CN103073950B - Water-base frosted gravure ink and preparation method thereof - Google Patents
Water-base frosted gravure ink and preparation method thereof Download PDFInfo
- Publication number
- CN103073950B CN103073950B CN201310030182.2A CN201310030182A CN103073950B CN 103073950 B CN103073950 B CN 103073950B CN 201310030182 A CN201310030182 A CN 201310030182A CN 103073950 B CN103073950 B CN 103073950B
- Authority
- CN
- China
- Prior art keywords
- water
- high speed
- ink
- frosted
- base gravure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses water-base frosted gravure ink and a preparation method thereof, and belongs to the technical field of printing ink. The water-base frosted gravure ink is a mixed dispersion formed through high-speed dispersing of polyethene wax powder, gaseous silicon dioxide, frost powder, alcohol/water acrylic acid, styrene-acrylate copolymer emulsion, a dispersing agent and an alcohol/water mixed solvent. As ethanol amine is added when resin is dissolved, the pre-dispersibility and solubility of a resin system are improved greatly; the excellent leveling property and stability of the ink are kept; the production efficiency is effectively improved; when the ink is used for printing a product, the release property of a solvent is good; the printed product residue is extremely less; the problem of high residual quantity of the organic solvent is solved effectively; as alcohol and water serve as main solvents of the ink, the preparation cost is low; the ink is free from volatile organic compounds (VOCs); requirements on the cigarette packaging VOCs can be met; and the ink is harmless to a human body, and can meet increasingly strict environmental requirements.
Description
Technical field
The invention belongs to printing-ink technical field, is a kind of water-base gravure frosted ink and preparation method thereof specifically.
Background technology
The advantages such as intaglio printing is as the one of typography, real, bright-colored with its printing product China ink bed thickness, saturation ratio is high, forme press resistance rate is high, print quality stable, print speed is fast occupy extremely important status in printing packaging and picture and text publishing area.From applicable cases, abroad, gravure is mainly used in the meticulous publication such as magazine, products catalogue, the printing of the Valued Securities such as packages printing and banknote, stamp, and be applied to the special dimensions such as finishing material; At home, gravure is mainly used in flexible packaging printing, along with the development of Chinese gravure techniques, also in sheet package, graining, leather substance, drug packaging, is used widely.
Water-base gravure frosted printing effect was realized with silk screen printing in the past, there is the problems such as ink smell is large, production efficiency is low, change subsequently solvent-borne type intaglio printing into, can carry out intaglio plate high speed printing, although production efficiency is improved, also exist the environmental problems such as organic solvent residual is high, exhaust gas emission is large.
Summary of the invention
The present invention, for the problem that above-mentioned technology exists, provides water-base gravure frosted ink that a kind of organic solvent residual is low, exhaust gas emission is little and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is: a kind of water-base gravure frosted ink, it is prepared from by the component of following weight percent: the mixed solvent 16-31% being made up of quality such as ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid 5-10%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 37-40%, polyethylene wax powder 16-18%, aerosil 3-4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 2-3%.
Further: it is prepared from by the component of following weight percent: the mixed solvent 19-28% being formed by quality such as ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid 6-8%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 38-40%, polyethylene wax powder 16-18%, aerosil 3-4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 2-3%.
Further: it is prepared from by the component of following weight percent: the mixed solvent being formed by quality such as ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid 9%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 38%, polyethylene wax powder 18%, aerosil 4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 2%.
Another object of the present invention is to provide a kind of preparation method of water-base gravure frosted ink, comprises the steps:
(1), prepare burden pre-dispersed: by the mixed solvent being become by the mass mixing such as 10-20% ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid, 0.5% thanomin, drop into high speed dispersor, adjusting rotary speed and time are carried out dispersing and dissolving, and after dissolving completely, then the mixed solvent that latex of copolymer in cinnamic acrylic ester is become by ethanol, n-propyl alcohol, water balanced mix with 4-6% drops into high speed dispersor, adjusting rotary speed and time carry out redispersion and obtain water-base gravure ink work in-process, for subsequent use;
(2), frosted agitating procedure: the water-base gravure frosted ink work in-process of gained in step (1) are dropped into high speed dispersor, again the thanomin of polyethylene wax powder, aerosil, dispersion agent, defoamer and 0.5% is dropped into high speed dispersor one by one, adjusting rotary speed and time, stir and obtain water-base gravure ink work in-process, for subsequent use;
(3), ink adjustment: qualified step (2) sand milling water-base gravure ink work in-process are dropped into high speed dispersor, then the thanomin of frosting powder and 0.5% is dropped into high speed dispersor and carry out redispersion, and adjusting rotary speed and time; The mixed solvent again 2%-5% being made up of ethanol, n-propyl alcohol, water drops into high speed dispersor and carries out whole dispersion, adjusting rotary speed and time, and regulate pH value between 8-9, make water-base gravure frosted ink finished product.
Further: in described step (1), just disperse, high speed dispersor rotating speed is 600-700 rev/min when redispersion, jitter time is 25-35 minute.
Further: in described step (1), just disperse, high speed dispersor rotating speed is 700 revs/min when redispersion, jitter time is 30 minutes.
Further: while dispersion in described step (2), high speed dispersor rotating speed is 1100-1300 rev/min, and jitter time is 110-130 minute.
Further: while dispersion in described step (2), high speed dispersor rotating speed is 1200 revs/min, and jitter time is 120 minutes.
Further: when the middle redispersion of described step (3), high speed dispersor rotating speed is 900-1100 rev/min, and jitter time is 55-65 minute; When disperse described end, high speed dispersor rotating speed is 900-1100 rev/min, and jitter time is 15-25 minute.
Further: when the middle redispersion of described step (3), high speed dispersor rotating speed is 1000 revs/min, and jitter time is 60 minutes; When disperse described end, high speed dispersor rotating speed is 1000 revs/min, and jitter time is 20 minutes.
Compared with prior art, useful technique effect of the present invention is:
(1), the present invention selects the hybrid dispersions that polyethylene wax powder, aerosil, frosting powder, alcohol water type vinylformic acid, latex of copolymer in cinnamic acrylic ester, dispersion agent and alcohol water mixed solvent form through high speed dispersion, during due to dissolving resin, add thanomin, the pre-dispersed property of resin system and solvability are greatly improved, make ink can keep excellent levelling property, stability, effectively improved production efficiency;
(2), utilize product of the present invention to carry out print product, good to solvent release, printing is residual extremely low, has effectively solved the high problem of Determination of Residual Organic Solvents;
(3), the present invention is taking second alcohol and water as main solvent, preparation cost is cheap, containing volatile organic compounds, and can be satisfied with cigarette package VOC requirement, harmless, meets the environmental requirement of increasingly stringent.
Ink product of the present invention detects data as following table:
Name of product: water-base gravure frosted ink
Product operative norm: GB/T26395-2011 water-based tobacco bale gravure ink
The inspection of table 1 technical feature
The maximum limitation inspection (unit is mg/kg) of table 2 volatile organic compounds
The treasure cloud and mist tobacco bale of applying ink product of the present invention printing detects data as following table (table 3 and table 4): ink type: water-base gravure frosted ink product
Table 3 operative norm 1:YC/T330-2009 tobacco shred and box packaging paper printed matter
Table 4 operative norm 2:YC263-2008 tobacco shred with and wrapping paper in the limitation of volatile organic compounds
Embodiment
Embodiment 1
A kind of water-base gravure frosted ink and preparation method thereof;
It is prepared from by the component of following weight percent: the mixed solvent 27% that the quality such as ethanol, n-propyl alcohol, water form, alcohol water type vinylformic acid 9%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 36.5%, polyethylene wax powder 16%, aerosil 6%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 3%;
Produce the preparation method of 100kg frosted ink:
(1), prepare burden pre-dispersed: will be by ethanol 6.3kg, n-propyl alcohol 6.3kg, water 6.4kg mixing mixture, alcohol water type vinylformic acid 9kg, thanomin 0.5kg drop into rotating speed be 600 revs/min high speed dispersor disperse 30 minutes; By latex of copolymer in cinnamic acrylic ester 36.5kg, ethanol 2kg, n-propyl alcohol 2kg, water 2kg mixed solvent input rotating speed are that the high speed dispersor of 600 revs/min disperses 25 minutes, obtain water-base gravure ink work in-process, for subsequent use again;
(2), frosted agitating procedure: the water-base gravure ink work in-process of gained in step (1) are dropped into high speed dispersor, the high speed dispersor that polyethylene wax powder 16kg, aerosil 6kg, dispersion agent 0.5kg, defoamer 0.5kg, thanomin 0.5kg is dropped into one by one to rotating speed again and be 1100 revs/min disperses 110 minutes, obtain water-base gravure frosted ink work in-process, for subsequent use;
(3), ink adjustment: qualified step (2) sand milling water-base gravure frosted ink work in-process are dropped into high speed dispersor, then frosting powder 3kg and thanomin 0.5kg are dropped into rotating speed is that the high speed dispersor of 900 revs/min disperses 55 minutes, makes ink finished product.
Embodiment 2
A kind of water-base gravure frosted ink and preparation method thereof;
It is prepared from by the component of following weight percent: the mixed solvent 26.5% that the quality such as ethanol, n-propyl alcohol, water form, alcohol water type vinylformic acid 9%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 38%, polyethylene wax powder 18%, aerosil 4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 2%;
Produce the preparation method of 100kg frosted ink:
(1), prepare burden pre-dispersed: by the mixed solvent being formed by ethanol 6.4kg, n-propyl alcohol 6.3kg, water 6.3kg, alcohol water type vinylformic acid 9kg, thanomin 0.5kg drop into rotating speed be 700 revs/min high speed dispersor disperse 30 minutes; Latex of copolymer in cinnamic acrylic ester 38kg again, ethanol 1.6kg, n-propyl alcohol 1.7kg, water 1.7kg mixed solvent input rotating speed are that the high speed dispersor of 700 revs/min disperses 30 minutes, obtain water-base gravure ink work in-process, for subsequent use;
(2), frosted agitating procedure: the water-base gravure ink work in-process of gained in step (1) are dropped into high speed dispersor, the high speed dispersor that polyethylene wax powder 17kg, aerosil 3kg, dispersion agent 0.5kg, defoamer 0.5kg, thanomin 0.5kg is dropped into one by one to rotating speed again and be 1200 revs/min disperses within 120 minutes, to obtain water-base gravure frosted ink work in-process, for subsequent use;
(3), ink adjustment: water-base gravure frosted ink the work in-process qualified sand milling of step (2) gained are dropped into high speed dispersor, be that 1000 revs/min of high speed dispersors disperse 60 minutes by thanomin 0.5kg and frosting powder 2.5kg input rotating speed again, make water-base gravure frosted ink finished product.
Embodiment 3
A kind of water-base gravure frosted ink and preparation method thereof;
It is prepared from by the component of following weight percent: the mixed solvent 28% that the quality such as ethanol, n-propyl alcohol, water form, alcohol water type vinylformic acid 9%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 37%, polyethylene wax powder 17.5%, aerosil 4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 3%;
Produce the preparation method of 100kg frosted ink:
(1), prepare burden pre-dispersed: by 19kg by ethanol, n-propyl alcohol, water mixed dissolution, alcohol water type vinylformic acid 9kg, thanomin 0.5kg drop into rotating speed be 800 revs/min high speed dispersor disperse 35 minutes; It is that the high speed dispersor of 800 revs/min disperses 35 minutes that the mixed solvent again latex of copolymer in cinnamic acrylic ester 37kg and 6kg being made up of ethanol, n-propyl alcohol, water drops into rotating speed, obtains water-base gravure ink work in-process, for subsequent use;
(2), frosted agitating procedure: the water-base gravure ink work in-process of gained in step (1) are dropped into high speed dispersor, the high speed dispersor that polyethylene wax powder 17.5kg, aerosil 4kg, dispersion agent 0.5kg, defoamer 0.5kg, thanomin 0.5kg is dropped into one by one to machine rotating speed again and be 1300 revs/min disperses within 130 minutes, to obtain water-base gravure frosted ink work in-process, for subsequent use;
(3), ink adjustment: water-base gravure frosted ink the work in-process qualified sand milling of step (2) gained are dropped into high speed dispersor, the high speed dispersor of thanomin 0.5kg and frosting powder 3kg being put into rotating speed again and be 1100 revs/min disperses 65 minutes, makes frosted ink finished product.
Claims (10)
1. a water-base gravure frosted ink, it is characterized in that: it is prepared from by the component of following weight percent: the mixed solvent 16-31% being formed by quality such as ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid 5-10%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 37-40%, polyethylene wax powder 16-18%, aerosil 3-4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 2-3%.
2. a kind of water-base gravure frosted ink according to claim 1, it is characterized in that: it is prepared from by the component of following weight percent: the mixed solvent 19-28% being formed by quality such as ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid 6-8%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 38-40%, polyethylene wax powder 16-18%, aerosil 3-4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 2-3%.
3. a kind of water-base gravure frosted ink according to claim 1, it is characterized in that: it is prepared from by the component of following weight percent: the mixing molten 26.5% being formed by quality such as ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid 9%, thanomin 1.5%, latex of copolymer in cinnamic acrylic ester 38%, polyethylene wax powder 18%, aerosil 4%, dispersion agent 0.5%, defoamer 0.5%, frosting powder 2%.
4. according to the preparation method of a kind of water-base gravure frosted ink described in claim 1,2 or 3, it is characterized in that:
(1), prepare burden pre-dispersed: the mixed solvent that 10-20% is become by the mass mixing such as ethanol, n-propyl alcohol, water, alcohol water type vinylformic acid, 0.5% thanomin, drop into high speed dispersor, adjusting rotary speed and time are carried out dispersing and dissolving, and after dissolving completely, then the mixed solvent that latex of copolymer in cinnamic acrylic ester is become by mass mixings such as ethanol, n-propyl alcohol, water with 4%-6% drops into high speed dispersor, adjusting rotary speed and time carry out redispersion and obtain water-base gravure ink work in-process, for subsequent use;
(2), frosted agitating procedure: the water-base gravure ink work in-process of gained in step (1) are dropped into high speed dispersor, again the thanomin of polyethylene wax powder, aerosil, dispersion agent, defoamer and 0.5% is dropped into high speed dispersor one by one, adjusting rotary speed and time, stir and obtain water-base gravure frosted ink work in-process, for subsequent use;
(3), ink adjustment: qualified step (2) sand milling water-base gravure frosted ink work in-process are dropped into high speed dispersor, then the thanomin of frosting powder and 0.5% is dropped into high speed dispersor and carry out redispersion, and adjusting rotary speed and time; The mixed solvent again 2%-5% being made up of ethanol, n-propyl alcohol, water drops into high speed dispersor and carries out whole dispersion, adjusting rotary speed and time, and regulate pH value between 8-9, make water-base gravure frosted ink finished product.
5. the preparation method of a kind of water-base gravure frosted ink according to claim 4, is characterized in that: in described step (1), just disperse, high speed dispersor rotating speed is 600-700 rev/min when redispersion, jitter time is 25-35 minute.
6. the preparation method of a kind of water-base gravure frosted ink according to claim 5, is characterized in that: in described step (1), just disperse, high speed dispersor rotating speed is 700 revs/min when redispersion, jitter time is 30 minutes.
7. the preparation method of a kind of water-base gravure frosted ink according to claim 4, is characterized in that: while dispersion in described step (2), high speed dispersor rotating speed is 1100-1300 rev/min, and jitter time is 110-130 minute.
8. the preparation method of a kind of water-base gravure frosted ink according to claim 7, is characterized in that: while dispersion in described step (2), high speed dispersor rotating speed is 1200 revs/min, and jitter time is 120 minutes.
9. the preparation method of a kind of water-base gravure frosted ink according to claim 4, is characterized in that: when the middle redispersion of described step (3), high speed dispersor rotating speed is 900-1100 rev/min, and jitter time is 55-65 minute; When disperse described end, high speed dispersor rotating speed is 900-1100 rev/min, and jitter time is 15-25 minute.
10. the preparation method of a kind of water-base gravure frosted ink according to claim 9, is characterized in that: when the middle redispersion of described step (3), high speed dispersor rotating speed is 1000 revs/min, and jitter time is 60 minutes; When disperse described end, high speed dispersor rotating speed is 1000 revs/min, and jitter time is 20 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310030182.2A CN103073950B (en) | 2013-01-28 | 2013-01-28 | Water-base frosted gravure ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310030182.2A CN103073950B (en) | 2013-01-28 | 2013-01-28 | Water-base frosted gravure ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103073950A CN103073950A (en) | 2013-05-01 |
| CN103073950B true CN103073950B (en) | 2014-06-18 |
Family
ID=48150653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310030182.2A Expired - Fee Related CN103073950B (en) | 2013-01-28 | 2013-01-28 | Water-base frosted gravure ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103073950B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038403A (en) * | 2015-08-26 | 2015-11-11 | 云南彩丰油墨有限公司 | Water-based gravure pearly luster varnish and preparation method thereof |
| CN105038402A (en) * | 2015-08-26 | 2015-11-11 | 云南彩丰油墨有限公司 | Water-based gravure metal gold varnish and preparation method thereof |
| CN107474630A (en) * | 2017-08-31 | 2017-12-15 | 武汉虹之彩包装印刷有限公司 | A kind of aquosity intaglio printing ink |
| CN107987607A (en) * | 2017-12-18 | 2018-05-04 | 苏州中科纳福材料科技有限公司 | Water-based ink and preparation method thereof |
| CN107892841A (en) * | 2017-12-25 | 2018-04-10 | 安徽省临泉县万隆塑料包装有限公司 | A kind of plastic packaging bag printing water ink and preparation method thereof |
| CN110608939B (en) * | 2019-08-28 | 2022-03-29 | 广东风华高新科技股份有限公司 | Ceramic electronic component metallographic section and preparation method thereof |
| CN112680025A (en) * | 2020-11-27 | 2021-04-20 | 江苏唐彩新材料科技股份有限公司 | Water-based gravure frosted ink and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6099944A (en) * | 1998-12-02 | 2000-08-08 | Avery Dennison Corporation | Heat-transfer label including a frosted ink design |
| CN101275043B (en) * | 2007-03-28 | 2012-03-14 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101284965B (en) * | 2007-04-10 | 2011-09-07 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| JP2009161710A (en) * | 2008-01-10 | 2009-07-23 | Dic Corp | Surface printing mat ink composition for laminated film |
| CN102241913B (en) * | 2011-05-24 | 2013-08-21 | 深圳扬丰印刷有限公司 | Gravure water-based frosted ink and preparation method thereof |
| CN102796417A (en) * | 2011-09-15 | 2012-11-28 | 武汉虹之彩包装印刷有限公司 | Gravure line ultraviolet (UV) frosted ink and method for preparing same |
-
2013
- 2013-01-28 CN CN201310030182.2A patent/CN103073950B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103073950A (en) | 2013-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103073950B (en) | Water-base frosted gravure ink and preparation method thereof | |
| CN103073952B (en) | Alcohol ester-soluble ink for cast coating cardboard intaglio printing and preparation method of alcohol ester-soluble ink | |
| CN106590162B (en) | Water-based gravure plastic film surface printing ink and preparation method thereof | |
| CN101979446B (en) | Gravure ink capable of generating special surface effects and preparation method | |
| CN102702861B (en) | Alcohol-soluble ink and flexible printing method of packaging film | |
| CN104449030B (en) | Solvent type gravure pearlescent ink and preparation method thereof | |
| CN101864210A (en) | Alcohol-soluble printing ink and preparation method thereof | |
| CN101942252A (en) | Non-benzene imaging layer for laser hot stamping foil and preparation method thereof | |
| CN105038403A (en) | Water-based gravure pearly luster varnish and preparation method thereof | |
| CN107022223A (en) | A kind of cork paper water-base gravure ink and preparation method thereof | |
| CN104212234A (en) | Alcohol-soluble type flexograhic printing ink | |
| CN103819962B (en) | High resolving power water-based flexographic ink and preparation method thereof | |
| CN105038402A (en) | Water-based gravure metal gold varnish and preparation method thereof | |
| CN104231735A (en) | Water-based gravure ink for cigarette packs and preparation method of ink | |
| CN111057411A (en) | Environment-friendly viscosity reducer for printing ink and preparation method thereof | |
| CN104830142A (en) | Environmental-friendly viscosity reducer used for printing ink | |
| CN105086608A (en) | Degradable UV offset printing ink and preparing method thereof | |
| CN107189540B (en) | UV offset frosted ink and preparation method thereof | |
| CN104387857A (en) | Environment-friendly nano paint and preparation method thereof | |
| CN111500113B (en) | Copper plate paper gravure water-based ink and preparation method thereof | |
| CN104312268A (en) | Environment-friendly printing ink with high adhesive force | |
| CN104559440A (en) | Formula and preparation method of Bluish printing ink | |
| CN107502053A (en) | Pearl ink for glass and preparation method thereof | |
| CN110527352A (en) | A kind of water-base gravure plastic film High-adhesion ink and preparation method thereof | |
| CN106049085B (en) | A kind of discharge printing composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140618 Termination date: 20190128 |