CN109971341A - A kind of water paint that oleophobic is hydrophobic and its manufacture, spraying method - Google Patents
A kind of water paint that oleophobic is hydrophobic and its manufacture, spraying method Download PDFInfo
- Publication number
- CN109971341A CN109971341A CN201711449673.5A CN201711449673A CN109971341A CN 109971341 A CN109971341 A CN 109971341A CN 201711449673 A CN201711449673 A CN 201711449673A CN 109971341 A CN109971341 A CN 109971341A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- modified
- oleophobic
- hydrophobic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2401/00—Form of the coating product, e.g. solution, water dispersion, powders or the like
- B05D2401/20—Aqueous dispersion or solution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2401/00—Form of the coating product, e.g. solution, water dispersion, powders or the like
- B05D2401/20—Aqueous dispersion or solution
- B05D2401/21—Mixture of organic solvent and water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of water paint and its manufactures, spraying method, the object of the present invention is to provide a kind of water paints and its manufacture safe and environment-friendly, oleophobic is hydrophobic, spraying method, and the present invention includes 5-20 parts of each component nano silica of following mass parts；5-10 parts of modified organic silicone resin；It is organopolysilazane 5-20 parts modified；5-10 parts of polysiloxanes；1-5 parts of titanate coupling agent；5-20 parts of nano aluminium oxide；5-20 parts of nano zircite；1-10 parts of silicone coupling agents；0.1-1 parts of levelling agent；0.1-1 parts of wetting agent；0.5-5 parts of coalescing agent；Do not glue auxiliary agent 0.1-3 parts；0.5-5 parts of dispersing agent；0.1-2 parts of defoaming agent；1-10 parts of curing agent；10-30 parts of diluent.Present invention is mainly used for coating material productions.
Description
Technical field
The present invention relates to metal, technique for treating plastic surface more particularly to a kind of water paint that oleophobic is hydrophobic and its systems
It makes, spraying method.
Background technique
In daily life, people are easy to use inorganic combination by the surface of oil pollution in kitchen, cooking stove, disinfection cabinet etc.
Coating also has most workpiece not use coating, is so easy to be polluted by greasy dirt, is if things go on like this difficult to clean
And not acid and alkali-resistance, do not have lipophobic hydrophobic, and the existing inorganic composite dope used usually uses on surfaces such as tablewares
PTFE fluorocarbon coating and Organic silicon anti-rust paint or organosilicon powder.It is mainly had the disadvantage that using PTFE fluorocarbon coating: not ring
It protects, toxic gas is also easy to produce after heated, and toxic gas injury is found in 30 Nian Houcai, it is dangerous, it is produced after encountering high temperature
Raw dense smoke, sintering temperature is high in 380 degree of production requirements, and waste of energy, and processing is complicated, needs to carry out 3 layers and sprays, and hardness≤
2H, not wear-resisting, non-stick not strong, self-cleaning is poor, not weathering.Organic silicon anti-rust paint or organosilicon, which dust, mainly to be had the disadvantage that:
Not environmentally, oxidizable pollution environment, not weather-proof, not acidproof, not salt tolerant；Aging is fast, usually maintenance cost is expensive, and change colour fast easy tortoise
Peeling is split, hardness≤2H easily scratches.Therefore produce it is a kind of it is safe and environment-friendly, the processing is simple, and weatherability is good, maintenance cost bottom, hardness
Inorganic composite dope high, that wearability is good is extremely urgent.
Summary of the invention
The invention discloses a kind of water paint that oleophobic is hydrophobic and its manufactures, spraying method, to solve the prior art
Deficiency.
The technical solution of the invention is as follows:
A kind of water paint that oleophobic is hydrophobic, it is characterised in that: each component including following mass parts: nano silica
5-20 parts；5-10 parts of modified organic silicone resin；It is organopolysilazane 5-20 parts modified；5-10 parts of polysiloxanes；Titanate esters coupling
1-5 parts of agent；5-20 parts of nano aluminium oxide；5-20 parts of nano zircite；1-10 parts of silicone coupling agents；0.1-1 parts of levelling agent；Profit
0.1-1 parts of humectant；0.5-5 parts of coalescing agent；Do not glue auxiliary agent 0.1-3 parts；0.5-5 parts of dispersing agent；0.1-2 parts of defoaming agent；Solidification
1-10 parts of agent；10-30 parts of diluent.
Further, the diluent is water, isopropanol, ethylene glycol, butanol, ethyl alcohol, acetone, butanone, cyclohexanone, propylene glycol
Methyl ether acetate, ethyl acetate, butyl acetate, ethyl orthosilicate, butyl acetate, normal octane, N-Methyl pyrrolidone, dimethyl
One or more of formamide, dimethylbenzene, toluene, diethylene glycol monobutyl ether mixture；The dispersing agent be polyethylene wax,
Polyvinyl chloride, vinyl bis-stearamides, polyvinylpyrrolidone, polyurethane, polyethylene glycol oxide, glyceryl tristearate, carboxylic
One or more of sodium carboxymethylcellulose pyce, polyethylene glycol, polyvinyl alcohol mixture；The defoaming agent be dimethicone,
One of benzyl carbinol oleate, Laurate alcohol ester phenylacetate, organosiloxane, tributyl phosphate, polyoxypropylene and polyethers are several
Kind mixture；The levelling agent is dimethyl silicone polymer, polyether polyester azo polyether polyeste, alkyl-modified organosilicon oxygen
Alkane, terminal groups modification organosilicon, organic modified polyorganosiloxane acrylic acid and fluorin modified crylic acid ester one or more of mixtures；Institute
The wetting agent stated is dimethyl sulfoxide, polyoxyethylene, alkyl sulfate, sulfonate, phosphate, polyoxyethylated alkyl phenol, is gathered
Ethylene oxide fatty alcohol ether, one or more of polyoxyethylene polyoxypropylene block copolymer and silicon alcohol compound mixture；
The coalescing agent is one or more of mixtures of benzyl alcohol, butyl glycol ether, propylene glycol phenylate and Lauryl Alcohol ester etc.；
The not viscous auxiliary agent is high viscosity polysiloxanes, methyl-silicone oil, ethyl silicon oil, phenyl silicone oil, Methyl Hydrogen Polysiloxane Fluid, methylbenzene
Base silicone oil, methylchlorophenyl silicone oil, MethylethoxylsiliconFluid Fluid, methyl trifluoro propyl silicone oil, methyl vinyl silicon oil, methylhydroxy
Silicone oil, ethyl containing hydrogen silicone oil, hydroxyl hydrogen silicone oil, one or more of mixtures containing nitrile silicone etc.；The curing agent is second
Diamines, diethylenetriamine, diamino diphenyl sulfone, triethylene tetramine, polyethylene polyamine, dipropylenetriamine, dibenamine base ether, three
Methyl hexamethylene diamine, trimethyl one or more of diamines, polyether diamine mixture.
The manufacturing method of the hydrophobic water paint of the oleophobic the steps include: a, deionized water be added in silicone coupling agents
In solution is made, by silica be added modified siloxane coupling agent solution in and stir, be made silica dispersions；
B, diluent, dispersing agent, defoaming agent, coalescing agent, not viscous auxiliary agent, wetting agent and levelling agent are mixed, system
Obtain auxiliary agent dispersion liquid；
C, after mixing nano zircite, nano aluminium oxide, modified organic silicone resin solution, silica dispersions are added
With auxiliary agent dispersion liquid, adds polysiloxanes, titanate coupling agent, is modified high speed dispersion after organopolysilazane and curing agent
500-1000r/min, time 10-15min, until viscosity of the coating reaches 10-30Pa.S.
The spraying method of the hydrophobic water paint of the oleophobic the steps include: aa, workpiece surface carried out oil removal treatment；
Bb, coating is deployed according to spraying equipment, deployed coating is passed through to the strainer filtering of 300 mesh；
Cc, coating is sprayed into workpiece surface using spraying equipment；
Dd, by 70-160 DEG C in the workpiece to oven after spraying, toast 5-15 minutes.
Further, workpiece is impregnated at normal temperature and is stirred 2-8 minutes using alkaline defatting agent in the step aa and removed
Oil.
Further, the step dd will be toasted 15 minutes in the workpiece to oven after spraying with 160 DEG C of temperature.
The beneficial effects of the present invention are: can be reached after use using the water paint of above-mentioned technical proposal production processing
Smog is not generated under to environmental protection, 400 DEG C of high temperature resistant or more, high temperature, is had a safety feature, hardness > 6H；Coating is not easy to scrape to foreign object
Rupture；4.5KG pressure wear-resisting 3000 times or more, flexibility, hardness are high, and wearability is good, have fabulous lipophobic hydrophobic, oil
Dirt, dust, steam and some sticky substances do not adhere on surface, will not generate bacterium, rotten, not by high temperature, extremely cold
The influence of low temperature, 400 ° of high temperature resistant >, low temperature resistant < -60 °, coating compactness is relatively good, at the same have well it is non-stick,
What substance surface can be adhered to almost without, does not go manually to handle, and the chance that bacterium does not grow, production process is simple
Convenient, sintering temperature is low to be readily produced and environmental protection.
Specific embodiment
Specific embodiments of the present invention will be described in further detail below.
The present invention is characterized in that: each component including following mass parts: 5-20 parts of nano silica；Modification is organic
5-10 parts of silicone resin；It is organopolysilazane 5-20 parts modified；5-10 parts of polysiloxanes；1-5 parts of titanate coupling agent；It is nano oxidized
5-20 parts of aluminium；5-20 parts of nano zircite；1-10 parts of silicone coupling agents；0.1-1 parts of levelling agent；0.1-1 parts of wetting agent；At
0.5-5 parts of film auxiliary agent；Do not glue auxiliary agent 0.1-3 parts；0.5-5 parts of dispersing agent；0.1-2 parts of defoaming agent；1-10 parts of curing agent；Diluent
10-30 parts.
Further, the diluent is water, isopropanol, ethylene glycol, butanol, ethyl alcohol, acetone, butanone, cyclohexanone, propylene glycol
Methyl ether acetate, ethyl acetate, butyl acetate, ethyl orthosilicate, butyl acetate, normal octane, N-Methyl pyrrolidone, dimethyl
One or more of formamide, dimethylbenzene, toluene, diethylene glycol monobutyl ether mixture；The dispersing agent be polyethylene wax,
Polyvinyl chloride, vinyl bis-stearamides, polyvinylpyrrolidone, polyurethane, polyethylene glycol oxide, glyceryl tristearate, carboxylic
One or more of sodium carboxymethylcellulose pyce, polyethylene glycol, polyvinyl alcohol mixture；The defoaming agent be dimethicone,
One of benzyl carbinol oleate, Laurate alcohol ester phenylacetate, organosiloxane, tributyl phosphate, polyoxypropylene and polyethers are several
Kind mixture；The levelling agent is dimethyl silicone polymer, polyether polyester azo polyether polyeste, alkyl-modified organosilicon oxygen
Alkane, terminal groups modification organosilicon, organic modified polyorganosiloxane acrylic acid and fluorin modified crylic acid ester one or more of mixtures；Institute
The wetting agent stated is dimethyl sulfoxide, polyoxyethylene, alkyl sulfate, sulfonate, phosphate, polyoxyethylated alkyl phenol, is gathered
Ethylene oxide fatty alcohol ether, one or more of polyoxyethylene polyoxypropylene block copolymer and silicon alcohol compound mixture；
The coalescing agent is one or more of mixtures of benzyl alcohol, butyl glycol ether, propylene glycol phenylate and Lauryl Alcohol ester etc.；
The not viscous auxiliary agent is high viscosity polysiloxanes, methyl-silicone oil, ethyl silicon oil, phenyl silicone oil, Methyl Hydrogen Polysiloxane Fluid, methylbenzene
Base silicone oil, methylchlorophenyl silicone oil, MethylethoxylsiliconFluid Fluid, methyl trifluoro propyl silicone oil, methyl vinyl silicon oil, methylhydroxy
Silicone oil, ethyl containing hydrogen silicone oil, hydroxyl hydrogen silicone oil, one or more of mixtures containing nitrile silicone etc.；The curing agent is second
Diamines, diethylenetriamine, diamino diphenyl sulfone, triethylene tetramine, polyethylene polyamine, dipropylenetriamine, dibenamine base ether, three
Methyl hexamethylene diamine, trimethyl one or more of diamines, polyether diamine mixture.
The manufacturing method of the hydrophobic water paint of the oleophobic the steps include: a, deionized water be added in silicone coupling agents
In solution is made, by silica be added modified siloxane coupling agent solution in and stir, be made silica dispersions；
B, diluent, dispersing agent, defoaming agent, coalescing agent, not viscous auxiliary agent, wetting agent and levelling agent are mixed, system
Obtain auxiliary agent dispersion liquid；
C, after mixing nano zircite, nano aluminium oxide, modified organic silicone resin solution, silica dispersions are added
With auxiliary agent dispersion liquid, adds polysiloxanes, titanate coupling agent, is modified high speed dispersion after organopolysilazane and curing agent
500-1000r/min, time 10-15min, until viscosity of the coating reaches 10-30Pa.S.
The spraying method of the hydrophobic water paint of the oleophobic the steps include: aa, workpiece surface carried out oil removal treatment；
Bb, coating is deployed according to spraying equipment, deployed coating is passed through to the strainer filtering of 300 mesh；
Cc, coating is sprayed into workpiece surface using spraying equipment；
Dd, by 70-160 DEG C in the workpiece to oven after spraying, toast 5-15 minutes.
Further, workpiece is impregnated at normal temperature and is stirred 2-8 minutes using alkaline defatting agent in the step aa and removed
Oil.
Further, the step dd will be toasted 15 minutes in the workpiece to oven after spraying with 160 DEG C of temperature.
First step oil removing in actual production: if it is the workpiece for having grease, it is desirable that workpiece surface should be clean gold
It must carry out removing grease, rust before metal surface Workpiece painting.Then preliminary examination is carried out to workpiece, workpiece is impaired or greasy dirt is serious
It is not online；Followed by alkaline degreasing, determines processing time, per tour by material and greasy dirt by degreasing agent 2-3%, room temperature 2-8 points
Basicity is surveyed, it is appropriate to supplement；Work appropriate to the occasion cooperation pneumatic stirring, monthly scarfing cinder, every 3-6 month replaces tank liquor, passes through circulating water, room temperature
Holding overflow in 2 minutes, control pH value are 7-9 point, and washing is twice.
Second step matches coating: the equipment the coating produced according to the above method according to factory is used, and spray gun uses
The viscosity of coating is diluted to the viscosity that equipment uses with diluent coating, and to stir and be allowed to evenly dispersed；More than 300 mesh
Strainer filtering filters out crystalline solid.
Third step coating: coating mode is a kind of in erasing, spraying, blade coating or Best-Effort request.
The sintering of 4th step: coating is sintered by 160 DEG C/15min in baking workshop.
Above-mentioned specific embodiment is the preferred embodiment of the present invention, can not be limited the invention, and others are appointed
The change or other equivalent substitute modes what is made without departing from technical solution of the present invention, are included in protection of the invention
Within the scope of.
Claims (6)
1. a kind of water paint that oleophobic is hydrophobic, it is characterised in that: each component including following mass parts: nano silica 5-
20 parts；5-10 parts of modified organic silicone resin；It is organopolysilazane 5-20 parts modified；5-10 parts of polysiloxanes；Titanate coupling agent
1-5 parts；5-20 parts of nano aluminium oxide；5-20 parts of nano zircite；1-10 parts of silicone coupling agents；0.1-1 parts of levelling agent；Wetting
0.1-1 parts of agent；0.5-5 parts of coalescing agent；Do not glue auxiliary agent 0.1-3 parts；0.5-5 parts of dispersing agent；0.1-2 parts of defoaming agent；Curing agent
1-10 parts；10-30 parts of diluent.
2. the hydrophobic water paint of oleophobic according to claim 1, it is characterised in that: the diluent be water, isopropanol,
Ethylene glycol, butanol, ethyl alcohol, acetone, butanone, cyclohexanone, propylene glycol methyl ether acetate, ethyl acetate, butyl acetate, positive silicic acid second
Ester, butyl acetate, normal octane, N-Methyl pyrrolidone, dimethylformamide, dimethylbenzene, toluene, in diethylene glycol monobutyl ether
One or more of mixtures；The dispersing agent is polyethylene wax, polyvinyl chloride, vinyl bis-stearamides, polyvinyl pyrrole
Alkanone, polyurethane, polyethylene glycol oxide, glyceryl tristearate, sodium carboxymethylcellulose, polyethylene glycol, one in polyvinyl alcohol
Kind or several mixtures；The defoaming agent is dimethicone, benzyl carbinol oleate, Laurate alcohol ester phenylacetate, organosilicon oxygen
One or more of alkane, tributyl phosphate, polyoxypropylene and polyethers mixture；The levelling agent is polydimethylsiloxanes
Alkane, polyether polyester azo polyether polyeste, alkyl-modified organosiloxane, terminal groups modification organosilicon, organic modified polyorganosiloxane
One or more of mixtures of acrylic acid and fluorin modified crylic acid ester；The wetting agent is dimethyl sulfoxide, polyoxyethylene, alkane
Base sulfate, sulfonate, phosphate, polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block
One or more of copolymer and silicon alcohol compound mixture；The coalescing agent is benzyl alcohol, butyl glycol ether, third
One or more of mixtures of glycol phenylate and Lauryl Alcohol ester etc.；The not viscous auxiliary agent is high viscosity polysiloxanes, methyl
Silicone oil, ethyl silicon oil, phenyl silicone oil, Methyl Hydrogen Polysiloxane Fluid, methyl phenyl silicone oil, methylchlorophenyl silicone oil, methyl ethoxy silicon
Oil, hydroxyl hydrogen silicone oil, contains methyl trifluoro propyl silicone oil, methyl vinyl silicon oil, methylhydroxy silicone oil, ethyl containing hydrogen silicone oil
One or more of mixtures of nitrile silicone etc.；The curing agent is ethylenediamine, diethylenetriamine, diamino diphenyl sulfone, three
Ethylene tetramine, polyethylene polyamine, dipropylenetriamine, dibenamine base ether, trimethylhexamethylenediamine, trimethyl diamines, poly-
One or more of ether diamine mixture.
3. a kind of manufacturing method for the water paint that oleophobic is hydrophobic, the steps include: a, deionized water is added in silicone coupling agents
In solution is made, by silica be added modified siloxane coupling agent solution in and stir, be made silica dispersions；
B, diluent, dispersing agent, defoaming agent, coalescing agent, not viscous auxiliary agent, wetting agent and levelling agent are mixed, are made and help
Agent dispersing liquid；
C, after mixing nano zircite, nano aluminium oxide, modified organic silicone resin solution, silica dispersions is added and help
Agent dispersing liquid adds polysiloxanes, titanate coupling agent, is modified high speed dispersion 500- after organopolysilazane and curing agent
1000r/min, time 10-15min, until viscosity of the coating reaches 10-30Pa.S.
4. a kind of spraying method for the water paint that oleophobic is hydrophobic the steps include: aa, workpiece surface carried out oil removal treatment；
Bb, coating is deployed according to spraying equipment, deployed coating is passed through to the strainer filtering of 300 mesh；
Cc, coating is sprayed into workpiece surface using spraying equipment；
Dd, by 70-160 DEG C in the workpiece to oven after spraying, toast 5-15 minutes.
5. the spraying method of the hydrophobic water paint of oleophobic according to claim 4, it is characterized in that: in the step aa
Workpiece is impregnated at normal temperature using alkaline defatting agent and stirs oil removing in 2-8 minutes.
6. the spraying method of the hydrophobic water paint of oleophobic according to claim 4, it is characterized in that: the step dd will
It is toasted 15 minutes in workpiece to oven after spraying with 160 DEG C of temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711449673.5A CN109971341A (en) | 2017-12-27 | 2017-12-27 | A kind of water paint that oleophobic is hydrophobic and its manufacture, spraying method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711449673.5A CN109971341A (en) | 2017-12-27 | 2017-12-27 | A kind of water paint that oleophobic is hydrophobic and its manufacture, spraying method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109971341A true CN109971341A (en) | 2019-07-05 |
Family
ID=67071751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711449673.5A Pending CN109971341A (en) | 2017-12-27 | 2017-12-27 | A kind of water paint that oleophobic is hydrophobic and its manufacture, spraying method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109971341A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110409183A (en) * | 2019-08-31 | 2019-11-05 | 三赢家居用品(河源)有限公司 | A kind of free-floride water-proof aagent and its methods for making and using same |
| CN110760259A (en) * | 2019-11-05 | 2020-02-07 | 深圳市百泉河实业有限公司 | Aluminum-plastic film smooth coating liquid and coating process thereof |
| CN111334189A (en) * | 2020-04-26 | 2020-06-26 | 广东四方威凯新材料有限公司 | Anti-fouling self-cleaning coating post-treatment agent and preparation method thereof |
| CN111454625A (en) * | 2020-03-13 | 2020-07-28 | 福清市景士兰涂料有限公司 | Wear-resistant antifouling water-based paint and preparation method thereof |
| CN111647350A (en) * | 2020-04-28 | 2020-09-11 | 江苏龙蟠科技股份有限公司 | Hydrophobic scratch-resistant long-life paint surface coating and preparation method thereof |
| CN111888803A (en) * | 2020-06-30 | 2020-11-06 | 浙江传化华洋化工有限公司 | Oleate modified organic silicon defoaming agent for coating and preparation method thereof |
| CN112480817A (en) * | 2020-11-26 | 2021-03-12 | 徐玲 | Heat-curable, moisture-curable or UV-curable corrosion-inhibiting composition |
| CN113400747A (en) * | 2021-06-30 | 2021-09-17 | 中山市富日印刷材料有限公司 | Environment-friendly degradable kraft paper printing ink packaging bag and preparation method thereof |
| CN114806237A (en) * | 2022-04-29 | 2022-07-29 | 江苏金陵特种涂料有限公司 | Self-cleaning organic-inorganic hybrid antifouling paint and preparation method thereof |
| CN116657406A (en) * | 2023-05-18 | 2023-08-29 | 扬州广泰化纤有限公司 | Oil-water separation material based on polyester bottle flake regenerated fiber and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408705A (en) * | 2013-08-08 | 2013-11-27 | 中科院广州化学有限公司 | Water-borne epoxy resin and super-amphiphobic coat as well as preparation method and application of water-borne epoxy resin and super-amphiphobic coat |
| CN104073031A (en) * | 2014-06-23 | 2014-10-01 | 华南理工大学 | Super-hydrophobic surface with moisture evacuating function and preparation method thereof |
| CN104356774A (en) * | 2014-11-21 | 2015-02-18 | 苏州大乘环保建材有限公司 | Water-based anti-doodling paint and preparation method thereof |
| CN105440851A (en) * | 2015-12-16 | 2016-03-30 | 三棵树涂料股份有限公司 | High-efficiency anti-sticking transparent outer wall water-based finishing varnish and preparation method thereof |
| CN106497406A (en) * | 2016-11-08 | 2017-03-15 | 苏州蓝锐纳米科技有限公司 | A kind of nano superhydrophobic coating and its production technology |
| CN106700927A (en) * | 2017-01-19 | 2017-05-24 | 北京国电富通科技发展有限责任公司 | Long-acting self-cleaning and antifouling paint as well as preparation and application methods thereof |
-
2017
- 2017-12-27 CN CN201711449673.5A patent/CN109971341A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408705A (en) * | 2013-08-08 | 2013-11-27 | 中科院广州化学有限公司 | Water-borne epoxy resin and super-amphiphobic coat as well as preparation method and application of water-borne epoxy resin and super-amphiphobic coat |
| CN104073031A (en) * | 2014-06-23 | 2014-10-01 | 华南理工大学 | Super-hydrophobic surface with moisture evacuating function and preparation method thereof |
| CN104356774A (en) * | 2014-11-21 | 2015-02-18 | 苏州大乘环保建材有限公司 | Water-based anti-doodling paint and preparation method thereof |
| CN105440851A (en) * | 2015-12-16 | 2016-03-30 | 三棵树涂料股份有限公司 | High-efficiency anti-sticking transparent outer wall water-based finishing varnish and preparation method thereof |
| CN106497406A (en) * | 2016-11-08 | 2017-03-15 | 苏州蓝锐纳米科技有限公司 | A kind of nano superhydrophobic coating and its production technology |
| CN106700927A (en) * | 2017-01-19 | 2017-05-24 | 北京国电富通科技发展有限责任公司 | Long-acting self-cleaning and antifouling paint as well as preparation and application methods thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110409183A (en) * | 2019-08-31 | 2019-11-05 | 三赢家居用品(河源)有限公司 | A kind of free-floride water-proof aagent and its methods for making and using same |
| CN110760259A (en) * | 2019-11-05 | 2020-02-07 | 深圳市百泉河实业有限公司 | Aluminum-plastic film smooth coating liquid and coating process thereof |
| CN111454625A (en) * | 2020-03-13 | 2020-07-28 | 福清市景士兰涂料有限公司 | Wear-resistant antifouling water-based paint and preparation method thereof |
| CN111334189B (en) * | 2020-04-26 | 2021-10-15 | 广东四方威凯新材料有限公司 | Anti-fouling self-cleaning coating post-treatment agent and preparation method thereof |
| CN111334189A (en) * | 2020-04-26 | 2020-06-26 | 广东四方威凯新材料有限公司 | Anti-fouling self-cleaning coating post-treatment agent and preparation method thereof |
| CN111647350A (en) * | 2020-04-28 | 2020-09-11 | 江苏龙蟠科技股份有限公司 | Hydrophobic scratch-resistant long-life paint surface coating and preparation method thereof |
| CN111888803B (en) * | 2020-06-30 | 2021-10-29 | 浙江传化华洋化工有限公司 | Oleate modified organic silicon defoaming agent for coating and preparation method thereof |
| CN111888803A (en) * | 2020-06-30 | 2020-11-06 | 浙江传化华洋化工有限公司 | Oleate modified organic silicon defoaming agent for coating and preparation method thereof |
| CN112480817A (en) * | 2020-11-26 | 2021-03-12 | 徐玲 | Heat-curable, moisture-curable or UV-curable corrosion-inhibiting composition |
| CN112480817B (en) * | 2020-11-26 | 2021-11-30 | 徐玲 | Heat-curable, moisture-curable or UV-curable corrosion-inhibiting composition |
| CN113400747A (en) * | 2021-06-30 | 2021-09-17 | 中山市富日印刷材料有限公司 | Environment-friendly degradable kraft paper printing ink packaging bag and preparation method thereof |
| CN114806237A (en) * | 2022-04-29 | 2022-07-29 | 江苏金陵特种涂料有限公司 | Self-cleaning organic-inorganic hybrid antifouling paint and preparation method thereof |
| CN116657406A (en) * | 2023-05-18 | 2023-08-29 | 扬州广泰化纤有限公司 | Oil-water separation material based on polyester bottle flake regenerated fiber and preparation method thereof |
| CN116657406B (en) * | 2023-05-18 | 2023-12-05 | 扬州广泰化纤有限公司 | Oil-water separation material based on polyester bottle flake regenerated fiber and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109971341A (en) | A kind of water paint that oleophobic is hydrophobic and its manufacture, spraying method | |
| CN101885943B (en) | Nano-glass heat insulation paint and preparation method thereof | |
| CN105111867A (en) | Water-based environment-friendly porcelain glaze-like plastic coating and preparation method thereof | |
| CN107151493A (en) | Aqueous PVDF fluorocarbon coatings and its coating process | |
| CN102146243A (en) | Waterborne single-component thermoplastic plastic paint and production method and construction method thereof | |
| CN103614032A (en) | Water-based paint | |
| CN110204978A (en) | A kind of aqueous plastic coating and preparation method thereof and application method | |
| CN108641424B (en) | Waterproof disc and preparation method thereof | |
| CN108329727A (en) | A kind of self-drying aqueous ceramic coating and preparation method | |
| CN102993796A (en) | Metal anti-rust paint and preparation method thereof | |
| CN1329465C (en) | Thermostable rustproof metallic paint and preparation method thereof | |
| CN105295459A (en) | Ecological shell powder wall paint | |
| CN108384447A (en) | It is a kind of can bat printing multicolour pattern type ceramic coating and preparation method | |
| CN111334136B (en) | Long-acting oil-proof coating and preparation method thereof | |
| CN105131831A (en) | Stone material surface anti-fouling paint and method of applying same to marble surface for preventing fouling | |
| CN110218472A (en) | A kind of strippable water-based paint | |
| CN102888156A (en) | Uvioresistant fluorocarbon metal anti-rust paint and preparation method thereof | |
| CN103013243A (en) | Nanometre modified high self-cleaning solar heat reflecting paint and preparation method thereof | |
| CN105419445A (en) | Automatic cleaning finish for exterior walls, and preparation method thereof | |
| KR19990028788A (en) | Hard Surface Liquid Cleaner Composition and Hard Surface Cleaning Method | |
| CN103436166B (en) | Building surface nano protecting liquid and preparation method thereof | |
| CN105925166B (en) | A kind of high anti-corrosion household electrical appliances primer base of solvent-borne type and preparation method and application | |
| CN110982387B (en) | Water-based epoxy coating with good adhesive force and corrosion resistance on surface of metal substrate and preparation method thereof | |
| CN105272380B (en) | A kind of preparation method and equipment of dumb light brick | |
| CN109370412A (en) | A kind of environment-friendly water-based polyurethane coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190705 |