CN110256899A - A kind of water-based ink and preparation method thereof - Google Patents
A kind of water-based ink and preparation method thereof Download PDFInfo
- Publication number
- CN110256899A CN110256899A CN201910479540.5A CN201910479540A CN110256899A CN 110256899 A CN110256899 A CN 110256899A CN 201910479540 A CN201910479540 A CN 201910479540A CN 110256899 A CN110256899 A CN 110256899A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- based ink
- ink
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water-based inks, raw material comprising following parts by weight of component: 20-30 parts of cinnamic acrylic ester, 2-5 parts of aqueous wear-resistant wax liquor of D-806 type, 6-12 parts of pigment, 1-4 parts of expanded graphite powder, 5-10 parts of aluminium triphosphate, 15-20 parts of ethyl acetate, 8-13 parts of TiO_2 nanoparticles, 3-7 parts of defoaming agent, 2-6 parts of levelling agent, it further include a kind of preparation method of water-based ink, dichloride in anatase type TiO2 powder has nontoxicity, the antibiotic property of wide spectrum, stability is good, it is resourceful, the advantages that cheap, it is added in ink, the ink anti-microbial property of preparation is good, it is at low cost.Make the ink that there is excellent rub resistance using formula of the invention, be not easy the resistance to mould performance of skinning, corrosion resistant, it is printed on the surface of plastic packaging bag, the rate of drying of ink is fast, fugitive color, the glossiness height of ink can not play mark and propaganda function well；Preparation process of the invention is simple, it is easy to accomplish, convenient for control, dosage is few, and overall cost is low.
Description
Technical field
The present invention relates to water-based ink technical field, specifically a kind of water-based ink and preparation method thereof.
Background technique
Ink is by chromoplast (such as pigment, dyestuff), link stuff, fills out and (fill) the uniform of the material compositions such as material, additional material
Mixture；It can be carried out printing, and dry in printed body；It is to have color, the pulpous state adherent with certain fluidity.Cause
This, color (form and aspect), body bone (rheological properties such as dilute thick, fluidity) and drying property are three most important performances of ink.
There are many their type, and physical property is also different, and some is very thick, very viscous；And some is quite dilute.Some is connected with vegetable oil work
Ramming material；Some resins and solvent or water etc. make link stuff.These be all according to the object i.e. stock of printing, printing process,
The type of printing plate and drying means etc. determine.
Water-based ink has environmental protection, free from environmental pollution, and the advantages that being harmful to human health, however traditional water-based ink is anti-
Bacterium performance is poor, and when paint microbial contamination, as long as the growth conditions such as temperature, humidity are suitable for, microorganism will breed without restraint,
After human contact, various diseases can be infected, threaten human health.
Summary of the invention
The purpose of the present invention is to provide a kind of water-based inks and preparation method thereof, to solve to propose in above-mentioned background technique
The problem of.
To achieve the above object, the invention provides the following technical scheme:
A kind of water-based ink, the raw material comprising following parts by weight of component: 20-30 parts of cinnamic acrylic ester, D-806 type
2-5 parts of aqueous wear-resistant wax liquor, 6-12 parts of pigment, 1-4 parts of expanded graphite powder, 5-10 parts of aluminium triphosphate, ethyl acetate 15-20
Part, 8-13 parts of TiO_2 nanoparticles, 3-7 parts of defoaming agent, 2-6 parts of levelling agent.
As a further solution of the present invention: the raw material comprising following parts by weight of component: cinnamic acrylic ester 23-27
Part, 3-4 parts of D-806 type aqueous wear-resistant wax liquor, 8-10 parts of pigment, 2-3 parts of expanded graphite powder, 6-9 parts of aluminium triphosphate, acetic acid second
18-22 parts of ester, 10-12 parts of TiO_2 nanoparticles, 4-6 parts of defoaming agent, 3-5 parts of levelling agent.
As a further solution of the present invention: the raw material comprising following parts by weight of component: 25 parts of cinnamic acrylic ester,
3 parts of D-806 type aqueous wear-resistant wax liquor, 9 parts of pigment, 2 parts of expanded graphite powder, 8 parts of aluminium triphosphate, ethyl acetate 20 part, nanometer
11 parts of TiO2 powder, 5 parts of defoaming agent, 4 parts of levelling agent.
As a further solution of the present invention: the expanded graphite Powder Particle Size is 50~100 mesh.
As a further solution of the present invention: the pigment is phthalocyanine blue or nigrosine.
As a further solution of the present invention: the TiO_2 nanoparticles are dichloride in anatase type TiO2 powder.
A kind of preparation method of water-based ink, steps are as follows:
(1) five kinds of cinnamic acrylic ester, levelling agent, defoaming agent, expanded graphite powder, deionized water raw materials are mixed, is added
To 45-55 DEG C, constant temperature stirs evenly heat, and the first mixed liquor is made；
(2) pigment, D-806 type aqueous wear-resistant wax liquor, aluminium triphosphate, ethyl acetate, TiO_2 nanoparticles are mixed, is surpassed
Sound is uniformly dispersed, and obtains the second mixed liquor；
It (3) is in mass ratio 1:0.4- by the second mixed liquor made from the first mixed liquor made from step (1) and step (2)
0.6
Mixing, disperses in advance in high speed disperser, stands, obtains thick water-based ink；
(4) by step (3) be made thick water-based ink be added in single tank planetary high-energy ball mill grind uniformly, be made water
Property ink.
As a further solution of the present invention: ultrasonic disperse disperses 1-2h under the conditions of 15-25 DEG C in the step (2).
As a further solution of the present invention: the revolving speed 4000-5000r/min of step (3) the high speed dispersion machine, dividing
Dissipate 15-20min.
Compared with prior art, the beneficial effects of the present invention are: dichloride in anatase type TiO2 powder is with non-toxic, wide spectrum
The advantages that antibiotic property, stability are good, resourceful, cheap, is added in ink, and the ink anti-microbial property of preparation is good, at
This is low.Using the high temperature resistant of expanded graphite powder, the feature that expansion multiple is high, heat insulation is strong, the fire endurance of ink is improved；Benefit
With the hydrophobicity of expanded graphite powder, improve ink instead of the pentaerythrite in existing many ink as the carbon source in ink
Water-resistance property of coating；The features such as specific surface using expanded graphite powder is big, sterile growth environment, overcoming must additional a variety of auxiliary agent
It just can guarantee the problems of stability in storage of ink system.And make the ink that there is excellent antifriction using formula of the invention
It wipes, be not easy the resistance to mould performance of skinning, corrosion resistant, be printed on the surface of plastic packaging bag, the rate of drying of ink is fast, is not easy to take off
The glossiness of color, ink is high, can play mark and propaganda function well；Preparation process of the invention is simple, is easy to
It realizes, convenient for control, dosage is few, and overall cost is low.
Specific embodiment
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.
Below in conjunction with embodiment, the present invention will be described in detail.
Embodiment one
A kind of water-based ink, the raw material comprising following parts by weight of component: 230 parts of cinnamic acrylic ester, D-806 type water
Wear-resisting 5 parts of the wax liquor of property, 12 parts of pigment, 4 parts of expanded graphite powder, 10 parts of aluminium triphosphate, 20 parts of ethyl acetate, TiO_2 nanoparticles
13 parts, 7 parts of defoaming agent, 6 parts of levelling agent.
The expanded graphite Powder Particle Size is 100 mesh.
The pigment is phthalocyanine blue or nigrosine.
The TiO_2 nanoparticles are dichloride in anatase type TiO2 powder.
A kind of preparation method of water-based ink, steps are as follows:
(1) five kinds of cinnamic acrylic ester, levelling agent, defoaming agent, expanded graphite powder, deionized water raw materials are mixed, is added
To 55 DEG C, constant temperature stirs evenly heat, and the first mixed liquor is made；
(2) pigment, D-806 type aqueous wear-resistant wax liquor, aluminium triphosphate, ethyl acetate, TiO_2 nanoparticles are mixed, is surpassed
Sound is uniformly dispersed, and obtains the second mixed liquor；
It (3) is in mass ratio 1:0.6 by the second mixed liquor made from the first mixed liquor made from step (1) and step (2)
Mixing, disperses in advance in high speed disperser, stands, obtains thick water-based ink；
(4) by step (3) be made thick water-based ink be added in single tank planetary high-energy ball mill grind uniformly, be made water
Property ink.
Ultrasonic disperse disperses 2h under the conditions of 25 DEG C in the step (2).
Revolving speed 5000r/min, the dispersion 20min of step (3) the high speed dispersion machine.
Embodiment two
A kind of water-based ink, the raw material comprising following parts by weight of component: 20 parts of cinnamic acrylic ester, D-806 type are aqueous
2 parts of wear-resisting wax liquor, 6 parts of pigment, 1 part of expanded graphite powder, 5 parts of aluminium triphosphate, 15 parts of ethyl acetate, 8 parts of TiO_2 nanoparticles,
3 parts of defoaming agent, 2 parts of levelling agent.
The expanded graphite Powder Particle Size is 50 mesh.
The pigment is phthalocyanine blue or nigrosine.
The TiO_2 nanoparticles are dichloride in anatase type TiO2 powder.
A kind of preparation method of water-based ink, steps are as follows:
(1) five kinds of cinnamic acrylic ester, levelling agent, defoaming agent, expanded graphite powder, deionized water raw materials are mixed, is added
To 45 DEG C, constant temperature stirs evenly heat, and the first mixed liquor is made；
(2) pigment, D-806 type aqueous wear-resistant wax liquor, aluminium triphosphate, ethyl acetate, TiO_2 nanoparticles are mixed, is surpassed
Sound is uniformly dispersed, and obtains the second mixed liquor；
It (3) is in mass ratio 1:0.4 by the second mixed liquor made from the first mixed liquor made from step (1) and step (2)
Mixing, disperses in advance in high speed disperser, stands, obtains thick water-based ink；
(4) by step (3) be made thick water-based ink be added in single tank planetary high-energy ball mill grind uniformly, be made water
Property ink.
Ultrasonic disperse disperses 1-2h under the conditions of 15 DEG C in the step (2).
Revolving speed 4000r/min, the dispersion 15min of step (3) the high speed dispersion machine.
Embodiment three
A kind of water-based ink, the raw material comprising following parts by weight of component: 25 parts of cinnamic acrylic ester, D-806 type are aqueous
3 parts of wear-resisting wax liquor, 9 parts of pigment, 2 parts of expanded graphite powder, 8 parts of aluminium triphosphate, 20 parts of ethyl acetate, TiO_2 nanoparticles 11
Part, 5 parts of defoaming agent, 4 parts of levelling agent.
The expanded graphite Powder Particle Size is 75 mesh.
The pigment is phthalocyanine blue or nigrosine.
The TiO_2 nanoparticles are dichloride in anatase type TiO2 powder.
A kind of preparation method of water-based ink, steps are as follows:
(1) five kinds of cinnamic acrylic ester, levelling agent, defoaming agent, expanded graphite powder, deionized water raw materials are mixed, is added
To 20 DEG C, constant temperature stirs evenly heat, and the first mixed liquor is made；
(2) pigment, D-806 type aqueous wear-resistant wax liquor, aluminium triphosphate, ethyl acetate, TiO_2 nanoparticles are mixed, is surpassed
Sound is uniformly dispersed, and obtains the second mixed liquor；
It (3) is in mass ratio 1:0.5 by the second mixed liquor made from the first mixed liquor made from step (1) and step (2)
Mixing, disperses in advance in high speed disperser, stands, obtains thick water-based ink；
(4) by step (3) be made thick water-based ink be added in single tank planetary high-energy ball mill grind uniformly, be made water
Property ink.
Ultrasonic disperse disperses 1.5h at 20 °C in the step (2).
Revolving speed 4500r/min, the dispersion 17min of step (3) the high speed dispersion machine.
Comparative example one
Common water-based ink in the market.
Experimental example
Rub resistance test carries out identical rub to printing batten with SUTHERLAND2000 printing friction testing machine respectively
Erasure reason (85 turns/min, 21b clump weight rubs 50 times), carries out the batten rub resistance after friction using density decay rate
Evaluation detects layer of ink water resistance according to the principle that 5.7 water resistances in GB/T17121-1997 are examined；Testing result such as table institute
Show.
| Water resistance rank | Wearability (density decay rate %) | |
| Embodiment one | 4 | 2.35 |
| Embodiment two | 5 | 5.18 |
| Embodiment three | 4 | 3.69 |
| Comparative example one | 3 | 11.24 |
Dichloride in anatase type TiO2 powder has nontoxicity, the antibiotic property of wide spectrum, stability good, resourceful, cheap
The advantages that, it is added in ink, the ink anti-microbial property of preparation is good, at low cost.Utilize the high temperature resistant of expanded graphite powder, expansion times
The feature that number is high, heat insulation is strong, improves the fire endurance of ink；Using the hydrophobicity of expanded graphite powder, as in ink
Carbon source improves the water-resistance property of coating of ink instead of the pentaerythrite in existing many ink；Utilize the specific surface of expanded graphite powder
Greatly, the features such as sterile growth environment, overcome must additional a variety of auxiliary agents just can guarantee the problems of stability in storage of ink system.
And makes the ink that there is excellent rub resistance using formula of the invention, is not easy the resistance to mould performance of skinning, corrosion resistant, printed
On the surface of plastic packaging bag, the rate of drying of ink is fast, fugitive color, the glossiness height of ink can not play good mark
Knowledge and propaganda function；Preparation process of the invention is simple, it is easy to accomplish, convenient for control, dosage is few, and overall cost is low.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of water-based ink, which is characterized in that the raw material comprising following parts by weight of component: cinnamic acrylic ester 20-30
Part, 2-5 parts of D-806 type aqueous wear-resistant wax liquor, 6-12 parts of pigment, 1-4 parts of expanded graphite powder, 5-10 parts of aluminium triphosphate, acetic acid
15-20 parts of ethyl ester, 8-13 parts of TiO_2 nanoparticles, 3-7 parts of defoaming agent, 2-6 parts of levelling agent.
2. a kind of water-based ink according to claim 1, which is characterized in that the raw material comprising following parts by weight of component: benzene
23-27 parts of ethylene-acrylate, 3-4 parts of D-806 type aqueous wear-resistant wax liquor, 8-10 parts of pigment, 2-3 parts of expanded graphite powder, trimerization
6-9 parts of aluminum phosphate, 18-22 parts of ethyl acetate, 10-12 parts of TiO_2 nanoparticles, 4-6 parts of defoaming agent, 3-5 parts of levelling agent.
3. a kind of water-based ink according to claim 1, which is characterized in that the raw material comprising following parts by weight of component: benzene
25 parts of ethylene-acrylate, 3 parts of D-806 type aqueous wear-resistant wax liquor, 9 parts of pigment, 2 parts of expanded graphite powder, 8 parts of aluminium triphosphate,
20 parts of ethyl acetate, 11 parts of TiO_2 nanoparticles, 5 parts of defoaming agent, 4 parts of levelling agent.
4. a kind of water-based ink according to claim 1, which is characterized in that the expanded graphite Powder Particle Size is 50~100
Mesh.
5. a kind of water-based ink according to claim 1, which is characterized in that the pigment is phthalocyanine blue or nigrosine.
6. a kind of water-based ink according to claim 1, which is characterized in that the TiO_2 nanoparticles are dichloride in anatase type
TiO2 powder.
7. a kind of preparation method of water-based ink as described in claim 1, which is characterized in that steps are as follows: (1) by benzene second
Five kinds of alkene-acrylate, levelling agent, defoaming agent, expanded graphite powder, deionized water raw material mixing, are heated to 45-55 DEG C, constant temperature
It stirs evenly, the first mixed liquor is made；(2) by pigment, D-806 type aqueous wear-resistant wax liquor, aluminium triphosphate, ethyl acetate, receive
Rice TiO2 powder mixing, ultrasonic disperse is uniform, obtains the second mixed liquor；(3) by the first mixed liquor and step made from step (1)
(2) the second mixed liquor made from is 1:0 .4-0 .6 in mass ratio
Mixing, disperses in advance in high speed disperser, stands, obtains thick water-based ink；(4) thick aqueous oil is made in step (3)
Ink, which is added in single tank planetary high-energy ball mill, to be ground uniformly, and water-based ink is made.
8. a kind of preparation method of water-based ink as claimed in claim 7, which is characterized in that ultrasound point in the step (2)
Disperse 1-2h under the conditions of being dispersed in 15-25 DEG C.
9. a kind of preparation method of water-based ink as claimed in claim 7 or 8, which is characterized in that step (3) high speed
Revolving speed 4000-5000r/min, the dispersion 15-20min of dispersion machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910479540.5A CN110256899A (en) | 2019-06-04 | 2019-06-04 | A kind of water-based ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910479540.5A CN110256899A (en) | 2019-06-04 | 2019-06-04 | A kind of water-based ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110256899A true CN110256899A (en) | 2019-09-20 |
Family
ID=67916603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910479540.5A Pending CN110256899A (en) | 2019-06-04 | 2019-06-04 | A kind of water-based ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110256899A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634317A (en) * | 2015-10-28 | 2017-05-10 | 上海船舶工艺研究所 | Aqueous two-component fireproof paint containing core-shell structure expansion flame-retardation system and preparation method thereof |
| CN107892841A (en) * | 2017-12-25 | 2018-04-10 | 安徽省临泉县万隆塑料包装有限公司 | A kind of plastic packaging bag printing water ink and preparation method thereof |
| CN107903677A (en) * | 2017-12-24 | 2018-04-13 | 严致迪 | A kind of waterborne antibacterial paint for adding nano-titanium dioxide and preparation method thereof |
-
2019
- 2019-06-04 CN CN201910479540.5A patent/CN110256899A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634317A (en) * | 2015-10-28 | 2017-05-10 | 上海船舶工艺研究所 | Aqueous two-component fireproof paint containing core-shell structure expansion flame-retardation system and preparation method thereof |
| CN107903677A (en) * | 2017-12-24 | 2018-04-13 | 严致迪 | A kind of waterborne antibacterial paint for adding nano-titanium dioxide and preparation method thereof |
| CN107892841A (en) * | 2017-12-25 | 2018-04-10 | 安徽省临泉县万隆塑料包装有限公司 | A kind of plastic packaging bag printing water ink and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| [加]GEORGE WYPYCH 编著，程斌等译: "《填料手册》", 28 February 2003, 中国石化出版社 * |
| 杨保祥等: "《钛基材料制造》", 30 January 2015, 冶金工业出版社 * |
| 边炳鑫等: "《石墨加工及石墨材料》", 30 May 2014, 中国矿业大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104892844B (en) | Vinyl chloride-based resin emulsion, water-based ink and paper used for recording | |
| CN1080748C (en) | Carbon black reacted with diazonium salts and products | |
| CN104507977B (en) | Offset litho printing ink with water and filler content | |
| CN107057518B (en) | Low-temperature quick-drying water epoxy primer and preparation method thereof | |
| CN1275150A (en) | Modified carbon products with leaving group for inks and coatings | |
| CN105968943A (en) | Water-based quick-drying ink composition for gravure | |
| CA2103719A1 (en) | Low rub printing ink | |
| CN102212298B (en) | Aqueous inner wall paint composition | |
| CN103362026A (en) | Coating for chromo board and coating method thereof | |
| CN108192400A (en) | A kind of pigment of drawing and preparation method thereof | |
| CN105504981A (en) | Water-based ink for intaglio printing process of aluminum foil and preparation method of water-based ink | |
| KR20150127950A (en) | Ink compositions for gravure print and Method for making of the same | |
| CN106009983A (en) | Waterborne tape measure bottom layer material and preparation method thereof | |
| EP0058256B1 (en) | Aqueous newsprint inks | |
| CN110256899A (en) | A kind of water-based ink and preparation method thereof | |
| JP3894645B2 (en) | crayon | |
| CN107936756A (en) | A kind of high stability aqueous epoxide resin paint for woodenware | |
| CN106398422A (en) | Antiskid finishing coat and preparation method thereof | |
| CN115746619B (en) | Antibacterial water-based ink and preparation method thereof | |
| CN106566280A (en) | Coated pigment composition and production method thereof | |
| CN104130620A (en) | Application of organosilicon composition in water-based coating | |
| CN109810583A (en) | A kind of super scrubbing resistance bottom surface unification easily japanning and preparation method thereof | |
| JP2004182788A (en) | Multicolor coating composition | |
| US8252105B2 (en) | Biodegradable vehicle/carrier for printing ink | |
| CN108165090A (en) | Water-base gravure plastic film table print dumb light ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190920 |