CN105440788B - Water-based ink and preparation method thereof - Google Patents
Water-based ink and preparation method thereof Download PDFInfo
- Publication number
- CN105440788B CN105440788B CN201610007920.5A CN201610007920A CN105440788B CN 105440788 B CN105440788 B CN 105440788B CN 201610007920 A CN201610007920 A CN 201610007920A CN 105440788 B CN105440788 B CN 105440788B
- Authority
- CN
- China
- Prior art keywords
- water
- based ink
- acrylic resin
- glass microsphere
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000011521 glass Substances 0.000 claims abstract description 60
- 239000000049 pigment Substances 0.000 claims abstract description 60
- 239000004005 microsphere Substances 0.000 claims abstract description 55
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 50
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 50
- 239000008187 granular material Substances 0.000 claims abstract description 41
- 239000002562 thickening agent Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 14
- -1 neutralizer Substances 0.000 claims abstract description 11
- 239000003125 aqueous solvent Substances 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims description 40
- 239000000178 monomer Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 17
- 229920001577 copolymer Polymers 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 11
- 230000033228 biological regulation Effects 0.000 claims description 10
- 229920000570 polyether Polymers 0.000 claims description 9
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 8
- 150000008065 acid anhydrides Chemical class 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 230000002194 synthesizing effect Effects 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 230000002209 hydrophobic effect Effects 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000000908 ammonium hydroxide Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 150000003377 silicon compounds Chemical class 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- GILMNGUTRWPWSY-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(O)COC(=O)C=C GILMNGUTRWPWSY-UHFFFAOYSA-N 0.000 claims description 2
- WUMMIJWEUDHZCL-UHFFFAOYSA-N 3-prop-2-enyloxolane-2,5-dione Chemical compound C=CCC1CC(=O)OC1=O WUMMIJWEUDHZCL-UHFFFAOYSA-N 0.000 claims description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 229940014800 succinic anhydride Drugs 0.000 claims description 2
- 229940117958 vinyl acetate Drugs 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000004945 emulsification Methods 0.000 claims 1
- 238000001802 infusion Methods 0.000 claims 1
- JKJJSJJGBZXUQV-UHFFFAOYSA-N methyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OC JKJJSJJGBZXUQV-UHFFFAOYSA-N 0.000 claims 1
- 239000000976 ink Substances 0.000 abstract description 61
- 238000007639 printing Methods 0.000 abstract description 11
- 238000000227 grinding Methods 0.000 abstract description 9
- 238000009826 distribution Methods 0.000 abstract description 8
- 239000006185 dispersion Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000000945 filler Substances 0.000 abstract description 3
- 239000011888 foil Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000002985 plastic film Substances 0.000 abstract description 2
- 229920006255 plastic film Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 description 36
- 229920005989 resin Polymers 0.000 description 36
- 239000003999 initiator Substances 0.000 description 14
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000011049 pearl Substances 0.000 description 8
- 229910052726 zirconium Inorganic materials 0.000 description 8
- 239000002270 dispersing agent Substances 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000001965 increasing effect Effects 0.000 description 6
- 238000000498 ball milling Methods 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- ONTQJDKFANPPKK-UHFFFAOYSA-L chembl3185981 Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C=C1N=NC1=CC(S([O-])(=O)=O)=C(C=CC=C2)C2=C1O ONTQJDKFANPPKK-UHFFFAOYSA-L 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- MCEBKLYUUDGVMD-UHFFFAOYSA-N [SiH3]S(=O)=O Chemical compound [SiH3]S(=O)=O MCEBKLYUUDGVMD-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- BUZRAOJSFRKWPD-UHFFFAOYSA-N isocyanatosilane Chemical class [SiH3]N=C=O BUZRAOJSFRKWPD-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical group [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 2
- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical compound NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 2
- ZNEMGFATAVGQSF-UHFFFAOYSA-N 1-(2-amino-6,7-dihydro-4H-[1,3]thiazolo[4,5-c]pyridin-5-yl)-2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]ethanone Chemical compound NC=1SC2=C(CN(CC2)C(CC=2OC(=NN=2)C=2C=NC(=NC=2)NC2CC3=CC=CC=C3C2)=O)N=1 ZNEMGFATAVGQSF-UHFFFAOYSA-N 0.000 description 1
- MTLWTRLYHAQCAM-UHFFFAOYSA-N 2-[(1-cyano-2-methylpropyl)diazenyl]-3-methylbutanenitrile Chemical compound CC(C)C(C#N)N=NC(C#N)C(C)C MTLWTRLYHAQCAM-UHFFFAOYSA-N 0.000 description 1
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 description 1
- UNIYDALVXFPINL-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propylsilicon Chemical compound CC(=C)C(=O)OCCC[Si] UNIYDALVXFPINL-UHFFFAOYSA-N 0.000 description 1
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
- NYNKCGWJPNZJMI-UHFFFAOYSA-N Clebopride malate Chemical compound [O-]C(=O)C(O)CC(O)=O.COC1=CC(N)=C(Cl)C=C1C(=O)NC1CC[NH+](CC=2C=CC=CC=2)CC1 NYNKCGWJPNZJMI-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- RFFFKMOABOFIDF-UHFFFAOYSA-N Pentanenitrile Chemical compound CCCCC#N RFFFKMOABOFIDF-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012502 risk assessment Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water-based inks, contain aqueous solvent, water soluble acrylic resin's spheric granules, pigment, levelling agent, neutralizer, thickener and defoaming agent.Water soluble acrylic resin's spheric granules is the sphere that water soluble acrylic resin coats glass microsphere, and its sphere partial size is 2-8mm.Water-based ink provided by the invention not only can carry out grinding distribution to pigment but also can be very good the granules of pigments soaked and stable dispersion is good, and granules of pigments fineness is less than 8 μm, and glass microsphere is eventually as the lesser filler of fineness.The water-based ink can be used for the printing of the materials such as paper, corrugated case, plastic film, metal foil, have the advantages that waterproof, wear-resisting, attachment fastness is good and tinting strength, tinting power is high, and show excellent printing effect.
Description
Technical field
The present invention relates to a kind of water-based inks and preparation method thereof.
Background technique
Ink is the important materials in printing technology, and printing industry of today uses solvent-based ink, benzene, toluene, two more
The organic solvent usage amount of toluene etc is larger, and solvent is volatized into atmosphere after printing, causes seriously to pollute to air；Separately
Outside, organic solvent itself is flammable liquid, forms mixed gas with air after volatilization, meets open fire meeting after reaching explosible limit concentration
It explodes, the Fire risk analysis of production operation environment is very high；Secondly, the toxicity of organic solvent is for the strong of producers
Health is totally unfavorable.With environmental protection and sustainable development require further increase and ink use process in operator
Health, security performance guarantee reinforcement, market constantly increasing the demand of non-organic solvent ink, water-based ink
This demand for development has been complied in development and application.
Water-based ink is to take water as a solvent manufactured ink, greatly reduces or avoid the usage amount of organic solvent, so that
The environmental-protecting performance of ink, security performance and to the health care of operator to being substantially improved.Also, now aqueous
Ink can gradually compare favourably in terms of printing quality and stability with solvent-based ink.Oil-based ink and water-based ink at present
Preparation will be by grinding so that pigment reaches certain fineness and fully dispersed into binder.Milling apparatus uses more
Ball mill and sand mill, mainly by ball or sand under different containers and motion mode to the shock of liquid material, rub
It wipes and shears and have the function that crushing and dispersion pigment particles.Since pigment type is more, accomplish the dedicated then equipment money of spot color
The investment of gold is quite huge；If an equipment is ground as polychrome, equipment cleaning generates a large amount of washes, ring again
Guaranteed cost decline, increased production cost.And ball mill generally uses zirconium pearl as its abrasive media.Zirconia content in pure zirconium pearl
94.6%, also known as 95 zirconium pearls；The zirconia content of zirconium silicate pearl is in 65%, also known as 65 zirconium pearls.65 zirconium bead mills consumption is pure relative to 95
Abrasion want larger for zirconium pearl, and because price is more economical, use is more.With the use of abrasive material, the abrasion of zirconium pearl constantly increases
Greatly, the periodic replacement of zirconium pearl and the clast remained in ink can make Printing ink producing cost increase and ink quality decline.
It is therefore desirable to which a kind of further novel water-based ink of developmental research, can be good at for pigment being dispersed in connection
In material, so that granules of pigments is reached certain fineness and settle out, improve the properties of ink and efficiently controls Printing ink producing
Cost.
Summary of the invention
The purpose of the present invention is to solve the above-mentioned problems of the prior art, and provide a kind of water-based ink and its system
Preparation Method, the acrylic resin particle contained can be used as the abrasive media of pigment in water-based ink, can grind, disperse simultaneously
Stable pigments particle after being completely dissolved to resin, and can be used as binder use, and glass microsphere is invaded in alkaline environment
Erosion, eventually as inorganic filler.
The present invention provides a kind of water-based ink, contains: aqueous solvent, water soluble acrylic resin's spheric granules, pigment, stream
Flat agent, neutralizer, thickener and defoaming agent.
Further, the content of water soluble acrylic resin's spheric granules is 20-35% in the water-based ink；The face
The content of material is 8-25%；The content of the levelling agent is 0.1-0.4%；The content of the neutralizer is 5-10%；The increasing
Thick dose of content is 0.3-5%；The content of the defoaming agent is 0.05-0.5%；The content of the aqueous solvent is 35-65%.
Further, the aqueous solvent is selected from distilled water or deionized water.
Further, the pigment is selected from pigment red 4 8:3, paratonere 57:1, pigment red 81, pigment red 4 9:1, paratonere
122, pigment red 146, pigment blue 15, pigment blue 15: 1, pigment blue 15: 3, pigment yellow 3, pigment Yellow 12, pigment yellow 13, carbon black
One or more of BP470, pigment black 32, titanium dioxide.
Further, the levelling agent is selected from Siloxane-Oxyalkylene Copolymers BYK333, Siloxane-Oxyalkylene Copolymers BNK-
LK600, Siloxane-Oxyalkylene Copolymers MONENG1080, acrylic acid esters co-polymer BNK-M3550, acrylic acid esters co-polymer
One or more of MONENG1153, fluorocarbons levelling agent BNK-4010.
Further, the neutralizer is selected from sodium hydroxide and ammonium hydroxide, N, N- dimethylethanolamine, triethanolamine, a second
One or more of hydramine.
Further, the thickener is selected from the swollen acrylic emulsion thickener TT935 of hydrophobically modified association type alkali soluble, hydrophobic
It is modified the swollen acrylic emulsion thickener ASE-60 of non-association type alkali soluble, association type non-ionic hydrophobic modified polyurethane type thickener
One or more of PS 166 and RM-2020.
Further, the defoaming agent chooses Siloxane-Oxyalkylene Copolymers, trimethyl silicone oil, silicone emulsion, polyethylene glycol
In fatty acid type surfactant and polyethers and organic silicon compound defoaming agent, polyethers and silicon-containing polyether Compounded Antifoamer DF-220
One or more.
Water soluble acrylic resin's spheric granules in the present invention coats glass microsphere for water soluble acrylic resin
Sphere, and its sphere partial size is 2-8mm.
Further, the partial size of the glass microsphere is the 1/5-4/5 of the sphere partial size, and the glass microsphere is real
The heart or hollow ball.
Further, the partial size of the glass microsphere is 10-50 μm, density 0.12-2.6g/cm3, Mohs' hardness is
5.5-7.5.Wherein, the density of the glass microsphere refers to the bulk density of microballoon.In such partial size, density and hardness
Under, after enabling to outermost resin to dissolve within the scope of certain pH, the glass microsphere in resin particle is to granules of pigments
Certain wearability is effectively ground and is had, when later period pH increases, glass microsphere can gradually be etched, refine,
Fineness becomes smaller or even is etched completely, as ink filler.
Further, the glass microsphere surface handles by 5-10% hydrofluoric acid solution or is handled with silane coupling agent.
Further, the silane coupling agent is selected from amino silane, aliphatic epoxy silane, methacryloxy silicon
One or more of alkane, hydrosulphonyl silane, sulfenyl silane, vinyl silanes, isocyanato silanes, ureido silane.Benefit
Make glass microsphere surface that there is certain degree of roughness with hydrofluoric acid treatment, and pass through coupling agent treatment, enables to microballoon
Reinforce in the compatibility of resin, can firm embedded resin matrix, the later period also more efficient for the grinding of granules of pigments
Be conducive to the refinement of glass microsphere.
Further, the monomer for synthesizing the water soluble acrylic resin is acrylic acid, the second list with double bond
The Third monomer of body and carboxylic acid or acid anhydrides with double bond.
Further, the second comonomer with double bond is selected from methyl acrylate, ethyl acrylate, methyl methacrylate
Ester, ethyl methacrylate, butyl methacrylate, vinylacetate, styrene, methyl styrene, Glycidyl methacrylate
One or more of glyceride, methacrylic acid-β-hydroxypropyl acrylate, acrylonitrile.
Further, the Third monomer of the carboxylic acid or acid anhydrides with double bond be selected from maleic anhydride, succinic anhydride,
One or more of itaconic acid, allyl succinic anhydride.One or more are introduced in acrylic resin to have
The hardness and toughness of the adjustable acrylic resin of the second comonomer of double bond so that its to granules of pigments have one it is preliminary broken
Broken and dispersion effect, and acrylic resin can be increased by introducing one or more kinds of carboxylic acids with double bond or acid anhydrides
Acid value has the function that dispersion, stable pigments particle so that resin has good wetting action for granules of pigments.
Further, needed for synthesizing water soluble acrylic resin's spheric granules in terms of 100 parts of monomer weight, described third
The dosage of acrylic monomer is 20-50 parts, and the dosage of the second comonomer with double bond is 40-60 parts, described containing double bonds
The dosage of the Third monomer of carboxylic acid or acid anhydrides is 5-15 parts, and the dosage of the glass microsphere is 5-10 parts.
The preparation method of water soluble acrylic resin's spheric granules in the present invention comprising:
Step 1, the monomer for being used for acrylic acid synthesizing resin and initiator premixing are uniformly obtained into pre-composition；
Step 2, the part pre-composition is added in the water containing dispersing agent and is stirred, obtain polymerization system；
Step 3, glass microsphere is added in the polymerization system and is stirred；
Step 4, the remaining pre-composition is added in the polymerization system and is stirred；
Step 5, by gained particle filtering, cleaning, drying to get water soluble acrylic resin's spheric granules.
Wherein, this preparation method belongs to the method for polymerization (especially suspension polymerisation), it is aggregated made of acrylic resin
Molecular weight is more concentrated, and impurity is less, and resin particle size can be controlled by dispersing agent and speed of agitator, different size of tree
Rouge particulate abrasive effect is different.
Further, step 2 includes that the pre-composition of 1/2-3/5 is added in the water containing dispersing agent, stirring speed
Degree is 200-1000r/min, and temperature is 70-90 DEG C, and mixing time is 2-3 hours；Mixing time is that 0.3-0.8 is small in step 3
When；Mixing speed is 200-1000r/min in step 4, and temperature is 70-90 DEG C, and mixing time is 2-3 hours, and is stopping stirring
0.3-0.8 hours are kept the temperature after mixing.
Further, needed for synthesizing water soluble acrylic resin's spheric granules in terms of 100 parts of monomer weight, described third
The dosage of acrylic monomer is 20-50 parts, and the dosage of the second comonomer with double bond is 40-60 parts, described containing double bonds
The dosage of the Third monomer of carboxylic acid or acid anhydrides is 5-15 parts, and the dosage of the glass microsphere is 5-10 parts, the dispersing agent
Dosage is 0.1-0.4 parts, preferably K238T；The dosage of the initiator is 0.05-0.5 parts, and the type of the initiator includes even
Nitrogen initiator and peroxide initiator, the preferred azodiisobutyronitrile of the azo-initiator, azobisisoheptonitrile, azo two are different
Valeronitrile, azo diisopropyl imidazoline hydrochloride, azo-bis-iso-dimethyl, the preferred dibenzoyl peroxide of peroxide initiator.
The present invention also provides a kind of preparation methods of above-mentioned water-based ink comprising:
Step 1, water soluble acrylic resin's spheric granules, pigment, defoaming agent, partial solvent water are added to mixing plant
Middle stirring；
Step 2, part neutralizer is added, the pH value of regulation system is in 9-10, stirring；
Step 3, thickener, levelling agent, remaining neutralizer, remaining aqueous solvent is added, the pH value of regulation system is in 10-
12, stirring；
Step 4, the pH value of regulation system obtains the water-based ink in 8.5-9.5.
Wherein, the additional amount of amount of water and water soluble acrylic resin's spheric granules is matched according to ball-milling technology in step 1
Rule determine.
Further, the speed of agitator in step 1 and 2 be 600-1000r/min, step 1 and 2 stirring total time be 3-
6 hours；Speed of agitator in step 3 is 1000-1500r/min, continues stirring 2-4 hours after having adjusted pH value.
At stirring initial stage, slightly lower revolving speed is set, the pH value for adjusting system is alkalescent, so that resin particle is in ground pigment
While particle, dissolution gradually, since wetability of the resin to granules of pigments is preferable, so that the granules of pigments tentatively dispersed obtains
To certain stabilization.Due to the gradually dissolution of resin, the glass microsphere being embedded in resin particle is gradually revealed, due to glass
Glass microballoon intensity with higher, and the surface with certain roughness, the pigment tentatively dispersed is further ground,
Dispersion suitably increases speed of agitator at this time, so that shock and increased friction between particle, shear action enhancing, a period of time
Afterwards, increasing the pH value of system, the surface of glass microsphere is etched at this time, and the resin for wrapping up glass microsphere also further dissolves,
Final resin is completely dissolved.Acrylic resin at this point, granules of pigments has reached certain fineness, and after being dissolved soaks,
It settles out, the pH value of final regulation system obtains the preferable water-based ink of stability between 8.5-9.5.
Wherein, " one or more " in the present invention " more than " comprising this number " two kinds ".
Water soluble acrylic resin's spheric granules of the invention, can be used as the abrasive media of pigment in water-based ink, can
To grind, disperse simultaneously stable pigments particle, after being completely dissolved to resin, and binder use can be used as, glass microsphere exists
Alkaline environment is etched, eventually as inorganic filler.The synthesis of resin and easy to operate with the process of lapping of ink, consume energy it is low and
A large amount of waste water are not generated, Printing ink producing cost is effectively reduced, so that the production of water-based ink is more environmentally-friendly, economical.
Water-based ink provided by the invention uses the water-based acrylic resin spheric granules for containing glass microsphere to grind as it
Grinding media and binder not only can carry out grinding distribution to pigment but also can be very good the pigment soaked and stable dispersion is good
Grain, granules of pigments fineness is at 10 μm or so, and glass microsphere is eventually as the lesser filler of fineness.The water-based ink can be used for paper
, the printings of the materials such as corrugated case, plastic film, metal foil, have that waterproof, wear-resisting, attachment fastness is good and tinting strength, tinting power is high
Advantage, and show excellent printing effect.
Specific embodiment
The present invention is further illustrated below by the mode of embodiment, does not therefore limit the present invention to the implementation
Among example range.
Detection project and detection method include: in the present embodiment
1. ink fineness test: reference standard GB/T 13217.3-2008 is detected；
2. ink colorant power detects: reference standard GB/T 13217.6-2008 is detected；
3. ink attachment fastness detects: reference standard GB/T 13217.7-2009 is detected；
4. ink gloss detects: reference standard GB/T 13217.2-2009 is detected；
5. ink fluidity detects: reference standard GB/T 14624.3-2008 is detected；
6. ink stability detects: reference standard QB 567-1983 is detected.
Embodiment 1-5
Table 1 shows the composition of water soluble acrylic resin in water soluble acrylic resin's spheric granules of embodiment 1-5,
In terms of needed for synthesizing water-solubility acrylic resin spheric granules 100 parts of monomer weight.
Water soluble acrylic resin in water soluble acrylic resin's spheric granules of 1 embodiment 1-5 of table
Wherein, the glass microsphere of embodiment 1-5 is handled by 5-10% hydrofluoric acid solution or is handled with silane coupling agent.Compared with
Goodly, silane coupling agent is selected from amino silane, aliphatic epoxy silane, methacryloxypropyl silane, hydrosulphonyl silane, sulfenyl silicon
One or more of alkane, vinyl silanes, isocyanato silanes, ureido silane.
In embodiment 1-5, the dosage of each component of second comonomer is as shown in table 1, the preparation method of the particle of embodiment 1-5
Are as follows:
Step 1, the first monomer, second comonomer, Third monomer and the initiator that are used for acrylic acid synthesizing resin are pre-mixed
Uniformly obtain pre-composition；
Step 2, partly-premixed object is added in the water containing dispersing agent and is stirred, obtain polymerization system；
Step 3, glass microsphere is added in polymerization system and is stirred；
Step 4, remaining pre-composition is added in polymerization system and is stirred；
Step 5, by gained particle filtering, cleaning, drying to get water soluble acrylic resin's spheric granules.
Wherein, step 2 includes that the pre-composition of 1/2-3/5 is added to the water, and mixing speed is preferably 200-1000r/
Min, the present embodiment 700r/min, temperature are preferably 70-90 DEG C, and the present embodiment is 80 DEG C, and mixing time is preferably 2-3
Hour, the present embodiment is 2.5 hours；Mixing time is preferably 0.3-0.8 hours in step 3, and the present embodiment is 0.5 hour；
Mixing speed is preferably 200-1000r/min, the present embodiment 700r/min in step 4, and temperature is preferably 70-90 DEG C,
The present embodiment is 80 DEG C, and mixing time is preferably 2-3 hours, and the present embodiment is 0.5 hour, is preferably being stopped in step 4
0.3-0.8 hours are kept the temperature after stirring, the present embodiment is 0.5 hour.
Wherein, the dosage of dispersing agent is preferably 0.1-0.4 parts, and the present embodiment selects the K238T of 0.2 part of weight；Cause
The dosage of agent is preferably 0.05-0.5 parts, and the present embodiment selects the azodiisobutyronitrile of 0.15 part of weight as initiator.It is real
In the application of border, initiator can select azo initiator and peroxide initiator, the preferred azodiisobutyronitrile of azo-initiator,
Azobisisoheptonitrile, azobisisovaleronitrile, azo diisopropyl imidazoline hydrochloride, azo-bis-iso-dimethyl, peroxide initiator are excellent
Select dibenzoyl peroxide.
The partial size of 1 particle of embodiment obtained according to above-mentioned preparation method is 5mm, and the partial size of glass microsphere is 20 μm, close
Degree is 0.5g/cm3, Mohs' hardness 6.0；It is acrylic resin spheric granules radius that glass microsphere, which concentrates the position of dispersion,
1/5-1/2 at.
Embodiment 2-5 by the control of condition, dispersing agent etc., obtained grain diameter be respectively 2mm, 6mm, 4mm and
8mm, the partial size of glass microsphere are respectively 10 μm, 40 μm, 30 μm and 50 μm, and density is respectively 0.12g/cm3、0.2g/cm3、
1.85g/cm3And 2.5g/cm3, Mohs' hardness is respectively 5.5,6.9,6.2 and 7.5.The diameter of glass microsphere is substantially in particle
Between the 1/5-4/5 of diameter.Wherein, glass microsphere can select solid or hollow sphere.
The particle of embodiment 1-5 is prepared into water-based ink respectively, by taking embodiment 1 as an example, water-based ink contains embodiment 1
25 parts of particle multiple with 15 parts of pigment, BYK3330.6 parts of levelling agent, DF-2208 parts of defoaming agent, neutralizer sodium hydroxide and ammonia 3:2
It is equipped with and is adjusted to that suitable ph is dosage, aqueous solvent is surplus.Preparation method includes:
Step 1, water soluble acrylic resin's spheric granules, pigment, defoaming agent, partial solvent water are added to mixing plant
Middle stirring；
Step 2, part neutralizer is added, the pH value of regulation system is in 9-10, stirring；
Step 3, thickener, levelling agent, remaining neutralizer, remaining aqueous solvent is added, the pH value of regulation system is in 10-
12, stirring；
Step 4, the pH value of regulation system obtains water-based ink in 8.5-9.5.
Wherein, the mixing speed in step 1 and 2 is preferably 600-1000r/min, the present embodiment 700r/min, step
Rapid 1 and 2 total mixing time is 3-6 hours, and the present embodiment is 8 hours, and mixing speed is preferably 1000- in step 3
1500r/min, the present embodiment 1200r/min adjust pH value to 10-12 and continue stirring 2-4 hours, the present embodiment 3 later
Hour.
Wherein, pigment is selected from pigment red 4 8:3, paratonere 57:1, pigment red 81, pigment red 4 9:1, pigment red 122, pigment
Red 146, pigment blue 15, pigment blue 15: 1, pigment blue 15: 3, pigment yellow 3, pigment Yellow 12, pigment yellow 13, black B P470, pigment
Black 32, one or more of titanium dioxide；Levelling agent is selected from Siloxane-Oxyalkylene Copolymers BYK333, polyether-modified poly- silicon oxygen
Alkane BNK-LK600, Siloxane-Oxyalkylene Copolymers MONENG1080, acrylic acid esters co-polymer BNK-M3550, esters of acrylic acid are total
One or more of polymers MONENG1153, fluorocarbons levelling agent BNK-4010；Neutralizer is selected from sodium hydroxide
With ammonium hydroxide, N, one or more of N- dimethylethanolamine, triethanolamine, monoethanolamine；Thickener is selected from hydrophobic change
The swollen acrylic emulsion thickener TT935 of property association type alkali soluble, the non-swollen acrylic emulsion thickener of association type alkali soluble of hydrophobically modified
One or both of ASE-60, association type non-ionic hydrophobic modified polyurethane type thickener PS 166 and RM-2020 with
On；Defoaming agent chooses Siloxane-Oxyalkylene Copolymers, trimethyl silicone oil, silicone emulsion, polyethylene glycol fatty acid type surfactant
And one or more of polyethers and organic silicon compound defoaming agent, polyethers and silicon-containing polyether Compounded Antifoamer DF-220.
Embodiment 6-11 is the water-based ink obtained according to the method described above based on embodiment 1.Table 2 shows implementation
The partial size of water soluble acrylic resin's spheric granules, dosage in the water-based ink of example 6-11.
The partial size of water soluble acrylic resin's spheric granules, dosage in 2 embodiment 6-11 of table
| Resin particle partial size (mm) | Different-grain diameter particle consumption proportion | The total dosage of resin particle (%) | |
| Embodiment 6 | 2、5、8 | 1:2:1 | 25 |
| Embodiment 7 | 2、4、6 | 1:2:1 | 25 |
| Embodiment 8 | 4、6、8 | 1:1:1 | 30 |
| Embodiment 9 | 3、5、7 | 1:1:1 | 30 |
| Embodiment 10 | 2、3、7 | 2:2:1 | 35 |
| Embodiment 11 | 2、6、8 | 2:2:1 | 35 |
In embodiment 6-11, the total weight of resin particle and pigment is 45%, wherein grinding amount of water early period and acrylic acid
The additional amount proportion of resin particle determines according to the rule of ball-milling technology, the dosage of solvent deionized water cooperation resin, pigment,
The dosage of auxiliary agent is 100%, changes the total dosage of partial size, consumption proportion and resin of resin particle and prepares water according to above-mentioned steps
Property ink.
Embodiment 12-17 is the water-based ink obtained according to the method described above based on embodiment 2.Table 3 shows implementation
Dosage, partial size and the different-grain diameter ratio of glass microsphere in the resin particle of example 12-17.
Dosage, partial size and the different-grain diameter ratio of glass microsphere in 3 embodiment 12-17 of table
| The dosage (part) of glass microsphere | The partial size (μm) of glass microsphere | The ratio of different-grain diameter glass microsphere | |
| Embodiment 12 | 5 | 10、30、50 | 1:3:1 |
| Embodiment 13 | 6 | 10、25、50 | 1:1:1 |
| Embodiment 14 | 7 | 10、20、30 | 1:2:3 |
| Embodiment 15 | 8 | 15、30、45 | 1:2:1 |
| Embodiment 16 | 9 | 20、30、50 | 2:3:1 |
| Embodiment 17 | 10 | 10、40、50 | 2:2:1 |
In embodiment 12-17, the total weight of resin particle and pigment is 40%, total dosage of acrylic resin spheric granules
It is 25%, wherein the additional amount of grinding amount of water early period and acrylic resin particle proportion is according to the rule of ball-milling technology come really
Calmly, the dosage cooperation resin, pigment of solvent deionized water, the dosage of auxiliary agent are 100%, and it is micro- to change glass in spherical resin particle
The dosage of ball, the consumption proportion of partial size and different-grain diameter glass microsphere simultaneously prepare water-based ink according to above-mentioned steps.
Embodiment 18-23 is the water-based ink obtained according to the method described above based on embodiment 12-17.Table 4 is shown
The dosage of glass microsphere, partial size and radial distribution in the resin particle of embodiment 18-23.
Dosage, partial size and the radial distribution of glass microsphere in 4 embodiment 18-23 of table
| Glass microsphere dosage (part) | Glass microsphere partial size and proportion | Glass microsphere radial distribution range | |
| Embodiment 18 | 5 | 10、30、50(1:3:1) | 1/4-3/4 |
| Embodiment 19 | 6 | 10、25、50(1:1:1) | 1/2-2/3 |
| Embodiment 20 | 7 | 10、20、30(1:2:3) | 1/5-2/3 |
| Embodiment 21 | 8 | 15、30、45(1:2:1) | 1/5-1/2 |
| Embodiment 22 | 9 | 20、30、50(2:3:1) | 1/2-4/5 |
| Embodiment 23 | 10 | 10、40、50(2:2:1) | 2/5-4/5 |
In embodiment 18-23, the total weight of resin particle and pigment is 40%, total dosage of acrylic resin spheric granules
It is 25%, wherein the additional amount of grinding amount of water early period and acrylic resin particle proportion is according to the rule of ball-milling technology come really
Calmly, the dosage cooperation resin, pigment of solvent deionized water, the dosage of auxiliary agent are 100%, and it is micro- to change glass in spherical resin particle
The dosage of ball, the consumption proportion of partial size and different-grain diameter glass microsphere simultaneously prepare water-based ink according to above-mentioned steps.
Embodiment 24-29 is the water-based ink obtained according to the method described above based on embodiment 18-23.Table 5 is shown
The dosage of glass microsphere, partial size and radial distribution in the resin particle of embodiment 24-29.
Dosage, partial size and the radial distribution of glass microsphere in 5 embodiment 24-29 of table
| Glass microsphere dosage (part) | Glass microsphere partial size and proportion | Glass microsphere radial distribution range | |
| Embodiment 18 | 5 | 10、30、50(1:3:1) | 1/4-3/4 |
| Embodiment 19 | 6 | 10、25、50(1:1:1) | 1/2-2/3 |
| Embodiment 20 | 7 | 10、20、30(1:2:3) | 1/5-2/3 |
| Embodiment 21 | 8 | 15、30、45(1:2:1) | 1/5-1/2 |
| Embodiment 22 | 9 | 20、30、50(2:3:1) | 1/2-4/5 |
| Embodiment 23 | 10 | 10、40、50(2:2:1) | 2/5-4/5 |
In embodiment 24-29, the total weight of resin particle and pigment is 40%, total dosage of acrylic resin spheric granules
It is 25%, wherein the additional amount of grinding amount of water early period and acrylic resin particle proportion is according to the rule of ball-milling technology come really
Calmly, the dosage cooperation resin, pigment of solvent deionized water, the dosage of auxiliary agent are 100%, and it is micro- to change glass in spherical resin particle
The dosage of ball, the consumption proportion of partial size and different-grain diameter glass microsphere simultaneously prepare water-based ink according to above-mentioned steps.
Comparative example 1
Based on embodiment 1, it is added without glass microsphere in the acrylic resin particle of synthesis, remaining condition and factor are set
It sets same as Example 1, and prepares ink according to above-mentioned steps.
Comparative example 2
Based on embodiment 2, glass microsphere, the acrylic resin of synthesis are added without in the acrylic resin particle of synthesis
It is added without second comonomer in the monomer of particle, remaining condition and factor setting are same as Example 1, and prepare according to above-mentioned steps
Ink.
Above-described embodiment 1-29 and comparative example 1 and 2 water-based ink being prepared are printed on not using proofing facility
Same surface of the stock, and the performance of ink and printed sample is tested, resulting test result is as shown in table 6.
Each embodiment of table 6 and comparative example the performance test results
Acrylic resin spheric granules of the invention is used it can be seen from the test result in table 6, and utilizes this hair
Water-based ink made from bright acrylic resin spheric granules, fineness, attachment fastness, tinting strength, tinting power, glossiness and fluidity are more right
Test result in ratio is excellent, and ink shows preferable stability, has good using effect.
Claims (7)
1. a kind of water-based ink, it is characterised in that: it contains aqueous solvent, water soluble acrylic resin's spheric granules, pigment, levelling
Agent, neutralizer, thickener and defoaming agent, wherein the monomer for synthesizing the water soluble acrylic resin is acrylic acid, has
The Third monomer of the second comonomer of double bond and carboxylic acid or acid anhydrides with double bond, water soluble acrylic resin's spheric granules
The sphere of glass microsphere is coated for water soluble acrylic resin, and its sphere partial size is 2-8mm；
Wherein, needed for synthesizing water soluble acrylic resin's spheric granules in terms of 100 parts of monomer weight, the acrylic monomers
Dosage be 20-50 part, the dosage of the second comonomer with double bond is 40-60 parts, the carboxylic acid containing double bonds or acid
The dosage of the Third monomer of acid anhydride is 5-15 parts, and the dosage of the glass microsphere is 5-10 parts；
Wherein, the second comonomer with double bond is selected from methyl acrylate, ethyl acrylate, methyl methacrylate, methyl
Ethyl acrylate, butyl methacrylate, vinylacetate, styrene, methyl styrene, glycidyl methacrylate,
One or more of methacrylic acid-β-hydroxypropyl acrylate, acrylonitrile；The third list of the carboxylic acid or acid anhydrides with double bond
Body is selected from one or more of maleic anhydride, succinic anhydride, itaconic acid, allyl succinic anhydride.
2. water-based ink according to claim 1, it is characterised in that: the glass microsphere surface is by weight percent
The processing of 5-10% hydrofluoric acid solution is handled with silane coupling agent.
3. water-based ink according to claim 1, it is characterised in that: water soluble acrylic resin's ball in the water-based ink
The weight content of shape particle is 20-35%；The weight content of the pigment is 8-25%；The weight content of the levelling agent is
0.1-0.4%；The weight content of the neutralizer is 5-10%；The weight content of the thickener is 0.3-5%；The defoaming
The weight content of agent is 0.05-0.5%；The weight content of the aqueous solvent is 35-65%.
4. water-based ink according to claim 3, it is characterised in that: the partial size of the glass microsphere is the sphere partial size
1/5-4/5, and the glass microsphere is solid or hollow sphere, and the partial size of the glass microsphere is 10-50 μm, and density is
0.12-2.6g/cm3, Mohs' hardness 5.5-7.5.
5. water-based ink according to claim 1, it is characterised in that: the levelling agent is selected from Siloxane-Oxyalkylene Copolymers
BYK333, Siloxane-Oxyalkylene Copolymers BNK-LK600, Siloxane-Oxyalkylene Copolymers MONENG1080, acrylic acid esters co-polymer
One or both of BNK-M3550, acrylic acid esters co-polymer MONENG1153, fluorocarbons levelling agent BNK-4010 with
On；The neutralizer be selected from sodium hydroxide and ammonium hydroxide, N, one of N- dimethylethanolamine, triethanolamine, monoethanolamine or
It is two or more；The thickener is selected from that the swollen acrylic emulsion thickener TT935 of hydrophobically modified association type alkali soluble, hydrophobically modified is non-forms
Mould assembly alkali soluble is swollen acrylic emulsion thickener ASE-60, association type non-ionic hydrophobic modified polyurethane type thickener PS 166 with
And one or more of RM-2020；The defoaming agent chooses Siloxane-Oxyalkylene Copolymers, trimethyl silicone oil, emulsification silicon
Oil, polyethylene glycol fatty acid type surfactant and polyethers compound with silicon-containing polyether with organic silicon compound defoaming agent, polyethers and disappear
One or more of infusion DF-220.
6. a kind of preparation method of water-based ink described in claim 1 comprising following steps:
Step 1, water soluble acrylic resin's spheric granules, pigment, defoaming agent, partial solvent water are added in mixing plant and are stirred
It mixes；
Step 2, part neutralizer is added, the pH value of regulation system is in 9-10, stirring；
Step 3, be added thickener, levelling agent, remaining neutralizer, remaining aqueous solvent, the pH value of regulation system in 10-12,
Stirring；
Step 4, the pH value of regulation system obtains the water-based ink in 8.5-9.5.
7. the preparation method of water-based ink according to claim 6, it is characterised in that: the speed of agitator in step 1 and 2 is
600-1000r/min, step 1 and 2 stirring total time be 3-6 hours；Speed of agitator in step 3 is 1000-1500r/
Min continues stirring 2-4 hours after having adjusted pH value.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610007920.5A CN105440788B (en) | 2016-01-06 | 2016-01-06 | Water-based ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610007920.5A CN105440788B (en) | 2016-01-06 | 2016-01-06 | Water-based ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105440788A CN105440788A (en) | 2016-03-30 |
| CN105440788B true CN105440788B (en) | 2019-01-04 |
Family
ID=55551448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610007920.5A Expired - Fee Related CN105440788B (en) | 2016-01-06 | 2016-01-06 | Water-based ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105440788B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106810647B (en) * | 2016-12-27 | 2020-08-11 | 东莞市浩彩油墨科技有限公司 | Water-based ink resin binder and preparation method thereof |
| CN107118614A (en) * | 2017-06-22 | 2017-09-01 | 汕头市瑞宇科技有限公司 | A kind of environment-friendly type aqueous ink and preparation method thereof |
| CN109517442A (en) * | 2019-01-11 | 2019-03-26 | 济南阿波罗文化用品有限公司 | A kind of wide-format printer aqueous pigment ink and its preparation method and application |
| CN111334125A (en) * | 2020-04-22 | 2020-06-26 | 德化县新高圣包装彩印有限公司 | High-water-resistance environment-friendly water-based ink and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100384941C (en) * | 2005-04-16 | 2008-04-30 | 中国科学院合肥物质科学研究院 | Resin/glass hollow microsphere composite material and preparation method thereof |
| CN103554341B (en) * | 2013-10-30 | 2016-03-02 | 华南理工大学 | Low-temperature self-crosslinking acrylic ester emulsion of nucleocapsid structure and preparation method thereof and application |
-
2016
- 2016-01-06 CN CN201610007920.5A patent/CN105440788B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN105440788A (en) | 2016-03-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105440788B (en) | Water-based ink and preparation method thereof | |
| TWI428403B (en) | Pigment dispersants, their production process, and their use | |
| CN1813002B (en) | Aqueous dispersions of microparticles having a nanoparticulate phase and coating compositions containing the same | |
| CN100395296C (en) | Aqueous ink capable of being erased by rubber and writing material using the same | |
| CN104263069B (en) | A kind of aqueous thermosetting glass printing ink and preparation method thereof | |
| CN107523143A (en) | A kind of general no fat mill base of water nano and preparation method thereof | |
| CN109233611A (en) | A kind of aqueous polyurethane dull finishing coat and preparation method thereof | |
| WO2009151018A1 (en) | Composition containing crystalline cellulose composite | |
| CN101845122B (en) | Water-based polymer pigment dispersant and leather cationic pigment paste prepared from same | |
| CN102134434A (en) | High-performance water-based white sealing primer | |
| CN108276890A (en) | A kind of aqueous automobile floating coating composition and preparation method thereof | |
| CN100473670C (en) | Alcohol water-soluble resin and method for making the same | |
| CN105860653A (en) | Modified-chitosan-containing high-waterproofness modified waterborne polyurethane printing ink and preparation method thereof | |
| CN105885529A (en) | Modified water-based polyurethane ink containing nano-hydroxyapatite and preparation method of modified water-based polyurethane ink | |
| CN101475763B (en) | Printing ink printed on finishing oil and preparation thereof | |
| JP2016121237A (en) | Production method of water-based pigment dispersion for inkjet recording | |
| CN108373650A (en) | A kind of aqueous PET ink for screen printing and preparation method thereof | |
| CN100393826C (en) | Water fluorine carbon emulsion paint and preparation process thereof | |
| JP2001019889A (en) | Eraser-usable water-base writing ink composition and writing utensil having the same therein | |
| CN105482026B (en) | Water soluble acrylic resin's spheric granules and preparation method thereof | |
| CN105925061A (en) | Water-based inkjet ink for inkjet printing and preparation method thereof | |
| CN106916491A (en) | High solids content, high-strength aqueous carbon black mill base preparation method | |
| CN108559347A (en) | A kind of water paint for automotive plastic parts | |
| CN105838139A (en) | Modified waterborne polyurethane ink containing hydrophobic oxidized starch and preparing method of modified waterborne polyurethane ink | |
| JP2019019293A (en) | Pigment water dispersion, and aqueous ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 201114 room D104, No. 245, Xinjun Ring Road, Minhang District, Shanghai Patentee after: Shanghai huanbaochuan New Material Technology Co.,Ltd. Address before: 201318 1201, building 4, No. 500, Jianyun Road, Pudong New Area, Shanghai Patentee before: SHANGHAI MOCHUAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| CP03 | Change of name, title or address | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190104 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |