cg-RX-API-DMAC7.html)
DE (1) DE68901679T2 (cg-RX-API-DMAC7.html)
DK (1) DK157089A (cg-RX-API-DMAC7.html)
ES (1) ES2037414T3 (cg-RX-API-DMAC7.html)
FI (1) FI96613C (cg-RX-API-DMAC7.html)
FR (1) FR2629461B1 (cg-RX-API-DMAC7.html)
GR (1) GR3005019T3 (cg-RX-API-DMAC7.html)
IN (1) IN174772B (cg-RX-API-DMAC7.html)
NO (1) NO172851C (cg-RX-API-DMAC7.html)
SG (1) SG73592G (cg-RX-API-DMAC7.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102834420A (zh) * 2010-02-24 2012-12-19 巴斯夫公司 用于烯烃聚合催化剂ii的内部和外部给体化合物

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2649708B1 (fr) * 1989-07-17 1991-10-25 Bp Chem Int Ltd Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite
FR2651234B1 (fr) * 1989-08-29 1993-03-12 Bp Chem Int Ltd Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite.
US5247032A (en) * 1989-12-29 1993-09-21 Mitsui Petrochemical Industries, Ltd. Solid catalyst components for olefin polymerization and processes for the polymerization of olefin using same
JP2940684B2 (ja) * 1989-12-29 1999-08-25 三井化学株式会社 オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法
IT1246614B (it) * 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
EP0564211A3 (en) * 1992-04-03 1993-10-20 BP Chemicals Limited Process for the preparation of a ziegler-natta catalyst
FR2697526B1 (fr) * 1992-10-30 1994-12-16 Bp Chemicals Snc Procédé de préparation d'un catalyseur de type Ziegler-Natta pour la polymérisation des oléfines.
FR2689510B1 (fr) * 1992-04-03 1995-07-21 Bp Chemicals Snc Procede de preparation d'un catalyseur de type ziegler natta pour la polymerisation des olefines.
US6046126A (en) * 1998-05-12 2000-04-04 Kelly; Mark Titanium process for making catalyst
KR20040018238A (ko) 2001-06-26 2004-03-02 바셀 폴리올레핀 이탈리아 에스.피.에이. 올레핀 중합용 성분 및 촉매
US8893725B2 (en) 2011-01-28 2014-11-25 R. J. Reynolds Tobacco Company Polymeric materials derived from tobacco
JP5918486B2 (ja) * 2011-07-06 2016-05-18 サンアロマー株式会社 α−オレフィン重合方法
US8933180B2 (en) 2013-03-14 2015-01-13 Basf Corporation Internal and external donor compounds for olefin polymerization catalysts IV

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4497904A (en) * 1982-06-24 1985-02-05 Bp Chimie Societe Anonyme Catalysts for the polymerization and copolymerization of ethylene and polymerization processes using these catalysts
US4511703A (en) * 1982-06-24 1985-04-16 Bp Chimie Societe Anonyme Catalysts for the polymerization and copolymerization of propylene and polymerization processes using these catalysts
US4673661A (en) * 1985-01-22 1987-06-16 Neste Oy Catalyst components, a catalyst and a process for the polymerization of olefins
US4721763A (en) * 1982-06-24 1988-01-26 Bp Chemicals Limited Process for the polymerization and copolymerization of alpha-olefins in fluidized bed

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953414A (en) * 1972-09-13 1976-04-27 Montecatini Edison S.P.A., Catalysts for the polymerization of olefins to spherically shaped polymers
US4295991A (en) * 1978-09-26 1981-10-20 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
US4326988A (en) * 1980-08-12 1982-04-27 Phillips Petroleum Company Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4543389A (en) * 1984-04-10 1985-09-24 Shell Oil Company Copolymerization catalyst and process for polymerizing impact resistant ethylene-propylene polymers
FR2596052A1 (fr) * 1986-03-20 1987-09-25 Bp Chimie Sa Catalyseurs de polymerisation des alpha-olefines a base de trichlorure de titane
IT1199833B (it) * 1986-11-10 1989-01-05 Himont Inc Catalizzatori per la preparazione di polimeri delle alfa-olefine a stretta distribuzione dei pesi molecolari
FR2628110B1 (fr) * 1988-03-03 1994-03-25 Bp Chimie Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4497904A (en) * 1982-06-24 1985-02-05 Bp Chimie Societe Anonyme Catalysts for the polymerization and copolymerization of ethylene and polymerization processes using these catalysts
US4511703A (en) * 1982-06-24 1985-04-16 Bp Chimie Societe Anonyme Catalysts for the polymerization and copolymerization of propylene and polymerization processes using these catalysts
US4721763A (en) * 1982-06-24 1988-01-26 Bp Chemicals Limited Process for the polymerization and copolymerization of alpha-olefins in fluidized bed
US4673661A (en) * 1985-01-22 1987-06-16 Neste Oy Catalyst components, a catalyst and a process for the polymerization of olefins

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102834420A (zh) * 2010-02-24 2012-12-19 巴斯夫公司 用于烯烃聚合催化剂ii的内部和外部给体化合物
CN102834420B (zh) * 2010-02-24 2014-10-22 巴斯夫公司 用于烯烃聚合催化剂ii的内部和外部给体化合物

Also Published As

Publication number Publication date
NO891345D0 (no) 1989-03-30
DE68901679T2 (de) 1992-12-10
KR0137773B1 (ko) 1998-05-01
FR2629461B1 (fr) 1993-05-07
FI891561L (fi) 1989-10-01
CA1331377C (en) 1994-08-09
SG73592G (en) 1992-10-02
DK157089A (da) 1989-10-01
EP0338676B1 (en) 1992-06-03
NO172851B (no) 1993-06-07
FI96613C (fi) 1996-07-25
JP2755669B2 (ja) 1998-05-20
NO172851C (no) 1993-09-15
CN1037346A (zh) 1989-11-22
DE68901679D1 (de) 1992-07-09
JPH01289809A (ja) 1989-11-21
IN174772B (cg-RX-API-DMAC7.html) 1995-03-04
US5032560A (en) 1991-07-16
ES2037414T3 (es) 1993-06-16
CS401391A3 (en) 1992-05-13
DK157089D0 (da) 1989-03-31
KR890014589A (ko) 1989-10-24
FR2629461A1 (fr) 1989-10-06
GR3005019T3 (cg-RX-API-DMAC7.html) 1993-05-24
AU621349B2 (en) 1992-03-12
EP0338676A1 (en) 1989-10-25
AU3164089A (en) 1989-10-05
FI891561A0 (fi) 1989-03-31
FI96613B (fi) 1996-04-15
NO891345L (no) 1989-10-02

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C15 Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
OR01 Other related matters
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee