CN103104046B - A kind of construction wall thermal insulating composite panel and preparation method thereof - Google Patents
A kind of construction wall thermal insulating composite panel and preparation method thereof Download PDFInfo
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- CN103104046B CN103104046B CN201310039386.2A CN201310039386A CN103104046B CN 103104046 B CN103104046 B CN 103104046B CN 201310039386 A CN201310039386 A CN 201310039386A CN 103104046 B CN103104046 B CN 103104046B
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- 239000002131 composite material Substances 0.000 title claims abstract description 72
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000010276 construction Methods 0.000 title claims description 28
- 238000009413 insulation Methods 0.000 claims abstract description 97
- 239000006260 foam Substances 0.000 claims abstract description 93
- 239000000463 material Substances 0.000 claims abstract description 82
- 239000004814 polyurethane Substances 0.000 claims abstract description 56
- 229920002635 polyurethane Polymers 0.000 claims abstract description 55
- 239000004568 cement Substances 0.000 claims abstract description 30
- 229920001971 elastomer Polymers 0.000 claims abstract description 26
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 26
- 239000011810 insulating material Substances 0.000 claims abstract description 15
- 239000003063 flame retardant Substances 0.000 claims description 107
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 70
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 40
- 229920000570 polyether Polymers 0.000 claims description 40
- 239000000839 emulsion Substances 0.000 claims description 36
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- -1 chloro flame retardant Chemical compound 0.000 claims description 26
- 238000004519 manufacturing process Methods 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 23
- 239000004604 Blowing Agent Substances 0.000 claims description 21
- 239000003381 stabilizer Substances 0.000 claims description 19
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 18
- 229920005862 polyol Polymers 0.000 claims description 17
- 150000003077 polyols Chemical class 0.000 claims description 17
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 230000015572 biosynthetic process Effects 0.000 claims description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 15
- 239000011256 inorganic filler Substances 0.000 claims description 15
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 10
- 238000005187 foaming Methods 0.000 claims description 9
- 229920001228 polyisocyanate Polymers 0.000 claims description 9
- 239000005056 polyisocyanate Substances 0.000 claims description 9
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims description 8
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 claims description 8
- 101710130081 Aspergillopepsin-1 Proteins 0.000 claims description 8
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 8
- 230000007613 environmental effect Effects 0.000 claims description 8
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 229920005906 polyester polyol Polymers 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 claims description 7
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 7
- PZBFGYYEXUXCOF-UHFFFAOYSA-N TCEP Chemical compound OC(=O)CCP(CCC(O)=O)CCC(O)=O PZBFGYYEXUXCOF-UHFFFAOYSA-N 0.000 claims description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 7
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 7
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 7
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 7
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 claims description 7
- 239000002270 dispersing agent Substances 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000010030 laminating Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 6
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002956 ash Substances 0.000 claims description 5
- 229940008099 dimethicone Drugs 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 238000003786 synthesis reaction Methods 0.000 claims description 5
- 239000012970 tertiary amine catalyst Substances 0.000 claims description 5
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- 239000011152 fibreglass Substances 0.000 claims description 4
- 239000010881 fly ash Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 150000007974 melamines Chemical class 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 4
- 125000005375 organosiloxane group Chemical group 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- KNXVOGGZOFOROK-UHFFFAOYSA-N trimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane Chemical compound [Mg+2].[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O KNXVOGGZOFOROK-UHFFFAOYSA-N 0.000 claims description 4
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 3
- 239000004809 Teflon Substances 0.000 claims description 3
- 229920006362 Teflon® Polymers 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 230000000740 bleeding effect Effects 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000002655 kraft paper Substances 0.000 claims description 3
- 239000011496 polyurethane foam Substances 0.000 claims description 3
- 238000011417 postcuring Methods 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 238000004134 energy conservation Methods 0.000 abstract description 10
- 238000004078 waterproofing Methods 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 27
- 239000012774 insulation material Substances 0.000 description 16
- 230000008901 benefit Effects 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 238000004873 anchoring Methods 0.000 description 6
- 239000004570 mortar (masonry) Substances 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000010009 beating Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/242—Slab shaped vacuum insulation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/10—Insulation, e.g. vacuum or aerogel insulation
Landscapes
- Building Environments (AREA)
Abstract
The present invention relates to a kind of wall thermal insulating rigid foam polyurethane and preparation method thereof, belong to building energy-saving heat-insulating material and preparation method's technical field.A kind of wall thermal insulating rigid foam polyurethane, comprise inner core, be coated on the overcoat of inner core periphery and be covered on the boundary layer of overcoat upper and lower surface, inner core is vacuum thermal insulation plate.A preparation method for wall thermal insulating rigid foam polyurethane, comprises the following steps: one, the preparation of interface coiled material: be coated on base material by the flame-proof type polyalcohol rubber cement prepared and produce interface coiled material; Two, the making of overcoat and wall thermal insulating rigid foam polyurethane.This thermal insulating composite panel has very excellent insulation, waterproof, heat-proof quality, the requirement of building energy conservation 65% can be met well, adhesion strength is high, constructing operation is convenient, considerably increase the overall fireproof performance of wall insulation system after upper wall, building masonry wall inner, external wall and roof heat insulation, heat insulation, waterproofing system can be widely used in.
Description
Technical field
The present invention relates to a kind of construction wall thermal insulating composite panel and preparation method thereof, belong to building energy-saving heat-insulating material and preparation method's technical field.
Background technology
Building energy conservation is the strategy of sustainable development that the Chinese government vigorously advocates in recent years, is the important state basic policy contributing to energy-saving and emission-reduction, environmental protection, is incubated building masonry wall, one of heat insulation process is the important measures implementing building energy conservation.In order to meet the requirement of building energy conservation 65%, building masonry wall insulation material is day by day obvious to the effect of building energy conservation, and country is also more and more higher to the requirement of building masonry wall fireproof performance.
At present, the material for building heat preserving that can meet building energy conservation 65% requirement well mainly contains heat cured hard-foam polyurethane heat insulating material (PU) and phenolic aldehyde foam thermal insulation material (PF).Hard-foam polyurethane heat insulating material has very excellent insulation, heat insulation, water resistance, its coefficient of thermal conductivity is lower than 0.024 W/mK, belong to thermosetting heat insulating material, to meet the building energy conservation 65% even desirable wall heat insulation material of requirements at the higher level well, but it belongs to organic material, in order to improve the fireproof performance of hard-foam polyurethane heat insulating material, usually need to add a certain amount of fire retardant, these fire retardants generally can produce some adverse effects to some performance of hard-foam polyurethane heat insulating material, but also its cost can be increased, this have impact on the extensive use of hard-foam polyurethane heat insulating material in building masonry wall insulation to a certain extent.
Phenolic aldehyde foam thermal insulation material has excellent insulation and fireproof performance simultaneously, coefficient of thermal conductivity is lower than 0.03 W/mK, its oxygen index (OI) can reach more than 50%, but common phenolic foam heat insulation plate generally all also exists surperficial efflorescence, fall the shortcomings such as adhesion strength is low between slag serious and adhesive mortar, limits the application of phenolic aldehyde foam thermal insulation material in building heat preserving.
Vacuum thermal insulation material, it is heat insulating material prepared by a kind of sophistication, there is very excellent insulation, heat-proof quality and fireproof performance simultaneously, belong to A level material, its coefficient of thermal conductivity can lower than 0.01 W/mK, but there is again following problem when it is incubated for building masonry wall: 1, between itself and common adhesive mortar, adhesion stress is inadequate, and anchoring piece cannot be beaten carry out auxiliary bonding, therefore it is firm not to bond between itself and body of wall; 2, in the processes such as transport and storage, distortion and damaged gas leakage may be there is in vacuum thermal insulation material, after its surface is destroyed, the vacuum of its inside can reduce and cause the sharply decline of its heat-insulating property, and that is the vacuum of its inside cannot continue to ensure; 3, constructing operation is inconvenient, during air storage, expose to the sun and rain very easily cause plate distortion, damage, etc., these shortcomings limit the extensive use of vacuum thermal insulation material in building masonry wall insulation.
Summary of the invention
The object of the invention is to solve above-mentioned the deficiencies in the prior art part, there is provided a kind of reasonable in design, excellent combination property, constructing operation construction wall thermal insulating composite panel easily, another object of the present invention is also the preparation method providing a kind of construction wall thermal insulating composite panel.
The object of the invention is to be achieved through the following technical solutions:
A kind of construction wall thermal insulating composite panel, its special character is to comprise inner core 1, is coated on the overcoat 2 of inner core 1 periphery and is covered on the boundary layer 3 of overcoat 2 upper and lower surface, the length of described thermal insulating composite panel is 600-3000mm, and width is 300-1500mm, and thickness is 10-200mm.
Described inner core 1 is the various forms of vacuum thermal insulation plate or common phenolic foam heat insulation plate sold on the market, has very excellent insulation, heat insulation and fireproof performance, and length is 200-1000mm, and width is 50-500mm, and thickness is 5-150mm.
Described overcoat 2 is the hard-foam polyurethane heat insulating material being wrapped up by inner core 1, seal up, formed by polyisocyanates and flame retardant type premixed systems mixture foamable reaction, shaping, slaking on polyurethane foam production line, be incubated, heat insulation, water resistance is excellent, adhesion strength is high;
Described flame retardant type premixed systems mixture fully mixes rear formation by the raw material of following weight proportion: polyether/polyester polyol 30-70%, flame-retardant polyether glycol 10-40%, fire retardant 3-20%, blowing agent 8-25%, foam stabilizer 0.5-8%, catalyzer 0.05-3%;
Described polyether/polyester polyol is the polyether polyol for hard foam polyurethane or PEPA commonly used on the market;
Described flame-retardant polyether glycol be melamine derivative flame retardant polyether polyol, take epoxychloropropane as at least one in the chloro flame retardant polyether polyol of Material synthesis and the flame retardant polyether polyol prepared for raw material with trichlorine cyclobutane;
Described fire retardant is at least one in hexabromo-Cyclododecane, deca-BDE, TCPP, DMMP, TCEP, magnesium hydroxide, aluminium hydroxide and ammonium polyphosphate flame retardant;
Described blowing agent is at least one in 141B blowing agent, pentane foaming agent;
Described foam stabilizer is at least one in dimethicone, organosiloxane and alkyl phenol polyethylene glycol oxide ether foam stabilizer;
Described catalyzer is at least one in tertiary amine catalyst, organic metal salt catalyzer.
Described boundary layer 3 is at least one in the flame retardant type boundary materials such as flame retardant type interface coiled material, flame retardant type type interface sheet material, and thickness is 0.01-5.0mm, is to be coated in by interface coil production line by flame-proof type polyalcohol rubber cement base material forms thin layer post-drying to form;
Described base material is at least one in fiberglass gridding cloth, glass mat, non-woven fabrics, Polypropylence Sheet, release liners, kraft, Teflon cloth and composite non woven lining;
Described flame-proof type polyalcohol rubber cement fully mixes rear formation by the raw material of following weight proportion: inorganic filler 30-70%, fire retardant 5-30%, polymer emulsion 5-30%, auxiliary agent 0.05-10.0%, water 10-30%;
Described inorganic filler is at least one in sand, cement, quartz powder, dicalcium powder, French chalk, flyash, breeze, silicon ash etc.;
Described fire retardant is at least one in hexabromo-Cyclododecane, deca-BDE, TCPP, DMMP, TCEP, magnesium hydroxide, aluminium hydroxide and ammonium polyphosphate flame retardant;
Described polymer emulsion is at least one in VAE emulsion, acrylic ester emulsion, aqueous polyurethane emulsion, bipolymer emulsion, compound emulsion;
Described auxiliary agent is at least one in dispersing agent, coalescents, thickener, defoamer, activating agent, bleeding agent, toner, suspending agent.
The outer surface of described construction wall thermal insulating composite panel is also provided with the mark line 5 for marking inner core outline, by clear for the relative position of the inner core 1 of its inside mark, when being convenient to be carried out cutting or beating anchoring piece by thermal insulating composite panel at the construction field (site), the inner core of its inside can not be destroyed;
Described construction wall thermal insulating composite panel inside can also be provided with several relatively independent inner core 1 as required, and inner core 1 is evenly distributed on the diverse location of thermal insulating composite panel inside.
A preparation method for construction wall thermal insulating composite panel, its special character is to comprise the following steps:
The first step: allotment flame-proof type polyalcohol rubber cement
The inorganic filler 30-70% of weight proportion meter, fire retardant 5-30%, polymer emulsion 5-30%, auxiliary agent 0.05-10.0%, water 10-30% are fully mixed rear formation flame-proof type polyalcohol rubber cement;
Described inorganic filler is at least one in sand, cement, quartz powder, dicalcium powder, French chalk, flyash, breeze, silicon ash etc.;
Described fire retardant is at least one in hexabromo-Cyclododecane, deca-BDE, TCPP, DMMP, TCEP, magnesium hydroxide, aluminium hydroxide and ammonium polyphosphate flame retardant;
Described polymer emulsion is at least one in VAE emulsion, acrylic ester emulsion, aqueous polyurethane emulsion, bipolymer emulsion, compound emulsion;
Described auxiliary agent is at least one in dispersing agent, coalescents, thickener, defoamer, activating agent, bleeding agent, toner, suspending agent.
Second step: prepare boundary material
The above-mentioned flame-proof type polyalcohol rubber cement mixed is coated in by interface coil production line base material to produce flame retardant type boundary material for subsequent use;
Described base material is at least one in fiberglass gridding cloth, glass mat, non-woven fabrics, Polypropylence Sheet, release liners, kraft, Teflon cloth and composite non woven lining.
3rd step: allotment flame retardant type premixed systems mixture
The polyether/polyester polyol 30-70% of weight proportion meter, flame-retardant polyether glycol 10-40%, fire retardant 3-20%, blowing agent 8-25%, foam stabilizer 0.5-8%, catalyzer 0.05-3% are fully mixed rear formation flame retardant type premixed systems mixture;
Described polyether/polyester polyol is the hard-foam polyurethane polyether/polyester polyol commonly used on the market;
Described flame-retardant polyether glycol be melamine derivative flame retardant polyether polyol, take epoxychloropropane as at least one in the chloro flame retardant polyether polyol of Material synthesis and the flame retardant polyether polyol prepared for raw material with trichlorine cyclobutane;
Described fire retardant is at least one in hexabromo-Cyclododecane, deca-BDE, TCPP, DMMP, TCEP, magnesium hydroxide, aluminium hydroxide and ammonium polyphosphate flame retardant;
Described blowing agent is at least one in 141B blowing agent, pentane foaming agent;
Described foam stabilizer is at least one in dimethicone, organosiloxane and alkyl phenol polyethylene glycol oxide ether foam stabilizer;
Described catalyzer is at least one in tertiary amine catalyst, organic metal salt catalyzer.
4th step: make composite insulation boards
Boundary material is divided on the upper and lower two-layer upper and lower carrier bar introducing hard-foam polyurethane continuous foamed line level press respectively, the vacuum thermal insulation plate or phenolic foam heat insulation plate that preset good position are fixed on the centre position of upper and lower bed boundary material simultaneously; Then by polyisocyanates and flame retardant type premixed systems mixture by polyurethane foaming machine according to (1.0-1.8): the part by weight of 1.0 is cast in the middle of the material of upper and lower bed boundary, and enter in laminating machine and foam, formed in the process of hard-foam polyurethane insulation layer (i.e. overcoat) vacuum thermal insulation plate or phenolic foam heat insulation plate environmental sealing to live, make it form composite insulation boards simultaneously together with the material strong bond of upper and lower bed boundary;
5th step: post curing of rolling off the production line is cut
Composite insulation boards rolls off the production line after abundant slaking, cuts into required size.
A kind of construction wall thermal insulating composite panel of the present invention reasonable in design, take full advantage of hard-foam polyurethane material and vacuum thermal insulation material or phenolic aldehyde foam thermal insulation material advantage separately, active caking property extremely strong when utilizing overcoat 2 hard-foam polyurethane foaming is by inner core vacuum thermal insulation plate or phenolic foam heat insulation plate parcel, seal up, solve common vacuum thermal insulation plate and phenolic foam heat insulation plate well for Problems existing during wall thermal insulating, simultaneously overcoat 2 by inner core 1 together with boundary layer 3 secure bond, form a guaranteed organic whole of adhesion strength, the boundary layer that boundary layer 3 forms for flame retardant type boundary material, further enhancing the fireproof performance of this thermal insulating composite panel, also serve good interface humidification simultaneously, directly by general polymer mortar bonding during upper wall, without the need to carrying out loaded down with trivial details interface processing, constructing operation is convenient and swift.
Construction wall thermal insulating composite panel of the present invention has very excellent insulation, waterproof, heat-proof quality, the requirement of building energy conservation 65% can be met well, adhesion strength is high, constructing operation is convenient, considerably increase the overall fireproof performance of wall insulation system after upper wall, building masonry wall inner, external wall and roof heat insulation, heat insulation, waterproofing system can be widely used in.
Accompanying drawing explanation
Fig. 1: front view of the present invention;
Fig. 2: a-a' cross-sectional view of the present invention;
Fig. 3: be a kind of in the specific embodiment of the invention 1 front view of wall insulating composite board;
In figure: 1, inner core, 2, overcoat, 3, boundary layer, 4, thermal insulating composite panel, 5, mark line.
Detailed description of the invention
Provide the specific embodiment of the present invention below with reference to accompanying drawing, be used for that the present invention is described further.
Embodiment 1
A kind of construction wall thermal insulating composite panel, with reference to Fig. 1-3, comprises four inner cores 1, is coated on the overcoat 2 of inner core 1 periphery and is covered on the boundary layer 3 of overcoat 2 upper and lower surface.The length of described wall insulating composite board is 1200mm, width is 600mm, thickness is 40mm, and described four inner cores 1 are all the vacuum thermal insulation plates sold on the market, and its length is 450mm, width is 150mm, thickness is 20mm, belongs to A level material, can effectively delay flame transmission, spreads after upper wall, and itself there is very excellent insulation, heat-proof quality, its coefficient of thermal conductivity is lower than 0.010 W/mK; Overcoat 2 is the hard-foam polyurethane materials being wrapped up by inner core 1, seal up, and be incubated, heat insulation, water resistance is excellent, coefficient of thermal conductivity is lower than 0.024W/mK, and adhesion strength is high; Boundary layer 3 is that flame-proof type polyalcohol rubber cement is coated in flame retardant type interface coiled material, the type interface sheet material of base material being dried rear formation, and thickness is 1.0mm, plays good protective action and interface humidification; The outer surface of described wall thermal insulating rigid foam polyurethane is also provided with mark line 5, by clear for the relative position of the inner core 1 vacuum thermal insulation plate of its inside mark, when being convenient to be carried out cutting or beating anchoring piece by thermal insulating composite panel at the construction field (site), the vacuum thermal insulation plate of its inside can not be destroyed; The inside of described thermal insulating composite panel is provided with four relatively independent and inner core 1 vacuum thermal insulation materials be evenly distributed on diverse location.
Described overcoat 2 is the hard-foam polyurethane heat insulating material being wrapped up by inner core 1, seal up, formed by polyisocyanates and flame retardant type premixed systems mixture foamable reaction, shaping, slaking on polyurethane foam production line, be incubated, heat insulation, water resistance is excellent, adhesion strength is high;
Described boundary layer 3 is at least one in the flame retardant type boundary materials such as flame retardant type interface coiled material, flame retardant type type interface sheet material, and thickness is 1.0mm, is to be coated in by interface coil production line by flame-proof type polyalcohol rubber cement base material forms thin layer post-drying to form.
A preparation method for construction wall thermal insulating composite panel, comprises the following steps:
The first step: allotment flame-proof type polyalcohol rubber cement
Flame-proof type polyalcohol rubber cement is formed by after the inorganic filler 30% of weight proportion meter, fire retardant 20%, polymer emulsion 20%, auxiliary agent 5%, water water 25% etc. fully mixing; Described inorganic filler is sand 15%, cement 15%; Described fire retardant is hexabromo-Cyclododecane; Described polymer emulsion is VAE emulsion 10%, acrylic ester emulsion 10%; Described auxiliary agent is dispersing agent 4.5%, thickener 0.5%.
Second step: prepare boundary material
The above-mentioned flame-proof type polyalcohol rubber cement mixed is coated in by interface coil production line base material to produce flame retardant type boundary material for subsequent use; Described base material is fiberglass gridding cloth.
3rd step: allotment flame retardant type premixed systems mixture
Flame retardant type premixed systems mixture is formed by after the PEPA 45% of weight proportion meter, flame-retardant polyether glycol 25%, fire retardant 10%, blowing agent 15%, foam stabilizer 4.5%, catalyzer 0.5% etc. fully mixing;
Described PEPA is the hard-foam polyurethane PEPA commonly used on the market; Described flame-retardant polyether glycol is the flame retardant polyether polyol of melamine derivative; Described fire retardant is hexabromo-Cyclododecane, deca-BDE; Described blowing agent is 141B blowing agent, pentane foaming agent; Described foam stabilizer is dimethicone; Described catalyzer is tertiary amine catalyst.
4th step: make composite insulation boards
Boundary material is divided on the upper and lower two-layer upper and lower carrier bar introducing hard-foam polyurethane continuous foamed line level press respectively, the vacuum thermal insulation plate presetting good position is fixed on the centre position of upper and lower bed boundary material simultaneously; Then polyisocyanates and flame retardant type premixed systems mixture are cast in the middle of the material of upper and lower bed boundary by polyurethane foaming machine according to the part by weight of 1.2:1, and enter in laminating machine and foam, formed in the process of hard-foam polyurethane insulation layer (i.e. overcoat) vacuum thermal insulation plate environmental sealing to live, make it form composite insulation boards simultaneously together with the material strong bond of upper and lower bed boundary;
5th step: post curing of rolling off the production line is cut
Composite insulation boards rolls off the production line after abundant slaking, cuts into required size.
The present embodiment wall insulating composite board reasonable in design, take full advantage of inorganic vacuum thermal insulation material and hard-foam polyurethane heat insulating material advantage separately, there is excellent fire prevention, heat-insulating property, inner core 1 vacuum thermal insulation plate wraps up by active caking property extremely strong when utilizing overcoat 2 hard-foam polyurethane foaming materials shaping, seal up, the vacuum material of its inside can be protected, effectively prevent the reduction of its vacuum, simultaneously overcoat 2 by inner core 1 together with boundary layer 3 secure bond, form a guaranteed organic whole of adhesion strength, therefore, it is low that this thermal insulating composite panel overcomes conventional vacuum heat-insulating material surface adhesion strength well, vacuum cannot continue the shortcomings such as guarantee, the surface layer up and down of this thermal insulating composite panel is the type interface sheet material formed after flame-proof type polyalcohol rubber cement is dried simultaneously, further enhancing the fireproof performance of this thermal insulating composite panel, also serve good interface humidification simultaneously, directly by general polymer mortar bonding during upper wall, without the need to carrying out loaded down with trivial details interface processing, constructing operation is convenient and swift, and bond firmly between itself and body of wall basic unit, safety is guaranteed.Surface due to this thermal insulating composite panel is provided with cutting, anchoring mark line, can by clear for the relative position of the vacuum thermal insulation plate of its inside mark, on-site cutting and would not destroy inner vacuum heat-insulation plate when beating anchoring piece, solves the problem that anchoring piece cannot be cut, be beaten in conventional vacuum heat insulating thermal preserving board scene.On this wall insulating composite board after wall, inner core 1 vacuum thermal insulation plate inherently fire barrier wherein, can effectively delay flame transmission when fire occurs, spread, substantially increase the overall fireproof performance of wall insulation system.Therefore, this wall insulating composite board can be widely used in building masonry wall inner, external wall and roof heat insulation, heat insulation, waterproofing system.
Embodiment 2
The difference of the present embodiment and embodiment 1 is
A preparation method for construction wall thermal insulating composite panel, comprises the following steps:
The first step: allotment flame-proof type polyalcohol rubber cement
By the inorganic filler 50% of weight proportion meter, fire retardant 15%, polymer emulsion 15%, auxiliary agent 10.0%, water 10% is mixing rear formation flame-proof type polyalcohol rubber cement fully; Described inorganic filler is French chalk 25%, flyash 25%; Described fire retardant is magnesium hydroxide; Described polymer emulsion is aqueous polyurethane emulsion 10%, bipolymer emulsion 5%; Described auxiliary agent is dispersing agent 7%, coalescents 0.5%, defoamer 2.5%.
Second step: prepare boundary material
The above-mentioned flame-proof type polyalcohol rubber cement mixed is coated in by interface coil production line base material to produce flame retardant type boundary material for subsequent use; Described base material is glass mat.
3rd step: allotment flame retardant type premixed systems mixture
Flame retardant type premixed systems mixture is formed by after the PPG 60% of weight proportion meter, flame-retardant polyether glycol 10%, fire retardant 10%, blowing agent 10%, foam stabilizer 8%, catalyzer 2% fully mixing;
Described PPG is the polyether polyol for hard foam polyurethane commonly used on the market; Described flame-retardant polyether glycol is take epoxychloropropane as the chloro flame retardant polyether polyol of Material synthesis; Described fire retardant is deca-BDE, DMMP; Described blowing agent is pentane foaming agent; Described foam stabilizer is organosiloxane; Described catalyzer is organic metal salt catalyzer.
4th step: make composite insulation boards
Boundary material is divided on the upper and lower two-layer upper and lower carrier bar introducing hard-foam polyurethane continuous foamed line level press respectively, the phenolic foam heat insulation plate presetting good position is fixed on the centre position of upper and lower bed boundary material simultaneously; Then polyisocyanates and flame retardant type premixed systems mixture are cast in the middle of the material of upper and lower bed boundary by polyurethane foaming machine according to the part by weight of 1.6:1.0, and enter in laminating machine and foam, formed in the process of hard-foam polyurethane insulation layer (i.e. overcoat) phenolic foam heat insulation plate environmental sealing to live, make it form composite insulation boards simultaneously together with the material strong bond of upper and lower bed boundary;
5th step: slaking of rolling off the production line is cut
Composite insulation boards rolls off the production line after abundant slaking, cuts into required size.
This wall insulating composite board takes full advantage of hard-foam polyurethane heat insulating material and phenolic aldehyde foam thermal insulation material advantage separately, compared with common phenolic foam heat insulation plate, in this thermal insulating composite panel, there is the protection of the hard-foam polyurethane plastic layer of excellent performance inner core 1 phenolic foam heat insulation plate periphery, no longer there is surperficial efflorescence, fall the serious problem of slag, the upper and lower surface of this thermal insulating composite panel is boundary layer 3, without the need to carrying out loaded down with trivial details interface processing again during upper wall, and bonding is firm between itself and adhesive mortar, therefore, the adhesion strength between itself and body of wall is guaranteed; Compared with common hard-foam polyurethane warming plate, this thermal insulating composite panel not only has excellent heat-insulating property, there is better fireproof performance simultaneously, the inner core 1 phenolic foam heat insulation plate inherently fire barrier of its inside after upper wall, fire can effectively delay flame transmission when occurring, spread, and substantially increases the overall fireproof performance of wall insulation system.In addition because hard-foam polyurethane and phenolic aldehyde foam thermal insulation material belong to heat cured organic material, there is good compatibility between the two, therefore this thermal insulating composite panel has good stability.
Therefore, this thermal insulating composite panel has very excellent insulation, waterproof, heat-proof quality, the requirement of building energy conservation 65% can be met well, adhesion strength is high, constructing operation is convenient, considerably increase the overall fireproof performance of building heat preserving system after upper wall, building masonry wall inner, external wall and roof heat insulation, heat insulation, waterproofing system can be widely used in.
Embodiment 3
The difference of the present embodiment and embodiment 1 is
A preparation method for construction wall thermal insulating composite panel, comprises the following steps:
The first step: allotment flame-proof type polyalcohol rubber cement
Flame-proof type polyalcohol rubber cement is formed by after the inorganic filler 50% of weight proportion meter, fire retardant 15%, polymer emulsion 15%, auxiliary agent 5%, water 15% fully mixing; Described inorganic filler is breeze 25%, silicon ash 25%; Described fire retardant is magnesium hydroxide 10%, aluminium hydroxide 5%; Described polymer emulsion is aqueous polyurethane emulsion; Described auxiliary agent is dispersing agent 4%, toner 0.5%, coalescents 0.5%.
Second step: prepare boundary material
The above-mentioned flame-proof type polyalcohol rubber cement mixed is coated in by interface coil production line base material to produce flame retardant type boundary material for subsequent use; Described base material is non-woven fabrics.
3rd step: allotment flame retardant type premixed systems mixture
Flame retardant type premixed systems mixture is formed by after the PEPA 50% of weight proportion meter, flame-retardant polyether glycol 25%, fire retardant 10%, blowing agent 10.5%, foam stabilizer 4%, catalyzer 0.5% fully mixing;
Described PEPA is the hard-foam polyurethane PEPA commonly used on the market; Described flame-retardant polyether glycol is the flame retardant polyether polyol prepared for raw material with trichlorine cyclobutane; Described fire retardant is ammonium polyphosphate flame retardant; Described blowing agent is 141B blowing agent; Described foam stabilizer is alkyl phenol polyethylene glycol oxide ether foam stabilizer; Described catalyzer is organic metal salt catalyzer.
4th step: make composite insulation boards
Boundary material is divided on the upper and lower two-layer upper and lower carrier bar introducing hard-foam polyurethane continuous foamed line level press respectively, the phenolic foam heat insulation plate presetting good position is fixed on the centre position of upper and lower bed boundary material simultaneously; Then polyisocyanates and flame retardant type premixed systems mixture are cast in the middle of the material of upper and lower bed boundary by polyurethane foaming machine according to the part by weight of 1.4:1.0, and enter in laminating machine and foam, formed in the process of hard-foam polyurethane insulation layer (i.e. overcoat) phenolic foam heat insulation plate environmental sealing to live, make it form composite insulation boards simultaneously together with the material strong bond of upper and lower bed boundary;
5th step: slaking of rolling off the production line is cut
Composite insulation boards rolls off the production line after abundant slaking, cuts into required size.
Embodiment 4
A preparation method for construction wall thermal insulating composite panel, comprises the following steps:
The first step: allotment flame-proof type polyalcohol rubber cement
Flame-proof type polyalcohol rubber cement is formed by after the inorganic filler 45% of weight proportion meter, fire retardant 15%, polymer emulsion 13.5%, auxiliary agent 6.5%, water 20% fully mixing; Described inorganic filler is breeze 20%, silicon ash 25%; Described fire retardant is TCPP; Described polymer emulsion is aqueous polyurethane emulsion; Described auxiliary agent is dispersing agent 5%, coalescents 1.0%, toner 0.5%.
Second step: prepare boundary material
The above-mentioned flame-proof type polyalcohol rubber cement mixed is coated in by interface coil production line base material to produce flame retardant type boundary material for subsequent use; Described base material is release liners.
3rd step: allotment flame retardant type premixed systems mixture
Flame retardant type premixed systems mixture is formed by after the PPG 55% of weight proportion meter, flame-retardant polyether glycol 15%, fire retardant 10%, blowing agent 10%, foam stabilizer 9%, catalyzer 1% fully mixing;
Described PPG is the polyether polyol for hard foam polyurethane commonly used on the market; Described flame-retardant polyether glycol is take epoxychloropropane as the chloro flame retardant polyether polyol of Material synthesis; Described fire retardant is hydrogen TCEP; Described blowing agent is 141B blowing agent; Described foam stabilizer is dimethicone; Described catalyzer is tertiary amine catalyst.
4th step: make composite insulation boards
Boundary material is divided on the upper and lower two-layer upper and lower carrier bar introducing hard-foam polyurethane continuous foamed line level press respectively, the vacuum thermal insulation plate presetting good position is fixed on the centre position of upper and lower bed boundary material simultaneously; Then polyisocyanates and flame retardant type premixed systems mixture are cast in the middle of the material of upper and lower bed boundary by polyurethane foaming machine according to the part by weight of 1.3:1.0, and enter in laminating machine and foam, formed in the process of hard-foam polyurethane insulation layer (i.e. overcoat) vacuum thermal insulation plate environmental sealing to live, make it form composite insulation boards simultaneously together with the material strong bond of upper and lower bed boundary;
5th step: slaking of rolling off the production line is cut
Composite insulation boards rolls off the production line after abundant slaking, cuts into required size.
A kind of construction wall thermal insulating composite panel reasonable in design of above embodiment, take full advantage of hard-foam polyurethane material and vacuum thermal insulation material or phenolic aldehyde foam thermal insulation material advantage separately, active caking property extremely strong when utilizing overcoat 2 hard-foam polyurethane foaming is by inner core 1 vacuum thermal insulation plate or phenolic foam heat insulation plate parcel, seal up, solve common vacuum thermal insulation plate and phenolic foam heat insulation plate well for Problems existing during wall thermal insulating, simultaneously overcoat 2 by inner core 1 together with boundary layer 3 secure bond, form a guaranteed organic whole of adhesion strength, the boundary layer that boundary layer 3 forms for flame retardant type boundary material, further enhancing the fireproof performance of this thermal insulating composite panel, also serve good interface humidification simultaneously, directly by general polymer mortar bonding during upper wall, without the need to carrying out loaded down with trivial details interface processing, constructing operation is convenient and swift.
Therefore, construction wall thermal insulating composite panel of the present invention has very excellent insulation, waterproof, heat-proof quality, the requirement of building energy conservation 65% can be met well, adhesion strength is high, constructing operation is convenient, considerably increase the overall fireproof performance of wall insulation system after upper wall, building masonry wall inner, external wall and roof heat insulation, heat insulation, waterproofing system can be widely used in.
Above-described embodiment is just described the preferred embodiment of the present invention; not scope of the present invention is limited; under the prerequisite not departing from practicalness of the present invention; the various distortion that those of ordinary skill in the art make technical scheme of the present invention and improvement, all should fall within protection scope of the present invention.
Claims (7)
1. a construction wall thermal insulating composite panel, is characterized in that comprising inner core (1), is coated on the overcoat (2) of inner core (1) periphery and is covered on the boundary layer (3) of overcoat (2) upper and lower surface;
Described inner core (1) is vacuum thermal insulation plate or common phenolic foam heat insulation plate;
Described overcoat (2) for inner core (1) environmental sealing is lived, by the hard-foam polyurethane heat insulating material of polyisocyanates and flame retardant type premixed systems mixture foamable reaction, shaping, slaking on polyurethane foam production line;
Described boundary layer (3) is at least one in flame retardant type interface coiled material, flame retardant type type interface sheet material, is to be coated in by interface coil production line by flame-proof type polyalcohol rubber cement base material forms thin layer post-drying to form;
Described flame retardant type premixed systems mixture fully mixes rear formation by the raw material of following weight proportion: polyether/polyester polyol 30-70%, flame-retardant polyether glycol 10-40%, fire retardant 3-20%, blowing agent 8-25%, foam stabilizer 0.5-8%, catalyzer 0.05-3%;
Described flame-proof type polyalcohol rubber cement fully mixes rear formation by the raw material of following weight proportion: inorganic filler 30-70%, fire retardant 5-30%, polymer emulsion 5-30%, auxiliary agent 0.05-10.0%, water 10-30%.
2. a kind of construction wall thermal insulating composite panel as claimed in claim 1, is characterized in that
Described polyether/polyester polyol is the polyether polyol for hard foam polyurethane or PEPA commonly used on the market;
Described flame-retardant polyether glycol be melamine derivative flame retardant polyether polyol, take epoxychloropropane as at least one in the chloro flame retardant polyether polyol of Material synthesis and the flame retardant polyether polyol prepared for raw material with trichlorine cyclobutane;
Described fire retardant is at least one in hexabromo-Cyclododecane, deca-BDE, TCPP, DMMP, TCEP, magnesium hydroxide, aluminium hydroxide and ammonium polyphosphate flame retardant;
Described blowing agent is at least one in 141B blowing agent, pentane foaming agent;
Described foam stabilizer is at least one in dimethicone, organosiloxane and alkyl phenol polyethylene glycol oxide ether foam stabilizer;
Described catalyzer is at least one in tertiary amine catalyst, organic metal salt catalyzer.
3. a kind of construction wall thermal insulating composite panel as claimed in claim 1, is characterized in that
Described inorganic filler is at least one in sand, cement, quartz powder, dicalcium powder, French chalk, flyash, breeze, silicon ash;
Described fire retardant is at least one in hexabromo-Cyclododecane, deca-BDE, TCPP, DMMP, TCEP, magnesium hydroxide, aluminium hydroxide and ammonium polyphosphate flame retardant;
Described polymer emulsion is at least one in VAE emulsion, acrylic ester emulsion, aqueous polyurethane emulsion, bipolymer emulsion, compound emulsion;
Described auxiliary agent is at least one in dispersing agent, coalescents, thickener, defoamer, activating agent, bleeding agent, toner, suspending agent.
4. a kind of construction wall thermal insulating composite panel as claimed in claim 1, is characterized in that
Described base material is at least one in fiberglass gridding cloth, glass mat, non-woven fabrics, Polypropylence Sheet, release liners, kraft, Teflon cloth and composite non woven lining.
5. a kind of construction wall thermal insulating composite panel as claimed in claim 1, is characterized in that
The outer surface of described construction wall thermal insulating composite panel is also provided with the mark line (5) for marking inner core outline.
6. a preparation method for construction wall thermal insulating composite panel, is characterized in that comprising the following steps:
The first step: allotment flame-proof type polyalcohol rubber cement
The inorganic filler 30-70% of weight proportion meter, fire retardant 5-30%, polymer emulsion 5-30%, auxiliary agent 0.05-10.0%, water 10-30% are fully mixed rear formation flame-proof type polyalcohol rubber cement;
Second step: prepare boundary material
The above-mentioned flame-proof type polyalcohol rubber cement mixed is coated in by interface coil production line base material to produce flame retardant type boundary material for subsequent use;
3rd step: allotment flame retardant type premixed systems mixture
The polyether/polyester polyol 30-70% of weight proportion meter, flame-retardant polyether glycol 10-40%, fire retardant 3-20%, blowing agent 8-25%, foam stabilizer 0.5-8%, catalyzer 0.05-3% are fully mixed rear formation flame retardant type premixed systems mixture;
4th step: make composite insulation boards
Boundary material is divided on the upper and lower two-layer upper and lower carrier bar introducing hard-foam polyurethane continuous foamed line level press respectively, the vacuum thermal insulation plate or phenolic foam heat insulation plate that preset good position are fixed on the centre position of upper and lower bed boundary material simultaneously; Then by polyisocyanates and flame retardant type premixed systems mixture by polyurethane foaming machine according to (1.0-1.8): the part by weight of 1.0 is cast in the middle of the material of upper and lower bed boundary, and enter in laminating machine and foam, formed in the process of hard-foam polyurethane insulation layer vacuum thermal insulation plate or phenolic foam heat insulation plate environmental sealing to live, make it form composite insulation boards simultaneously together with the material strong bond of upper and lower bed boundary.
7. the preparation method of a kind of construction wall thermal insulating composite panel as claimed in claim 6, is characterized in that described 4th step is further comprising the steps of after making composite insulation boards:
5th step: post curing of rolling off the production line is cut
Composite insulation boards rolls off the production line after abundant slaking, cuts into required size.
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Cited By (1)
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| CN114161805A (en) * | 2021-12-07 | 2022-03-11 | 中国铁路设计集团有限公司 | Preparation method of polymer waterproof type cement-based cloth composite hard polyurethane insulation board |
| CN117285885B (en) * | 2023-11-20 | 2024-02-13 | 锦绣防水科技有限公司 | Waterproof and heat-insulating coiled material for roof and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005350995A (en) * | 2004-06-11 | 2005-12-22 | Tostem Corp | Roof underlayer panel and thermal insulation structure of roof of building using it |
| CN101487297A (en) * | 2009-01-19 | 2009-07-22 | 夏良强 | Production method for multifunctional rigid foam polyurethane composite heat-conservation board |
| CN201649497U (en) * | 2010-01-04 | 2010-11-24 | 营口沃飞斯节能科技有限公司 | Fire-preventive isolation belt board for building exterior wall |
| CN202577625U (en) * | 2012-03-26 | 2012-12-05 | 北京建筑技术发展有限责任公司 | Composite insulation board with organic materials coated by inorganic materials |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1082118A (en) * | 1996-09-09 | 1998-03-31 | Naritomo Shiraki | Production method of basic layer of thermal insulation floor and composite thermal insulation plate used therefor |
-
2013
- 2013-02-01 CN CN201310039386.2A patent/CN103104046B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005350995A (en) * | 2004-06-11 | 2005-12-22 | Tostem Corp | Roof underlayer panel and thermal insulation structure of roof of building using it |
| CN101487297A (en) * | 2009-01-19 | 2009-07-22 | 夏良强 | Production method for multifunctional rigid foam polyurethane composite heat-conservation board |
| CN201649497U (en) * | 2010-01-04 | 2010-11-24 | 营口沃飞斯节能科技有限公司 | Fire-preventive isolation belt board for building exterior wall |
| CN202577625U (en) * | 2012-03-26 | 2012-12-05 | 北京建筑技术发展有限责任公司 | Composite insulation board with organic materials coated by inorganic materials |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2736470C1 (en) * | 2017-01-23 | 2020-11-17 | Либхерр-Хаусгерете Линц Гмбх | Refrigeration and/or freezer manufacturing method |
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| CN103104046A (en) | 2013-05-15 |
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