CN103130796A - 一种3-叔丁基吡唑酰胺类化合物及其应用 - Google Patents
一种3-叔丁基吡唑酰胺类化合物及其应用 Download PDFInfo
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- CN103130796A CN103130796A CN2013100438420A CN201310043842A CN103130796A CN 103130796 A CN103130796 A CN 103130796A CN 2013100438420 A CN2013100438420 A CN 2013100438420A CN 201310043842 A CN201310043842 A CN 201310043842A CN 103130796 A CN103130796 A CN 103130796A
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- tertiary butyl
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- -1 3-tertiary butyl pyrazole amides compounds Chemical class 0.000 title claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 33
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 6
- 241000238631 Hexapoda Species 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 5
- 230000000749 insecticidal effect Effects 0.000 abstract description 4
- 229910052794 bromium Inorganic materials 0.000 abstract description 3
- 230000002265 prevention Effects 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 description 36
- 238000004809 thin layer chromatography Methods 0.000 description 28
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 238000003756 stirring Methods 0.000 description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 238000000967 suction filtration Methods 0.000 description 14
- 238000005406 washing Methods 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000001816 cooling Methods 0.000 description 11
- 238000010792 warming Methods 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- GFAUNYMRSKVDJL-UHFFFAOYSA-N formyl chloride Chemical compound ClC=O GFAUNYMRSKVDJL-UHFFFAOYSA-N 0.000 description 10
- 239000002994 raw material Substances 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- 238000009835 boiling Methods 0.000 description 9
- 238000001035 drying Methods 0.000 description 9
- 239000012065 filter cake Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000012044 organic layer Substances 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- 241001498622 Cixius wagneri Species 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- LOXQQUJUBRXMHJ-UHFFFAOYSA-N 5-bromo-2-methylpyrazole-3-carboxylic acid Chemical compound CN1N=C(Br)C=C1C(O)=O LOXQQUJUBRXMHJ-UHFFFAOYSA-N 0.000 description 5
- CSKGTUGORXMNNS-UHFFFAOYSA-N 5-chloro-2-methylpyrazole-3-carboxylic acid Chemical compound CN1N=C(Cl)C=C1C(O)=O CSKGTUGORXMNNS-UHFFFAOYSA-N 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
- JCOHRMJIHAFFBC-UHFFFAOYSA-N ethyl 5-tert-butyl-2-methylpyrazole-3-carboxylate Chemical compound CCOC(=O)C1=CC(C(C)(C)C)=NN1C JCOHRMJIHAFFBC-UHFFFAOYSA-N 0.000 description 5
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 5
- 238000005160 1H NMR spectroscopy Methods 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 230000008034 disappearance Effects 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000005457 ice water Substances 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 0 CC(C)(C)c1n[n](C)c(C(N*)=O)c1* Chemical compound CC(C)(C)c1n[n](C)c(C(N*)=O)c1* 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- 229940125904 compound 1 Drugs 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000003457 sulfones Chemical class 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- XPARFBOWIYMLMY-UHFFFAOYSA-N (6-chloropyridin-3-yl)methanamine Chemical compound NCC1=CC=C(Cl)N=C1 XPARFBOWIYMLMY-UHFFFAOYSA-N 0.000 description 2
- SFSXXMXHJOSBAZ-UHFFFAOYSA-N 5-tert-butyl-2-methylpyrazole-3-carboxylic acid Chemical compound CN1N=C(C(C)(C)C)C=C1C(O)=O SFSXXMXHJOSBAZ-UHFFFAOYSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- WYACBZDAHNBPPB-UHFFFAOYSA-N diethyl oxalate Chemical compound CCOC(=O)C(=O)OCC WYACBZDAHNBPPB-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- RCXMILPYEKVQLB-UHFFFAOYSA-N ethyl 5-tert-butyl-1h-pyrazole-3-carboxylate Chemical compound CCOC(=O)C=1C=C(C(C)(C)C)NN=1 RCXMILPYEKVQLB-UHFFFAOYSA-N 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- VRMUIVKEHJSADG-UHFFFAOYSA-N 2-chloro-5-(chloromethyl)-1,3-thiazole Chemical compound ClCC1=CN=C(Cl)S1 VRMUIVKEHJSADG-UHFFFAOYSA-N 0.000 description 1
- OOKGNGYUNBYGEL-UHFFFAOYSA-N 5-bromo-1h-pyrazole-3-carboxylic acid Chemical compound OC(=O)C=1C=C(Br)NN=1 OOKGNGYUNBYGEL-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000005925 Pymetrozine Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229940125773 compound 10 Drugs 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- PJGSXYOJTGTZAV-UHFFFAOYSA-N pinacolone Chemical compound CC(=O)C(C)(C)C PJGSXYOJTGTZAV-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
Description
化合物 | 浓度(ppm) | 校正死亡率(%) |
1 | 10 | 76.52 |
2 | 10 | 68.34 |
4 | 10 | 80.50 |
5 | 10 | 56.08 |
9 | 10 | 68.73 |
KC | 10 | 59.07 |
Claims (3)
Priority Applications (1)
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CN201310043842.0A CN103130796B (zh) | 2013-01-25 | 2013-01-25 | 一种3-叔丁基吡唑酰胺类化合物及其应用 |
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CN201310043842.0A CN103130796B (zh) | 2013-01-25 | 2013-01-25 | 一种3-叔丁基吡唑酰胺类化合物及其应用 |
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CN103130796A true CN103130796A (zh) | 2013-06-05 |
CN103130796B CN103130796B (zh) | 2015-07-29 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103755700A (zh) * | 2013-12-26 | 2014-04-30 | 青岛科技大学 | 一种新型吡唑酰胺类化合物及其用途 |
CN108203450A (zh) * | 2016-12-19 | 2018-06-26 | 南京工业大学 | 一种含氨基膦酸酯芳基吡唑类化合物的制备方法及应用 |
CN109535154A (zh) * | 2018-12-14 | 2019-03-29 | 南通大学 | 含4-芳基噻唑结构的吡唑酰胺类化合物及其制备方法和用途 |
Citations (4)
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US5185354A (en) * | 1990-06-18 | 1993-02-09 | Mitsubishi Kasei Corporation | Pyrazolecarboxamide, insecticidal and miticidal composition, and fungicidal composition for use in agriculture and horticulture |
JPH05255268A (ja) * | 1992-03-17 | 1993-10-05 | Mitsubishi Kasei Corp | ピラゾールカルボキサミド類、これを有効成分とする殺虫、殺ダニ剤および農園芸用殺菌剤 |
JPH07173139A (ja) * | 1991-04-05 | 1995-07-11 | Mitsubishi Chem Corp | アルコキシピラゾールカルボキサミド類、これを有効成分とする殺虫・殺ダニ剤および農園芸用殺菌剤 |
CN1541063A (zh) * | 2001-08-13 | 2004-10-27 | ��Ļ���Ű˾ | 使用邻氨基苯甲酰胺化合物防治特殊害虫的方法 |
-
2013
- 2013-01-25 CN CN201310043842.0A patent/CN103130796B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US5185354A (en) * | 1990-06-18 | 1993-02-09 | Mitsubishi Kasei Corporation | Pyrazolecarboxamide, insecticidal and miticidal composition, and fungicidal composition for use in agriculture and horticulture |
JPH07173139A (ja) * | 1991-04-05 | 1995-07-11 | Mitsubishi Chem Corp | アルコキシピラゾールカルボキサミド類、これを有効成分とする殺虫・殺ダニ剤および農園芸用殺菌剤 |
JPH05255268A (ja) * | 1992-03-17 | 1993-10-05 | Mitsubishi Kasei Corp | ピラゾールカルボキサミド類、これを有効成分とする殺虫、殺ダニ剤および農園芸用殺菌剤 |
CN1541063A (zh) * | 2001-08-13 | 2004-10-27 | ��Ļ���Ű˾ | 使用邻氨基苯甲酰胺化合物防治特殊害虫的方法 |
Non-Patent Citations (1)
Title |
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王宝珠,等: "嘧啶酮类衍生物的合成及杀虫活性", 《农药学学报》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103755700A (zh) * | 2013-12-26 | 2014-04-30 | 青岛科技大学 | 一种新型吡唑酰胺类化合物及其用途 |
CN103755700B (zh) * | 2013-12-26 | 2015-07-29 | 青岛科技大学 | 一种吡唑酰胺类化合物及其用途 |
CN108203450A (zh) * | 2016-12-19 | 2018-06-26 | 南京工业大学 | 一种含氨基膦酸酯芳基吡唑类化合物的制备方法及应用 |
CN108203450B (zh) * | 2016-12-19 | 2020-05-19 | 南京工业大学 | 一种含氨基膦酸酯芳基吡唑类化合物的制备方法及应用 |
CN109535154A (zh) * | 2018-12-14 | 2019-03-29 | 南通大学 | 含4-芳基噻唑结构的吡唑酰胺类化合物及其制备方法和用途 |
CN109535154B (zh) * | 2018-12-14 | 2021-09-10 | 南通大学 | 含4-芳基噻唑结构的吡唑酰胺类化合物及其制备方法和用途 |
Also Published As
Publication number | Publication date |
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CN103130796B (zh) | 2015-07-29 |
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