CN103316682A - 一种铜锌催化剂及其制备方法和用途 - Google Patents
一种铜锌催化剂及其制备方法和用途 Download PDFInfo
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- CN103316682A CN103316682A CN2013102983417A CN201310298341A CN103316682A CN 103316682 A CN103316682 A CN 103316682A CN 2013102983417 A CN2013102983417 A CN 2013102983417A CN 201310298341 A CN201310298341 A CN 201310298341A CN 103316682 A CN103316682 A CN 103316682A
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- propyl alcohol
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- 239000003054 catalyst Substances 0.000 title claims abstract description 39
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 229910017518 Cu Zn Inorganic materials 0.000 title abstract 4
- 229910017752 Cu-Zn Inorganic materials 0.000 title abstract 4
- 229910017943 Cu—Zn Inorganic materials 0.000 title abstract 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims abstract description 72
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 23
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 14
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 83
- 239000000463 material Substances 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 229910052593 corundum Inorganic materials 0.000 claims description 13
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 13
- 229960004643 cupric oxide Drugs 0.000 claims description 12
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 7
- 241000282326 Felis catus Species 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 239000012071 phase Substances 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 3
- 230000002950 deficient Effects 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 238000002309 gasification Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005751 Copper oxide Substances 0.000 abstract 1
- 208000005156 Dehydration Diseases 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 150000001868 cobalt Chemical class 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- -1 propyl alcohols Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
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CN201310298341.7A CN103316682B (zh) | 2013-07-16 | 2013-07-16 | 一种铜锌催化剂及其制备方法和用途 |
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CN201310298341.7A CN103316682B (zh) | 2013-07-16 | 2013-07-16 | 一种铜锌催化剂及其制备方法和用途 |
Publications (2)
Publication Number | Publication Date |
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CN103316682A true CN103316682A (zh) | 2013-09-25 |
CN103316682B CN103316682B (zh) | 2015-01-14 |
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CN201310298341.7A Active CN103316682B (zh) | 2013-07-16 | 2013-07-16 | 一种铜锌催化剂及其制备方法和用途 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4762817A (en) * | 1986-11-03 | 1988-08-09 | Union Carbide Corporation | Aldehyde hydrogenation catalyst |
JP2007289855A (ja) * | 2006-04-25 | 2007-11-08 | Sakai Chem Ind Co Ltd | 水素化触媒とその利用とその製造方法 |
CN101225019A (zh) * | 2008-01-31 | 2008-07-23 | 淄博诺奥化工有限公司 | 铜锌催化剂下丙醛加氢制备正丙醇的生产工艺 |
CN102408304A (zh) * | 2010-09-21 | 2012-04-11 | 中国石油化工股份有限公司 | 醛选择加氢制备醇的方法 |
-
2013
- 2013-07-16 CN CN201310298341.7A patent/CN103316682B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4762817A (en) * | 1986-11-03 | 1988-08-09 | Union Carbide Corporation | Aldehyde hydrogenation catalyst |
JP2007289855A (ja) * | 2006-04-25 | 2007-11-08 | Sakai Chem Ind Co Ltd | 水素化触媒とその利用とその製造方法 |
CN101225019A (zh) * | 2008-01-31 | 2008-07-23 | 淄博诺奥化工有限公司 | 铜锌催化剂下丙醛加氢制备正丙醇的生产工艺 |
CN102408304A (zh) * | 2010-09-21 | 2012-04-11 | 中国石油化工股份有限公司 | 醛选择加氢制备醇的方法 |
Non-Patent Citations (2)
Title |
---|
宫原孝四郎等著: "《什么是催化剂》", 31 August 1986 * |
黄仲涛等编著: "《工业催化》", 31 August 2006, 化学工业出版社 * |
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CN103316682B (zh) | 2015-01-14 |
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Effective date of registration: 20181220 Address after: Room 1129, 11th floor, Traffic Bureau Building, 95 Yingbin Avenue, Xinhua Street, Huadu District, Guangzhou City, Guangdong 510800 Patentee after: GUANGZHOU XINSHIJI NEW ENERGY DEVELOPMENT Co.,Ltd. Address before: 224211 No. 168-095 Fangshui Road, Chemical Industry Park, Liuhe District, Nanjing City, Jiangsu Province Patentee before: Nanjing RongXin Chemical Co.,Ltd. |
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Effective date of registration: 20201216 Address after: 210047 -095, Fang Shui Road, Nanjing Chemical Industrial Park, Nanjing, Jiangsu, China, 168 Patentee after: Nanjing RongXin Chemical Co.,Ltd. Address before: Room 1129, 11th floor, Traffic Bureau Building, 95 Yingbin Avenue, Xinhua Street, Huadu District, Guangzhou City, Guangdong 510800 Patentee before: GUANGZHOU XINSHIJI NEW ENERGY DEVELOPMENT Co.,Ltd. |
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Denomination of invention: A copper zinc catalyst and its preparation method and application Effective date of registration: 20231229 Granted publication date: 20150114 Pledgee: Bank of Nanjing Co.,Ltd. Nanjing Chengnan sub branch Pledgor: Nanjing RongXin Chemical Co.,Ltd. Registration number: Y2023980074754 |