CN103118764A - 用于选择性还原NOx的含铜ZSM-34、OFF和/或ERI沸石材料 - Google Patents

用于选择性还原NOx的含铜ZSM-34、OFF和/或ERI沸石材料 Download PDF

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Publication number
CN103118764A
CN103118764A CN2011800439795A CN201180043979A CN103118764A CN 103118764 A CN103118764 A CN 103118764A CN 2011800439795 A CN2011800439795 A CN 2011800439795A CN 201180043979 A CN201180043979 A CN 201180043979A CN 103118764 A CN103118764 A CN 103118764A
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China
Prior art keywords
zsm
copper
cupric
zeolitic material
eri
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CN2011800439795A
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Chinese (zh)
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I·布尔
U·米勒
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BASF SE
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BASF SE
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Application filed by BASF SE filed Critical BASF SE
Publication of CN103118764A publication Critical patent/CN103118764A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B01J29/52—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
    • B01J29/56—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/202—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
CN2011800439795A 2010-07-15 2011-07-13 用于选择性还原NOx的含铜ZSM-34、OFF和/或ERI沸石材料 Pending CN103118764A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10169692.0 2010-07-15
EP10169692 2010-07-15
PCT/IB2011/053126 WO2012007914A2 (en) 2010-07-15 2011-07-13 Copper containing zsm-34, off and/or eri zeolitic material for selective reduction of nox

Publications (1)

Publication Number Publication Date
CN103118764A true CN103118764A (zh) 2013-05-22

Family

ID=45469862

Family Applications (1)

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CN2011800439795A Pending CN103118764A (zh) 2010-07-15 2011-07-13 用于选择性还原NOx的含铜ZSM-34、OFF和/或ERI沸石材料

Country Status (7)

Country Link
EP (1) EP2593212B2 (https=)
JP (1) JP5902682B2 (https=)
KR (1) KR20130041943A (https=)
CN (1) CN103118764A (https=)
BR (1) BR112013001018A2 (https=)
IN (1) IN2013CN00093A (https=)
WO (1) WO2012007914A2 (https=)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106232209A (zh) * 2014-03-24 2016-12-14 庄信万丰股份有限公司 用于处理废气的系统和方法
CN107081168A (zh) * 2016-02-12 2017-08-22 现代自动车株式会社 制备沸石催化剂的方法
CN107427777A (zh) * 2015-03-25 2017-12-01 庄信万丰股份有限公司 包含贵金属和具有OFF骨架类型的分子筛的被动NOx吸附剂
CN108472586A (zh) * 2016-02-01 2018-08-31 优美科股份公司及两合公司 在包含基本上不含碱金属的fe-aei沸石材料的催化剂的存在下从尾气中去除一氧化二氮的方法
US10981153B2 (en) 2016-02-12 2021-04-20 Hyundai Motor Company Catalyst and method for preparing catalyst
CN113795331A (zh) * 2019-05-09 2021-12-14 巴斯夫公司 包含碳酸铜的选择性催化还原催化剂

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5883000B2 (ja) 2010-07-15 2016-03-09 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ＮＯｘの選択的還元用の銅含有ＺＳＭ−３４、オフレタイト（ＯＦＦ）及び／又はエリオナイト（ＥＲＩ）ゼオライト材料
US9527751B2 (en) 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
US9782761B2 (en) 2013-10-03 2017-10-10 Ford Global Technologies, Llc Selective catalytic reduction catalyst

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1439457A (zh) * 2003-03-27 2003-09-03 南开大学 用于汽车尾气处理的催化剂及制备方法
CN1711134A (zh) * 2002-11-18 2005-12-21 株式会社Ict 废气净化用催化剂与废气净化方法
JP2006055771A (ja) * 2004-08-20 2006-03-02 Idemitsu Kosan Co Ltd 金属担持ゼオライト成型体の製造方法及び該ゼオライトを含有する硫黄化合物除去用吸着剤
US20070134146A1 (en) * 2005-12-14 2007-06-14 Ivor Bull Zeolite catalyst with improved NOX reduction in SCR

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NL238953A (https=) 1958-05-08
US4086186A (en) 1976-11-04 1978-04-25 Mobil Oil Corporation Crystalline zeolite ZSM-34 and method of preparing the same
NZ185397A (en) * 1976-11-04 1979-12-11 Mobil Oil Corp Crystalline aluminosilicate zeolites and use as catalysts
FR2575741B1 (fr) * 1985-01-09 1990-03-16 Inst Francais Du Petrole Obtention d'une offretite synthetique riche en silice. application a la production d'hydrocarbures riches en olefines legeres par transformation du methanol et/ou de dimethylether
JPH0639415B2 (ja) * 1988-03-11 1994-05-25 軽質留分新用途開発技術研究組合 プロピレンを主成分とする低級オレフィンの製造方法
JP3242126B2 (ja) * 1991-06-17 2001-12-25 日石三菱株式会社 窒素酸化物の除去方法
WO2006006702A1 (ja) * 2004-07-15 2006-01-19 Nikki-Universal Co., Ltd. 有機窒素化合物含有排ガスの浄化用触媒、および同排ガスの浄化方法
EP3981502B8 (en) * 2007-04-26 2025-04-16 Johnson Matthey Public Limited Company Transition metal/zeolite scr catalysts
US10583424B2 (en) 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1711134A (zh) * 2002-11-18 2005-12-21 株式会社Ict 废气净化用催化剂与废气净化方法
CN1439457A (zh) * 2003-03-27 2003-09-03 南开大学 用于汽车尾气处理的催化剂及制备方法
JP2006055771A (ja) * 2004-08-20 2006-03-02 Idemitsu Kosan Co Ltd 金属担持ゼオライト成型体の製造方法及び該ゼオライトを含有する硫黄化合物除去用吸着剤
US20070134146A1 (en) * 2005-12-14 2007-06-14 Ivor Bull Zeolite catalyst with improved NOX reduction in SCR

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106232209A (zh) * 2014-03-24 2016-12-14 庄信万丰股份有限公司 用于处理废气的系统和方法
CN106232209B (zh) * 2014-03-24 2022-09-02 庄信万丰股份有限公司 用于处理废气的系统和方法
CN107427777A (zh) * 2015-03-25 2017-12-01 庄信万丰股份有限公司 包含贵金属和具有OFF骨架类型的分子筛的被动NOx吸附剂
CN108472586A (zh) * 2016-02-01 2018-08-31 优美科股份公司及两合公司 在包含基本上不含碱金属的fe-aei沸石材料的催化剂的存在下从尾气中去除一氧化二氮的方法
US11224868B2 (en) 2016-02-01 2022-01-18 Umicore Ag & Co. Kg Method for the removal of nitrous oxide from off gas in presence of catalyst comprising an Fe-AEI zeolite material essentially free of alkali metal
CN107081168A (zh) * 2016-02-12 2017-08-22 现代自动车株式会社 制备沸石催化剂的方法
US10981153B2 (en) 2016-02-12 2021-04-20 Hyundai Motor Company Catalyst and method for preparing catalyst
CN107081168B (zh) * 2016-02-12 2021-08-27 现代自动车株式会社 制备沸石催化剂的方法
CN113795331A (zh) * 2019-05-09 2021-12-14 巴斯夫公司 包含碳酸铜的选择性催化还原催化剂

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Publication number Publication date
JP2013535317A (ja) 2013-09-12
EP2593212B1 (en) 2015-12-16
BR112013001018A2 (pt) 2016-05-24
JP5902682B2 (ja) 2016-04-13
EP2593212A2 (en) 2013-05-22
IN2013CN00093A (https=) 2015-07-03
WO2012007914A2 (en) 2012-01-19
KR20130041943A (ko) 2013-04-25
EP2593212A4 (en) 2014-02-12
EP2593212B2 (en) 2021-06-02
WO2012007914A3 (en) 2012-03-08

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