CN103241996A - Imitation lime stone and method for fabricating the same - Google Patents
Imitation lime stone and method for fabricating the same Download PDFInfo
- Publication number
- CN103241996A CN103241996A CN2013100447909A CN201310044790A CN103241996A CN 103241996 A CN103241996 A CN 103241996A CN 2013100447909 A CN2013100447909 A CN 2013100447909A CN 201310044790 A CN201310044790 A CN 201310044790A CN 103241996 A CN103241996 A CN 103241996A
- Authority
- CN
- China
- Prior art keywords
- weight
- limestone
- mixture
- rostone
- sand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/20—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein the material is extruded
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/04—Macromolecular compounds
- C04B16/06—Macromolecular compounds fibrous
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/02—Selection of the hardening environment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
An artificial limestone and a manufacturing method thereof are provided to provide various colors and rough texture as a limestone to surface of artificial stones by using silica. An artificial limestone comprises a mixture of 35-40 weight% of cement, 55-60 weight% of silica having 10-80 mesh, 0.5-1.0 weight% of plasticizer, 1.5-3 weight% of cellulose fiber, 0-3.0 weight% of sepiolite, and 0.1-0.15 weight% of polypropylene, and 20-25 weight% of water based on total weight of the mixture. A manufacturing method of the artificial limestone comprises the following steps: pulverizing cellulosic fibers(s10); adding the pulverized cellulosic fiber, cement, silica, plasticizer, sepiolite, and polypropylene in a dry batch mixer(s20); wet mixing the dried mixture by adding water(s40); vacuum extrusion molding the wet mixture by using a extruder(s50); steam curing the molding(s60); and curing the steamed outcome in an autoclave(s70).
Description
Technical field
The present invention relates to rostone limestone and manufacture method thereof, be specifically related to the ground silica of non-interpolation powder shape, but visually silica sand or the glass sand of particle shape have been added, by vacuum extruding form or casting, make the texture on surface seem rostone limestone and manufacture method thereof as limestone (limestone).
Background technology
The inorganic building material major part of producing by the vacuum extruding form method is that the asbestos that add more than 10% are made.Therefore but this asbestos are harmful, operator and user existed the problem of security aspect.Thereby Korea S's login special permission discloses the vacuum extruding form cement constructional material that replaces the method for asbestos to make by blended cellulosic fibres and sepiolite and polypropylene fibre for No. 389660.
Above-mentioned existing vacuum extruding form cement is that cement 50 ~ 65 weight %, ground silica 30 ~ 40 weight %, softening agent 0.5~1.0 weight %, cellulosic fibre 1.5~3.0 weight %, sepiolite 0~3.0 weight %, polypropylene 0.1~0.15 weight %, water 23~30 weight % are mixed, and extrusion moulding is made.But because using ground silica, the surperficial texture of the cement plate of extrusion moulding and the general cement products indistinction as the powder shape of flour.At this, so-called powder shape refers to have the size of particles of 80 ~ 325 mesh sieves (mesh) as following table 1, certainly, also can have than its littler size of particles.
Table 1.
Simultaneously, limestone (limestone) major part has soft beautiful color and luster, and lower than marble hardness, therefore processes easily, need to be applied to building decoration or the finishing material of exquisite engraving operation more.This is because limestone has the surperficial texture more different than general cement products.Therefore, a lot of have unique surperficial texture and the rostone limestone of various color and lusters about enterprises are devoted to make.
The rostone limestone should show various surperficial texture and various color and luster, excellence aspect quality again, but aforesaid existing vacuum extruding form cement are when using the ground silica of powder shape, surface texture or color and luster and general cement are smooth equally, do not have exclusive characteristic.And what adopted is by making and inject the method for die production rostone limestone by hand in the past, but need carry out mass production.
Summary of the invention
Thereby, the problem that the present invention will solve provides a kind of in order to be conducive to mass production, method manufacturing by vacuum extruding form, and be not the ground silica that uses powder shape, and use the silica sand of particle shape visually, to give shaggy texture and soft texture or various color and luster, append the nature sense thus, embody the various texture of limestone (limestone), and with existing building template or ceramic plate etc. in rostone limestone and manufacture method thereof differential aspect surperficial texture, the color and luster.
Technical solution of the present invention is
In order to realize above-mentioned problem, according to rostone limestone of the present invention, it is characterized in that, gross weight for the mixture of the silica sand that comprises cement 35~55 weight %, 10 ~ 80 mesh sieves (mesh) size of particles or glass sand 40~60 weight %, softening agent 0.5~1.0 weight %, cellulosic fibre 1.5~3.0 weight %, sepiolite 0~3.0 weight %, polypropylene 0.1~0.15 weight %, the water that mixes 20~25 weight %, and by extrusion moulding or castmethod manufacturing.
In order to realize above-mentioned problem, comprise according to the manufacture method of rostone limestone of the present invention: the step of described cellulosic fibre being carried out opener; The described cellulosic fibre of opener, described cement, described silica sand or glass sand, described softening agent, described sepiolite, described polypropylene are devoted the step of dry mixer; Water is devoted in the mixture of finishing the dry type mixing in described dry mixer, carry out the step of wet mixing with this; The mixture of finishing described wet mixing is devoted forcing machine, with the step of this vacuum extruding form; The forming composition of described vacuum extruding form is carried out the step of steam (steam) maintenance.
The present invention can also comprise the step of carrying out maintenance through the thing as a result of steam curing in autoclave sterilizer with described after described steam curing step.
Technique effect of the present invention is
According to the present invention, discarded by making by hand and utilize mould to make the existing mode of artificial limestone, and use the forcing machine vacuum extruding form, therefore, can the high-quality rostone limestone of mass production, and help to improve the quality rank of material of construction.And, the rostone limestone and extrude cement be the building site from texture, color and luster, quality, be suitable for aspect the strict material of distinguishing, therefore use the mode of production of the rostone limestone of forcing machine to make initiative contribution to the senior building scene of becoming privileged as mentioned above.
Description of drawings
Fig. 1 is for being used for explanation according to the process flow sheet of rostone limestone of the present invention and manufacture method thereof;
Fig. 2 is the image that illustrates according to the surperficial texture of rostone limestone of the present invention;
Fig. 3 is the image that the surperficial texture of existing vacuum extruding form cement is shown.
Embodiment
Below, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.Following embodiment just provides in order to help to understand content of the present invention, and those of ordinary skill in the art can carry out various changes in technological thought scope of the present invention.Therefore, claim scope of the present invention is not to be defined in described embodiment.
Fig. 1 is for being used for explanation according to the process flow sheet of rostone limestone of the present invention and manufacture method thereof.According to rostone limestone of the present invention, be for comprise cement 35~55 weight %, visually the gross weight of the mixture of the silica sand of differentiable particle shape or glass sand 40~60 weight %, softening agent 0.5~1.0 weight %, cellulosic fibre 1.5~3.0 weight %, sepiolite 0~3.0 weight %, polypropylene 0.1~0.15 weight % is mixed the water of 20~25 weight %, and manufactures various material of construction shapes such as sheet material, external decorative material, interior material, soundproof wall, sash stuff, sculpture, pillar by extrusion moulding or forging type.
Common vacuum extruding form cement uses asbestos, but this asbestos are the fearful materials that bring out diseases such as asbestosis, lung cancer, mesothelioma, and the disease that causes because of asbestos is difficult for being diagnosed, and is difficult to treat.According to relevant research, as long as once be exposed to asbestos, even be not exposed later on, disease also will continue, and can develop into fatal state after about 20 years.Therefore, need to replace asbestos and harmless replacement fiber.But asbestos not only play the effect that strengthens hardness, but also have various functions such as extrudability, model keeping character, moisture retention, therefore are difficult to replace asbestos with a kind of fiber merely.Thereby the present invention does not use asbestos, and blended cellulosic fibres, sepiolite, polypropylene are to replace asbestos.
Mierocrystalline cellulose (cellulose) fiber is produced from timber as organic fibre, and that uses in the present invention obtains from the newspaper shredded paper.Though the hardness of cellulosic fibre and dispersibility are not as other fibers, water absorbing properties is outstanding, and therefore the surface drying phenomenon that takes place in the time of can solving products production has mixed cellulosic fibre.The reason of mixing sepiolite is that it is natural inorganic fiber, has outstanding thermotolerance and dispersibility, thereby can improve physicals.The reason of polypropylene (polypropylene) fiber is, though its poor heat resistance can remedy when extruding the hollow space sinkage of the product that takes place.
In order to embody various color and lusters at the rostone limestone, can use colour silicon sand or the stained glass sand with self color, and also can irrespectively throw in pigment in addition with the color of silica sand or glass sand.
Concrete manufacture method is as follows.
At first, cellulosic fibre is carried out opener (S10).Because of the dispersibility of cellulosic fibre not as asbestos, therefore in order to remedy this shortcoming, through the opener process.As without the opener process, the phenomenon that cellulosic fibre is piled up will take place, and cause condition of surface bad of extrudability and product.The opener of cellulosic fibre can be undertaken by other opener, but also can be earlier being used for dropping into other raw materials after dry mixer that dry type mixes starts cellulosic fibre 60 seconds separately, carry out dry type with this and mix, carry out opener.
Secondly, measure cellulosic fibre, cement, silica sand or glass sand, softening agent, sepiolite, the polypropylene of opener, and drop into dry mixer, making becomes aforesaid weight % (S20).As mentioned above, the opener of cellulosic fibre also can use dry mixer to carry out, and at this moment, the cellulosic fibre of opener in dry mixer, therefore directly devotes dry mixer with surplus stock and gets final product.
At this moment, be characterised in that the present invention uses silica sand or the ORGANDY of the particle shape that can distinguish by vision.When making existing vacuum extruding form cement, used the ground silica of powder shape, but in the present invention, used the silica sand of bigger particle shape.At this, so-called powder shape refers to the size of particles littler than 80 mesh sieves, and what is called can refer to the size of particles bigger than 80 mesh sieves by the particle shape that vision is distinguished.Among the present invention, preferably, use the silica sand of 10 ~ 80 mesh sieve sizes.
At this moment, preferably, silica sand uses environmental protection silica sand, for example jade silica sand, medical stone silica sand, loess stone silica sand, other silica sands to human body beneficial's material.
In order to give surperficial texture and the various color and luster as limestone, its components matching amount is very important, of the present invention being characterized as, and cement accounts for 35~55 weight %, and silica sand accounts for 40~65 weight %.When making vacuum extruding form cement in the past, drop into cement 50 ~ 65 weight %, ground silica 30 ~ 40 weight %, so that the amount of ground silica is lacked than cement, but in the present invention, for the coarse and natural slightly surperficial texture that embodies limestone and soft texture and various color and luster, make the amount of silica sand of the particle shape that can distinguish by vision more than cement.
As silica sand or glass sand, can use colour silicon sand or stained glass sand with self color, thereby give various color and lusters, also can irrespectively drop into pigment with the color of silica sand or glass sand, thereby give color and luster.For the latter's situation, preferably, drop into pigment in the step that devotes dry mixer or wet mixing step described later (S40).
Softening agent is for the oilness of giving cement raw material and viscosity, mainly uses Vltra tears, and the desired viscosity of vacuum extruding form technology is more than the 15000cps.
Then, the dry type of carrying out in dry mixer 150 ~ 240 seconds is mixed (S30).After finishing dry type and mixing, drop into water and carry out 120 ~ 180 seconds wet mixing (S40).After finishing wet mixing, mixture is devoted forcing machine, vacuum extruding form is material of construction shapes (S50) such as external decorative material, interior material, soundproof wall, sash stuff.Vacuum extruding form is that the mixture that will finish wet mixing mixes in mixing machine (small kneader) again, devote forcing machine, and by shift fork screw rod (fork screw), vacuum chamber, wimble (auger screw), gate and finally finish towards film.Outgas at the vacuum pressure of vacuum chamber with about 75mmHg.
The forming composition that vacuum is extruded moves to subsequent technique, and is cut off for the first time, and carry out maintenance (S60) by steam (steam) by the travelling belt that the speed of keeping to be same as extruded velocity moves.Finish after the steam curing, the bending of testing product and condition of surface after carrying out at last cutting off for the 2nd time, are carried out autoclaving (S70).Finish after the autoclaving, through physical property and the last processing of detection, shipping products (S80).
As cement, when using high rigidity cement, even also can obtain the limestone of required hardness without autoclaving (S70), so in these cases, can omit autoclaving (S70).
Fig. 2 is the image that illustrates according to the surperficial texture of rostone limestone of the present invention; Fig. 3 is the image that the surperficial texture of existing vacuum extruding form cement is shown.With reference to Fig. 2 and Fig. 3, in the present invention, because using the silica sand of the particle shape that can distinguish by vision, can embody surperficial texture and the shades of colour of limestone, but existing vacuum extruding form cement then uses the ground silica as the powder shape of flour, and is therefore as broad as long with the very smooth general cement of surperficial texture and color and luster.
As mentioned above, rostone limestone according to the present invention has surperficial texture and the various color and luster of natural stone limestone, and discarded making by hand and die operation in the past, makes artificial limestone in the vacuum extruding form mode, therefore can obtain high-quality product in a large number.Thereby, can supply in the building site endlessly and rebuild on-the-spot required rostone limestone, can also diversity select material of construction, and it is more attractive in appearance that building external is decorated.And, because not using asbestos, harmless.
Claims (6)
1. rostone limestone, it is characterized in that, mix the water of 20~25 weight % for the gross weight of the mixture of the silica sand that comprises cement 35~55 weight %, 10 ~ 80 mesh sieves (mesh) size of particles or glass sand 40~60 weight %, softening agent 0.5~1.0 weight %, cellulosic fibre 1.5~3.0 weight %, sepiolite 0~3.0 weight %, polypropylene 0.1~0.15 weight %, and by extrusion moulding or forging type manufacturing.
2. rostone limestone according to claim 1 is characterized in that, described silica sand or glass sand are colour silicon sand or the stained glass sand with self color and luster.
3. rostone limestone according to claim 1 is characterized in that, goes back hybrid pigment in described mixture.
4. the manufacture method of a rostone limestone, mix water and the extrusion moulding of 20~25 weight % for the gross weight of the mixture of the silica sand of the size of particles that comprises cement 35~55 weight %, 10 ~ 80 mesh sieves (mesh) or glass sand 40~60 weight %, softening agent 0.5~1.0 weight %, cellulosic fibre 1.5~3.0 weight %, sepiolite 0~3.0 weight %, polypropylene 0.1~0.15 weight %, it is characterized in that, comprise the steps:
Described cellulosic fibre is carried out the step of opener;
The described cellulosic fibre of opener, described cement, described silica sand or glass sand, described softening agent, described sepiolite, described polypropylene are devoted the step of dry mixer;
Water is devoted in the mixture of finishing the dry type mixing in described dry mixer, carry out the step of wet mixing with this;
The mixture of finishing described wet mixing is devoted forcing machine, with the step of this vacuum extruding form;
The forming composition of described vacuum extruding form is carried out the step of steam (steam) maintenance.
5. the manufacture method of rostone limestone according to claim 4 is characterized in that, after described steam curing step, also comprises the step of carrying out maintenance through the thing as a result of steam curing in autoclave sterilizer with described.
6. the method for the artificial limestone of manufacturing according to claim 4 is characterized in that, also drops into pigment in the step of the step that devotes described dry mixer or wet mixing.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020120012079A KR101160594B1 (en) | 2012-02-07 | 2012-02-07 | Imitation lime stone and method for fabricating the same |
KR10-2012-0012079 | 2012-02-07 |
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CN103241996A true CN103241996A (en) | 2013-08-14 |
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CN2013100447909A Pending CN103241996A (en) | 2012-02-07 | 2013-02-05 | Imitation lime stone and method for fabricating the same |
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KR (1) | KR101160594B1 (en) |
CN (1) | CN103241996A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101438650B1 (en) * | 2013-06-03 | 2014-09-12 | (주)미코인더스트리 | Imitation lime stone and method for fabricating the same |
KR101478637B1 (en) * | 2013-10-10 | 2015-01-07 | (주)미코인더스트리 | Green panel using loess and thereof manufacturing method |
CN103909557B (en) * | 2014-04-22 | 2017-02-08 | 余以富 | Production method for artificial stone |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101143986A (en) * | 2007-08-07 | 2008-03-19 | 何良金 | Terrace paint |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100389660B1 (en) | 2000-08-14 | 2003-06-27 | 한국건설기술연구원 | extrusion cement construction material and formation method thereof |
KR100578385B1 (en) | 2003-12-02 | 2006-05-10 | (주)영광산업개발 | Polymer moltal for mending and reinforcement using sepiolite |
KR100854516B1 (en) | 2007-07-09 | 2008-08-26 | 장원건설(주) | Powder cement for adhesion |
KR100841892B1 (en) | 2007-12-26 | 2008-06-26 | 세기하이테크건설 주식회사 | A repair method of deteriorated concrete structures using uniformity distribution system of fiber for cement mortar reinforcement |
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2012
- 2012-02-07 KR KR1020120012079A patent/KR101160594B1/en not_active IP Right Cessation
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2013
- 2013-02-05 CN CN2013100447909A patent/CN103241996A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101143986A (en) * | 2007-08-07 | 2008-03-19 | 何良金 | Terrace paint |
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KR101160594B1 (en) | 2012-06-28 |
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Application publication date: 20130814 |