CN103338831A - 用于减少汞排放的溴化无机吸附剂 - Google Patents

用于减少汞排放的溴化无机吸附剂 Download PDF

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Publication number
CN103338831A
CN103338831A CN201180055980XA CN201180055980A CN103338831A CN 103338831 A CN103338831 A CN 103338831A CN 201180055980X A CN201180055980X A CN 201180055980XA CN 201180055980 A CN201180055980 A CN 201180055980A CN 103338831 A CN103338831 A CN 103338831A
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CN
China
Prior art keywords
inorganic
bromination
bromine
source
adsorbent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201180055980XA
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English (en)
Chinese (zh)
Inventor
C.J.奈尔帕
周群辉
C.瓦多维奇
G.H.兰贝思
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Albemarle Corp
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Albemarle Corp
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Publication of CN103338831A publication Critical patent/CN103338831A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/027—Compounds of F, Cl, Br, I
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B01D2251/108—Halogens or halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
CN201180055980XA 2010-11-22 2011-11-14 用于减少汞排放的溴化无机吸附剂 Pending CN103338831A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US41607710P 2010-11-22 2010-11-22
US61/416,077 2010-11-22
PCT/US2011/060605 WO2012071206A1 (en) 2010-11-22 2011-11-14 Brominated inorganic sorbents for reduction of mercury emissions

Publications (1)

Publication Number Publication Date
CN103338831A true CN103338831A (zh) 2013-10-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180055980XA Pending CN103338831A (zh) 2010-11-22 2011-11-14 用于减少汞排放的溴化无机吸附剂

Country Status (16)

Country Link
US (1) US20130272936A1 (enExample)
EP (1) EP2643071A1 (enExample)
JP (1) JP2013544185A (enExample)
KR (1) KR20140002642A (enExample)
CN (1) CN103338831A (enExample)
AR (1) AR083944A1 (enExample)
AU (1) AU2011332149A1 (enExample)
BR (1) BR112013012524A2 (enExample)
CA (1) CA2815090A1 (enExample)
CL (1) CL2013001404A1 (enExample)
CO (1) CO6801783A2 (enExample)
PH (1) PH12013500868A1 (enExample)
RU (1) RU2013128615A (enExample)
TW (1) TW201228722A (enExample)
WO (1) WO2012071206A1 (enExample)
ZA (1) ZA201303131B (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112135695A (zh) * 2018-05-04 2020-12-25 雅宝公司 降低环境污染物的环境有效性的工艺
CN113713769A (zh) * 2021-09-06 2021-11-30 中南大学 一种改性炭基吸附剂及其制备方法和应用

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8863404B1 (en) * 2010-12-06 2014-10-21 Astec, Inc. Apparatus and method for dryer performance optimization system
US9382672B2 (en) 2010-12-06 2016-07-05 Astec, Inc. Apparatus and method for dryer performance optimization system
DE102011103829A1 (de) * 2011-06-01 2012-12-06 Rheinbraun Brennstoff Gmbh Verfahren zur Abscheidung von Quecksilber aus Rauchgasen von Hochtemperaturanlagen
DE102012012367B4 (de) 2012-06-21 2014-03-27 Ftu Gmbh Forschung Und Technische Entwicklung Im Umweltschutz Aktivierter trass,dessen herstellung und verwendung
US9199898B2 (en) 2012-08-30 2015-12-01 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
CN104736222B (zh) 2012-09-07 2017-09-08 雪佛龙美国公司 从流体中除去重金属的工艺、方法和系统
GB2525524A (en) * 2013-01-28 2015-10-28 Cabot Corp Mercury removal from flue gas streams using treated sorbents
US8551431B1 (en) * 2013-01-28 2013-10-08 Cabot Corporation Mercury removal from flue gas streams using treated sorbents
US20160030915A1 (en) * 2013-03-13 2016-02-04 Novinda Corporation Supported Sulfides for Mercury Capture
TWI619550B (zh) * 2013-03-15 2018-04-01 亞比馬利股份有限公司 煙道氣吸附劑、其製造方法及其自氣流移除汞之用途
DE102014113620A1 (de) 2014-09-22 2016-03-24 Ftu Gmbh Puzzolane zur Abgasreinigung
CN104351065A (zh) * 2014-11-25 2015-02-18 芜湖悠派卫生用品有限公司 一种矿质吸附猫砂及其制备方法
PE20180862A1 (es) 2015-08-21 2018-05-22 Ecolab Usa Inc Formacion de complejos y remocion de mercurio de los sistemas de desulfuracion de gases de combustion
CR20180165A (es) 2015-08-21 2018-06-14 Ecolab Usa Inc Complejación y eliminación del mercurio de sistema de desulfuración de gas de combustión
CN105854544A (zh) * 2016-05-24 2016-08-17 南京华电节能环保设备有限公司 一种烟气的除汞净化方法
US11110393B2 (en) 2017-07-06 2021-09-07 Ecolab Usa Inc. Enhanced injection of mercury oxidants
KR102248568B1 (ko) * 2018-07-26 2021-05-06 한국원자력연구원 방사성 핵종 흡착제, 이의 제조방법 및 이를 이용한 방사성 핵종의 제거 방법
AU2020348298A1 (en) 2019-09-16 2022-03-24 Albemarle Corporation Processes for reducing environmental availability of environmental pollutants
CA3153371A1 (en) * 2019-09-16 2021-03-25 Albemarle Corporation Processes for reducing environmental availability of environmental pollutants
US20250353760A1 (en) * 2020-05-28 2025-11-20 Albemarle Corporation Method of reducing environmental methylmercury and limiting its uptake into plants and organisms
EP4377000A1 (en) 2021-07-30 2024-06-05 Albemarle Corporation Processes for suppressing emission of mercury vapor
CN115445418B (zh) * 2022-08-23 2024-06-14 国家能源集团新能源技术研究院有限公司 一种用于协同脱除燃煤烟气中汞和二氧化碳的系统及方法
KR20250096724A (ko) 2022-10-26 2025-06-27 알베마를 코포레이션 환경 오염물질의 환경 이용가능성을 감소시키는 방법

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86102713A (zh) * 1985-04-17 1986-10-22 东洋曹达工业株式会社 用于回收溴的吸附剂及应用该吸附剂回收溴的工艺
US5952541A (en) * 1992-07-30 1999-09-14 Exxon Chemical Patents, Inc. Method of loading hydrogen halide onto an adsorbent to enable removal of lead impurities from liquid hydrocarbons
CN1665947A (zh) * 2002-05-06 2005-09-07 小西德尼·G·尼尔逊 用于脱除烟气中汞的吸附剂及相应的脱汞方法
CN101274190A (zh) * 2007-03-30 2008-10-01 高化环保技术有限公司 利用硫化处理铁氧化物的除汞用吸附剂及其制造方法
US20090136401A1 (en) * 2007-09-24 2009-05-28 Basf Catalysts Llc Pollutant Emission Control Sorbents and Methods of Manufacture and Use
CN101502737A (zh) * 2009-01-21 2009-08-12 东华大学 一种用溴化处理过的碳粉脱除燃煤烟气中重金属汞的方法及装置
CN101553301A (zh) * 2006-12-08 2009-10-07 普莱克斯技术有限公司 适用作水泥添加剂的水银吸附剂

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3749754A (en) * 1971-04-28 1973-07-31 Exxon Hydroisomerization process with hydrogen faujasite containing a group viii metal
US4101631A (en) 1976-11-03 1978-07-18 Union Carbide Corporation Selective adsorption of mercury from gas streams
FR2438083A1 (fr) * 1978-10-02 1980-04-30 Mobil Oil Corp Procede pour eliminer les composes azotes presents dans les hydrocarbures liquides
JPH08330720A (ja) 1995-05-29 1996-12-13 Temic Telefunken Microelectron Gmbh 絶縁された線材をはんだ付けする方法
TW510820B (en) 1999-11-30 2002-11-21 Japan Pionics Method of cleaning of harmful gas and cleaning apparatus
US6610263B2 (en) 2000-08-01 2003-08-26 Enviroscrub Technologies Corporation System and process for removal of pollutants from a gas stream
PL2440328T3 (pl) 2009-06-12 2017-06-30 Albemarle Europe Sprl. Katalizatory z sitem molekularnym sapo, ich otrzymywanie i zastosowania
JP5658351B2 (ja) * 2010-04-07 2015-01-21 カルゴン カーボン コーポレーション 煙道ガスからの水銀除去方法
AU2011296403A1 (en) * 2010-08-30 2013-03-14 Albemarle Corporation Improved sorbents for removing mercury from emissions produced during fuel combustion
EP2635529A1 (en) * 2010-11-03 2013-09-11 Carus Corporation Manganese based sorbent for removal of mercury species from fluids

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86102713A (zh) * 1985-04-17 1986-10-22 东洋曹达工业株式会社 用于回收溴的吸附剂及应用该吸附剂回收溴的工艺
US5952541A (en) * 1992-07-30 1999-09-14 Exxon Chemical Patents, Inc. Method of loading hydrogen halide onto an adsorbent to enable removal of lead impurities from liquid hydrocarbons
CN1665947A (zh) * 2002-05-06 2005-09-07 小西德尼·G·尼尔逊 用于脱除烟气中汞的吸附剂及相应的脱汞方法
CN101553301A (zh) * 2006-12-08 2009-10-07 普莱克斯技术有限公司 适用作水泥添加剂的水银吸附剂
CN101274190A (zh) * 2007-03-30 2008-10-01 高化环保技术有限公司 利用硫化处理铁氧化物的除汞用吸附剂及其制造方法
US20090136401A1 (en) * 2007-09-24 2009-05-28 Basf Catalysts Llc Pollutant Emission Control Sorbents and Methods of Manufacture and Use
CN101502737A (zh) * 2009-01-21 2009-08-12 东华大学 一种用溴化处理过的碳粉脱除燃煤烟气中重金属汞的方法及装置

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112135695A (zh) * 2018-05-04 2020-12-25 雅宝公司 降低环境污染物的环境有效性的工艺
CN113713769A (zh) * 2021-09-06 2021-11-30 中南大学 一种改性炭基吸附剂及其制备方法和应用
CN113713769B (zh) * 2021-09-06 2022-07-26 中南大学 一种改性炭基吸附剂及其制备方法和应用

Also Published As

Publication number Publication date
AU2011332149A1 (en) 2013-06-13
WO2012071206A1 (en) 2012-05-31
CL2013001404A1 (es) 2013-12-13
BR112013012524A2 (pt) 2016-09-06
JP2013544185A (ja) 2013-12-12
TW201228722A (en) 2012-07-16
KR20140002642A (ko) 2014-01-08
RU2013128615A (ru) 2014-12-27
AR083944A1 (es) 2013-04-10
PH12013500868A1 (en) 2013-06-03
ZA201303131B (en) 2014-10-29
CA2815090A1 (en) 2012-05-31
US20130272936A1 (en) 2013-10-17
EP2643071A1 (en) 2013-10-02
CO6801783A2 (es) 2013-11-29

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