CN101117501A - Aqueous hammer paint - Google Patents
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- CN101117501A CN101117501A CNA2007100727923A CN200710072792A CN101117501A CN 101117501 A CN101117501 A CN 101117501A CN A2007100727923 A CNA2007100727923 A CN A2007100727923A CN 200710072792 A CN200710072792 A CN 200710072792A CN 101117501 A CN101117501 A CN 101117501A
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Abstract
The present invention relates to a paint material, in particular to a waterborne hammer paint. The present invention is characterized by comprising water, waterborne aluminum silver paste, film forming additive, antifreeze, anti-corrosion fungicide, defoaming agent, dispersant, regulator, waterborne bi-crosslinking acrylic emulsion, epoxy acrylic emulsion, paint sizing agent, thickening agent, flow agent, hammer tone agent, antitarnish agent and hardening agent. After being evenly stirred, the mixture is emulsified mechanically, the speed is reduced to between 400 and 600 rounds per minute; the waterborne bi-crosslinking acrylic emulsion is added and thickened after PH valve is adjusted between 8 and 9 with the regulator; after viscosity reaches between 80 and 160 seconds (T-4/23 DEG C) the waterborne hammer tone agent, antitarnish agent and hardening agent are added, and the paint sizing agent is added according to requirements, stirred evenly, filtered by a filter and then discharged to be packed into products. The present invention has the advantages of smooth appearance of paint film, vivid flower pattern and excellent antifouling, water and chemical resistant performances. The product can be widely applied to motors, machine tools, machinery, household electrical appliances and inside and outside building decoration. Compared with unctuous paint, the product has long life-span and durability and meets requirements of various environmental protection indexes. The product is nontoxic, harmless, noncombustible, nonexplosive and safe and reliable in storage and transportation.
Description
Technical field:
The present invention relates to a kind of paint material, be specially a kind of aqueous hammer paint.
Background technology:
At present, the various paint of production because it be butyrous, scent of, poisonous, inflammable, explosive, transportation is also inconvenient, all human body is had harm, and environment is had harm.With two crosslinking acrylic acid emulsions or fluorine-containing copolymer resins is the aqueous hammer paint that main film forming substance is produced.Compare with general oil-base paint, have weathering resistance, wear resistance, easy construction, characteristics such as nontoxic.With water is solvent, and three-waste free discharge, excellent property are paid attention to by each side deeply.For a long time, the oiliness hammer paint is big because of smell, pollution is heavy, harmful, inflammable and explosive, do not meet environmental requirement.Thereby countries in the world turn to the research of water-borne coatings one after another, to replace the oiliness hammer paint.
Summary of the invention:
The object of the present invention is to provide a kind of is filmogen with the two crosslinking acrylic acid emulsions of water-based, and the agent of water-based mallear stria is material modified, and other adds pigment, auxiliary agent and water and makes formulated aqueous hammer paints such as thinner.The object of the present invention is achieved like this: it comprises water, water aluminum-silver slurry, film coalescence aid, frostproofer, anticorrosion and bactericidal agent, defoamer, dispersion agent, adjustment agent, water-based two crosslinking acrylic acid emulsion, epoxy-acrylate emulsion, dispersible pigment color paste, thickening material, flow agent, mallear stria agent, rust-preventive agent, increases hard agent.Water 5-25 part, water aluminum-silver slurry 15-24 part, film coalescence aid 2.0-5.1 part, frostproofer 2.0-5.1 part, anticorrosion and bactericidal agent 0.1-0.3 part, defoamer 0.05-0.3 part, dispersion agent 0.1-0.3 part, adjust agent 0.1-0.6 part, the two crosslinking acrylic acid emulsion 30-60 parts of water-based, epoxy-acrylate emulsion 4.0-6.0 part, dispersible pigment color paste 3.0-5.1 part, thickening material 30-60 part, thickening material II0.2-0.9 part, flow agent 0.2-0.8 part, mallear stria agent 0.5-1.2 part, rust-preventive agent 0.5-1.2 part, increase hard agent 0.1-1.2 part.Described water aluminum-silver slurry is that the oxidation synthetics of titanium is that the oxidation synthetics of 5-12 part, aluminium is 10-12 part.Described film coalescence aid is a kind of of 12 carbon alcohol esters, ethylene glycol monobutyl ether, butyl glycol ether, propylene glycol butyl ether, propylene-glycol ethyl ether, ethylene glycol ethyl ether, and umber is 15-24; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described frostproofer is a kind of in ethylene glycol, propylene glycol, carbitol, polyvalent alcohol, the polyoxyethylene glycol, and umber is 2.1-5.1; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described anticorrosion and bactericidal agent is a kind of in nitrogenous organic heterocyclic molecule, termil, 5 chlorodiphenyls-4 isothiazoline-3 ketone, 2 n-octyls-4 isothiazoline-3 ketone, 2 methyl-4 isothiazoline-3 ketone, and umber is 0.1-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described defoamer is a kind of in the emulsification of the silica-based mixture of mineral oil, aliphatic hydrocarbon, non-silicone organic ester hydrocarbon polymer, non-silicone amine hydrocarbon polymer, polyethers organic compound, the polyoxyethylene mixture type siloxane, and umber is 0.05-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.。The special acid of described dispersion agent unsaturated polyester acid amides/high molecular weight acids ester mixture, the esters polymer with acid groups, high molecular weight block copolymer, unsaturated polyester carboxylic acid amide, aliphatic amide polycarboxylate, anionic surfactant compound, nonionic interface compound is polymer-modified, a kind of among the polycarboxylate sodium, polysiloxane, and umber is 0.1-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described adjustment agent is a kind of in sodium methyl silicate, potassium silicate, amido alcohol phosphoric acid saline solution, alcamines organism, dimethylethanolamine, trolamine, thanomin, ammoniacal liquor, the potassium hydroxide, and umber is 0.1-0.6; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described thickening material I is a kind of in modified polypropene hydrochlorate, ethoxyquin urethane polymer, the acrylate cross linked multipolymer, and umber is 30-60; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described thickening material II is that non-ionic polyurethane polymkeric substance, nonionic polyoxyalkylene type polyurethane, thickened oil acid glyceride derivative, ethyl cellulose are a kind of, and umber is 0.2-0.9; Or the mixture of above 2 kinds of materials or 3 kinds of materials.The agent of described water-based mallear stria is a kind of in the organic polymer soln, modified silicone, polymer organosilicon, polydimethylsiloxane of siloxanes, and umber is 0.5-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described rust-preventive agent is a kind of in the deriving mixture of organic acid sodium salt compound, sulfur-bearing, phosphorus, amine and nitrogen, non-oxide inorganic salt, inorganic slow rotten pigment, nitrocarboxylic acid salt, zinc salt, dinonylnaphthalene sulfonic acid salt, metatitanic acid salt, Sodium phosphate dibasic, dipotassium hydrogen phosphate, organic zinc complex, nitrogen phosphorus compound, the metal ion organic compound, and umber is 0.5-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Describedly increase polymkeric substance a kind of that hard agent is modified polyamide serum, modified silicone, special modified polyamide wax liquid, water-based styrene acrylic emulsion, Water-borne modification oxidized polyethlene wax, water-based siloxanes, umber is 0.1-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.With water, water aluminum-silver slurry, film coalescence aid, frostproofer, defoamer, dispersion agent, the two crosslinking acrylic acid emulsions of water-based, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add the two crosslinking acrylic acid emulsions of water-based and regulate PH with conditioning agent and carry out thickening behind the 8-9, add the agent of water-based mallear stria after making viscosity reach 80-160 second (T-4/23 ℃), rust-preventive agent and increase hard agent, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.Advantage of the present invention is: paint film appearance is smooth, and decorative pattern is bright-coloured, and antifouling and water-fast, chemical resistant properties etc. is good.Product can be widely used on motor, lathe, machinery, the household appliances, on the internal and external ornament that also can be applicable to build.Product is long, durable and meet every environmental protection index requirement than the oil-base paint life-span.Product is nontoxic, do not fire, not quick-fried, store and transportation safety reliable.In the construction, the person and environment are not had noxious gas emission, problems such as heavy metal free pollution produce.Weathering resistance, wear resistance, self-cleaning, nontoxic, do not fire not quick-fried, three-waste free discharge, meet Europe III environmental requirement.
Embodiment:
Water 5-25 part, water aluminum-silver slurry 15-24 part, film coalescence aid 2.0-5.1 part, frostproofer 2.0-5.1 part, anticorrosion and bactericidal agent 0.1-0.3 part, defoamer 0.05-0.3 part, dispersion agent 0.1-0.3 part, adjust agent 0.1-0.6 part, the two crosslinking acrylic acid emulsion 30-60 parts of water-based, epoxy-acrylate emulsion 4.0-6.0 part, dispersible pigment color paste 3.0-5.1 part, thickening material 30-60 part, thickening material II0.2-0.9 part, flow agent 0.2-0.8 part, mallear stria agent 0.5-1.2 part, rust-preventive agent 0.5-1.2 part, increase hard agent 0.1-1.2 part.Described water aluminum-silver slurry is that the oxidation synthetics of titanium is that the oxidation synthetics of 5-12 part, aluminium is 10-12 part.Described film coalescence aid is a kind of of 12 carbon alcohol esters, ethylene glycol monobutyl ether, butyl glycol ether, propylene glycol butyl ether, propylene-glycol ethyl ether, ethylene glycol ethyl ether, and umber is 15-24; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described frostproofer is a kind of in ethylene glycol, propylene glycol, carbitol, polyvalent alcohol, the polyoxyethylene glycol, and umber is 2.1-5.1; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described anticorrosion and bactericidal agent is a kind of in nitrogenous organic heterocyclic molecule, termil, 5 chlorodiphenyls-4 isothiazoline-3 ketone, 2 n-octyls-4 isothiazoline-3 ketone, 2 methyl-4 isothiazoline-3 ketone, and umber is 0.1-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described defoamer is a kind of in the emulsification of the silica-based mixture of mineral oil, aliphatic hydrocarbon, non-silicone organic ester hydrocarbon polymer, non-silicone amine hydrocarbon polymer, polyethers organic compound, the polyoxyethylene mixture type siloxane, and umber is 0.05-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.The special acid of described dispersion agent unsaturated polyester acid amides/high molecular weight acids ester mixture, the esters polymer with acid groups, high molecular weight block copolymer, unsaturated polyester carboxylic acid amide, aliphatic amide polycarboxylate, anionic surfactant compound, nonionic interface compound is polymer-modified, a kind of among the polycarboxylate sodium, polysiloxane, and umber is 0.1-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described adjustment agent is a kind of in sodium methyl silicate, potassium silicate, amido alcohol phosphoric acid saline solution, alcamines organism, dimethylethanolamine, trolamine, thanomin, ammoniacal liquor, the potassium hydroxide, and umber is 0.1-0.6; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described thickening material I is a kind of in modified polypropene hydrochlorate, ethoxyquin urethane polymer, the acrylate cross linked multipolymer, and umber is 30-60; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described thickening material II is a kind of in non-ionic polyurethane polymkeric substance, nonionic polyoxyalkylene type polyurethane, thickened oil acid glyceride derivative, the ethyl cellulose, and umber is 0.2-0.9; Or the mixture of above 2 kinds of materials or 3 kinds of materials.The agent of described water-based mallear stria is a kind of in the organic polymer soln, modified silicone, polymer organosilicon, polydimethylsiloxane of siloxanes, and umber is 0.5-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Described rust-preventive agent is a kind of in the deriving mixture of organic acid sodium salt compound, sulfur-bearing, phosphorus, amine and nitrogen, non-oxide inorganic salt, inorganic slow rotten pigment, nitrocarboxylic acid salt, zinc salt, dinonylnaphthalene sulfonic acid salt, metatitanic acid salt, Sodium phosphate dibasic, dipotassium hydrogen phosphate, organic zinc complex, nitrogen phosphorus compound, the metal ion organic compound, and umber is 0.5-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.Describedly increase polymkeric substance a kind of that hard agent is modified polyamide serum, modified silicone, special modified polyamide wax liquid, water-based styrene acrylic emulsion, Water-borne modification oxidized polyethlene wax, water-based siloxanes, umber is 0.1-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.With water, water aluminum-silver slurry, film coalescence aid, frostproofer, defoamer, dispersion agent, the two crosslinking acrylic acid emulsions of water-based, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add the two crosslinking acrylic acid emulsions of water-based and regulate PH with conditioning agent and carry out thickening behind the 8-9, add the agent of water-based mallear stria after making viscosity reach 80-160 second (T-4/23 ℃), rust-preventive agent and increase hard agent, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.
Lift specific embodiment below and further specify technical solution of the present invention:
Example 1,5 parts in water, water aluminum-silver slurry is that the oxidation synthetics of titanium is 5 parts, the oxidation synthetics of aluminium is 10 parts, film coalescence aid is 15 parts of 12 carbon alcohol esters, frostproofer is 2.0 parts of ethylene glycol, anticorrosion and bactericidal agent is 0.1 part of a termil, defoamer is 0.05 part in the silica-based mixture of mineral oil, dispersion agent is 0.1 part of a unsaturated polyester acid amides, adjusting agent is 0.1 part of sodium methyl silicate, the two crosslinking acrylic acid emulsions of water-based are 30 parts, epoxy-acrylate emulsion is 4.0 parts, dispersible pigment color paste is 3.0 parts, thickening material I is 30 parts of modified polypropene hydrochlorates, thickening material II is 0.2 part of a nonionic polyether polyols with reduced unsaturation, flow agent is 0.2 part, the mallear stria agent is 0.5 part of a modified silicone, rust-preventive agent is 0.5 part of non-an oxidising inorganic salt, increasing hard agent is that 0.1 part of modified polyamide serum is standby.With above-mentioned water, the oxidation synthetics of titanium, the oxidation synthetics of aluminium, 12 carbon alcohol esters, ethylene glycol, termil, the silica-based mixture of mineral oil, the unsaturated polyester acid amides, the epoxy acrylic epoxy emulsion, the modified polypropene hydrochlorate, the nonionic polyoxyalkylene type polyurethane, flow agent, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add two crosslinking acrylic acid emulsions, and regulate PH with sodium methyl silicate and carry out thickening behind the 8-9, add modified silicone after making viscosity reach 80-160 second (T-4/23 ℃), non-oxide inorganic salt and modified polyamide serum, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.
Example 2,25 parts in water, water aluminum-silver slurry is that the oxidation synthetics of titanium is 12 parts, the oxidation synthetics of aluminium is 10 parts, film coalescence aid is 24 parts of ethylene glycol monobutyl ethers, frostproofer is 5.0 parts of propylene glycol, anticorrosion and bactericidal agent is 0.3 part of 5 chlorodiphenyls-4 isothiazoline-3 ketone, defoamer is 0.3 part of the emulsification of aliphatic hydrocarbon, dispersion agent is 0.3 part of a high molecular weight block copolymer, adjusting agent is 0.6 part of potassium silicate, the two crosslinking acrylic acid emulsions of water-based are 60 parts, epoxy-acrylate emulsion is 6.0 parts, dispersible pigment color paste is 5.0 parts, thickening material I is 60 parts of ethoxyquin urethane polymers, thickening material II is the nonionic polyether(poly)urethane, flow agent is 0.8 part, the mallear stria agent is 1.2 parts of polymer organosilicons, rust-preventive agent is 1.2 parts of nitrocarboxylic acid salt, increasing hard agent is that 1.2 parts of water-based styrene acrylic emulsions are standby.With above-mentioned water, the oxidation synthetics of titanium, the oxidation synthetics of aluminium, ethylene glycol monobutyl ether, propylene glycol, 5 chlorodiphenyls-4 isothiazoline-3 ketone, the emulsification of aliphatic hydrocarbon, high molecular weight block copolymer, epoxy-acrylate emulsion, the ethoxyquin urethane polymer, the nonionic polyoxyalkylene type polyurethane, flow agent, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add the two crosslinking acrylic acid emulsions of water-based, and use the nonionic polyoxyalkylene type polyurethane, potassium silicate is regulated PH and is carried out thickening behind the 8-9, add the polymer organosilicon after making viscosity reach 80-160 second (T-4/23 ℃), nitrocarboxylic acid salt, water-based styrene acrylic emulsion, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.
Example 3,20 parts in water, water aluminum-silver slurry is that the oxidation synthetics of titanium is 9 parts, the oxidation synthetics of aluminium is 11 parts, film coalescence aid is 19 parts of butyl glycol ethers, frostproofer is 3.0 parts of polyoxyethylene glycol, anticorrosion and bactericidal agent is 0.2 part of 2 n-octyls-4 isothiazoline-3 ketone, defoamer is 0.1 part in a non-silicone organic ester hydrocarbon polymer, dispersion agent is 0.2 part of an aliphatic amide polycarboxylate, adjusting agent is 0.2 part of trolamine, the two crosslinking acrylic acid emulsions of water-based are 40 parts, epoxy-acrylate emulsion is 5.0 parts, dispersible pigment color paste is 4.0 parts, thickening material I is 50 parts of acrylate cross linked multipolymers, thickening material II is 0.6 part of an ethyl cellulose, flow agent is 0.6 part, the mallear stria agent is 1.0 parts of polydimethylsiloxanes, rust-preventive agent is 0.8 part of Sodium phosphate dibasic, increasing hard agent is that 0.6 part of Water-borne modification oxidized polyethlene wax is standby.With above-mentioned water, the oxidation synthetics of titanium, the oxidation synthetics of aluminium, butyl glycol ether, polyoxyethylene glycol, 2 n-octyls-4 isothiazoline-3 ketone, non-silicone organic ester hydrocarbon polymer, the aliphatic amide polycarboxylate, acrylate cross linked multipolymer, ethyl cellulose, epoxy-acrylate emulsion, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add the two crosslinking acrylic acid emulsions of water-based, and regulate PH with trolamine and carry out thickening behind the 8-9, add polydimethylsiloxane after making viscosity reach 80-160 second (T-4/23 ℃), Sodium phosphate dibasic, the Water-borne modification oxidized polyethlene wax, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.
Example 4,25 parts in water, water aluminum-silver slurry is that the oxidation synthetics of titanium is 7 parts, the oxidation synthetics of aluminium is 12 parts, film coalescence aid is 10 parts of propylene glycol butyl ether, 13 parts of ethylene glycol ethyl ethers, frostproofer is 1.5 parts of carbitols, 2.5 parts of polyvalent alcohols, anticorrosion and bactericidal agent is 0.2 part of a termil, 0.1 part of 2 methyl-4 isothiazoline-3 ketone, defoamer is 0.05 part in a non-silicone amine hydrocarbon polymer, 0.1 part of polyethers organic compound, dispersion agent is 0.1 part of an anionic surfactant compound, 0.2 part of polycarboxylate sodium, adjusting agent is 0.1 part of amido alcohol phosphoric acid saline solution, 0.2 part of alcamines organism, the two crosslinking acrylic acid emulsions of water-based are 40 parts, epoxy-acrylate emulsion is 5.0 parts, dispersible pigment color paste is 5.0 parts, thickening material I is 30 parts of modified polypropene hydrochlorates, 25 parts of ethoxyquin urethane polymers, thickening material II is 0.2 part of a nonionic polyether polyols with reduced unsaturation, 0.7 part in thickened oil acid glyceride derivative, flow agent is 0.8 part, the mallear stria agent is 0.5 part of a modified silicone, 0.7 part of polymer organosilicon, rust-preventive agent is 0.5 part of dinonylnaphthalene sulfonic acid salt, 0.7 part of metatitanic acid salt, increasing hard agent is 0.5 part of modified silicone, 0.7 part of special modified polyamide wax liquid is standby.With above-mentioned water, the oxidation synthetics of titanium, the oxidation synthetics of aluminium, the propylene glycol butyl ether, ethylene glycol ethyl ether, carbitol, polyvalent alcohol, termil, 2 methyl-4 isothiazoline-3 ketone, non-silicone amine hydrocarbon polymer, the polyethers organic compound, anionic surfactant compound, the special acid of nonionic interface compound is polymer-modified, the modified polypropene hydrochlorate, the ethoxyquin urethane polymer, the non-ionic polyurethane polymkeric substance, thickened oil acid glyceride derivative, epoxy-acrylate emulsion, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add the two crosslinking acrylic acid emulsions of water-based, and with amido alcohol phosphoric acid saline solution, the alcamines organism is regulated PH and is carried out thickening behind the 8-9, add modified silicone after making viscosity reach 80-160 second (T-4/23 ℃), the polymer organosilicon, 0.5 part of dinonylnaphthalene sulfonic acid salt, the metatitanic acid salt, modified silicone, special modified polyamide wax liquid, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.
Example 5,25 parts in water, water aluminum-silver slurry is that the oxidation synthetics of titanium is 8 parts, the oxidation synthetics of aluminium is 12 parts, film coalescence aid is 6 parts of 12 carbon alcohol esters, 10 parts of ethylene glycol monobutyl ethers, 7 parts of propylene-glycol ethyl ether parts, frostproofer is 1.5 parts of 1.1 parts of carbitols of ethylene glycol, 2.5 parts of polyvalent alcohols, anticorrosion and bactericidal agent is 0.1 part of a termil, 0.1 part of termil, 0.1 part of 2 methyl-4 isothiazoline-3 ketone, defoamer is 0.1 part in 0.05 part of non-silicone amine hydrocarbon polymer of polyoxyethylene mixture siloxanes, 0.1 part of polyethers organic compound, dispersion agent is 0.1 part of a polysiloxane, 0.1 part of anionic surfactant compound, 0.1 part of unsaturated polyester carboxylic acid amide, adjusting agent is 0.1 part of thanomin, 0.1 part of ammoniacal liquor, 0.1 part in potassium hydroxide, the two crosslinking acrylic acid emulsions of water-based are 40 parts, epoxy-acrylate emulsion is 5.0 parts, dispersible pigment color paste is 5.0 parts, thickening material I is 15 parts of modified polypropene hydrochlorates, 15 parts of modified polypropene hydrochlorates, 25 parts of ethoxyquin urethane polymers, thickening material II is 0.3 part of a nonionic polyether(poly)urethane, 0.3 part in thickened oil acid glyceride derivative, 0.3 part of ethyl cellulose, flow agent is 0.8 part, the mallear stria agent is 0.4 part of the organic polymer soln of siloxanes, 0.4 part of modified silicone, 0.4 part of polymer organosilicon, rust-preventive agent is 0.4 part of nitrocarboxylic acid salt, 0.4 part of zinc salt, 0.4 part of Sodium phosphate dibasic, increasing hard agent is 0.4 part of modified polyamide serum, 0.4 part of modified silicone, 0.4 part of water-based styrene acrylic emulsion is standby.With above-mentioned water, the oxidation synthetics of titanium, the oxidation synthetics of aluminium, 12 carbon alcohol esters, ethylene glycol monobutyl ether, propylene-glycol ethyl ether part, ethylene glycol, carbitol, polyvalent alcohol, termil, termil, 2 methyl-4 isothiazoline-3 ketone, polyoxyethylene mixture siloxanes, non-silicone amine hydrocarbon polymer, the polyethers organic compound, polysiloxane, anionic surfactant compound, the unsaturated polyester carboxylic acid amide, the modified polypropene hydrochlorate, the modified polypropene hydrochlorate, the ethoxyquin urethane polymer, the nonionic polyoxyalkylene type polyurethane, thickened oil acid glyceride derivative, the ethyl cellulose epoxy-acrylate emulsion, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add the two crosslinking acrylic acid emulsions of water-based, and use thanomin, ammoniacal liquor, potassium hydroxide is regulated PH and is carried out thickening behind the 8-9, make viscosity reach the organic polymer soln that adds siloxanes behind 80-160 second (T-4/23 ℃), modified silicone, the polymer organosilicon, nitrocarboxylic acid salt, zinc salt, Sodium phosphate dibasic, the modified polyamide serum, modified silicone, water-based styrene acrylic emulsion, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.
The salient features that production method of the present invention makes aqueous hammer paint is as follows:
| Interventions Requested, title and unit | This technical target of the product | The oil product index |
| Paint film color and 23 ℃/h of outward appearance surface drying time of drying do solid work 23 ℃/h viscosity 4 #/ 23 ℃ of S snappiness m/m shock strength kg/cm 223 ℃/h 〉=alkali resistance 5%NaCl/h 〉=acid resistance 3%HCl/h of water tolerance 〉= | Meet that the model decorative pattern is clear, aquatic foods have reflected 0.2 2 112 1 50 168 96 48 | Meet model 1 24 124 1 50 168 96 48 |
Claims (14)
1. aqueous hammer paint, it comprises water, water aluminum-silver slurry, film coalescence aid, frostproofer, anticorrosion and bactericidal agent, defoamer, dispersion agent, adjust agent, the two crosslinking acrylic acid emulsions of water-based, epoxy-acrylate emulsion, dispersible pigment color paste, thickening material, flow agent, the mallear stria agent, rust-preventive agent, increase hard agent, it is characterized in that: water 5-25 part, water aluminum-silver slurry 15-24 part, film coalescence aid 2.0-5.1 part, frostproofer 2.0-5.1 part, anticorrosion and bactericidal agent 0.1-0.3 part, defoamer 0.05-0.3 part, dispersion agent 0.1-0.3 part, adjust agent 0.1-0.6 part, the two crosslinking acrylic acid emulsion 30-60 parts of water-based, epoxy-acrylate emulsion 4.0-6.0 part, dispersible pigment color paste 3.0-5.1 part, thickening material 30-60 part, thickening material II0.2-0.9 part, flow agent 0.2-0.8 part, mallear stria agent 0.5-1.2 part, rust-preventive agent 0.5-1.2 part, increase hard agent 0.1-1.2 part.
2. a kind of aqueous hammer paint according to claim 1 is characterized in that: described water aluminum-silver slurry is that the oxidation synthetics of titanium is that the oxidation synthetics of 5-12 part, aluminium is 10-12 part.
3. a kind of aqueous hammer paint according to claim 1 is characterized in that: described film coalescence aid is a kind of of 12 carbon alcohol esters, ethylene glycol monobutyl ether, butyl glycol ether, propylene glycol butyl ether, propylene-glycol ethyl ether, ethylene glycol ethyl ether, and umber is 15-24; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
4. a kind of aqueous hammer paint according to claim 1 is characterized in that: described frostproofer is a kind of in ethylene glycol, propylene glycol, carbitol, polyvalent alcohol, the polyoxyethylene glycol, and umber is 2.1-5.1; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
5. a kind of aqueous hammer paint according to claim 1, it is characterized in that: described anticorrosion and bactericidal agent is a kind of in nitrogenous organic heterocyclic molecule, termil, 5 chlorodiphenyls-4 isothiazoline-3 ketone, 2 n-octyls-4 isothiazoline-3 ketone, 2 methyl-4 isothiazoline-3 ketone, and umber is 0.1-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
6. a kind of aqueous hammer paint according to claim 1 is characterized in that: described defoamer is a kind of in the emulsification of the silica-based mixture of mineral oil, aliphatic hydrocarbon, non-silicone organic ester hydrocarbon polymer, non-silicone amine hydrocarbon polymer, polyethers organic compound, the polyoxyethylene mixture type siloxane, and umber is 0.05-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
7. a kind of aqueous hammer paint according to claim 1 is characterized in that: the special acid of described dispersion agent unsaturated polyester acid amides, high molecular weight acids ester mixture, the esters polymer with acid groups, high molecular weight block copolymer, unsaturated polyester carboxylic acid amide, aliphatic amide polycarboxylate, anionic surfactant compound, nonionic interface compound is polymer-modified, a kind of among the polycarboxylate sodium, polysiloxane, and umber is 0.1-0.3; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
8. a kind of aqueous hammer paint according to claim 1, it is characterized in that: described adjustment agent is a kind of in sodium methyl silicate, potassium silicate, amido alcohol phosphoric acid saline solution, alcamines organism, dimethylethanolamine, trolamine, thanomin, ammoniacal liquor, the potassium hydroxide, and umber is 0.1-0.6; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
9. a kind of aqueous hammer paint according to claim 1 is characterized in that: described thickening material I is a kind of in modified polypropene hydrochlorate, ethoxyquin urethane polymer, the acrylate cross linked multipolymer, and umber is 30-60; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
10. a kind of aqueous hammer paint according to claim 1 is characterized in that: described thickening material II is a kind of in non-ionic polyurethane polymkeric substance, nonionic polyoxyalkylene type polyurethane, thickened oil acid glyceride derivative, the ethyl cellulose, and umber is 0.2-0.9; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
11. a kind of aqueous hammer paint according to claim 1 is characterized in that: the agent of described water-based mallear stria is a kind of in the organic polymer soln, modified silicone, polymer organosilicon, polydimethylsiloxane of siloxanes, and umber is 0.5-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
12. a kind of aqueous hammer paint according to claim 1, it is characterized in that: described rust-preventive agent is a kind of in the deriving mixture of organic acid sodium salt compound, sulfur-bearing, phosphorus, amine and nitrogen, non-oxide inorganic salt, inorganic slow rotten pigment, nitrocarboxylic acid salt, zinc salt, dinonylnaphthalene sulfonic acid salt, metatitanic acid salt, Sodium phosphate dibasic, dipotassium hydrogen phosphate, organic zinc complex, nitrogen phosphorus compound, the metal ion organic compound, and umber is 0.5-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
13. a kind of aqueous hammer paint according to claim 1, it is characterized in that: describedly increase polymkeric substance a kind of that hard agent is modified polyamide serum, modified silicone, special modified polyamide wax liquid, water-based styrene acrylic emulsion, Water-borne modification oxidized polyethlene wax, water-based siloxanes, umber is 0.1-1.2; Or the mixture of above 2 kinds of materials or 3 kinds of materials.
14. a kind of aqueous hammer paint according to claim 1, it is characterized in that: with water, water aluminum-silver slurry, film coalescence aid, frostproofer, defoamer, dispersion agent, the two crosslinking acrylic acid emulsions of water-based, be added in the pot in order, the limit edged stirs, the speed of two stirrings is 800-1200 rev/min, after the above-mentioned mixture that stirs carried out machinery emulsification, slow down to 400-600 rev/min, add the two crosslinking acrylic acid emulsions of water-based and regulate PH with conditioning agent and carry out thickening behind the 8-9, add the agent of water-based mallear stria after making viscosity reach 80-160 second (T-4/23 ℃), rust-preventive agent and increase hard agent, and add dispersible pigment color paste on request, stir, filter the back discharging with strainer and be packaged into product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100727923A CN101117501A (en) | 2007-09-12 | 2007-09-12 | Aqueous hammer paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100727923A CN101117501A (en) | 2007-09-12 | 2007-09-12 | Aqueous hammer paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101117501A true CN101117501A (en) | 2008-02-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007100727923A Pending CN101117501A (en) | 2007-09-12 | 2007-09-12 | Aqueous hammer paint |
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| Country | Link |
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| CN (1) | CN101117501A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102408789A (en) * | 2010-09-21 | 2012-04-11 | 苏州美亚美建筑涂料有限公司 | Ethylbenzene emulsion waterproof coating |
| CN102559037A (en) * | 2011-12-29 | 2012-07-11 | 肇庆千江高新材料科技有限公司 | Non-yellowing low-carbon aqueous hammer paint, preparation method and using method thereof |
| CN102746789A (en) * | 2012-07-23 | 2012-10-24 | 江苏华夏制漆科技有限公司 | High temperature resistant low temperature quick-drying hammer paint |
| CN104178009A (en) * | 2014-08-28 | 2014-12-03 | 广西梧州龙鱼漆业有限公司 | Self-drying hammer paint |
| CN105001770A (en) * | 2015-07-30 | 2015-10-28 | 广西梧州龙鱼漆业有限公司 | Naturally-drying hammer paint |
| CN105176352A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Novel water-based hammer pattern material and preparation method thereof |
| CN105315853A (en) * | 2015-11-24 | 2016-02-10 | 安徽旺家源门业有限公司 | Self-drying hammer paint for door and preparing method thereof |
| CN106118424A (en) * | 2016-08-05 | 2016-11-16 | 安庆市汇东机械有限责任公司 | A kind of extruder vinyl perchloride anti-corrosion paint |
| CN106189781A (en) * | 2016-08-05 | 2016-12-07 | 吴静 | The preparation method of the special polyurethane hammer finiss of reactor and product |
| CN106221354A (en) * | 2016-08-19 | 2016-12-14 | 袁中良 | A kind of multi-functional coalescents and preparation method and application |
| CN106634465A (en) * | 2017-01-05 | 2017-05-10 | 广东绿色大地化工有限公司 | Waterborne hammer paint and coating method thereof |
| CN107365549A (en) * | 2017-06-26 | 2017-11-21 | 河北晨阳工贸集团有限公司 | A kind of aqueous one-component orange-peel paint and preparation method thereof |
| CN107815220A (en) * | 2017-10-11 | 2018-03-20 | 湖南文理学院 | A kind of aqueous hammer paint applied to textile machine and preparation method thereof |
| CN107987635A (en) * | 2017-11-30 | 2018-05-04 | 青岛圣世恒业化工有限公司 | A kind of outer finishing coat applied to steel and preparation method thereof |
| CN108373638A (en) * | 2018-03-01 | 2018-08-07 | 温州环诺新材料科技有限公司 | A kind of universal aqueous mallear stria self-drying paint |
| CN109181446A (en) * | 2018-08-08 | 2019-01-11 | 云和县泊璟工贸有限公司 | A kind of roller Lacquer finish hammer tone effect aqueous clear coating and its preparation method and application |
| CN115537085A (en) * | 2021-11-09 | 2022-12-30 | 西藏君怡装饰材料有限公司 | Special water-based paint for Qinghai-Tibet plateau and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408789A (en) * | 2010-09-21 | 2012-04-11 | 苏州美亚美建筑涂料有限公司 | Ethylbenzene emulsion waterproof coating |
| CN102559037A (en) * | 2011-12-29 | 2012-07-11 | 肇庆千江高新材料科技有限公司 | Non-yellowing low-carbon aqueous hammer paint, preparation method and using method thereof |
| CN102746789A (en) * | 2012-07-23 | 2012-10-24 | 江苏华夏制漆科技有限公司 | High temperature resistant low temperature quick-drying hammer paint |
| CN104178009A (en) * | 2014-08-28 | 2014-12-03 | 广西梧州龙鱼漆业有限公司 | Self-drying hammer paint |
| CN105001770A (en) * | 2015-07-30 | 2015-10-28 | 广西梧州龙鱼漆业有限公司 | Naturally-drying hammer paint |
| CN105176352A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Novel water-based hammer pattern material and preparation method thereof |
| CN105315853A (en) * | 2015-11-24 | 2016-02-10 | 安徽旺家源门业有限公司 | Self-drying hammer paint for door and preparing method thereof |
| CN106118424A (en) * | 2016-08-05 | 2016-11-16 | 安庆市汇东机械有限责任公司 | A kind of extruder vinyl perchloride anti-corrosion paint |
| CN106189781A (en) * | 2016-08-05 | 2016-12-07 | 吴静 | The preparation method of the special polyurethane hammer finiss of reactor and product |
| CN106221354A (en) * | 2016-08-19 | 2016-12-14 | 袁中良 | A kind of multi-functional coalescents and preparation method and application |
| CN106634465A (en) * | 2017-01-05 | 2017-05-10 | 广东绿色大地化工有限公司 | Waterborne hammer paint and coating method thereof |
| CN106634465B (en) * | 2017-01-05 | 2018-08-31 | 广东绿色大地化工有限公司 | A kind of aqueous hammer paint and its coating process |
| CN107365549A (en) * | 2017-06-26 | 2017-11-21 | 河北晨阳工贸集团有限公司 | A kind of aqueous one-component orange-peel paint and preparation method thereof |
| CN107815220A (en) * | 2017-10-11 | 2018-03-20 | 湖南文理学院 | A kind of aqueous hammer paint applied to textile machine and preparation method thereof |
| CN107987635A (en) * | 2017-11-30 | 2018-05-04 | 青岛圣世恒业化工有限公司 | A kind of outer finishing coat applied to steel and preparation method thereof |
| CN108373638A (en) * | 2018-03-01 | 2018-08-07 | 温州环诺新材料科技有限公司 | A kind of universal aqueous mallear stria self-drying paint |
| CN109181446A (en) * | 2018-08-08 | 2019-01-11 | 云和县泊璟工贸有限公司 | A kind of roller Lacquer finish hammer tone effect aqueous clear coating and its preparation method and application |
| CN109181446B (en) * | 2018-08-08 | 2020-12-25 | 云和县泊璟工贸有限公司 | Roller finishing hammer effect water-based transparent coating and preparation method and application thereof |
| CN115537085A (en) * | 2021-11-09 | 2022-12-30 | 西藏君怡装饰材料有限公司 | Special water-based paint for Qinghai-Tibet plateau and preparation method thereof |
| CN115537085B (en) * | 2021-11-09 | 2023-11-10 | 西藏君怡装饰材料有限公司 | Special water-based paint for Tibet plateau and preparation method thereof |
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