CN102559037A - Non-yellowing low-carbon aqueous hammer paint, preparation method and using method thereof - Google Patents

Non-yellowing low-carbon aqueous hammer paint, preparation method and using method thereof Download PDF

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Publication number
CN102559037A
CN102559037A CN2011104536813A CN201110453681A CN102559037A CN 102559037 A CN102559037 A CN 102559037A CN 2011104536813 A CN2011104536813 A CN 2011104536813A CN 201110453681 A CN201110453681 A CN 201110453681A CN 102559037 A CN102559037 A CN 102559037A
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carbon
agent
aqueous
low
xanthochromia
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李会宁
陈仕箐
王江兵
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Zhaoqing Qianjiang Advanced Material Technology Co Ltd
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Zhaoqing Qianjiang Advanced Material Technology Co Ltd
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Abstract

The invention discloses non-yellowing low-carbon aqueous hammer paint, a preparation method and a using method thereof. The aqueous hammer paint consists of aqueous acrylic acid polyurethane resin, aqueous color paste, a film-forming aid, deionized water, aqueous aluminum silver slurry, a dispersing agent, a wetting agent, a PH regulator, a defoamer, an anti-setting agent, a preservative, a thickening agent, an antirusting agent and an aqueous hammer agent. The preparation method comprises the step of: adding the components sequentially according to a certain process parameter. The using method comprises the following steps of: weighing the non-yellowing low-carbon aqueous hammer paint, stirring the non-yellowing low-carbon aqueous hammer paint and an aqueous curing agent uniformly in a weight ratio of paint preparation of (4-6):1, adding the deionized water or tap water, diluting by 0.2 time, spraying to hardware substrates, and drying naturally. By the non-yellowing low-carbon aqueous hammer paint, a carbon-rich organic solvent is avoided or reduced greatly, carbon emission is reduced, and the non-yellowing low-carbon aqueous hammer paint is non-toxic, tasteless, safe and environment-friendly.

Description

Not xanthochromia low-carbon (LC) aqueous hammer paint, preparation method and method of use
Technical field
The present invention relates to not xanthochromia low-carbon (LC) aqueous hammer paint and the not preparation method and the method for use of xanthochromia low-carbon (LC) aqueous hammer paint.
Background technology
China has been global coating first big producing country; But solvent based coating but accounts for 52.1% of ultimate production; Annual have 3,500,000 tons organic solvent after coating uses, to evaporate in the atmosphere approximately, both caused serious topsoil, wasted valuable ample resources again.The hammer paint of producing on the market at present is butyrous basically, and it has, and smell is big, poisonous, inflammable and explosive, and gas all dangerous, that give off is produced in transportation not only has harm to human body, and disadvantage such as contaminate environment greatly.
Summary of the invention
First purpose of the present invention provides a kind of not xanthochromia low-carbon (LC) aqueous hammer paint, and aqueous hammer paint of the present invention is avoided or significantly reduced rich carbon organic solvent, has reduced the discharging of carbon, and is nontoxic, tasteless, safety, environmental protection.
Second purpose of the present invention provides a kind of preparation method of not xanthochromia low-carbon (LC) aqueous hammer paint; Preparing method's technology of the present invention is simple, and the aqueous hammer paint for preparing avoids or significantly reduced rich carbon organic solvent, has reduced the discharging of carbon; Nontoxic, tasteless, safety, environmental protection.
The 3rd purpose of the present invention provides a kind of method of use of not xanthochromia low-carbon (LC) aqueous hammer paint, and rich carbon organic solvent can avoided or significantly reduce to this method of use, reduces the discharging of carbon, and is nontoxic, tasteless, safety, environmental protection.
For reaching above-mentioned first purpose, a kind of not xanthochromia low-carbon (LC) aqueous hammer paint is in parts by weight, and prescription is made up of following component:
Figure BDA0000126245620000021
For reaching above-mentioned second purpose, the preparation method of xanthochromia low-carbon (LC) aqueous hammer paint not may further comprise the steps:
(1) aqueous acrylic urethane resins, skimmer, dispersion agent, wetting agent and part deionized water are joined in the stirring tank successively, under 400~800r/min speed conditions, stirred 5~10 minutes.
(2) add the PH regulator, PH is adjusted to 8~9, under 400~800r/min speed conditions, stirred 10~15 minutes.
(3) add anti-settling agent, under 800~1200r/min speed conditions, dispersed with stirring 20~30 minutes.
(4) add aqueous color paste, water aluminum-silver slurry, film coalescence aid, sanitas, rust-preventive agent, thickening material successively, under 400~800r/min speed conditions, dispersed with stirring 20~30 minutes.
(5) add the agent of water-based mallear stria, under 400~600r/min speed conditions, dispersed with stirring 10~15 minutes.
(6) add remaining deionized water at last, regulate viscosity, under 400~600r/min speed conditions, stirred 10~15 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
For reaching above-mentioned the 3rd purpose; A kind of as the method for use described not xanthochromia of above-mentioned component low-carbon (LC) aqueous hammer paint is: take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: waterborne curing agent=4~6: after 1 (in parts by weight) stir; Add again deionized water or tap water the dilution 0.1~0.3 times after, be sprayed on the base material seasoning.
The invention has the beneficial effects as follows:
(1) owing to being medium with the deionized water, therefore, clean simply, the instrument of use is simple; Fire security measure is simple in storage, transportation and the use, and the healthy measure of gas defence is simple.
(2), nontoxicly, tasteless can not work the mischief to human body owing to be medium with the deionized water.
(3) owing to be medium with the deionized water; Avoid or significantly reduced rich carbon organic solvent; Such as YLENE, toluene, trimethylbenzene, pimelinketone, 200# gasoline, vinyl acetic monomer, N-BUTYL ACETATE or the like the discharging in atmosphere; Just significantly reduce carbon emission, both reduced topsoil, saved ample resources again.
(4) on the five metals surface, can form sticking power is that 0 grade, snappiness are 1mm, excellent weather resistance and hard, not xanthochromia, hammer tone effect that stereoscopic sensation is strong, bright in colour have outstanding protectiveness and ornamental complete filming.
Embodiment
Below in conjunction with embodiment the present invention is further elaborated.
A kind of not xanthochromia low-carbon (LC) aqueous hammer paint is made up of aqueous acrylic urethane resins, aqueous color paste, film coalescence aid, deionized water, water aluminum-silver slurry, dispersion agent, wetting agent, PH regulator, skimmer, anti-settling agent, sanitas, thickening material, rust-preventive agent and the agent of water-based mallear stria.
Wherein, the aqueous acrylic urethane resins solids content is 45 ± 2%, and hydroxy radical content 3.9%, pH value are 7.0~9.0.Aqueous color paste is the real mill base of water-based.Said water aluminum-silver slurry is the non-floating type water aluminum-silver slurry of aluminium powder surface through organic-inorganic and functional resin coating.Said film coalescence aid is a kind of in propylene glycol monomethyl ether, propylene-glycol ethyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, butanols, ethanol or the Virahol.Said skimmer is the modified polyorganosiloxane emulsion, preferentially selects the high TEGO902 of DOW CORNING DC 62 or enlightening for use; Dispersion agent is a nonionogenic tenside; Wetting agent is that modification gathers the silica tensio-active agent, preferentially selects moral modest 461 for use; Sanitas is a heterogeneous ring compound; Anti-settling agent is the silicate colloid, selects the nano grade inorganic silicate or the fresh breeze chemical industry 2R of synthetic for use; The PH regulator is a 2-amino-2-methyl-1-propanol, and thickening material is the polyurethanes thickening material, can select bright icepro chemical industry PU40 for use; Rust-preventive agent is the modified Zn inner complex, like auspicious precious RB60; The agent of water-based mallear stria is the polyphosphazene polymer silicone compounds, like auspicious precious RB66.
In the present invention, waterborne curing agent is the hexamethylene diisocyanate tripolymer of hydrophilic modifying, and solids content is 100 ± 1%.
Embodiment 1
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 53 grams, dispersion agent 0.5 gram, skimmer 0.3 gram, wetting agent 0.1 gram and deionized water 5 grams, joins successively in the stirring tank, under the 500r/min speed conditions, stirred 10 minutes.
(2) add PH regulator 0.1 gram, PH is adjusted to 8.4, under the 600r/min speed conditions, stirred 15 minutes.
(3) add anti-settling agent 1.5 grams, under the 1100r/min speed conditions, dispersed with stirring 25 minutes.
(4) add aqueous white slurry 14 grams, yellow slurry 1 gram of water-based, aqueous black paste 0.3 gram, water aluminum-silver slurry 10 grams, Virahol 2 grams, dipropylene glycol butyl ether 2 grams, sanitas 0.1 gram, rust-preventive agent 0.3 gram, thickening material 0.5 gram successively; Under the 600r/min speed conditions, dispersed with stirring 20 minutes.
(5) add water-based mallear stria agent 1.0 grams, under the 400r/min speed conditions, dispersed with stirring 10 minutes.
(6) add deionized water 8.3 grams at last, regulate viscosity, under the 400r/min speed conditions, stirred 15 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=6: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.2 times after; Be sprayed on the five metals base material seasoning.
Embodiment 2
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 56 grams, dispersion agent 0.4 gram, skimmer 0.4 gram, wetting agent 0.1 gram and deionized water 5 grams, joins successively in the stirring tank, under the 500r/min speed conditions, stirred 10 minutes;
(2) add PH regulator 0.1 gram, PH is adjusted to 8.3, under the 650r/min speed conditions, stirred 13 minutes;
(3) add anti-settling agent 1.4 grams, under the 1150r/min speed conditions, dispersed with stirring 27 minutes;
(4) add yellow slurry 12 grams of water-based, aqueous white slurry 1.5 grams, water aluminum-silver slurry 9.5 grams, Virahol 2.5 grams, dipropylene glycol butyl ether 2 grams, sanitas 0.1 gram, rust-preventive agent 0.4 gram, thickening material 0.5 gram successively; Under the 600r/min speed conditions, dispersed with stirring 23 minutes;
(5) add water-based mallear stria agent 0.9 gram, under the 400r/min speed conditions, dispersed with stirring 12 minutes;
(6) add deionized water 7.2 grams at last, regulate viscosity, under the 400r/min speed conditions, stirred 14 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=5.5: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.2 times after; Be sprayed on the five metals base material seasoning.
Embodiment 3
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 60 grams, dispersion agent 0.3 gram, skimmer 0.5 gram, wetting agent 0.1 gram and deionized water 5 grams, joins successively in the stirring tank, under the 550r/min speed conditions, stirred 12 minutes;
(2) add PH regulator 0.1 gram, PH is adjusted to 8.5, under the 650r/min speed conditions, stirred 15 minutes;
(3) add anti-settling agent 1.3 grams, under the 1100r/min speed conditions, dispersed with stirring 25 minutes;
(4) add water soluble green slurry 9 grams, yellow slurry 0.8 gram of water-based, water aluminum-silver slurry 8 grams, Virahol 3 grams, dipropylene glycol butyl ether 2 grams, sanitas 0.1 gram, rust-preventive agent 0.4 gram, thickening material 0.4 gram successively; Under the 550r/min speed conditions, dispersed with stirring 26 minutes;
(5) add water-based mallear stria agent 0.6 gram, under the 450r/min speed conditions, dispersed with stirring 10 minutes;
(6) add deionized water 8.4 grams at last, regulate viscosity, under the 400r/min speed conditions, stirred 14 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=5: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.2 times after; Be sprayed on the five metals base material seasoning.
Embodiment 4
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 62 grams, dispersion agent 0.3 gram, skimmer 0.5 gram, wetting agent 0.1 gram and deionized water 5 grams, joins successively in the stirring tank, under the 600r/min speed conditions, stirred 11 minutes;
(2) add PH regulator 0.1 gram, PH is adjusted to 8.8, under the 550r/min speed conditions, stirred 14 minutes;
(3) add anti-settling agent 1.2 grams, under the 1000r/min speed conditions, dispersed with stirring 28 minutes;
(4) add blue mill base 6 grams of water-based, aqueous white slurry 1.5 grams, red slurry 0.5 gram of water-based, water aluminum-silver slurry 7 grams, Virahol 3 grams, dipropylene glycol butyl ether 2 grams, sanitas 0.1 gram, rust-preventive agent 0.5 gram, thickening material 0.5 gram successively; Under the 600r/min speed conditions, dispersed with stirring 30 minutes;
(5) add water-based mallear stria agent 0.7 gram, under the 400r/min speed conditions, dispersed with stirring 12 minutes;
(6) add deionized water 9.0 grams at last, regulate viscosity, under the 400r/min speed conditions, stirred 13 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=5: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.15 times after; Be sprayed on the five metals base material seasoning.
Embodiment 5
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 65 grams, dispersion agent 0.3 gram, skimmer 0.6 gram, wetting agent 0.3 gram and deionized water 5 grams, joins successively in the stirring tank, under the 500r/min speed conditions, stirred 15 minutes;
(2) add PH regulator 0.2 gram, PH is adjusted to 8.7, under the 700r/min speed conditions, stirred 10 minutes;
(3) add anti-settling agent 1.1 grams, under the 1050r/min speed conditions, dispersed with stirring 22 minutes;
(4) add water soluble green slurry 7 grams, water aluminum-silver slurry 7.25 grams, Virahol 3.5 grams, dipropylene glycol butyl ether 2 grams, sanitas 0.1 gram, rust-preventive agent 0.5 gram, thickening material 0.4 gram successively, under the 600r/min speed conditions, dispersed with stirring 27 minutes;
(5) add water-based mallear stria agent 0.6 gram, under the 400r/min speed conditions, dispersed with stirring 10 minutes;
(6) add deionized water 6.15 grams at last, regulate viscosity, under the 400r/min speed conditions, stirred 10 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=4.5: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.1 times after; Be sprayed on the five metals base material seasoning.
Embodiment 6
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 68 grams, dispersion agent 0.3 gram, skimmer 0.8 gram, wetting agent 0.1 gram and deionized water 5 grams, joins successively in the stirring tank, under the 500r/min speed conditions, stirred 12 minutes;
(2) add PH regulator 0.15 gram, PH is adjusted to 8.8, under the 600r/min speed conditions, stirred 10 minutes;
(3) add anti-settling agent 0.9 gram, under the 1100r/min speed conditions, dispersed with stirring 22 minutes;
(4) add blue mill base 5 grams of water-based, water aluminum-silver slurry 5.5 grams, Virahol 3.5 grams, dipropylene glycol butyl ether 2.5 grams, sanitas 0.1 gram, rust-preventive agent 0.5 gram, thickening material 0.4 gram successively, under the 700r/min speed conditions, dispersed with stirring 24 minutes;
(5) add water-based mallear stria agent 0.5 gram, under the 450r/min speed conditions, dispersed with stirring 13 minutes;
(6) add deionized water 6.75 grams at last, regulate viscosity, under the 500r/min speed conditions, stirred 12 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=4.0: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.1 times after; Be sprayed on the five metals base material seasoning.
Embodiment 7
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 59.1 grams, dispersion agent 0.3 gram, skimmer 0.2 gram, wetting agent 0.1 gram and deionized water 6 grams, joins successively in the stirring tank, under the 500r/min speed conditions, stirred 10 minutes;
(2) add PH regulator 0.1 gram, PH is adjusted to 8.3, under the 650r/min speed conditions, stirred 13 minutes;
(3) add anti-settling agent 0.8 gram, under the 1150r/min speed conditions, dispersed with stirring 27 minutes;
(4) add yellow slurry 3 grams of water-based, aqueous white slurry 12 grams, water aluminum-silver slurry 5 grams, ethanol 4 grams, propylene glycol monomethyl ether 3 grams, sanitas 0.2 gram, rust-preventive agent 0.8 gram, thickening material 0.2 gram successively, under the 600r/min speed conditions, dispersed with stirring 23 minutes;
(5) add water-based mallear stria agent 0.2 gram, under the 400r/min speed conditions, dispersed with stirring 12 minutes;
(6) add deionized water 4 grams at last, regulate viscosity, under the 400r/min speed conditions, stirred 14 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=5.5: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.2 times after; Be sprayed on the five metals base material seasoning.
Embodiment 8
The method steps for preparing xanthochromia low-carbon (LC) aqueous hammer paint not is following:
(1) with aqueous acrylic urethane resins 54 grams, dispersion agent 0.4 gram, skimmer 0.2 gram, wetting agent 0.2 gram and deionized water 8 grams, joins successively in the stirring tank, under the 550r/min speed conditions, stirred 12 minutes;
(2) add PH regulator 0.1 gram, PH is adjusted to 8.5, under the 650r/min speed conditions, stirred 15 minutes;
(3) add anti-settling agent 0.8 gram, under the 1100r/min speed conditions, dispersed with stirring 25 minutes;
(4) add water soluble green slurry 10 grams, yellow slurry 1 gram of water-based, water aluminum-silver slurry 6 grams, butanols 4 grams, propylene-glycol ethyl ether, dipropylene glycol methyl ether or dipropylene glycol butyl ether 3 grams successively; Sanitas 0.2 gram, rust-preventive agent 0.7 gram, thickening material 0.2 gram; Under the 550r/min speed conditions, dispersed with stirring 26 minutes;
(5) add water-based mallear stria agent 0.2 gram, under the 450r/min speed conditions, dispersed with stirring 10 minutes;
(6) add deionized water 11 grams at last, regulate viscosity, under the 400r/min speed conditions, stirred 14 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
Utilize the method for use of the not xanthochromia low-carbon (LC) aqueous hammer paint that present embodiment prepares to be: to take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: after waterborne curing agent=5: 1 (in parts by weight) stirs; Add again deionized water or tap water the dilution 0.2 times after; Be sprayed on the five metals base material seasoning.
Table 1 installs to the test result that forms the back physicals of filming on the tinplate for the not xanthochromia low-carbon (LC) aqueous hammer paint of the foregoing description is coated with.
Table 1
Figure BDA0000126245620000121
Figure BDA0000126245620000131
Can draw from above-mentioned experiment structure that to form sticking power when xanthochromia low-carbon (LC) aqueous hammer paint is not coated the five metals base material be that 0 grade, snappiness are 1mm, excellent weather resistance and hard, strong solidity to corrosion, not xanthochromia, hammer tone effect that stereoscopic sensation is strong, bright in colour have outstanding protectiveness and ornamental complete filming.
Table 2 is the test result of the not xanthochromia low-carbon (LC) aqueous hammer paint environmental-protecting performance of the foregoing description.
Table 2
Figure BDA0000126245620000132
Utilize preparation method of the present invention; Production process safety, environmental protection, simple, construction are used relatively environment friendly convenient, because be thinner with water; Organic solvent discharging not; Just reduced the discharging of carbon, saved ample resources, so the prepared not xanthochromia of the present invention low-carbon (LC) aqueous hammer paint is a kind of low-carbon environment-friendly product.

Claims (10)

1. xanthochromia low-carbon (LC) aqueous hammer paint not, it is characterized in that: in parts by weight, prescription is made up of following component:
2. not xanthochromia low-carbon (LC) aqueous hammer paint according to claim 1, it is characterized in that: said aqueous acrylic urethane resins solids content is 45 ± 2%, hydroxy radical content 3.9%, pH value are 7.0~9.0.
3. not xanthochromia low-carbon (LC) aqueous hammer paint according to claim 1 is characterized in that: said water aluminum-silver slurry is the non-floating type water aluminum-silver slurry of aluminium powder surface through organic-inorganic and functional resin coating.
4. not xanthochromia low-carbon (LC) aqueous hammer paint according to claim 1 is characterized in that: said film coalescence aid is a kind of in propylene glycol monomethyl ether, propylene-glycol ethyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, butanols, ethanol or the Virahol.
5. not xanthochromia low-carbon (LC) aqueous hammer paint according to claim 1, it is characterized in that: said skimmer is the modified polyorganosiloxane emulsion, dispersion agent is a nonionogenic tenside; Wetting agent is that modification gathers the silica tensio-active agent, and sanitas is a heterogeneous ring compound, and anti-settling agent is the silicate colloid; The PH regulator is a 2-amino-2-methyl-1-propanol; Thickening material is the polyurethanes thickening material, and rust-preventive agent is the modified Zn inner complex, and the agent of water-based mallear stria is the polyphosphazene polymer silicone compounds.
6. the preparation method of a not xanthochromia low-carbon (LC) aqueous hammer paint as claimed in claim 1 is characterized in that: may further comprise the steps:
(1) aqueous acrylic urethane resins, skimmer, dispersion agent, wetting agent and part deionized water are joined in the stirring tank successively, under 400~800r/min speed conditions, stirred 5~10 minutes;
(2) add the PH regulator, PH is adjusted to 8~9, under 400~800r/min speed conditions, stirred 10~15 minutes;
(3) add anti-settling agent, under 800~1200r/min speed conditions, dispersed with stirring 20~30 minutes;
(4) add aqueous color paste, water aluminum-silver slurry, film coalescence aid, sanitas, rust-preventive agent, thickening material successively, under 400~800r/min speed conditions, dispersed with stirring 20~30 minutes;
(5) add the agent of water-based mallear stria, under 400~600r/min speed conditions, dispersed with stirring 10~15 minutes;
(6) add remaining deionized water at last, regulate viscosity, under 400~600r/min speed conditions, stirred 10~15 minutes, can accomplish the preparation process of whole not xanthochromia low-carbon (LC) aqueous hammer paint.
7. the preparation method of not xanthochromia low-carbon (LC) aqueous hammer paint according to claim 6 is characterized in that: said aqueous acrylic urethane resins solids content is 45 ± 2%, and hydroxy radical content 3.9%, pH value are 7.0~9.0.
8. the preparation method of not xanthochromia low-carbon (LC) aqueous hammer paint according to claim 6 is characterized in that: said water aluminum-silver slurry is the non-floating type water aluminum-silver slurry of aluminium powder surface through organic-inorganic and functional resin coating; Said film coalescence aid is propylene glycol monomethyl ether, propylene-glycol ethyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, butanols, ethanol, Virahol etc.; Said skimmer is the modified polyorganosiloxane emulsion, and dispersion agent is a nonionogenic tenside, and wetting agent is that modification gathers the silica tensio-active agent; Sanitas is a heterogeneous ring compound; Anti-settling agent is the silicate colloid, and the PH regulator is a 2-amino-2-methyl-1-propanol, and thickening material is the polyurethanes thickening material; Rust-preventive agent is the modified Zn inner complex, and the agent of water-based mallear stria is the polyphosphazene polymer silicone compounds.
9. the method for use of a not xanthochromia low-carbon (LC) aqueous hammer paint as claimed in claim 1; It is characterized in that: take by weighing not xanthochromia low-carbon (LC) aqueous hammer paint; In joining the lacquer ratio: xanthochromia low-carbon (LC) aqueous hammer paint not: waterborne curing agent=4~6: after 1 (in parts by weight) stir; Add again deionized water or tap water the dilution 0.1~0.3 times after, be sprayed on the base material seasoning.
10. the method for use of not xanthochromia low-carbon (LC) aqueous hammer paint according to claim 9 is characterized in that: said aqueous acrylic urethane resins solids content is 45 ± 2%, and hydroxy radical content 3.9%, pH value are 7.0~9.0; Said waterborne curing agent is the hexamethylene diisocyanate tripolymer of hydrophilic modifying, and solids content is 100 ± 1%; Said film coalescence aid is propylene glycol monomethyl ether, propylene-glycol ethyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, butanols, ethanol, Virahol etc.Said water aluminum-silver slurry is the non-floating type water aluminum-silver slurry of aluminium powder surface through organic-inorganic and functional resin coating.Said skimmer is the modified polyorganosiloxane emulsion, and dispersion agent is a nonionogenic tenside, and wetting agent is that modification gathers the silica tensio-active agent; Sanitas is a heterogeneous ring compound; Anti-settling agent is the silicate colloid, and the PH regulator is a 2-amino-2-methyl-1-propanol, and thickening material is the polyurethanes thickening material; Rust-preventive agent is the modified Zn inner complex, and the agent of water-based mallear stria is the polyphosphazene polymer silicone compounds.
CN2011104536813A 2011-12-29 2011-12-29 Non-yellowing low-carbon aqueous hammer paint, preparation method and using method thereof Pending CN102559037A (en)

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CN103194144A (en) * 2013-04-18 2013-07-10 广东溢达纺织有限公司 Button with hammer effect and preparation method of button
CN103232798A (en) * 2013-04-18 2013-08-07 广东溢达纺织有限公司 Collar stay with hammer texture effect and preparation method thereof
CN105176352A (en) * 2015-10-10 2015-12-23 徐州市三为水性漆科技有限公司 Novel water-based hammer pattern material and preparation method thereof
CN105315813A (en) * 2015-07-02 2016-02-10 江苏足迹涂料有限公司 Water-based automobile metal base coat and preparing method thereof
CN105885659A (en) * 2016-05-23 2016-08-24 清远市贝客音涂料有限公司 Bicomponent water-borne paint with orange peel texture/ripple effect and preparation method thereof
CN106046974A (en) * 2016-08-05 2016-10-26 吴静 Preparation method for special waterborne vinylidene chloride anticorrosive paint used for agitator tank
CN106085038A (en) * 2016-08-05 2016-11-09 安庆市汇东机械有限责任公司 A kind of extruder vinyl perchloride anti-corrosion paint
CN106118424A (en) * 2016-08-05 2016-11-16 安庆市汇东机械有限责任公司 A kind of extruder vinyl perchloride anti-corrosion paint
CN106189781A (en) * 2016-08-05 2016-12-07 吴静 The preparation method of the special polyurethane hammer finiss of reactor and product
CN107365549A (en) * 2017-06-26 2017-11-21 河北晨阳工贸集团有限公司 A kind of aqueous one-component orange-peel paint and preparation method thereof
CN107619628A (en) * 2017-08-09 2018-01-23 河北晨阳工贸集团有限公司 A kind of aqueous double-component acrylic hammer paint and preparation method thereof
CN107815220A (en) * 2017-10-11 2018-03-20 湖南文理学院 A kind of aqueous hammer paint applied to textile machine and preparation method thereof
CN107892858A (en) * 2017-11-22 2018-04-10 纳梁(上海)新材料科技有限公司 A kind of new aqueous double-component epoxy hammer paint
CN109337429A (en) * 2018-08-03 2019-02-15 广东中星科技股份有限公司 A kind of aqueous mallear stria agent and the aqueous polyurethane paint using mallear stria agent
CN109971326A (en) * 2017-12-28 2019-07-05 东莞市广信知识产权服务有限公司 A kind of two component polyurethane hammer paint
CN111777926A (en) * 2020-07-16 2020-10-16 进彩涂料科技(上海)有限公司 Household appliance color plate dermatoglyph finish paint and preparation method thereof

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103194144A (en) * 2013-04-18 2013-07-10 广东溢达纺织有限公司 Button with hammer effect and preparation method of button
CN103232798A (en) * 2013-04-18 2013-08-07 广东溢达纺织有限公司 Collar stay with hammer texture effect and preparation method thereof
CN103232798B (en) * 2013-04-18 2015-12-23 广东溢达纺织有限公司 Slotting bamboo with hammer tone effect and preparation method thereof
CN105315813A (en) * 2015-07-02 2016-02-10 江苏足迹涂料有限公司 Water-based automobile metal base coat and preparing method thereof
CN105176352A (en) * 2015-10-10 2015-12-23 徐州市三为水性漆科技有限公司 Novel water-based hammer pattern material and preparation method thereof
CN105885659A (en) * 2016-05-23 2016-08-24 清远市贝客音涂料有限公司 Bicomponent water-borne paint with orange peel texture/ripple effect and preparation method thereof
CN106118424A (en) * 2016-08-05 2016-11-16 安庆市汇东机械有限责任公司 A kind of extruder vinyl perchloride anti-corrosion paint
CN106085038A (en) * 2016-08-05 2016-11-09 安庆市汇东机械有限责任公司 A kind of extruder vinyl perchloride anti-corrosion paint
CN106046974A (en) * 2016-08-05 2016-10-26 吴静 Preparation method for special waterborne vinylidene chloride anticorrosive paint used for agitator tank
CN106189781A (en) * 2016-08-05 2016-12-07 吴静 The preparation method of the special polyurethane hammer finiss of reactor and product
CN107365549A (en) * 2017-06-26 2017-11-21 河北晨阳工贸集团有限公司 A kind of aqueous one-component orange-peel paint and preparation method thereof
CN107619628A (en) * 2017-08-09 2018-01-23 河北晨阳工贸集团有限公司 A kind of aqueous double-component acrylic hammer paint and preparation method thereof
CN107815220A (en) * 2017-10-11 2018-03-20 湖南文理学院 A kind of aqueous hammer paint applied to textile machine and preparation method thereof
CN107892858A (en) * 2017-11-22 2018-04-10 纳梁(上海)新材料科技有限公司 A kind of new aqueous double-component epoxy hammer paint
CN109971326A (en) * 2017-12-28 2019-07-05 东莞市广信知识产权服务有限公司 A kind of two component polyurethane hammer paint
CN109337429A (en) * 2018-08-03 2019-02-15 广东中星科技股份有限公司 A kind of aqueous mallear stria agent and the aqueous polyurethane paint using mallear stria agent
CN111777926A (en) * 2020-07-16 2020-10-16 进彩涂料科技(上海)有限公司 Household appliance color plate dermatoglyph finish paint and preparation method thereof

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Application publication date: 20120711