CN103205077B - 丙烯酸共混物 - Google Patents
丙烯酸共混物 Download PDFInfo
- Publication number
- CN103205077B CN103205077B CN201310092959.8A CN201310092959A CN103205077B CN 103205077 B CN103205077 B CN 103205077B CN 201310092959 A CN201310092959 A CN 201310092959A CN 103205077 B CN103205077 B CN 103205077B
- Authority
- CN
- China
- Prior art keywords
- hmwa
- polymer
- alkyl
- lmwa
- product according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 108
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims description 56
- 229920000642 polymer Polymers 0.000 claims abstract description 150
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 68
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 59
- 238000000034 method Methods 0.000 claims abstract description 33
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 19
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 18
- 125000005250 alkyl acrylate group Chemical group 0.000 claims abstract description 11
- 229920001577 copolymer Polymers 0.000 claims description 58
- 239000000178 monomer Substances 0.000 claims description 34
- 238000002156 mixing Methods 0.000 claims description 29
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 20
- 125000005907 alkyl ester group Chemical group 0.000 claims description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 18
- 239000004609 Impact Modifier Substances 0.000 claims description 16
- 239000012803 melt mixture Substances 0.000 claims description 13
- 239000011258 core-shell material Substances 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 4
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 4
- 238000012662 bulk polymerization Methods 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 15
- 239000004926 polymethyl methacrylate Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 13
- 230000009477 glass transition Effects 0.000 description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
- 239000000155 melt Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 229920005601 base polymer Polymers 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000012512 characterization method Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229920000193 polymethacrylate Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 229920000891 common polymer Polymers 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 238000004627 transmission electron microscopy Methods 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical group CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- -1 PMMA Chemical compound 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000004590 computer program Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000003550 marker Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 206010042618 Surgical procedure repeated Diseases 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0508255.7A GB0508255D0 (en) | 2005-04-25 | 2005-04-25 | Acrylic blends |
| GB0508255.7 | 2005-04-25 | ||
| CN2006800139408A CN101166787B (zh) | 2005-04-25 | 2006-04-18 | 丙烯酸共混物 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800139408A Division CN101166787B (zh) | 2005-04-25 | 2006-04-18 | 丙烯酸共混物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103205077A CN103205077A (zh) | 2013-07-17 |
| CN103205077B true CN103205077B (zh) | 2015-09-09 |
Family
ID=34640022
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310092959.8A Expired - Fee Related CN103205077B (zh) | 2005-04-25 | 2006-04-18 | 丙烯酸共混物 |
| CN2013100928932A Pending CN103254537A (zh) | 2005-04-25 | 2006-04-18 | 丙烯酸共混物 |
| CN2006800139408A Expired - Fee Related CN101166787B (zh) | 2005-04-25 | 2006-04-18 | 丙烯酸共混物 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013100928932A Pending CN103254537A (zh) | 2005-04-25 | 2006-04-18 | 丙烯酸共混物 |
| CN2006800139408A Expired - Fee Related CN101166787B (zh) | 2005-04-25 | 2006-04-18 | 丙烯酸共混物 |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US8263706B2 (enExample) |
| EP (5) | EP2277946B1 (enExample) |
| JP (5) | JP5285422B2 (enExample) |
| KR (1) | KR101420691B1 (enExample) |
| CN (3) | CN103205077B (enExample) |
| AU (1) | AU2006238988B2 (enExample) |
| CA (1) | CA2603957C (enExample) |
| DK (1) | DK1877486T3 (enExample) |
| ES (5) | ES2671385T3 (enExample) |
| GB (1) | GB0508255D0 (enExample) |
| MX (4) | MX340193B (enExample) |
| PL (3) | PL1877486T5 (enExample) |
| PT (1) | PT1877486E (enExample) |
| RU (1) | RU2418828C2 (enExample) |
| SI (1) | SI1877486T1 (enExample) |
| TW (1) | TWI504657B (enExample) |
| WO (1) | WO2006114576A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0508255D0 (en) | 2005-04-25 | 2005-06-01 | Lucite Int Uk Ltd | Acrylic blends |
| DE102006053390A1 (de) * | 2006-11-10 | 2008-05-15 | Lanxess Deutschland Gmbh | Verfahren zur Bestimmung einer Molekulargewichtsverteilung in einem Polymer |
| GB0711017D0 (en) * | 2007-06-08 | 2007-07-18 | Lucite Int Uk Ltd | Polymer Composition |
| JPWO2010140317A1 (ja) * | 2009-06-01 | 2012-11-15 | 株式会社カネカ | 発泡性成形用加工性改良剤、及びこれを含有する塩化ビニル系樹脂組成物 |
| US8835544B2 (en) | 2009-11-17 | 2014-09-16 | Arkema France | Impact resistant acrylic alloy |
| US9987820B2 (en) | 2009-11-17 | 2018-06-05 | Arkema France | Multilayer structures containing biopolymers |
| JP2012111860A (ja) * | 2010-11-25 | 2012-06-14 | Sumitomo Chemical Co Ltd | 車両部材用メタクリル樹脂組成物 |
| KR101436080B1 (ko) * | 2010-12-29 | 2014-08-29 | 제일모직주식회사 | 열안정성이 우수한 열가소성수지 조성물 |
| JP5249366B2 (ja) | 2011-01-26 | 2013-07-31 | 住友化学株式会社 | 連続重合装置および重合体組成物の製造方法 |
| JP5431376B2 (ja) | 2011-01-26 | 2014-03-05 | 住友化学株式会社 | 連続重合装置および重合体組成物の製造方法 |
| KR101394814B1 (ko) * | 2011-11-23 | 2014-05-14 | (주)엘지하우시스 | 투명성 및 내충격성이 우수한 아크릴 수지 필름 및 그 제조 방법 |
| DE102012207100A1 (de) * | 2012-04-27 | 2013-10-31 | Evonik Industries Ag | Coextrudierte schlagzähmodifizierte PMMA-Folie |
| JP6002017B2 (ja) | 2012-12-03 | 2016-10-05 | 住友化学株式会社 | メタクリル系重合体組成物の製造方法 |
| JP2015010948A (ja) * | 2013-06-28 | 2015-01-19 | キヤノン株式会社 | 物品処理装置、生成方法、およびプログラム |
| EP3432893B1 (en) * | 2016-03-25 | 2022-10-26 | Trinseo Europe GmbH | Enhanced melt strength acrylic formulation |
| FR3053348B1 (fr) * | 2016-06-29 | 2020-03-27 | Arkema France | Composition comprenant un polymere a phases multiples et deux polymeres (meth)acryliques differents, son procede de preparation et article la compenant |
| EP3481910B1 (en) | 2016-07-06 | 2020-08-19 | Eastman Chemical Company | (meth)acrylic oligomers |
| JP6986514B2 (ja) | 2016-10-04 | 2021-12-22 | 住友化学株式会社 | メタクリル樹脂組成物およびその成形体 |
| JP7328989B2 (ja) * | 2018-11-30 | 2023-08-17 | 株式会社クラレ | （メタ）アクリル系樹脂組成物及び（メタ）アクリル系樹脂フィルム |
| EP3805312B1 (en) | 2019-10-08 | 2023-12-06 | Trinseo Europe GmbH | Impact modified copolymers of (meth)acrylate esters and/or free radically polymerizable monomers containing nucleophilic groups |
| EP4455206A4 (en) * | 2021-12-20 | 2025-04-02 | Mitsubishi Chemical Corporation | METHACRYLIC RESIN COMPOSITION FOR INJECTION MOLDING OR EXTRUSION MOLDING, RESIN MOLDED BODY AND PRODUCTION METHOD THEREOF |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1986005503A1 (en) * | 1985-03-14 | 1986-09-25 | Avery International Corporation | Pressure-sensitive adhesives based on similar polymers |
| EP1013713A1 (en) * | 1998-12-22 | 2000-06-28 | H.B. Fuller Coatings Ltd. | Flame retardant polymer composition |
| CN1335872A (zh) * | 1999-06-17 | 2002-02-13 | 罗姆两合公司 | 改善流动性的抗冲改性聚甲基丙烯酸酯模塑材料 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB505255A (en) | 1937-11-04 | 1939-05-04 | William Jepson | Float-actuated valve-releasing mechanism |
| US3632366A (en) * | 1968-01-11 | 1972-01-04 | Asahi Glass Co Ltd | Method of producing moldable reinforced thermoplastic material |
| GB1286272A (en) * | 1968-09-16 | 1972-08-23 | Rohm & Haas | Thermoformable acrylic sheet |
| US3867481A (en) * | 1970-06-02 | 1975-02-18 | Rohm & Haas | Low molecular weight acrylic modifiers for rigid vinyl halide polymers |
| JPS5346861B2 (enExample) * | 1972-04-11 | 1978-12-16 | ||
| JPS6013168B2 (ja) | 1977-07-25 | 1985-04-05 | 富士ゼロツクス株式会社 | 電子写真トナ− |
| JPS5837348B2 (ja) | 1979-06-30 | 1983-08-16 | 日東電工株式会社 | 水分散型感圧接着剤組成物 |
| GB8329249D0 (en) | 1983-11-02 | 1983-12-07 | Allied Colloids Ltd | Materials in drilling muds |
| US5063259A (en) | 1990-07-03 | 1991-11-05 | Rohm And Haas Company | Clear, impact-resistant plastics |
| US5344891A (en) * | 1990-07-07 | 1994-09-06 | Mitsubishi Rayon Co., Ltd. | Biodegradable polymers |
| KR930006089A (ko) | 1991-09-18 | 1993-04-20 | 제이 이이 휘립프스 | 폴리에틸렌 블렌드 |
| CA2078366A1 (en) | 1991-09-18 | 1993-03-19 | Joel L. Martin | Polyethylene blends |
| KR930006091A (ko) | 1991-09-18 | 1993-04-20 | 제이 이이 휘립프스 | 폴리에틸렌 블렌드 및 그로부터 제조된 필름, 병 또는 파이프 |
| CA2099750C (en) | 1992-09-01 | 1996-05-07 | William Richard Coutant | Process for producing polymer blends |
| US5322731A (en) | 1993-03-09 | 1994-06-21 | Minnesota Mining And Manufacturing Company | Adhesive beads |
| JP3564641B2 (ja) | 1993-06-01 | 2004-09-15 | ザ、トップ・フライト、ゴルフ、カムパニ | 改良された多重層ゴルフボール |
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