CN103255005A - Rosemary sterilization-deodorization detergent - Google Patents

Rosemary sterilization-deodorization detergent Download PDF

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CN103255005A
CN103255005A CN2013102073089A CN201310207308A CN103255005A CN 103255005 A CN103255005 A CN 103255005A CN 2013102073089 A CN2013102073089 A CN 2013102073089A CN 201310207308 A CN201310207308 A CN 201310207308A CN 103255005 A CN103255005 A CN 103255005A
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sterilization
deodorization
parts
detergent
rosemary
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CN103255005B (en
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陈龙弟
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Zhejiang Shen Ying Science And Technology Co ltd
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Shanghai Yanzi Chemical Technology Co Ltd
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Abstract

The invention discloses a rosemary sterilization-deodorization detergent. The rosemary sterilization-deodorization detergent is composed of the following raw materials in parts by weight: 4-6 parts of sodium myristoamphoacetate, 4-6 parts of lauramidopropyl betaine, 2-4 parts of babassu oil amidopropyl amine oxide, 5-7 parts of dialkyl glucoside, 0.05-0.15 parts of rosmarinic acid, and 80 parts of water. According to the rosemary sterilization-deodorization detergent disclosed by the invention, a non-ionic surfactant and an ampholytic surfactant are compounded, and the traditional anionic surfactant is abandoned, so that irritation on the surfaces of hands is greatly reduced while good decontamination and washing effects are guaranteed; and simultaneously, rosmarinic acid is compounded, so that sterilization and bacterium sterilization can be effectively performed while tableware are cleaned by using the rosemary sterilization-deodorization detergent disclosed by the invention.

Description

Rosmarinus officinalis deodorization and sterilization liquid detergent
Technical field:
The present invention relates to a kind of liquid detergent, particularly a kind of Rosmarinus officinalis deodorization and sterilization liquid detergent.
Background technology:
Liquid washing agent is a big class in the synthetic detergent, and the output maximum is washing powder in the synthetic detergent, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities than solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid washing agent is that it has the characteristic of surfactant soln with water or other organic solvents articles for washing as base-material.The liquid product that generally will have cleaning function is called liquid washing agent.Be divided into liquid detergent, fabric liquid washing agent, shampoo and skin cleaner and hard surface cleaner according to purposes or function.
Liquid detergent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be used for washing fruit, vegetables and the heavy clothing of greasy dirt.It is the indispensable washing product of catering industry and family.
Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent on the market is a feast for the eyes, have superpower, that concentrated type is arranged and the strong sterilizing power of detersive power etc.Along with the progressively enhancing of people's environmental consciousness, dish washing detergent development in future direction will be to be main flow with the environment-friendly and green type.Except the function that strong detersive power, harmless, sterilization and disinfection, gentle high bubble are arranged, also should degrade easily, free from environmental pollution.The effective constituent of dish washing detergent mainly is tensio-active agent, and traditional dish washing detergent is raw material with synthetic surfactant (as LAS, AS, AES, SAS etc.) mainly.Maybe can't degrade but they are difficult for degraded mostly, environment is polluted.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, and particularly functional liquid detergent is just fewer.
Summary of the invention:
At the prior art above shortcomings, technical problem to be solved by this invention provides a kind of Rosmarinus officinalis deodorization and sterilization liquid detergent.
Technical problem of the present invention is achieved by following technical proposals:
A kind of Rosmarinus officinalis deodorization and sterilization liquid detergent is made up of the raw material of following weight part: mnyristoyl both sexes guanidine-acetic acid sodium 4-6 part, dodecanamide propyl trimethyl-glycine 4-6 part, babassu oil amido propyl amine oxide 2-4 part, dodecyl glucoside 5-7 part, rosmarinic acid 0.05-0.15 part, 80 parts in water.
Mnyristoyl both sexes guanidine-acetic acid sodium, dodecanamide propyl trimethyl-glycine, babassu oil amido propyl amine oxide, dodecyl glucoside and rosmarinic acid are added to the water, are heated to 40-60 ℃, mix, can make this Rosmarinus officinalis deodorization and sterilization liquid detergent.
Below, raw material involved in the present invention is made simple introduction:
Mnyristoyl both sexes guanidine-acetic acid sodium, SODIUM MYRISTOAMPHOACETATE, CAS number: 68647-45-0.
The dodecanamide propyl trimethyl-glycine, LAURAMIDOPROPYL BETAINE, CAS number: 4292-10-8.
Babassu oil amido propyl amine oxide, Babassuamidopropylamine oxide, 124046-26-0.
The dodecyl glucoside, CAS accession number: 110615-47-9.
Rosmarinic acid, Rosmarinic acid, CAS accession number 20283-92-5.Rosmarinic acid is a kind of polyphenol that is present in many plants, especially wild marjoram, Rosmarinus officinalis, have very high density in Herba melissae axillaris, Salvia japonica Thunb. and the marjoram.To Bacillus subtilus.Micrococcus luteus and intestinal bacteria are significant inhibitory effect.
Rosmarinus officinalis deodorization and sterilization liquid detergent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, when guaranteeing good decontamination washing effect, greatly reduce the pungency to watch face, composite rosmarinic acid simultaneously uses the present invention's effective bactericidal in the cleaning tableware.
Embodiment:
Following embodiment further specifies of the present invention, rather than limits the scope of the invention.In the present invention, if no special instructions, each raw material is 100% in working substance content all.
Embodiment 1
0.1 kilogram of 5 kilograms in mnyristoyl both sexes guanidine-acetic acid sodium, 5 kilograms of dodecanamide propyl trimethyl-glycines, 3 kilograms of babassu oil amido propyl amine oxides, 6 kilograms of dodecyl glucosides and rosmarinic acid added in 80 kilograms the deionized water, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative Examples 1
0.1 kilogram of 13 kilograms in mnyristoyl both sexes guanidine-acetic acid sodium, 6 kilograms of dodecyl glucosides and rosmarinic acid added in 80 kilograms the deionized water, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative Examples 2
0.1 kilogram of 13 kilograms of dodecanamide propyl trimethyl-glycines, 6 kilograms of dodecyl glucosides and rosmarinic acid added in 80 kilograms the deionized water, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Comparative Examples 3
0.1 kilogram of 13 kilograms of babassu oil amido propyl amine oxides, 6 kilograms of dodecyl glucosides and rosmarinic acid added in 80 kilograms the deionized water, be heated to 50 ℃, mix, be cooled to room temperature, can make this liquid detergent.
Test case 1:
Detergency test:
1) preparation of artificial dirt
Mixing oil prescription: be the 0.5:0.5:1 preparation with butter, lard, vegetables oil mass ratio, and add the glyceryl monostearate of its total mass 5%, this is artificial dirt.
Artificial dirt put be heated to 180 ℃ on the electric furnace, stir and keep this temperature 10min, beaker is moved to magnetic stirrer stir, naturally cool to temperature required standby.The temperature of defiling is recommended reference: when room temperature is 20 ℃, need 80 ℃ of oil temperature; When room temperature is 25 ℃, need 45 ℃ of oil temperature; When room temperature is lower than 17 ℃ or when being higher than 27 ℃, test should not be carried out, and need carry out at air conditioning room.Should use the vertical spotter of attached freezing plant in case of necessity.
2) preparation of dirty sheet
With the slide glass upper edge 10mm line that draws, be limited in this below line to show to defile; With the slide glass lower edge 5mm line that draws, be limited in this below line to show the unnecessary greasy dirt of wiping.
3) newly purchase slide glass and need in detergent solution, boil 15min after, the clear water washing to do not hang the globule put again soak 1h in the acid wash liquid after, clear water rinsing and distilled water flushing are put after the loft drier drying standby.
4) preparation of standard dish washing detergent
Take by weighing 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts in urea adds water to 100 parts, and mixing is regulated pH to 7-8 with hydrochloric acid or sodium hydroxide, and is standby.
5) defile
The slide glass of cleaning is one group with four puts on the weighing frame, with analytical balance accurately weigh (accurately to 1mg) be m0, the slide glass after weighing is sandwiched on the film airing stand one by one, clip should be clipped in along the line on the slide glass more than, film airing stand put to ward off prepares in the dish to defile.
When treating that greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, hand-held clip immerses in the greasy dirt slide glass to 10mm goes up following (1-2) s along the line, slowly taking-up, after treating that the following speed of greasy dirt is slack-off, hang back and prepare dirty sheet on the original film airing stand successively.After greasy dirt solidifies, dirty sheet taken off with filter paper or absorbent cotton the unnecessary greasy dirt in base and both sides in the dirty sheet lower edge 5mm is wiped, speckle with the absorbent cotton wiped clean of sherwood oil again with the tweezers folder.After hanging 4h under the room temperature, on the weighing frame, be m1 with the accurate weighing of analytical balance.Dirty amount should guarantee (0.5 ± 0.05) g on every group of dirt this moment sheet.
6) testing sequence
The slide glass of the known amount of defiling is inserted preparation washing in the corresponding wash stand.
Spotter is connected power supply, and wash temperature is set to 30 ℃, and velocity of rotation is set to 160r/min, and washing time is set to 3min.
Take by weighing the 5.00g sample to be tested in 2500mL hard water; after shaking up; measure the 800mL test solution respectively in three washing becks of vertical spotter; when treating that the test solution temperature rises to 30 ℃; rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand; after last wash stand is put into washing beck, begin to count soak time, rapidly agitator is installed simultaneously, when soaking 1min; start spotter; begin washing, during 3min, the machine auto stop; rapidly agitator is taken off; take out wash stand, press from both sides one by one and hang on the original film airing stand washing the dirty sheet in back, hanging and dirty sheet being put the weighing of corresponding weighing frame behind the 3h that dries in the air is m2.
(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)
In the formula: m0---slide glass quality before defiling, g; M1---the back slide glass quality of defiling, g; M2---the quality of the dirty sheet in washing back, g.
The rate of deoiling test chart
? The rate of deoiling ω, %
Embodiment 1 44.8
The standard dish washing detergent 38.2
Comparative Examples 1 38.8
Comparative Examples 2 38.2
Comparative Examples 3 39.6
Rosmarinus officinalis deodorization and sterilization liquid detergent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, and amphoterics mnyristoyl both sexes guanidine-acetic acid sodium as can be seen from the above table, dodecanamide propyl trimethyl-glycine and babassu oil amido propyl amine oxide and nonionogenic tenside dodecyl glucoside composite (embodiment 1) synergy, compare with nonionogenic tenside dodecyl glucoside composite (Comparative Examples 1-3) with single amphoterics, detersive power obviously improves.
Test case 2:
The pungency test
The simulation irritant experiment carries out in the laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 ℃ of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.Average after marking according to the standard of following table for the pungency of wrist-watch skin, it is more high to mark again, and pungency is more little.
Figure BDA00003262979300051
Pungency test data table
? Scoring
Embodiment 1 100
The standard dish washing detergent 50
Comparative Examples 1 95
Comparative Examples 2 90
Comparative Examples 3 95
Embodiment 2
For prolonging the quality guaranteed period of the present invention, the contriver has made following research pioneeringly.
In the prepared liquid detergent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, formed by weight by following component: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and tennecetins (CAS:7681-93-8).
Namely, this Rosmarinus officinalis deodorization and sterilization liquid detergent is made up of the raw material of following weight part: 5 kilograms in mnyristoyl both sexes guanidine-acetic acid sodium, 5 kilograms of dodecanamide propyl trimethyl-glycines, 3 kilograms of babassu oil amido propyl amine oxides, 6 kilograms of dodecyl glucosides, 0.1 kilogram of rosmarinic acid, 80 kilograms in water, 0.05 kilogram of composite environmental-friendly sanitas.
By adding the sanitas of specific proportioning on the basis of embodiment 1, prolonged the quality guaranteed period of this Rosmarinus officinalis deodorization and sterilization liquid detergent greatly.By 10 days 1 quality guaranteed perioves of embodiment, extend to 24 months.In addition, contrast, with the general single sanitas 1 of the industry of the composite environmental-friendly sanitas among the embodiment 2,3-dihydroxymethyl-5, the 5-T10 is replaced, and add-on is constant, and its quality guaranteed period only is 18 months.

Claims (2)

1. a Rosmarinus officinalis deodorization and sterilization liquid detergent is characterized in that, is made up of following raw material: mnyristoyl both sexes guanidine-acetic acid sodium, dodecanamide propyl trimethyl-glycine, babassu oil amido propyl amine oxide, dodecyl glucoside, rosmarinic acid and water.
2. Rosmarinus officinalis deodorization and sterilization liquid detergent as claimed in claim 1, it is characterized in that, raw material by following weight part is formed: mnyristoyl both sexes guanidine-acetic acid sodium 4-6 part, dodecanamide propyl trimethyl-glycine 4-6 part, babassu oil amido propyl amine oxide 2-4 part, dodecyl glucoside 5-7 part, rosmarinic acid 0.05-0.15 part, 80 parts in water.
CN201310207308.9A 2013-05-28 2013-05-28 Rosemary sterilization-deodorization detergent Active CN103255005B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104472569A (en) * 2014-11-27 2015-04-01 苏州市贝克生物科技有限公司 Medical sanitizer and preparation method thereof
CN104804904A (en) * 2015-03-25 2015-07-29 佩兰生物科技(上海)股份有限公司 Fully degradable plant dishwashing soap and preparation method thereof
CN108165385A (en) * 2017-12-04 2018-06-15 陈景芳 A kind of multifuctional cleaning agent
CN108944112A (en) * 2018-07-28 2018-12-07 黄智慧 A kind of preparation method for exempting from alcohol fountain solution

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1948447A (en) * 2005-10-14 2007-04-18 花王株式会社 Detersive for hard surface
CN101268177A (en) * 2005-07-22 2008-09-17 霍尼韦尔国际公司 Cleaner composition, article and method
CN101370466A (en) * 2005-12-09 2009-02-18 帝斯曼知识产权资产管理有限公司 Stabilizing composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101268177A (en) * 2005-07-22 2008-09-17 霍尼韦尔国际公司 Cleaner composition, article and method
CN1948447A (en) * 2005-10-14 2007-04-18 花王株式会社 Detersive for hard surface
CN101370466A (en) * 2005-12-09 2009-02-18 帝斯曼知识产权资产管理有限公司 Stabilizing composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SHUANG-SHENG HUANG ET.AL: "Rosmarinic acid inhibits angiogenesis and its mechanism of action in vitro", 《CANCER LETTERS》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104472569A (en) * 2014-11-27 2015-04-01 苏州市贝克生物科技有限公司 Medical sanitizer and preparation method thereof
CN104804904A (en) * 2015-03-25 2015-07-29 佩兰生物科技(上海)股份有限公司 Fully degradable plant dishwashing soap and preparation method thereof
CN108165385A (en) * 2017-12-04 2018-06-15 陈景芳 A kind of multifuctional cleaning agent
CN108944112A (en) * 2018-07-28 2018-12-07 黄智慧 A kind of preparation method for exempting from alcohol fountain solution

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Inventor after: Ying Zongxiao

Inventor before: Chen Longdi

TR01 Transfer of patent right
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Effective date of registration: 20180320

Address after: Taizhou City, Zhejiang Province, 318050 Luqiao street Luqiao District Tyrone Street No. 508

Patentee after: ZHEJIANG SHENYING TECHNOLOGY Co.,Ltd.

Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128

Patentee before: SHANGHAI YANZI CHEMICAL TECHNOLOGY Co.,Ltd.

CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 318050 508 street, Luqiao street, Luqiao District, Taizhou, Zhejiang.

Patentee after: Zhejiang Shen Ying Science and Technology Co.,Ltd.

Address before: 318050 508 street, Luqiao street, Luqiao District, Taizhou, Zhejiang.

Patentee before: ZHEJIANG SHENYING TECHNOLOGY Co.,Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right
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Denomination of invention: Rosemary sterilization and deodorization detergent

Effective date of registration: 20231018

Granted publication date: 20140806

Pledgee: Zhejiang Tailong commercial bank Taizhou branch of Limited by Share Ltd.

Pledgor: Zhejiang Shen Ying Science and Technology Co.,Ltd.

Registration number: Y2023980061420