CN103232798A - Collar stay with hammer texture effect and preparation method thereof - Google Patents
Collar stay with hammer texture effect and preparation method thereof Download PDFInfo
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- CN103232798A CN103232798A CN2013101364284A CN201310136428A CN103232798A CN 103232798 A CN103232798 A CN 103232798A CN 2013101364284 A CN2013101364284 A CN 2013101364284A CN 201310136428 A CN201310136428 A CN 201310136428A CN 103232798 A CN103232798 A CN 103232798A
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Abstract
The invention discloses a collar stay with a hammer texture effect and a preparation method thereof. The collar stay comprises a base material, wherein a coating with a hammer texture effect is sprayed on the base material. The preparation method of the collar stay comprises the steps of pre-treating the base material, spraying hammer paint, shaping and the like. The collar stay with the hammer texture effect has a unique decorative effect, the preparation method is simple and raw materials are easy to obtain, so that the preparation method is suitable for the collar stay of various materials.
Description
Technical field
The invention belongs to the garment accessories field, particularly a kind of slotting bamboo with hammer tone effect and preparation method thereof.
Background technology
Hammer paint has good covering decoration function to ground, and coatingsurface has looked sunk round dot one by one, and as being beaten by the dung beetle head, hand feels, and is smooth, and rugged sensation is arranged, and is a kind of extraordinary fancy paint.Hammer paint develops into self-drying type by baking-type; Kind develops into present vinylformic acid, urethane, epoxy by amino hammer paint, or even aqueous hammer paint etc.; Constructional method is developed into present " one is coated with method " by two step or multistep processes such as initial " spattering the lacquer method ", " spattering solvent method " and " spilling the silicon method "; It is widely used in the decoration of various grounds such as instrument, instrument surface decoration, wood furniture, plastics, cement plane and beautifies.The control of mallear stria form is by initial only relying on non-floating type aluminium powder and use the mixed solvent with very fast rate of volatilization to regulate, develop into and rely on auxiliary agent to help regulate, thereby simplified construction technology and operation easier widely, made the mallear stria of formation have more three-dimensional aesthetic feeling.
Though hammer paint is ubiquity on market, the coating content of inserting the spraying use of bamboo factory is on the low side, and color is on the high side, and this and coating factory are difficult to form interest relations, generally are difficult to obtain this coating so insert bamboo factory.
Summary of the invention
The purpose of this invention is to provide a kind of slotting bamboo with hammer tone effect.
Concrete technical scheme is as follows:
A kind of slotting bamboo with hammer tone effect, this slotting bamboo comprises base material, is coated with the coating with hammer tone effect on the described base material.
Among some embodiment, the thickness of described coating is 30-100 μ m therein.
Among some embodiment, the raw material of described coating consists of hammer paint, solidifying agent and the thinner that weight part ratio is 1:0.2-0.3:0.5 therein.
Among some embodiment, the raw material of described hammer paint is formed and weight part is: polyurethane lacquer 80-95 part, mallear stria auxiliary agent 0.1-0.8 part, un-suspension powdered aluminium 1-8 part, anti-settling agent 0.1-1 part, mill base or colored paint 0-10 part therein.
Therein among some embodiment, polyurethane lacquer 80-95 part, mallear stria auxiliary agent 0.1-0.8 part, un-suspension powdered aluminium 3-5 part, anti-settling agent 0.3-0.5 part, mill base or colored paint 0.5-3 part.
Among some embodiment, the fineness of described un-suspension powdered aluminium is 10-25 μ m therein.
Among some embodiment, described mallear stria auxiliary agent is polymeric silicone compound mallear stria auxiliary agent or polysiloxane mallear stria auxiliary agent therein.
Among some embodiment, described anti-settling agent is castor oil derivative, organic remodeling wilkinite, metallic soap, polyethylene wax, superfine silicon dioxide or polynite organic derivative therein.
Therein among some embodiment, the material of described base material is wooden, metal, nylon or polypropylene.
Another object of the present invention provides the preparation method of above-mentioned slotting bamboo.
Concrete technical scheme is as follows:
Above-mentioned preparation method with slotting bamboo of hammer tone effect may further comprise the steps:
(1) base material treatment: base material is carried out pre-treatment, guarantee that substrate surface is totally pollution-free;
(2) spraying: with hammer paint, solidifying agent and thinner in the weight part ratio of 1:0.2-0.3:0.5 mix compo, between second, evenly be sprayed on then on the pretreated base material of step (1) at 14-20 with the viscosity of rock field cup control compo;
(3) moulding: the slotting bamboo seasoning that step (2) spraying is good namely gets described slotting bamboo with hammer tone effect.
Principle of the present invention is as follows:
Hammer paint used in the present invention is to be optimized on the basis of existing polyurethane lacquer to obtain: adopt conventional polyurethanes varnish, utilize kalimeris lattice Buddhist nun (Marangoni) effect (under the microgravity, natural convection weakens, and under zero gravity, ought to all disappear.But because surface tension works in liquid surface, cause a surface tension gradient, surface tension gradient surpasses viscous force, makes liquid-flow, the kapillary convection current occurs.The rate of volatilization difference of each component in the mixed solvent in liquid coating, the fast component of rate of volatilization is at first overflowed, and causes each layer concentration distribution to differ; The volatilization of solvent simultaneously reduces the temperature on top layer, causes the temperature head between bottom and top layer, and the surface tension gradient that the two acting in conjunction forms makes solvent streams in the top layer to lower floor, and lower floor's solvent streams is to the upper strata, and circulation forms circulation repeatedly.), (formation of Benard nest mainly is because the imbalance of coating surface solvent evaporates to Benard (Benard) nest, the heterogeneity that makes paint film produce solids content and temperature distributes, thereby it is mobile to cause that surface tension difference and density difference drive, make coating surface form many little vortexs, and expansion gradually, meet and form interconnective sexangle in the border, the spitting image of honeycomb tissue, evaporation along with solvent, it is low further to be transformed into many centres, high roundlet on every side) formation and surface tension effects are three big these principles of major cause of impelling mallear stria to form, by just simply being optimized, polyurethane lacquer can prepare hammer paint, this had not only reduced obtaining difficulty but also having guaranteed that slotting bamboo factory to control and the adjustment of mallear stria state, has also guaranteed the supply of coating of raw material.
Usually, polyurethane lacquer has good levelling, anti scuffing, anti-wear, water resisting property and resistance to chemical corrosion, solid content is 50%-80% in the host, wherein main resin mostly is one or more of Synolac, Resins, epoxy, acrylic resin, and this provides the most basic condition for using polyurethane lacquer to be optimized to hammer paint.The sheet un-suspension powdered aluminium is that polyurethane lacquer is optimized to the main factor of hammer paint, after spraying into paint film, because the splash of lacquer liquid forms varnish stain, aluminium powder in the varnish stain sinks, be subjected to the influence of the whirly of solvent evaporates formation, aluminium powder is rotating sinking, so just forms the hammer nest, and each hammer nest couples together and just formed mallear stria.In order to make mallear stria more beautiful and stable, need to add the mallear stria auxiliary agent, mallear stria auxiliary agent and aluminium powder have certain repulsive interaction, so just, stereoscopic sensation and the degree of depth of hammer nest have been strengthened, in addition, most mallear stria auxiliary agent also have to reduce the capillary effect of hammer nest, reduces the levelling ability of paint film, prevents the mallear stria that formed levelling again in drying process.In order to guarantee the storage-stable of hammer paint, prevent aluminium powder sedimentation in storage process, guarantee that again aluminium powder can be heavy as to go down after spraying, so also need to add the anti-settling agent of thixotropic in the system.
Hammer paint after optimizing is added solidifying agent (ratio of solidifying agent recomputates in former ratio according to the host amount of using), adds and be sprayed directly on the slotting bamboo chip of having handled well after thinner stirs, both dry naturally the slotting bamboo of mallear stria.
Wherein, described aluminium powder has floating type aluminium powder and non-floating type aluminium powder, the preferred un-suspension powdered aluminium of the present invention; Un-suspension powdered aluminium has multiple fineness specification, and the present invention preferentially selects fineness un-suspension powdered aluminium between 10-25 μ m.
Described mallear stria auxiliary agent is common on market polymeric silicone compound mallear stria auxiliary agent, polysiloxane mallear stria auxiliary agent, the preferred polysiloxane mallear stria of a present invention auxiliary agent.
Described anti-settling agent has castor oil derivative, organic remodeling wilkinite, metallic soap, polyethylene wax, superfine silicon dioxide, polynite organic derivative, the preferred polynite organic derivative of the present invention anti-settling agent.
Advantage of the present invention is:
(1) have unique decoration function: uneven by the slotting bamboo of the mallear stria of the present invention's preparation, each nest size depth is close, overlapping between nest and the nest in addition, form the same decorative pattern of similar honeycomb, side is seen then seemingly chain of mountains rows of mountains, and more beautiful things than one can take in has extremely strong visual impact.Insert bamboo simultaneously and feel local uneven, whole smooth.
(2) simple to operate: the present invention only need add chemical substances such as mallear stria auxiliary agent, un-suspension powdered aluminium, anti-settling agent, mill base or colored paint in polyurethane lacquer just can obtain hammer paint, implementation method is simple, easy handling, need not to use expensive professional equipment, extensive operation and small-scale mode of operation all are fit to.
(3) raw material is easy to get: raw material used in the present invention is common raw material on the market, obtains easily.Can help to insert bamboo factory and break away from dependence to coating factory, be more suitable for the personalized production demand of short run.
(4) it is wide to be fit to material: polyurethane paint has good sticking power to wide variety of substrates, therefore, utilizes polyurethane lacquer optimization and the hammer paint that comes can be widely used on the slotting bamboos such as metal, wooden, polypropylene, nylon spraying and form good hammer tone effect.
(5) help to cut the waste: the prepared hammer paint of the present invention has extremely strong bridging effect for laser pattern literal, printing pattern, the slight surface imperfection of inserting on bamboo or other materials, resale for after the slotting bamboo of having scrapped application again, can reduce the trouble that wastage of material and waste disposal are brought.
Description of drawings
Fig. 1 has the slotting bamboo sectional view of hammer tone effect;
The polypropylene of the yellow hammer tone effect that Fig. 2 prepares for embodiment 1 is inserted bamboo;
The wooden slotting bamboo of the blue hammer tone effect that Fig. 3 prepares for embodiment 2;
The nylon of the dark reddish purple look hammer tone effect that Fig. 4 prepares for embodiment 3 is inserted bamboo.
Description of reference numerals:
1, base material; 2, the coating that has hammer tone effect.
Embodiment
The employed raw material of the embodiment of the invention is as follows:
Polyurethane lacquer, solidifying agent, thinner: supplier is Northwest fine chemistry industry;
9526 un-suspension powdered aluminiums slurry: supplier is the outstanding pigment of Shenzhen fame company limited;
SP-903 polysiloxane mallear stria auxiliary agent: sincere chemical industry is won in the supplier Dongguan;
DC-61 silicone compounds mallear stria auxiliary agent: city far away, Wuhan Lion Rock chemistry painting industry factory;
BentoneSD-2 polynite organic derivative thixotropic anti-settling agent: this moral of supplier's hamming is modest;
Self-drying type nitro alkyd varnish: supplier is coating company limited of state nation
Silicon-dioxide anti-settling agent: the prosperous brightness chemical industry of Qingyuan City company limited
Below by specific embodiment the present invention is further elaborated.
Embodiment 1
With reference to Fig. 1-2, a kind of polypropylene of yellow hammer tone effect is inserted bamboo, comprises polypropylene base 1 and the yellow coating with hammer tone effect 2.
The preparation of hammer paint: get 94.2 parts of polyurethane lacquers, 0.6 part of SP-903 polysiloxane mallear stria auxiliary agent, 4.2 parts of 9526 un-suspension powdered aluminiums, 0.4 part of BentoneSD-2 polynite organic derivative thixotropic anti-settling agent, 0.6 part of yellow mill base; The rotating speed that earlier polyurethane lacquer host is mixed with the thixotropic anti-settling agent with high speed dispersor 2000r/min keeps being uniformly dispersed in 5 minutes, adding non-floating type aluminium powder and mill base subsequently keeps being uniformly dispersed in 10 minutes with the rotating speed of high speed dispersor 2000r/min, add the mallear stria auxiliary agent at last and keep again being uniformly dispersed in 2 minutes, namely get hammer paint.
The preparation method is as follows:
(1) base material treatment: base material is carried out pre-treatment, guarantee that substrate surface is totally pollution-free;
(2) spraying: with hammer paint, solidifying agent and thinner in the weight part ratio of 1:0.25:0.5 mix compo, the viscosity of controlling compo with rock field cup is 18 seconds, evenly is sprayed on then on the pretreated base material of step (1); The operating parameters of spraying: adopt 1.5mm bore spray gun, about 300ml/min, air pressure adjustment is to the 0.6MPa with flow control, and from being 25cm, spraying swath is adjusted to medium the rifle mouth from identity distance to be painted, sprays a cross and gets final product.
(3) moulding: the slotting bamboo seasoning that step (2) spraying is good namely gets described slotting bamboo with hammer tone effect.
Embodiment 2
With reference to figure 3, a kind of wood of blue hammer tone effect is inserted bamboo, comprises wood substrate and the blue coating with hammer tone effect.
The preparation of hammer paint: get 91.8 parts of polyurethane lacquers, 0.6 part of SP-903 polysiloxane mallear stria auxiliary agent, 4.2 parts of 9526 un-suspension powdered aluminiums, 0.4 part of BentoneSD-2 polynite organic derivative thixotropic anti-settling agent, 2.6 parts of blue mill bases, 0.4 part of black color paste; The rotating speed that earlier polyurethane lacquer host is mixed with the thixotropic anti-settling agent with high speed dispersor 2000r/min keeps being uniformly dispersed in 5 minutes, adding non-floating type aluminium powder and mill base subsequently keeps being uniformly dispersed in 10 minutes with the rotating speed of high speed dispersor 2000r/min, add the mallear stria auxiliary agent at last and keep again being uniformly dispersed in 2 minutes, namely get hammer paint.
The preparation method is as follows:
(1) base material treatment: base material is carried out pre-treatment, guarantee that substrate surface is totally pollution-free;
(2) spraying: with hammer paint, solidifying agent and thinner in the weight part ratio of 1:0.23:0.5 mix compo, the viscosity of controlling compo with rock field cup is 17 seconds, evenly is sprayed on then on the pretreated base material of step (1); The operating parameters of spraying: adopt 1.5mm bore spray gun, about 300ml/min, air pressure adjustment is to the 0.6MPa with flow control, and from being 25cm, spraying swath is adjusted to medium the rifle mouth from identity distance to be painted, sprays a cross and gets final product.
(3) moulding: the slotting bamboo seasoning that step (2) spraying is good namely gets described slotting bamboo with hammer tone effect.
Embodiment 3
With reference to figure 4, a kind of dark reddish purple hammer tone effect nylon is inserted bamboo, comprises nylon base and the blue coating with hammer tone effect.
The preparation of hammer paint: get 91.3 parts of polyurethane lacquers, 0.6 part of SP-903 polysiloxane mallear stria auxiliary agent, 4.2 parts of 9526 un-suspension powdered aluminiums, 0.4 part of BentoneSD-2 polynite organic derivative thixotropic anti-settling agent, 1 part of plum mill base, 0.5 part of blue mill base, 0.4 part of black color paste, 1.6 parts of white colorants; The rotating speed that earlier polyurethane lacquer host is mixed with the thixotropic anti-settling agent with high speed dispersor 2000r/min keeps being uniformly dispersed in 5 minutes, adding non-floating type aluminium powder and mill base subsequently keeps being uniformly dispersed in 10 minutes with the rotating speed of high speed dispersor 2000r/min, add the mallear stria auxiliary agent at last and keep again being uniformly dispersed in 2 minutes, namely get hammer paint.
The preparation method is as follows:
(1) base material treatment: base material is carried out pre-treatment, guarantee that substrate surface is totally pollution-free;
(2) spraying: with hammer paint, solidifying agent and thinner in the weight part ratio of 1:0.23:0.5 mix compo, the viscosity of controlling compo with rock field cup is 17 seconds, evenly is sprayed on then on the pretreated base material of step (1); The operating parameters of spraying: adopt 1.5mm bore spray gun, about 300ml/min, air pressure adjustment is to the 0.6MPa with flow control, and from being 25cm, spraying swath is adjusted to medium the rifle mouth from identity distance to be painted, sprays a cross and gets final product.
(3) moulding: the slotting bamboo seasoning that step (2) spraying is good namely gets described slotting bamboo with hammer tone effect.
Of the present invention functional for further specifying, illustrate below by comparative tests.
Laboratory method and equipment:
1. friction resistant performance test, ATCC116 tests according to standard A, the experimental installation model: TNH06 manufacturer: Dongguan City east inscription Instr Ltd..
2. adhesion performance test, 2409-2007 tests according to standard ISO, the experimental installation model: A-5123 manufacturer: German BYK company.
3. press and scald test: ATCC-133 tests according to standard A, the experimental installation model: YG-605 manufacturer: Laizhou Electron Instrument Co., Ltd..
Comparative Examples 1
With embodiment 1, just do not add un-suspension powdered aluminium, polyurethane lacquer host ratio is increased to 98.8 parts.According to the step operation of embodiment 1, find that just there is oily nest in the hammer paint drying that does not add un-suspension powdered aluminium afterwards, there is no beautiful mallear stria and exists.
Comparative Examples 2
With embodiment 1, just do not add polysiloxane mallear stria auxiliary agent, the ratio of polyurethane lacquer host is increased to 95 parts, according to the step operation of embodiment 1, it is tiny and easily by levelling again to find not add after the hammer paint drying of polysiloxane mallear stria auxiliary agent mallear stria, hammer nest skewness.
Comparative Examples 3
With embodiment 1, just make polyurethane lacquer host into self-drying type nitro alkyd varnish, other remain unchanged, and the step operation according to embodiment 1 rubs, presses tests such as boiling hot with embodiment 1-3, and comparing result is as shown in the table:
The hammer paint performance comparison of the different lacquer base of table 1 preparation
* annotate: AATCC/ISO represents method and the standard of testing; 4.5/0 the standard of expression grading, AATCC to be being qualified more than 4.0 grades, is qualified with the 0-1 level among the ISO.
As can be seen, from the test result of last table, Comparative Examples 3 usefulness self-drying type nitro alkyd paints are that the basic moisture-proof of optimizing the hammer paint that obtains of lacquer rubs, withstand voltage boiling hot performance can't be up to standard from actually operating.
More than be at the specifying of possible embodiments of the present invention, but this embodiment is not in order to limiting claim of the present invention, does not allly break away from the equivalence that skill spirit of the present invention does and implement or change, all should be contained in the claim of the present invention.
Claims (10)
1. the slotting bamboo with hammer tone effect is characterized in that, this slotting bamboo comprises base material, is coated with the coating with hammer tone effect on the described base material.
2. the slotting bamboo with hammer tone effect according to claim 1 is characterized in that, the thickness of described coating is 30-100 μ m.
3. the slotting bamboo with hammer tone effect according to claim 1 is characterized in that, the raw material of described coating consists of hammer paint, solidifying agent and the thinner that weight part ratio is 1:0.2-0.3:0.5.
4. the slotting bamboo with hammer tone effect according to claim 3, it is characterized in that the raw material of described hammer paint is formed and weight part is: polyurethane lacquer 90-95 part, mallear stria auxiliary agent 0.5-0.8 part, un-suspension powdered aluminium 1-8 part, anti-settling agent 0.1-1 part, mill base or colored paint 0-10 part.
5. the slotting bamboo with hammer tone effect according to claim 4, it is characterized in that the raw material of described hammer paint is formed and weight part is: polyurethane lacquer 80-95 part, mallear stria auxiliary agent 0.1-0.8 part, un-suspension powdered aluminium 3-5 part, anti-settling agent 0.3-0.5 part, mill base or colored paint 0.5-3 part.
6. according to claim 4 or 5 described slotting bamboos with hammer tone effect, it is characterized in that the fineness of described un-suspension powdered aluminium is 10-25 μ m.
7. according to claim 4 or 5 described slotting bamboos with hammer tone effect, it is characterized in that described mallear stria auxiliary agent is polymeric silicone compound mallear stria auxiliary agent or polysiloxane mallear stria auxiliary agent.
8. according to claim 4 or 5 described slotting bamboos with hammer tone effect, it is characterized in that described anti-settling agent is castor oil derivative, organic remodeling wilkinite, metallic soap, polyethylene wax, superfine silicon dioxide or polynite organic derivative.
9. the slotting bamboo with hammer tone effect according to claim 1 is characterized in that, the material of described base material is wooden, metal, nylon or polypropylene.
10. each described preparation method with slotting bamboo of hammer tone effect of claim 1-9 is characterized in that, may further comprise the steps:
(1) base material treatment: base material is carried out pre-treatment, guarantee that substrate surface is totally pollution-free;
(2) spraying: with hammer paint, solidifying agent and thinner in the weight part ratio of 1:0.2-0.3:0.5 mix compo, between second, evenly be sprayed on then on the pretreated base material of step (1) at 14-20 with the viscosity of rock field cup control compo;
(3) moulding: the slotting bamboo seasoning that step (2) spraying is good namely gets described slotting bamboo with hammer tone effect.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111777926A (en) * | 2020-07-16 | 2020-10-16 | 进彩涂料科技(上海)有限公司 | Household appliance color plate dermatoglyph finish paint and preparation method thereof |
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| DE102010026407A1 (en) * | 2010-07-07 | 2012-01-12 | Basf Coatings Gmbh | Process for producing a color and / or effect multilayer coating |
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| CN203371976U (en) * | 2013-04-18 | 2014-01-01 | 广东溢达纺织有限公司 | Collar stay with hammer stripe effect |
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| CN101591502A (en) * | 2008-05-30 | 2009-12-02 | 比亚迪股份有限公司 | A kind of polyurethane coating and preparation method thereof |
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Effective date of registration: 20230329 Address after: No. 38, Mingli Road, Hecheng Street, Gaoming District, Foshan City, Guangdong Province, 528500 (residence application) Patentee after: Guangdong Kangpai Huanchuang Technology Co.,Ltd. Address before: 528500 Guangdong city of Foshan province river export processing zone Patentee before: Guangdong Esquel Textile Co.,Ltd. |
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