CN103289127B - 坡缕石硅烷交联剂制备及其在低密度聚乙烯交联中的应用 - Google Patents
坡缕石硅烷交联剂制备及其在低密度聚乙烯交联中的应用 Download PDFInfo
- Publication number
- CN103289127B CN103289127B CN201310279948.0A CN201310279948A CN103289127B CN 103289127 B CN103289127 B CN 103289127B CN 201310279948 A CN201310279948 A CN 201310279948A CN 103289127 B CN103289127 B CN 103289127B
- Authority
- CN
- China
- Prior art keywords
- palygorskite
- polygorskite
- silane
- silane crosslinker
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 229910000077 silane Inorganic materials 0.000 title claims abstract description 79
- 229910052625 palygorskite Inorganic materials 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 229920001684 low density polyethylene Polymers 0.000 title abstract description 36
- 239000004702 low-density polyethylene Substances 0.000 title abstract description 36
- 239000003431 cross linking reagent Substances 0.000 title abstract description 13
- 238000004132 cross linking Methods 0.000 title abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 8
- 239000008096 xylene Substances 0.000 claims abstract description 8
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims abstract description 6
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 4
- 238000012545 processing Methods 0.000 claims abstract description 4
- 229920000573 polyethylene Polymers 0.000 claims abstract 2
- 239000004971 Cross linker Substances 0.000 claims description 75
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 33
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 230000004913 activation Effects 0.000 claims description 16
- 238000000605 extraction Methods 0.000 claims description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 14
- 229960004756 ethanol Drugs 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 9
- 229960000583 acetic acid Drugs 0.000 claims description 7
- 238000010306 acid treatment Methods 0.000 claims description 7
- 239000012153 distilled water Substances 0.000 claims description 7
- 239000012362 glacial acetic acid Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 239000004927 clay Substances 0.000 abstract description 15
- 239000000243 solution Substances 0.000 abstract description 13
- 238000004458 analytical method Methods 0.000 abstract description 6
- 239000011259 mixed solution Substances 0.000 abstract description 6
- 238000000862 absorption spectrum Methods 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 238000000944 Soxhlet extraction Methods 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 238000011056 performance test Methods 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 238000011010 flushing procedure Methods 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 5
- 229920003020 cross-linked polyethylene Polymers 0.000 description 4
- 239000004703 cross-linked polyethylene Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000002329 infrared spectrum Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- ZMARGGQEAJXRFP-UHFFFAOYSA-N 1-hydroxypropan-2-yl 2-methylprop-2-enoate Chemical compound OCC(C)OC(=O)C(C)=C ZMARGGQEAJXRFP-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001541 aziridines Chemical class 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310279948.0A CN103289127B (zh) | 2013-07-04 | 2013-07-04 | 坡缕石硅烷交联剂制备及其在低密度聚乙烯交联中的应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310279948.0A CN103289127B (zh) | 2013-07-04 | 2013-07-04 | 坡缕石硅烷交联剂制备及其在低密度聚乙烯交联中的应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103289127A CN103289127A (zh) | 2013-09-11 |
CN103289127B true CN103289127B (zh) | 2015-05-06 |
Family
ID=49090696
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310279948.0A Expired - Fee Related CN103289127B (zh) | 2013-07-04 | 2013-07-04 | 坡缕石硅烷交联剂制备及其在低密度聚乙烯交联中的应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103289127B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105254978A (zh) * | 2015-11-10 | 2016-01-20 | 沈阳化工大学 | 一种添加新型交联剂的再生聚乙烯塑料及其制备方法 |
CN108641122B (zh) * | 2018-04-18 | 2019-03-29 | 西北师范大学 | 一种坡缕石黏土基多功能高分子材料助剂及其制备方法 |
CN111675844A (zh) * | 2020-07-30 | 2020-09-18 | 安徽华电线缆股份有限公司 | 一种轨道交通用交联聚乙烯绝缘阻燃电力电缆 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101613112A (zh) * | 2009-07-06 | 2009-12-30 | 江南大学 | 一种硅烷偶联剂改性凹凸棒土的制备 |
-
2013
- 2013-07-04 CN CN201310279948.0A patent/CN103289127B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN103289127A (zh) | 2013-09-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Lai et al. | Preparation and performance of lignin-based waterborne polyurethane emulsion | |
CN102002173B (zh) | 一种纳米微晶纤维素/白炭黑/橡胶复合材料的制备方法 | |
CN103289127B (zh) | 坡缕石硅烷交联剂制备及其在低密度聚乙烯交联中的应用 | |
CN111040612A (zh) | 碳纳米管改性耐光性水性聚氨酯涂料与胶粘剂的制备方法 | |
Reddy et al. | Alkali‐catalyzed low temperature wet crosslinking of plant proteins using carboxylic acids | |
CN101831801B (zh) | 一种耐久性纤维素纤维及其应用 | |
CN107057326A (zh) | 光响应形状记忆自修复的复合材料及其制备方法、修复方法和应用 | |
CN109181309B (zh) | 一种改性碳量子点/硅橡胶荧光复合材料的制备方法 | |
CN109486219B (zh) | 一种有机包覆纳米二氧化钛接枝sbs改性沥青及其制备方法 | |
CN116622333B (zh) | 一种高倍防霉脱醇型美容收边胶的制备方法 | |
CN104725705A (zh) | 一种新型聚乙烯木塑复合材料的制备方法 | |
CN109384936B (zh) | 碳纳米管接枝端羟基聚氨酯电泳树脂、阴极聚氨酯电泳漆及其制备方法 | |
CN108410032A (zh) | 一种轮胎胎面胶胶料及其制备方法 | |
CN113861538A (zh) | 一种自修复导电环氧化天然橡胶复合材料及其制备方法 | |
CN110358009B (zh) | 一种基于改性二氧化硅纳米粒子交联剂的可拉伸水凝胶及其制备方法与应用 | |
CN106675111A (zh) | 一种能提高机械加工性能的丙烯酸酯改性的碳酸钙填料及其制备方法 | |
CN103193890A (zh) | 功能化淀粉纳米晶及其制备方法 | |
CN111218119A (zh) | 一种可自修复、高强度、抗菌大豆蛋白膜及制备方法 | |
CN109517355B (zh) | 一种基于改性黑色素纳米颗粒的紫外屏蔽复合材料及其制备方法 | |
CN104448111A (zh) | 一种室温自修复及可回收交联聚合物及其制备方法和应用 | |
CN1927927A (zh) | 聚烯烃/苯乙烯系弹性体共混型形状记忆材料及制备方法 | |
CN109467683B (zh) | 一种改性聚酯切片的制备方法、聚酯切片和聚酯纤维 | |
CN115850834B (zh) | 一种高性能聚乙烯/纳米二氧化硅复合电缆绝缘树脂及其制备方法与应用 | |
CN105504633A (zh) | 一种木塑复合材料及其制备方法 | |
CN102153815A (zh) | 以植物纤维补强的耐热胶管内层胶 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhang Zhe Inventor after: Lei Ziqiang Inventor after: Wei Yongqian Inventor after: Yang Xuemin Inventor after: Yang Zhiwang Inventor before: Zhang Zhe Inventor before: Wei Bo Inventor before: Gao Shuling Inventor before: Zhao Shuai Inventor before: Ma Hengchang Inventor before: Yang Zhiwang Inventor before: Zhou Pengxin Inventor before: Lei Ziqiang |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180104 Address after: 730000 Gansu province Lanzhou Anning District Economic Development Zone Public Boulevard Co-patentee after: Northwest Normal University Patentee after: LANZHOU ZHONGBANG WIRE & CABLE GROUP CO.,LTD. Address before: 730070 Anning Road, Anning District, Gansu, Lanzhou, China, No. 967 Patentee before: Northwest Normal University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180411 Address after: 730000 Gansu province Lanzhou Anning District Economic Development Zone Public Boulevard Patentee after: LANZHOU ZHONGBANG WIRE & CABLE GROUP CO.,LTD. Address before: 730000 Gansu province Lanzhou Anning District Economic Development Zone Public Boulevard Co-patentee before: Northwest Normal University Patentee before: LANZHOU ZHONGBANG WIRE & CABLE GROUP CO.,LTD. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150506 |