CN107892841A - A kind of plastic packaging bag printing water ink and preparation method thereof - Google Patents
A kind of plastic packaging bag printing water ink and preparation method thereof Download PDFInfo
- Publication number
- CN107892841A CN107892841A CN201711416546.5A CN201711416546A CN107892841A CN 107892841 A CN107892841 A CN 107892841A CN 201711416546 A CN201711416546 A CN 201711416546A CN 107892841 A CN107892841 A CN 107892841A
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- water
- ink
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- plastic packaging
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Wrappers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of plastic packaging bag printing water ink, it is made up of following raw material：30 40 parts of styrene-acrylate, 46 parts of the type aqueous wear-resistant wax liquors of D 806,35 parts of pigment, 35 parts of nano-aluminium oxide, 23 parts of Glide482 types levelling agent, 12 parts of castor oil, dodecyl benzyl dimethyl ammonium chloride 12 part, nanometer MoB40.5 1 parts of cluster, 60 70 parts of deionized water；The invention also discloses the preparation method of the water-based ink, and each raw material is stirred, is uniformly dispersed, and the water-based ink is can be prepared by through ball mill grinding.The ink of the present invention uses styrene-acrylate as bridging agent, deionized water is solvent, other auxiliary agents of scientific matching are with the addition of simultaneously, make the ink that there is excellent rub resistance, be not easy the resistance to mould performance of skinning, corrosion resistant, it is printed on the surface of plastic packaging bag, the rate of drying of ink is fast, not fugitive color, and the glossiness of ink is high, can play mark and propaganda function well.
Description
Technical field
The invention belongs to Polywoven Bag print field, in particular it relates to a kind of plastic packaging bag printing water ink
And preparation method thereof.
Background technology
Plastic packaging bag is a kind of using plastics as raw material, for the packaging bag of various articles for use in production and living, is used extensively
In daily life and industrial production.Although plastic packaging bag has certain harm to environment, current utilization rate is still
Compare high.In use, it is necessary in plastic packaging bag surface printing ink, for the effect such as identifying, publicizing.
Water-based ink has environmental protection, free from environmental pollution, the advantages that being harmful to human health, in plastic packaging bag print field
Develop rapidly, but rub resistance, fugitive color, color be not poor for the water-based ink generally existing that plastic packaging bag surface uses at present
The problem of, the effect for identifying and publicizing well can not be played.
The content of the invention
For the deficiencies in the prior art in above-mentioned background technology, the invention provides a kind of plastic packaging bag printing water
Ink and preparation method thereof, it is bridging agent by using cinnamic acrylic ester, deionized water is solvent, while with the addition of section
Learn other auxiliary agents of proportioning so that ink has excellent rub resistance, is not easy the resistance to mould performance of skinning, corrosion resistant.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of plastic packaging bag printing water ink, is made up of following raw material：Cinnamic acrylic ester 30-
40 parts, D-806 type aqueous wear-resistant wax liquor 4-6 parts, pigment 3-5 parts, nano-aluminium oxide 3-5 parts, Glide482 type levelling agents
2-3 parts, castor oil 1-2 parts, dodecyl benzyl dimethyl ammonium chloride 1-2 parts, nanometer MoB4Cluster 0.5-1 parts, deionized water
60-70 parts；
The water-based ink is made up of following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionization
Four kinds of raw material mixing of water, are heated to 45-55 DEG C, constant temperature stirs, and the first mixed liquor is made；
(2) by pigment, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster mixes,
Ultrasonic disperse is uniform, obtains the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.4-
0.6 mixing, disperses in advance in high speed dispersor, stands, obtains thick water-based ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds uniform, obtained plastic packaging bag print
Brush water-based ink.
The pigment is phthalocyanine blue or nigrosine.
A kind of preparation method of plastic packaging bag printing water ink, comprises the following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionization
Four kinds of raw material mixing of water, are heated to 45-55 DEG C, constant temperature stirs, and the first mixed liquor is made；
(2) by pigment, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster mixes,
Ultrasonic disperse is uniform, obtains the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.4-
0.6 mixing, disperses in advance in high speed dispersor, stands, obtains thick water-based ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds uniform, obtained plastic packaging bag print
Brush water-based ink.
Ultrasonic disperse disperses 1-2h under the conditions of 15-25 DEG C in the step (2).
The rotating speed 4000-5000r/min of step (3) the high speed dispersion machine, scattered 15-20min.
Ball mill grinding 1.5-2h, ball milling speed 1000-1200r/min in the step (4).
Beneficial effects of the present invention：
A kind of plastic packaging bag water-based ink provided by the invention and preparation method thereof, the ink uses styrene-the third
Olefin(e) acid ester is bridging agent, and deionized water is solvent, while with the addition of other auxiliary agents of scientific matching, has the ink excellent
Rub resistance, the resistance to mould performance of skinning, corrosion resistant is not easy, is printed on the surface of plastic packaging bag, the rate of drying of ink is soon, no
Fugitive color, the glossiness of ink is high, can play mark and propaganda function well；The preparation process of the present invention is simple,
It is easily achieved, is easy to control, dosage is few, and integrated cost is low.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only part of the embodiment of the present invention to apply example, rather than whole embodiments.It is general based on the embodiment in the present invention, this area
All other embodiment that logical technical staff is obtained under the premise of creative work is not made, belong to what the present invention protected
Scope.
A kind of plastic packaging bag printing water ink, is made up of following raw material：Cinnamic acrylic ester 30-
40 parts, D-806 type aqueous wear-resistant wax liquor 4-6 parts, pigment 3-5 parts, nano-aluminium oxide 3-5 parts, Glide482 type levelling agents
2-3 parts, castor oil 1-2 parts, dodecyl benzyl dimethyl ammonium chloride 1-2 parts, nanometer MoB4Cluster 0.5-1 parts, deionized water
60-70 parts；
Pigment is phthalocyanine blue or nigrosine；
The hardness of deionized water is low, in water-based ink this alkaline system, it is not easy to ink is produced precipitation；
The addition of dodecyl benzyl dimethyl ammonium chloride causes ink to have the advantages of anticorrosive mildewproof；
Aqueous wear-resistant wax liquor is favorably improved the gloss of water-based ink；
Nanometer MoB4Cluster is the boron cluster of Mo doping, and the micro addition of the nano-sized materials of the sandwich structure can
Strengthen the adhesive force of ink；
A kind of preparation method of plastic packaging bag printing water ink, comprises the following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionization
Four kinds of raw material mixing of water, are heated to 45-55 DEG C, constant temperature stirs, and the first mixed liquor is made；
(2) by pigment, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster mixes,
The ultrasonic disperse 1-2h under the conditions of 15-25 DEG C, obtain the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.4-
0.6 mixing, disperses, the rotating speed 4000-5000r/min of high speed dispersor in advance in high speed dispersor, disperses 15-20min, quiet
Put, obtain thick water-based ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds 1.5-2h, ball milling speed 1000-
1200r/min, plastic packaging bag printing water ink is made.
Embodiment 1
A kind of plastic packaging bag printing water ink, is made up of following raw material：Cinnamic acrylic ester 30
Part, 4 parts of D-806 type aqueous wear-resistants wax liquor, 3 parts of phthalocyanine blue, 3 parts of nano-aluminium oxide, 2 parts of Glide482 types levelling agent, castor
1 part of sesame oil, dodecyl benzyl dimethyl ammonium chloride 1 part, nanometer MoB40.5 part of cluster, 60 parts of deionized water；
The preparation method of the water-based ink, comprises the following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionization
Four kinds of raw material mixing of water, are heated to 45 DEG C, constant temperature stirs, and the first mixed liquor is made；
(2) by phthalocyanine blue, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster is mixed
Close, the ultrasonic disperse 1h under the conditions of 15 DEG C, obtain the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.4
Mixing, disperses, the rotating speed 4000r/min of high speed dispersor in advance in high speed dispersor, disperses 15min, stands, obtains thick water
Property ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds 1.5h, ball milling speed 1000r/
Min, plastic packaging bag printing water ink is made.
Embodiment 2
A kind of plastic packaging bag printing water ink, is made up of following raw material：Cinnamic acrylic ester 35
Part, 5 parts of D-806 type aqueous wear-resistants wax liquor, 4 parts of nigrosine, 4 parts of nano-aluminium oxide, 2.5 parts of Glide482 types levelling agent,
1.5 parts of castor oil, dodecyl benzyl dimethyl ammonium chloride 1.5 part, nanometer MoB40.7 part of cluster, 65 parts of deionized water；
The preparation method of the water-based ink, comprises the following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionization
Four kinds of raw material mixing of water, are heated to 50 DEG C, constant temperature stirs, and the first mixed liquor is made；
(2) by nigrosine, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster is mixed
Close, the ultrasonic disperse 1.5h under the conditions of 20 DEG C, obtain the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.5
Mixing, disperses, the rotating speed 4000-5000r/min of high speed dispersor in advance in high speed dispersor, disperses 18min, stands, obtains
To thick water-based ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds 1.8h, ball milling speed 1100r/
Min, plastic packaging bag printing water ink is made.
Embodiment 3
A kind of plastic packaging bag printing water ink, is made up of following raw material：Cinnamic acrylic ester 40
Part, 6 parts of D-806 type aqueous wear-resistants wax liquor, 5 parts of phthalocyanine blue, 5 parts of nano-aluminium oxide, 3 parts of Glide482 types levelling agent, castor
2 parts of sesame oil, dodecyl benzyl dimethyl ammonium chloride 2 part, nanometer MoB41 part of cluster, 70 parts of deionized water；
The preparation method of the water-based ink, comprises the following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionization
Four kinds of raw material mixing of water, are heated to 55 DEG C, constant temperature stirs, and the first mixed liquor is made；
(2) by phthalocyanine blue, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster is mixed
Close, the ultrasonic disperse 2h under the conditions of 25 DEG C, obtain the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.6
Mixing, disperses, the rotating speed 5000r/min of high speed dispersor in advance in high speed dispersor, disperses 20min, stands, obtains thick water
Property ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds 2h, ball milling speed 1200r/
Min, plastic packaging bag printing water ink is made.
Present invention disclosed above preferred embodiment is only intended to help and illustrates the present invention.Preferred embodiment is not detailed
All details are described, it is only described embodiment also not limit the invention.Obviously, according to the content of this specification,
It can make many modifications and variations.This specification is chosen and specifically describes these embodiments, is to preferably explain the present invention
Principle and practical application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only
Limited by claims and its four corner and equivalent.
Claims (6)
1. a kind of plastic packaging bag printing water ink, it is characterised in that be made up of following raw material：Styrene-the third
Olefin(e) acid ester 30-40 parts, D-806 type aqueous wear-resistant wax liquor 4-6 parts, pigment 3-5 parts, nano-aluminium oxide 3-5 parts, Glide482
Type levelling agent 2-3 parts, castor oil 1-2 parts, dodecyl benzyl dimethyl ammonium chloride 1-2 parts, nanometer MoB4Cluster 0.5-1 parts,
Deionized water 60-70 parts；
The water-based ink is made up of following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionized water four
Kind raw material mixing, is heated to 45-55 DEG C, and constant temperature stirs, and the first mixed liquor is made；
(2) by pigment, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster mixes, ultrasound
It is uniformly dispersed, obtains the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.4-0.6
Mixing, disperses in advance in high speed dispersor, stands, obtains thick water-based ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds uniform, obtained plastic packaging bag printing use
Water-based ink.
2. a kind of plastic packaging bag printing water ink according to claim 1, it is characterised in that the pigment is phthalein
Cyanines indigo plant or nigrosine.
A kind of 3. preparation method of plastic packaging bag printing water ink according to claim 1, it is characterised in that bag
Include following steps：
(1) by cinnamic acrylic ester, Glide482 types levelling agent, dodecyl benzyl dimethyl ammonium chloride, deionized water four
Kind raw material mixing, is heated to 45-55 DEG C, and constant temperature stirs, and the first mixed liquor is made；
(2) by pigment, D-806 type aqueous wear-resistants wax liquor, nano-aluminium oxide, castor oil, nanometer MoB4Cluster mixes, ultrasound
It is uniformly dispersed, obtains the second mixed liquor；
(3) it is 1 in mass ratio by the second mixed liquor made from the first mixed liquor made from step (1) and step (2):0.4-0.6
Mixing, disperses in advance in high speed dispersor, stands, obtains thick water-based ink；
(4) thick water-based ink is added in single tank planetary high-energy ball mill and grinds uniform, obtained plastic packaging bag printing use
Water-based ink.
A kind of 4. preparation method of plastic packaging bag printing water ink according to claim 3, it is characterised in that institute
State ultrasonic disperse in step (2) and disperse 1-2h under the conditions of 15-25 DEG C.
A kind of 5. preparation method of plastic packaging bag printing water ink according to claim 3, it is characterised in that institute
State the rotating speed 4000-5000r/min of step (3) high speed dispersion machine, scattered 15-20min.
A kind of 6. preparation method of plastic packaging bag printing water ink according to claim 3, it is characterised in that institute
State ball mill grinding 1.5-2h, ball milling speed 1000-1200r/min in step (4).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711416546.5A CN107892841A (en) | 2017-12-25 | 2017-12-25 | A kind of plastic packaging bag printing water ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711416546.5A CN107892841A (en) | 2017-12-25 | 2017-12-25 | A kind of plastic packaging bag printing water ink and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107892841A true CN107892841A (en) | 2018-04-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201711416546.5A Pending CN107892841A (en) | 2017-12-25 | 2017-12-25 | A kind of plastic packaging bag printing water ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256899A (en) * | 2019-06-04 | 2019-09-20 | 浙江天地化工有限公司 | A kind of water-based ink and preparation method thereof |
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| CN102352151A (en) * | 2011-08-24 | 2012-02-15 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-based ink for plastic printing and preparation method thereof |
| CN103073950A (en) * | 2013-01-28 | 2013-05-01 | 云南彩丰油墨有限公司 | Water-base frosted gravure ink and preparation method thereof |
| US20140232782A1 (en) * | 2013-02-21 | 2014-08-21 | Seiko Epson Corporation | Ink composition and ink jet recording method |
| CN104140713A (en) * | 2014-08-05 | 2014-11-12 | 厦门格林泰新材料科技有限公司 | Water-based ink and preparation method and application thereof |
-
2017
- 2017-12-25 CN CN201711416546.5A patent/CN107892841A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352151A (en) * | 2011-08-24 | 2012-02-15 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Water-based ink for plastic printing and preparation method thereof |
| CN103073950A (en) * | 2013-01-28 | 2013-05-01 | 云南彩丰油墨有限公司 | Water-base frosted gravure ink and preparation method thereof |
| US20140232782A1 (en) * | 2013-02-21 | 2014-08-21 | Seiko Epson Corporation | Ink composition and ink jet recording method |
| CN104140713A (en) * | 2014-08-05 | 2014-11-12 | 厦门格林泰新材料科技有限公司 | Water-based ink and preparation method and application thereof |
Non-Patent Citations (1)
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| 王杨勇: ""水性油墨用苯乙烯-丙烯酸树脂的合成研究"", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256899A (en) * | 2019-06-04 | 2019-09-20 | 浙江天地化工有限公司 | A kind of water-based ink and preparation method thereof |
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