CN101284965B - Water-based intaglio ink equal to plate engraving ink and uses thereof - Google Patents

Abstract

The invention is equivalent to water soluble intaglio ink of plate engraving ink and/or equivalent to water-soluble screen printing ink of the ink, suitable for a gravure printing machine. The ink has the advantages of nontoxicity, tastelessness, nonflammable property, water solubility, non-environmental pollution and rapid drying; the printing effect of the obtained presswork is the same as or equivalent to the printing effect of the plate engraving presswork; the materialized firmness of the presswork is superior to the materialized firmness of the plate engraving presswork; the ink is low in printing cost and suitable for printing secure and confidential documents with deep printing lines, such as bank notes, securities, stamps, food packing, etc.

Description

Be equal to the water-base gravure ink and the application thereof of plate engraving ink

Technical field

The present invention relates to the printing-ink field, is water-base gravure ink specifically.The invention still further relates to the application of described water-base gravure ink.

Background technology

Base gravure ink is divided into plate engraving ink and photogravure ink.

Plate engraving ink is specially for engraving plate printer designs, and the trace (printing ink) of the printing that is obtained with the intaglio ink technology is to protrude from paper surface, and stroking it with hand has tangible rough sensation; The printing mass colour well arranged, stereoscopic sensation is strong.Plate engraving ink is widely used in the trade mark of printing bank money, Valued Securities, various certificate, tobacco package, drug packaging, famous-brand and high-quality goods etc.Before the present invention, the intaglio ink technology is safe and secret printing technology by generally acknowledging.Although plate engraving ink technology, intaglio ink technology have many advantages, because engraving plate printer is very expensive, the plate-making technology complexity, the printing condition strictness produces large amount of sewage in the printing process, bring severe contamination to environment.Therefore, many products for civilian use press for and utilize intaglio ink technology print product brand, but because printing cost is too high, hang back.

The present invention in the past, in the photogravure ink, the volatile solvent accounts for the total 70-80% that forms of printing ink, amount of solid content is very low, it is shallow to add edition line, the trace (printing ink) of the printing that obtains is flat, and stroking it with hand does not have uneven sensation, the printing that is far from being mass colour well arranged, stereoscopic sensation is strong and weak.This technology is widely used in printing tobacco package, plastics film etc.Printing press has rolled paper or sheet-fed press, and is cheap.In view of the handle effect of the handle effect of the printing that photogravure obtained and intaglio ink product not comparable, so the photogravure technology is used for common printed product more.Nobody with the photogravure technology as uses such as safe and secret printing technology, safe and secret typography, safety equipment.

For the concave-convex effect of the trace (printing ink) that makes the printed matter that the photogravure technology obtains can reach the intaglio ink effect, the printing mass colour is well arranged, stereoscopic sensation is strong, thoroughly eradicate the sewage that produces in the intaglio ink process, environment is not produced this technical barrier of pollution, the contriver is on existing water-soluble photogravure technical foundation, in conjunction with the intaglio ink situation, the carving intaglio printing ink principle of design, water-soluble gravure inks principle of design, water-soluble screen printing ink principle of design organically combines, a large amount of tests have been done, the present invention has been finished in experiment.

Summary of the invention

The object of the present invention is to provide the water-base gravure ink that is equal to plate engraving ink.Another object of the present invention provides the application of this printing ink.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that the water-soluble screen printing ink that this printing ink contains (A) water-base gravure ink and/or is equal to this printing ink accounts for the total 0-55% that forms of this printing ink with pigment and/or dyestuff, (B) the total 10-90% that forms of environment-friendly water-soluble polymkeric substance and/or this printing ink of polymer monomer binder constitutes, (C) the environment-friendly water-soluble solubility promoter accounts for the total 0.5-75% that forms of this printing ink, (D) water-base gravure ink and/or the water-soluble screen printing ink that is equal to this printing ink account for the total 0.1-52% that forms of this printing ink with film coalescence aid and/or neutralizing agent and/or whipping agent and/or swelling agent and/or UV light absorber and/or wax.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (A) pigment and/or dyestuff, be selected from water-soluble paint and/or printing-ink technical field used pigment dyestuff and/or dyestuff, mineral dye, in the stopping composition one or more, as organic pigment and/or dyestuff, mineral dye, Huang in the stopping composition, red, tangerine, blue, black, green, in vain, titanium dioxide, silicon-dioxide, lime carbonate, kaolin, wilkinite, aluminium or silver powder, copper or bronze, high-visibility pigment and/or dyestuff etc., these pigment and/or dyestuff can use separately or multiple being used.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, the 0-45% of this total weight of silica comprises in described (A) pigment and/or the dyestuff, preferred 3-35%, preferred again 4-20%; Lime carbonate accounts for the 0-40% of this total weight, preferred 3-30%, preferred again 4-25%; Barium sulfate accounts for the 0-15% of this total weight, preferred 0.5-4%.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention is characterized in that described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water soluble oils; Water-soluble modified vegetables oil; The water soluble phenol resin modified vegetable oil; Water soluble phenol resin; Water-soluble trimeric cyanamide and derivative formaldehyde resin thereof; Water-soluble fumaric acid modified rosin resin; Water-soluble rosin modified resin; Water-soluble epoxy ester; Water-soluble epoxy resin; The soluble epoxide acrylic resin; Water-soluble poly oxyethane and derivative thereof; Water soluble alkyd resin; Water soluble modified alkyd resin; The water soluble alkyd resin that contains free radical; Polyester Resin Water Soluble; The water soluble acrylate resin; Water-soluble poly butadiene resin and modified alkyd resin thereof; Waterborne polyurethane resin; Water-soluble bituminous resins; The water soluble salt of polyacrylic acid and derivative thereof; Water-soluble self-crosslinking acrylic; Water-soluble acrylic and derivatives resin thereof; The single component ACRYLIC EMULSION; Acrylate copolymer emulsion; Acrylate copolymer emulsion or single component ACRYLIC EMULSION and with the compound water soluble resin for preparing of addition Gum Rosin; Water-based dispersion resin and/or film-forming resin that polynary monomer copolymerization such as vinylbenzene and/or acrylate and/or N hydroxymethyl acrylamide and/or vinylformic acid and derivative thereof etc. obtains; Polyvinyl alcohol or vinyl alcohol derivatives base polymer; Acetate emulsion; Vinyl acetate between to for plastic-maleic acid and derivative copolymer emulsion thereof; Vinyl acetate between to for plastic-acrylate and derivative copolymer emulsion thereof; Acrylate and derivative emulsion thereof; The vinyl acetate-styrene copolymer emulsion; Water-soluble poly N-vinyl pyrrolidone; Keto-aldehyde modified soluble acrylate resin; , waterborne organic silicon oil, water-based fluoroalkyl (as fluorine carbon, fluorine silicon etc.), aqueous silicate, water-soluble ultraviolet curing with Epocryl, water-soluble ultraviolet curing with water-soluble paint such as polyester acrylate resin and/or printing-ink technical field can be water-soluble resin glue in one or more.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (C) environment-friendly water-soluble solubility promoter, be selected from water-soluble paint and/or the used alcohol of printing-ink technical field, ether, ester, ketone, in the water equal solvent one or more, as ethanol, n-propyl alcohol, Virahol, the trimethyl carbinol, butanols, ethylene glycol and ether thereof, neopentyl glycol and ether thereof, Diethylene Glycol and ether thereof, triethylene glycol and ether thereof, Tetraglycol 99 and ether thereof, dipropylene glycol and ether thereof, tripropylene glycol and ether thereof, three contract four propylene glycol and ethers thereof, glycerine and monoether thereof, the glycerol mono fatty acid ester, butyleneglycol and ether thereof, polyether Glycols, polyether-tribasic alcohol, the polyethers tetravalent alcohol, the polyethers pentavalent alcohol, polyoxyethylene glycol, polypropylene glycol, polymer polyatomic alcohol, polyester polyol, ethyl acetate, acetone, pimelinketone, in the water-soluble silicon wet goods one or more, these solvents can use separately or multiple being used.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) film coalescence aid and/or neutralizing agent and/or whipping agent and/or swelling agent and/or UV light absorber and/or wax are selected from used all film coalescence aid of water-soluble paint and/or printing-ink technical field and/or neutralizing agent and/or whipping agent and/or swelling agent and/or UV light absorber and/or the wax one or more.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) film coalescence aid is selected from the film coalescence aid such as the metal-salt (as: cobalt of unsaturated organic acid such as naphthenic acid, sad, capric acid, manganese, cerium, vanadium, lanthanum, iron, lithium, lead, zirconium, aluminium, calcium, zinc salt, manganese borate etc.) of organic acid and/or nitric acid and/or ammonia/zirconium complex one or more.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) neutralizing agent is selected from mineral alkali (as sodium hydroxide, potassium hydroxide, lithium hydroxide etc.) and/or inorganic ammonium salt (as bicarbonate of ammonia etc.) and/or be heated easily emit ammonia organic amine (as urotropine, urea etc.) and/or inorganic ammonia (as liquefied ammonia, ammoniacal liquor etc.) and/or organic amine (as diethylamine, triethylamine etc.) and/or thanomin (as Monoethanolamine MEA BASF, diethanolamine, trolamine etc.) etc. one or more in.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) whipping agent and/or swelling agent account for the 0-10% of this total weight, preferred 0.2-8%, preferred again 0.5-6%.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) whipping agent is selected from decomposition temperature one or more in the various whipping agents below 200 ℃, as modification carbonate etc.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) swelling agent is selected from expansion temperature one or more in the various swelling agent products below 200 ℃.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) UV light absorber is selected from all UV light absorber of paint such as st-yrax dme, michaelis ketone, benzophenone and/or technical field of ink one or more.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, described (D) wax, be selected from natural wax (as carnauba wax, little candle is counted wax, esparto wax, ouricury wax, Japan tallow, fir wax, palm wax, beeswax, insect wax, wool wax, paraffin, Microcrystalline Wax, montanin wax, ore deposit ceresine etc.), synthetic wax is (as the esterification products of stearic acid and derivative thereof or they and alcohol, stearyl alcohol, polyethylene wax etc.), modified waxes is (as oxidized polyethlene wax, chlorinated wax, the polymeric fatty acid amides, aluminum stearate, Vaseline etc.), synthetic wax also comprises other natural wax or synthetic wax, through chemistry or physical treatment (as purifying, oxidation, in all wax of technical field of ink such as the wax that obtains chlorination etc.) one or more.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that the drying mode of this printing ink is one or both or the two or more mixed type in oxypolymerization drying and/or volatile dry and/or infiltration drying and/or the ultraviolet curing.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, when the drying mode of this printing ink is the oxypolymerization drying, the desiccant wax of oxypolymerization accounts for the 0.1-15% of this total weight, preferred 5-12%, preferred again 6-10%; The desiccant film coalescence aid of oxypolymerization accounts for the 0.1-15% of this total weight, preferred 1-10%, preferred again 2-8%.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the seasoning time was not more than 8 hours; Drying mode is that volatile dry and/or infiltration are dry, and when printing press was not installed drying plant, printing time of drying was less than 4 hours; Drying mode is that volatile dry and/or infiltration are dry, when printing press is equipped with drying plant, but printing drying moment finish; Drying mode is that UV solidifies when dry, but printing drying moment finishes.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that, when the drying mode of this printing ink is UV curing drying, water-soluble ultraviolet curing Epocryl and/or water-soluble polyester acrylate resin in described (B) water-soluble polymers and/or the polymer monomer tackiness agent, be selected from the water-soluble diphenolic acid Resins, epoxy of acroleic acid esterification, by polyether glycol and organic acid reaction, solidify with in the resin glue one or more through water-soluble paint such as polyester acrylate resin that acroleic acid esterification obtains and/or all water-soluble UV of energy of technical field of ink again.

The application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of the present invention is characterized in that this printing ink is applicable to various types of rolled papers and/or sheet-fed gravure machine.

The application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of the present invention, it is characterized in that, the version line degree of depth of the forme of gravure machine is between the 20-200 micron, and forme is carved by known engraving mode or corroded the mode that combines with engraving or by known caustic solution acquisition.

The application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of the present invention, it is characterized in that, the version line of the forme of gravure machine is based on lines, the site be auxilliary or dotted line in conjunction with or all forms by lines, a wherein dark edition line structure must have the line of ink marker of holding.

The application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of the present invention, it is characterized in that, in printing process, the unnecessary printing ink of non-graphic part is by scraper or scrapes device for ink and scrape totally or wipe clean by a wiping edition device on the forme.

The application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of the present invention is characterized in that the bake out temperature of gravure machine or paper surface temperature are at 50-180 ℃.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention is characterized in that, oxypolymerization time of drying of this printing ink is less than 15 minutes/80 ℃ baking ovens.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention is characterized in that, the average acid number 0-55mgKOH/g of this printing ink; The printing viscosity of printing ink is less than 5Pa.s/40 ℃.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention; it is characterized in that, use the trace of the printed matter that this printing ink obtains or the ink film thickness that printing ink is stayed paper surface to be the 20-180 micron.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention, it is characterized in that this printing ink is nonflammable, do not have smell, there are not harm in the environment and the person, are fit to the printing security secret document and/or to food product pack and/or the banknote and/or the printings such as various certificate and/or equity certificate of health conditions requiring strictness.

Describe in detail

Below water-base gravure ink of the present invention and/or the water-soluble screen printing ink that is equal to this printing ink are described.

The water-soluble screen printing ink for preparing above-mentioned water-base gravure ink and/or be equal to this printing ink can adopt conventional three roller ink grinding mills, ball mill, sand mill to finish.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of water soluble oils in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent, can enumerate the oil and the unsaturated carboxylic acid that have conjugated double bond or isolated double bond in the molecule and carry out the oil that addition reaction obtains; Has the oil of unsaturated double-bond and the oil that unsaturated carboxylic acid reacts acquisition.The above-mentioned oil with conjugated double bond or isolated double bond or unsaturated double-bond is selected from vegetables oil such as tung oil, synourin oil, oleum lini, soya-bean oil, eleostearic acid, dehydrated castor oleic acid, linolenic acid, behenic acid and the acid thereof one or more.Above-mentioned unsaturated carboxylic acid is selected from the unsaturated carboxylic acids such as maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, methene butene dioic acid one or more.For example: water-soluble maleic anhydride modified tung oil, water-soluble maleic anhydride modified flax wet goods paint and/or all water soluble oils and/or the water-soluble modified oil of technical field of ink.These water soluble oilss and/or water-soluble modified oil can use separately or multiple water soluble resin is used, and can also and use with multiple water soluble resin.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to water-soluble modified vegetables oil in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent and/or the concrete example of water soluble phenol resin modified vegetable oil, can enumerate the phenolic resin modified oleum lini of water-soluble xylenol, water-soluble para-tertiary butyl phenol formaldehyde resin modification oleum lini, water-soluble rosin modified phenolic resins and cyclopentadiene modification flax wet goods water-soluble paint and/or all water-soluble modified vegetables oil of technical field of ink.These water-soluble modified vegetables oil can use separately or multiple water soluble resin is used, and can also and use with multiple water soluble resin.

Above-mentioned vegetables oil is selected from oleum lini, tung oil, synourin oil, Viscotrol C, perilla oil, Chinese catalpa oil, OITICICA oil, soya-bean oil, Oleum Helianthi, wine stone oil, vegetable oil acid, the tower fatty acid oil etc. one or more.

As the water-soluble modified plant oil modified used resin that is equal to plate engraving ink, be selected from water-soluble paints such as rosin and derivative thereof, vinylbenzene, divinyl, organic isocyanate, vinylformic acid and derivative thereof, Resins, epoxy, epoxy resin modification vegetables oil, maleic acid and acid anhydride thereof or FUMARIC ACID TECH GRADE modified vegetable oil, resol, rosin modified phenolic resin, aminoresin and/or technical field of ink all can with the chemical substance of vegetables oil and/or vegetable oil acid generation chemical reaction in one or more.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of water soluble phenol resin in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent, can enumerate water-soluble paint and/or all water soluble phenol resins of technical field of ink such as water-soluble xylenol resol, water-soluble para-tertiary butyl phenol formaldehyde resin.These water soluble phenol resins can use separately or multiple water soluble resin is used, and can also and use with multiple water soluble resin.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of water-soluble terpolycyantoamino-formaldehyde resin in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent, can enumerate in all water-soluble terpolycyantoamino-formaldehyde resins of water-soluble paints such as water-soluble low molecular weight terpolycyantoamino-formaldehyde resin and/or technical field of ink one or more.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of water-soluble rosin modified resin in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent, can enumerate rosin and unsaturated organic acid and carry out addition reaction generation multi-carboxy compound, again with the alcohol moiety esterification, react in all water-soluble rosin modified resin of water-soluble paints such as the water soluble resin that obtains and/or technical field of ink one or more through amine and/or alkanolamine and/or ammoniacal liquor etc.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to water-soluble epoxy ester in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent and/or the concrete example of water-soluble epoxy resin and/or soluble epoxide acrylic resin, can enumerate water-soluble diphenolic acid epoxy ester resin; Water soluble polyamide solidified glycerol epoxy resin; Water-soluble diphenolic acid Resins, epoxy (ultraviolet curing resin) through acroleic acid esterification; After vegetable oil acid and the Resins, epoxy esterification, again with unsaturated organic acid reaction, water-soluble epoxy ester that paint such as the water-soluble epoxy ester that obtains through operations such as neutralization, dilutions and/or technical field of ink are all and/or in water-soluble epoxy resin and/or the soluble epoxide acrylic resin one or more.These water-soluble epoxy esters and/or water-soluble epoxy resin and/or soluble epoxide acrylic resin can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

Above-mentioned vegetable oil acid, be selected from paint such as linolenic acid, eleostearic acid, dehydrated castor oleic acid, ricinolic acid, perillaseed oleic acid, Chinese catalpa oleic acid, OITICICA oleic acid, behenic acid, Semen Helianthi oleic acid, Semen Vitis viniferae oleic acid, tower fatty acid oil and/or technical field of ink all can with the vegetable oil acid of Resins, epoxy generation chemical reaction in one or more.

Above-mentioned unsaturated organic acid, be selected from paint such as maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, methene butene dioic acid and/or technical field of ink all can with the unsaturated organic acid of the biochemical reaction of water-soluble epoxy ester fry dried food ingredients in one or more.

Above-mentioned Resins, epoxy, be selected from paint such as diphenylol propane based epoxy resin and/or aliphatic category Resins, epoxy and/or heterocyclic Resins, epoxy (as A-95, B-63, E-03, E-06, E-12, E-14, E-20, E-31, E-35, E-42, E-44, E-51, F-44, F-46, ET-40, EG-02 etc.) and/or technical field of ink all can with the Resins, epoxy of organic acid generation chemical reactions such as vegetable oil acid and/or vinylformic acid in one or more.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent water soluble alkyd resin and/or water soluble modified alkyd resin and/or contain the water soluble alkyd resin of free radical and/or the concrete example of polybutadiene (as polyvalent alcohol or polyprotonic acid) modified alkyd resin, can enumerate Beijing Wanyang Anti-counterfeiting Technology Co., Ltd.'s product: WY-2802 water soluble modified alkyd resin tackiness agent, WY-2801, WY-2803, water soluble alkyd resin and/or the water soluble modified alkyd resin that paint such as WY-2805 modified alkyd resin tackiness agent and/or technical field of ink are all and/or contain the water soluble alkyd resin of free radical and/or in polybutadiene (as polyvalent alcohol or the polyprotonic acid) modified alkyd resin one or more.These water soluble alkyd resins and/or water soluble modified alkyd resin and/or the water soluble alkyd resin and/or polybutadiene (as polyvalent alcohol or the polyprotonic acid) modified alkyd resin etc. that contain free radical can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

Above-mentioned water soluble alkyd resin and/or water soluble modified alkyd resin and/or contain the modifier of the water soluble alkyd resin of free radical are selected from the used modifier of the paint such as the acid of water soluble amino resin and/or water soluble phenol resin and/or water-soluble rosin phenol-formaldehyde resin modified and/or ketone resin and/or vegetable oil and/or vegetable oil acid and/or water-soluble acrylic and derivatives resin thereof and/or polybutadiene (as polyalcohol or polyacid) and/or organic ternary and/or organic tetra-atomic acid and/or all water soluble modified alkyd resins of technical field of ink one or more.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of Polyester Resin Water Soluble in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent, can enumerate the water-soluble unsaturated polyester resin stand linseed oil of Beijing Wanyang Anti-counterfeiting Technology Co., Ltd.'s product: WY-5001, WY-5002 unsaturated polyester resin tackiness agent, in paint such as six hydroxyl methylated methylol melamine formaldehyde resin modified water-soluble unsaturated polyester resins and/or all Polyester Resin Water Solubles of technical field of ink one or more.These Polyester Resin Water Solubles can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to water soluble acrylate resin in used ( B ) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent and/or the water soluble salt of polyacrylic acid and derivative thereof and/or water-soluble self-crosslinking acrylic and/or water-soluble acrylic and derivatives resin thereof and/or single component ACRYLIC EMULSION and/or acrylate copolymer emulsion and/or acrylate copolymer emulsion or single component ACRYLIC EMULSION and the water-based dispersion resin that obtains with the compound water soluble resin for preparing of addition Gum Rosin and/or vinylbenzene and acrylate and/or N hydroxymethyl acrylamide and/or polynary monomer copolymerization such as vinylformic acid and derivative thereof or the concrete example of film-forming resin and/or keto-aldehyde modified soluble acrylate resin； Can enumerate the WY-3100 water soluble acrylic resin that Beijing full printing ink of ten thousand Yao; Penta own neoasozin company limited produces; The WY-3100A water soluble acrylic resin; The WY-3208A water soluble acrylic resin; The WY-3200 water soluble acrylic resin; The WY-3800 ACRYLIC EMULSION; The WY-3808 ACRYLIC EMULSION; the WY-3807 ACRYLIC EMULSION, the water soluble acrylate resin that paint such as WY-3899 ACRYLIC EMULSION and/or technical field of ink are all and/or the water soluble salt of polyacrylic acid and derivative thereof and/or water-soluble self-crosslinking acrylic and/or water-soluble acrylic and derivatives resin thereof and/or single component ACRYLIC EMULSION and/or acrylate copolymer emulsion and/or acrylate copolymer emulsion or single component ACRYLIC EMULSION and the water-based dispersion resin that obtains with the compound water soluble resin for preparing of addition Gum Rosin and/or vinylbenzene and acrylate and/or N hydroxymethyl acrylamide and/or polynary monomer copolymerization such as vinylformic acid and derivative thereof thereof or in film-forming resin and/or the keto-aldehyde modified soluble acrylate resin one or more.////////N-//。 That is to say, above-mentioned various acrylic resins and outside all paint and/or in all water-soluble acrylic ester resinoid of technical field of ink one or more.These resins can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of water soluble polyurethane resin in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent, can enumerate vegetables oil (or vegetable oil acid) and carry out alcoholysis (or esterification) with polyvalent alcohol, alcoholysate (or carboxylate) reacts with isocyanic ester, add organic acid then (as maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, the methene butene dioic acid, organic ternary acid, in organic tetraprotic acid etc. one or more) etc., be prepared into water-soluble modified ammonia ester oil or water soluble polyurethane resin.On this basis, can also be with the modification again of other resin (as in resol, aminoresin, the Resins, epoxy etc. a kind of).That is to say, above-mentioned various aqurous ployurethane resinoids and outside all paint and/or in all aqurous ployurethane resinoid of technical field of ink one or more.These aqurous ployurethane resinoids can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

Also can enumerate polyvalent alcohol and/or polyether glycol and isocyanic ester reacts, add organic acid (as in maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, methene butene dioic acid, organic ternary acid, organic tetraprotic acid etc. one or more) etc. then, through operations such as neutralizations, be prepared into water soluble polyurethane resin.That is to say, above-mentioned various aqurous ployurethane resinoids and outside all paint and/or in all aqurous ployurethane resinoid of technical field of ink one or more.These aqurous ployurethane resinoids can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of water-soluble bituminous resins in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent, can enumerate bituminous resins and vegetables oil and/or vegetable oil acid after the high temperature refining, with above-mentioned unsaturated organic acid addition, make water-soluble bituminous resins with salify in the carboxyl of the introducing warp.That is to say, above-mentioned various water-soluble bituminous resins and outside paint and/or in all water-soluble bituminous resins of technical field of ink one or more.These water-soluble bituminous resinss can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

Water-soluble bituminous resins is mainly used in the tackiness agent of black ink in printing ink production, can effectively reduce the consumption of carbon black pigment, and does not reduce the blackness of printing ink.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to polyvinyl alcohol in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent or the concrete example of vinyl alcohol derivatives base polymer and/or acetate emulsion and/or vinyl acetate between to for plastic-maleic acid and derivative copolymer emulsion and/or vinyl acetate between to for plastic-acrylate and derivative copolymer emulsion and/or acrylate and derivative emulsion and/or vinyl acetate-styrene copolymer emulsion, can enumerate 1799 of Yunnan Yun Wei Group Plc, 2099,2499 or SINOPEC Sichuan Vinylon Factory 2499,0588,1788,2488 wait one or more in all polyvinyl alcohol or vinyl alcohol derivatives base polymer and/or acetate emulsion and/or vinyl acetate between to for plastic-maleic acid and derivative copolymer emulsion and/or vinyl acetate between to for plastic-acrylate and derivative copolymer emulsion and/or acrylate and derivative emulsion and/or the vinyl acetate-styrene copolymer emulsion etc.Above-mentioned these polyvinyl alcohol or vinyl alcohol derivatives base polymer or copolymer emulsion are at photogravure ink and/or be equal in the water-soluble screen printing ink of this printing ink and can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal in used (B) water-soluble polymers of the water-soluble screen printing ink of this printing ink and/or the polymer monomer tackiness agent water-soluble ultraviolet curing with the concrete example of Epocryl and/or water-soluble polyester acrylate resin, but the water-soluble diphenolic acid Resins, epoxy of exemplified by acrylic esterification; By polyether glycol and organic acid reaction, the polyester acrylate resin that obtains through acroleic acid esterification again.The all ultraviolet curing of paint such as the WY-4005 soluble epoxide acrylate resin of producing as Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited, WY-4005A water-soluble polyester acrylate resin and/or technical field of ink is with in water-soluble Epocryl and/or the water-soluble polyester acrylate resin one or more.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of used (C) environment-friendly water-soluble solubility promoter of the water-soluble screen printing ink of this printing ink, can enumerate water-soluble paint and/or the used alcohol of printing-ink technical field, ether, ester, ketone, in the water equal solvent one or more, as ethanol, n-propyl alcohol, Virahol, the trimethyl carbinol, butanols, ethylene glycol and ether thereof, neopentyl glycol and ether thereof, Diethylene Glycol and ether thereof, triethylene glycol and ether thereof, Tetraglycol 99 and ether thereof, dipropylene glycol and ether thereof, tripropylene glycol and ether thereof, three contract four propylene glycol and ethers thereof, glycerine and monoether thereof, the glycerol mono fatty acid ester, butyleneglycol and ether thereof, polyether Glycols, polyether-tribasic alcohol, the polyethers tetravalent alcohol, the polyethers pentavalent alcohol, polyoxyethylene glycol, polypropylene glycol, polymer polyatomic alcohol, polyester polyol, ethyl acetate, acetone, pimelinketone, the water-soluble silicon wet goods, these solvents can use separately or multiple being used.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of used (D) film coalescence aid of the water-soluble screen printing ink of this printing ink, can exemplify in the film coalescence aid such as the metal-salt (as: cobalt of unsaturated organic acid such as naphthenic acid, sad, capric acid, manganese, cerium, vanadium, lanthanum, iron, lithium, lead, zirconium, aluminium, calcium, zinc salt, manganese borate etc.) of organic acid and/or nitric acid and/or ammonia/zirconium complex one or more.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of used (D) neutralizing agent of the water-soluble screen printing ink of this printing ink, can exemplify mineral alkali (as sodium hydroxide, potassium hydroxide, lithium hydroxide etc.) and/or inorganic ammonium salt (as bicarbonate of ammonia etc.) and/or be heated easily emit ammonia organic amine (as urotropine, urea etc.) and/or inorganic ammonia (as liquefied ammonia, ammoniacal liquor etc.) and/or and/or organic amine (as diethylamine, triethylamine etc.) and/or and/or thanomin (as Monoethanolamine MEA BASF, diethanolamine, trolamine etc.) etc. one or more in.In carrying out with above-mentioned neutralizing agent and the time, the consumption of neutralizing agent is determined with the measuring result of pH value.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of used (D) whipping agent of the water-soluble screen printing ink of this printing ink, can enumerate decomposition temperature at the various whipping agents below 200 ℃, believe in the whipping agents such as the auspicious plastic cement product G AT-2000 of Industries, Inc, modification carbonate one or more as Taiwan.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of used (D) swelling agent of the water-soluble screen printing ink of this printing ink, can enumerate expansion temperature at the various swelling agent products below 200 ℃, believe among product 120D that auspicious plastic cement Industries, Inc provides etc. one or more as Taiwan.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of used (D) wax of the water-soluble screen printing ink of this printing ink, can enumerate natural wax (as carnauba wax, little candle is counted wax, esparto wax, ouricury wax, Japan tallow, fir wax, palm wax, beeswax, insect wax, wool wax, paraffin, Microcrystalline Wax, montanin wax, ore deposit ceresine etc.), synthetic wax is (as the esterification products of stearic acid and derivative thereof or they and alcohol, stearyl alcohol, polyethylene wax etc.), modified waxes is (as oxidized polyethlene wax, chlorinated wax, the polymeric fatty acid amides, aluminum stearate, Vaseline etc.), synthetic wax also comprises other natural wax or synthetic wax, through chemistry or physical treatment (as purifying, oxidation, chlorination etc.) wax that obtains after.Above-mentioned wax can use separately or multiple being used.Two or more waxes are used, and also are blended wax.

As the water-base gravure ink that is equal to plate engraving ink and/or be equal to the concrete example of used (D) UV light absorber of the water-soluble screen printing ink of this printing ink, can exemplify the used all ultraviolet curings of water-soluble paint such as st-yrax dme, michaelis ketone, benzophenone and/or printing-ink technical field with in the UV light absorber one or more.

Below for example, the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention is described further, but the present invention is not subjected to the restriction of these concrete examples.

Embodiment 1

Mix also fully wetting 70.54 parts of water-soluble maleic anhydride modified tung oil (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 7.52 parts of silicon-dioxide, wax for 9.00 parts, be ground to certain fineness by three roller ink grinding mills, then 8.95 parts of liquid film coalescence aid and 3.99 parts of ethylene glycol monobutyl ethers are sneaked into wherein, obtain water-base gravure ink and/or be equal to the water-soluble screen printing ink of this printing ink.

The basic parameter of this product is as follows: viscosity: 2.5Pa.s/40 ℃; The average acid number of printing ink is less than 3.5mgKOH/g; Time of drying: 3 minutes/80 ℃ baking ovens.

Printing condition: the printing viscosity of printing ink: 1.5Pa.s/40 ℃; Version line degree of depth 30-70 micron; Print speed: 6500/hour; Paper: 90 gram offset paper; Bake out temperature (paper surface temperature): 70 ℃.

Printing effect: the trace of the printing that is obtained (printing ink), stroking it with hand has tangible rough sensation; The printing mass colour well arranged, stereoscopic sensation is strong; In 4 hours printing seasoning time; Contamination-proof property is good; Printability is good.

Embodiment 2

On the basis of embodiment 1, add the swelling agent 120D of total ink 4%, bake out temperature (paper surface temperature) is adjusted to 120-125 ℃, other printing condition is constant, the trace of the printing that is obtained (printing ink), stroking it with hand has tangible rough sensation, and ink film thickness can reach 80 microns.

Embodiment 3

With 35.05 parts of WY-3100 water soluble acrylic resins (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 13.91 parts of WY-3100A water soluble acrylic resins (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 12.84 parts of Macrogol 200s, 8.42 parts of Pigment Yellow 73s, 8.51 parts of silicon-dioxide, 16.27 parts of WY-616, mix also fully wetting, be ground to certain fineness by three roller ink grinding mills, viscosity size according to printing ink, adjust viscosity with 5.00 parts ethylene glycol monobutyl ethers, obtain water-base gravure ink and/or be equal to the water-soluble screen printing ink of this printing ink.

The basic parameter of this product is as follows: viscosity controller is at 1.0-4.5Pa.s/40 ℃, and the printing viscosity of printing ink should be less than 1Pa.s/40 ℃, printing viscosity ethanol and/or water and/or ethylene glycol monobutyl ether adjustment; The average acid number of printing ink is less than 1mgKOH/g; Wink-dry in 80 ℃ of baking ovens.

Printing condition: with reference to embodiment 1.Printing effect: close with embodiment 1.

Embodiment 4

With 31.87 parts of WY-3208A water soluble acrylic resins (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 42.10 parts of WY-3200 water soluble acrylic resins (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 5.49 parts of black smoke, 7.59 parts of silicon-dioxide, Macrogol 200 mixes also fully wetting for 7.95 parts, be ground to certain fineness by three roller ink grinding mills, viscosity size according to printing ink, adjust viscosity with 5.00 parts ethylene glycol monobutyl ethers, obtain water-base gravure ink and/or be equal to the water-soluble screen printing ink of this printing ink.

The basic parameter of this product is as follows: viscosity controller is less than 1Pa.s/40 ℃; The average acid number of printing ink: less than 1mgKOH/g; 80 ℃ of baking oven wink-dries.

Printing condition: with reference to embodiment 1.Printing effect: close with embodiment 1.

Embodiment 5

On the basis of embodiment 4, the whipping agent GAT-2000 (auspicious plastic cement Industries, Inc product is believed in Taiwan) that adds total ink 4%, bake out temperature (paper surface temperature) is adjusted to 120-125 ℃, other printing condition is constant, the trace of the printing that is obtained (printing ink), stroking it with hand has tangible rough sensation.

Embodiment 6

With 72.00 parts of WY-3807 ACRYLIC EMULSION (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 10.40 parts of WY-3899 ACRYLIC EMULSION (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 5 parts in lime carbonate, silicon-dioxide mixes also fully wetting for 7.60 parts, be ground to certain fineness by three roller ink grinding mills, viscosity size according to printing ink, adjust viscosity with 5.00 parts ethylene glycol monobutyl ethers, obtain water-base gravure ink and/or be equal to the water-soluble screen printing ink of this printing ink.

The basic parameter of this product is as follows: viscosity controller is less than 1Pa.s/40 ℃; The average acid number of printing ink is less than 1mgKOH/g; 80 ℃ of baking oven wink-dries.

Printing condition: with reference to embodiment 1.Printing effect: close with embodiment 1.

Embodiment 7

With 42.00 parts of WY-4005 soluble epoxide acrylate resins (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), 18.10 parts of WY-4005A water-soluble polyester acrylate resins (Beijing full printing ink of ten thousand Yao, penta own neoasozin company limited product), blue 5.50 parts of pigment, 7.60 parts of silicon-dioxide, wax mixes also fully wetting for 3.50 parts, be ground to certain fineness by three roller ink grinding mills, then with 2.00 parts of UV light absorber st-yrax dme, 2.00 parts of 2.00 parts of benzophenone of michaelis ketone, wax removes that 8.00 parts of sticks (the emerging printing ink of Tianjin cloud company product) are prior sneaks into wherein after ground, viscosity size according to printing ink, adjust viscosity with 9.30 parts triethylene glycol butyl ethers, obtain water-base gravure ink and/or be equal to the water-soluble screen printing ink of this printing ink.

The basic parameter of this product is as follows: viscosity controller is less than 1.5Pa.s/40 ℃; UV solidifies dry moment to be finished.

Printing condition: with reference to embodiment 1.Printing effect: close with embodiment 1.

The detection of ink viscosity: detect Tongji University's product with NDJ-79 type rotational viscosimeter.

To sum up, above-mentioned various chemical raw materials, compound, water soluble resin, water-soluble binder (but never being limited to these chemical raw materials, compound, water soluble resin, water-soluble binder) etc., by water-base gravure ink of the present invention and/or after being equal to the technical scheme combination of water-soluble screen printing ink of this printing ink, the photogravure ink that obtains and/or be equal to the water-soluble screen printing ink of this printing ink has nonpoisonous and tasteless; Nonflammable; Soluble in water; The contamination-proof property of printing ink is good; Ink setting is rapid; Thick and not sticking; Both the pine and lack; The average acid number 0-55mgKOH/g of printing ink; The viscosity of this printing ink is less than 3Pa.s/40 ℃; This printing ink is applicable to various types of rolled papers and/or sheet-fed gravure machine; Printing ink can be filled in edition line, and the printing ink of non-figure line part is easily scraped totally on the forme; Printing ink in the version line is easily transferred on the paper; The solid content height; Use the trace of the printed matter that this printing ink obtains or ink film thickness that printing ink is stayed paper surface can satisfy people's properties such as requirement.Therefore, technical scheme of the present invention be with above-mentioned various chemical raw materials, compound, water soluble resin, water-soluble binder and/or above-mentioned beyond various chemical raw materials, compound, water soluble resin, water-soluble binder etc. combine, after processing, water-base gravure ink that obtains and/or the water-soluble screen printing ink that is equal to this printing ink have above-mentioned property, all belong to scope of the present invention.

The above-mentioned water-base gravure ink that is equal to plate engraving ink also can be used for silk screen printing.In other words, being equal to water-soluble screen printing ink of the present invention can be used as water-base gravure ink of the present invention and is used for the photogravure process.Water-base gravure ink of the present invention no matter, still be equal to water-soluble screen printing ink of the present invention, whether the two is identical or be equal to, and key is that whether identical the handle effect of the printing that obtains by the printshop compare or be equal to the handle effect of intaglio ink product.Therefore, water-base gravure ink of the present invention and/or be equal to water-soluble screen printing ink of the present invention and be used for various types of rolled papers and/or sheet-fed gravure machine, the printing that obtains and the identical or effects equivalent of printing effect of intaglio ink product, and the environmentally safe person does not have, and to endanger be final purpose.

The application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of the present invention, other printing condition (as gap, print speed etc. between squeegee pressure, cylinder) is with reference to the printing condition of normal photogravure ink.This printing ink is used for wiring when printing, is that the angle by adjustment figure line when look China ink groove or the plate-making is finished with cooperating every look black groove.

The water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of the present invention is applicable to gravure machine.The advantage of this printing ink is nonpoisonous and tasteless; Nonflammable; Soluble in water; Environment do not had pollution; Rapidly dry; The printing effect of the printing that obtains is identical with the printing effect of intaglio ink product or be equal to; The materialization fastness of printing is better than the materialization fastness of intaglio ink product; Printing cost is low; Be particularly suitable for printing the safe and secret file of dark version line, as banknote, Valued Securities, stamp, food product pack etc.

Claims (71)

1. be equal to the water-base gravure ink of plate engraving ink and/or be equal to the water-soluble screen printing ink of this printing ink, it is characterized in that, the water-soluble screen printing ink that this printing ink contains (A) water-base gravure ink and/or is equal to this printing ink accounts for the total 0-55% that forms of this printing ink with pigment and/or dyestuff, (B) the total 10-90% that forms of environment-friendly water-soluble polymkeric substance and/or this printing ink of polymer monomer binder constitutes, (C) the environment-friendly water-soluble solubility promoter accounts for the total 0.5-75% that forms of this printing ink, (D) water-base gravure ink and/or the water-soluble screen printing ink that is equal to this printing ink account for the total 0.1-52% that forms of this printing ink, the wherein average acid number 0-55mgKOH/g of this printing ink with film coalescence aid and/or neutralizing agent and/or whipping agent and/or swelling agent and/or UV light absorber and/or wax; The printing viscosity of printing ink is less than 5Pa.s/40 ℃.

2. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that, described (A) pigment and/or dyestuff are selected from used pigment dyestuff of water-soluble paint and/or printing-ink technical field and/or dyestuff, mineral dye, the stopping composition one or more.

3. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that, described (A) pigment and/or dyestuff are selected from pigment dyestuff and/or dyestuff, mineral dye, high-visibility pigment and/or dyestuff, and these pigment and/or dyestuff can use separately or multiple being used.

4. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 2, it is characterized in that, described (A) pigment and/or dyestuff are selected from titanium dioxide, silicon-dioxide and lime carbonate, and these pigment and/or dyestuff can use separately or multiple being used.

5. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 4, it is characterized in that the 0-45% of this total weight of silica comprises in described (A) pigment and/or the dyestuff; Lime carbonate accounts for the 0-40% of this total weight.

6. according to each described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink among the claim 1-3, it is characterized in that, contain barium sulfate in described (A) pigment and/or the dyestuff, this barium sulfate accounts for the 0-15% of this total weight.

7. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 5, it is characterized in that the 3-35% of this total weight of silica comprises in described (A) pigment and/or the dyestuff.

8. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 5, it is characterized in that the 4-20% of this total weight of silica comprises in described (A) pigment and/or the dyestuff.

9. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 5 is characterized in that the lime carbonate in described (A) pigment and/or the dyestuff accounts for the 3-30% of this total weight.

10. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 5, it is characterized in that the lime carbonate in described (A) pigment and/or the dyestuff accounts for the 4-25% of this total weight.

11. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 6 is characterized in that the barium sulfate in described (A) pigment and/or the dyestuff accounts for this printing ink 0.5-4%.

12. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from the resin glue that water-soluble paint and/or printing-ink technical field can be water-soluble one or more.

13. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 12, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water soluble oils; Water soluble phenol resin; Water-soluble terpolycyantoamino-formaldehyde resin; Water-soluble fumaric acid modified rosin resin; Water-soluble rosin modified resin; Water-soluble epoxy resin; The soluble epoxide acrylic resin; Water soluble alkyd resin; Water soluble modified alkyd resin; Polyester Resin Water Soluble; The water soluble acrylate resin; Waterborne polyurethane resin; Water-soluble bituminous resins; Polyacrylic water soluble salt; Water-soluble self-crosslinking acrylic; The single component ACRYLIC EMULSION; Acrylate copolymer emulsion; Acrylate copolymer emulsion or single component ACRYLIC EMULSION and with the compound water soluble resin for preparing of addition Gum Rosin; Water-based dispersion resin and/or film-forming resin that vinylbenzene and/or acrylate and/or N hydroxymethyl acrylamide and/or acrylic acid multielement monomer copolymerization obtain; Polyvinyl alcohol; Acetate emulsion; Vinyl acetate between to for plastic-maleic acid copolymer emulsion; Acrylic ester emulsion; The vinyl acetate-styrene copolymer emulsion; Water-soluble poly N-vinyl pyrrolidone; Keto-aldehyde modified soluble acrylate resin; One or more in the polyester acrylate resin of water-based fluoroalkyl, aqueous silicate, water-soluble ultraviolet curing.

14. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water-soluble modified vegetables oil.

15. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from the water soluble phenol resin modified vegetable oil.

16. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from waterborne organic silicon oil.

17. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water-soluble epoxy ester.

18. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water-soluble poly oxyethane.

19. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water-soluble ultraviolet curing Epocryl.

20. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from the water soluble alkyd resin that contains free radical.

21. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water-soluble poly butadiene resin and modified alkyd resin thereof.

22. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from the water soluble acrylic resin.

23. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13, it is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from vinyl acetate between to for plastic-acrylate copolymer emulsion.

24. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 13 is characterized in that described water-based fluoroalkyl is fluorine carbon or fluorine silicon.

25. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that, described (C) environment-friendly water-soluble solubility promoter is selected from the used alcohol of water-soluble paint and/or printing-ink technical field, ether, ester, ketone, the water one or more.

26. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1 is characterized in that, described (C) environment-friendly water-soluble solubility promoter is selected from water-soluble silicon oil.

27. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 25, it is characterized in that, described (C) environment-friendly water-soluble solubility promoter is selected from ethanol, n-propyl alcohol, Virahol, the trimethyl carbinol, butanols, ethylene glycol and ether thereof, neopentyl glycol and ether thereof, Diethylene Glycol and ether thereof, triethylene glycol and ether thereof, Tetraglycol 99 and ether thereof, dipropylene glycol and ether thereof, tripropylene glycol and ether thereof, three contract four propylene glycol and ethers thereof, glycerine and monoether thereof, the glycerol mono fatty acid ester, butyleneglycol and ether thereof, polyether Glycols, polymer polyatomic alcohol, ethyl acetate, acetone, in the pimelinketone one or more, these solvents can use separately or multiple being used.

28. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 27, it is characterized in that described (C) environment-friendly water-soluble solubility promoter is selected from one or more in polyoxyethylene glycol, polyether-tribasic alcohol, polyethers tetravalent alcohol, polyethers pentavalent alcohol, the pure and mild polypropylene glycol of polyester polyols.

29. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that, described (D) film coalescence aid and/or neutralizing agent and/or whipping agent and/or swelling agent and/or UV light absorber and/or wax are selected from used all film coalescence aid of water-soluble paint and/or printing-ink technical field and/or neutralizing agent and/or whipping agent and/or swelling agent and/or UV light absorber and/or the wax one or more.

30. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 29, it is characterized in that, described (D) film coalescence aid is selected from the metal-salt of organic acid and/or nitric acid and/or in ammonia/zirconium complex film coalescence aid one or more.

31. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 30, it is characterized in that described (D) film coalescence aid is selected from cobalt, manganese, cerium, vanadium, lanthanum, iron, lithium, lead, zirconium, aluminium, calcium, zinc salt and the manganese borate of naphthenic acid, sad, capric acid.

32. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 29, it is characterized in that, described (D) neutralizing agent is selected from mineral alkali and/or inorganic ammonium salt and/or inorganic ammonia and/or the organic amine one or more.

33. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 32, it is characterized in that, described (D) neutralizing agent, being selected from is heated easily emits the organic amine of ammonia and in the thanomin one or more.

34. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 32 is characterized in that described mineral alkali is sodium hydroxide, potassium hydroxide, lithium hydroxide.

35. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 32 is characterized in that described inorganic ammonium salt is a bicarbonate of ammonia.

36. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 33 is characterized in that, the described organic amine of easily emitting ammonia that is heated is urotropine, urea.

37. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 32 is characterized in that described inorganic ammonia is liquefied ammonia, ammoniacal liquor.

38. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 32 is characterized in that described organic amine is diethylamine, triethylamine.

39. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 33 is characterized in that described thanomin is Monoethanolamine MEA BASF, diethanolamine, trolamine.

40. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 29 is characterized in that described (D) whipping agent and/or swelling agent account for the 0-10% of this total weight.

41., it is characterized in that described (D) whipping agent and/or swelling agent account for the 0.2-8% of this total weight according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 40.

42., it is characterized in that described (D) whipping agent and/or swelling agent account for the 0.5-6% of this total weight according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 40.

43. according to each described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink in the claim 29,40,41 and 42, it is characterized in that, described (D) whipping agent is selected from decomposition temperature one or more in the various whipping agents below 200 ℃.

44., it is characterized in that described whipping agent is a modification carbonate according to each described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink in the claim 29,40,41 and 42.

45. according to each described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink in the claim 29,40,41 and 42, it is characterized in that, described (D) swelling agent is selected from expansion temperature one or more in the various swelling agent products below 200 ℃.

46. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 29, it is characterized in that, described (D) UV light absorber is selected from paint and/or all UV light absorber of technical field of ink one or more.

47. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 46, it is characterized in that, described (D) UV light absorber is selected from st-yrax dme, michaelis ketone and the benzophenone one or more.

48. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 29 is characterized in that, described (D) wax is selected from natural wax, synthetic wax, the modified waxes one or more.

49. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 48, it is characterized in that described natural wax is that carnauba wax, little candle are counted wax, esparto wax, ouricury wax, Japan tallow, fir wax, palm wax, beeswax, insect wax, wool wax, paraffin, Microcrystalline Wax, montanin wax or ore deposit ceresine.

50. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 48, it is characterized in that described synthetic wax is esterification products, stearyl alcohol or the polyethylene wax of stearic acid or it and alcohol.

51. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 48, it is characterized in that described modified waxes is oxidized polyethlene wax, chlorinated wax, polymeric fatty acid amides, aluminum stearate or Vaseline.

52. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 48, it is characterized in that, described synthetic wax also comprises other natural wax or synthetic wax, one or more in the wax that obtains after chemistry or physical treatment.

53., it is characterized in that described chemistry or physical treatment are purification, oxidation or chlorination according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 52.

54. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that the drying mode of this printing ink is one or both or the two or more mixed type in oxypolymerization drying and/or volatile dry and/or infiltration drying and/or the ultraviolet curing.

55. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1 is characterized in that, oxypolymerization time of drying of this printing ink is less than 15 minutes/80 ℃ baking ovens.

56. according to claim 1 or the 54 described water-soluble screen printing inks that are equal to the water-base gravure ink of plate engraving ink and/or are equal to this printing ink, it is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the desiccant wax of oxypolymerization accounted for the 0.1-15% of this total weight; The desiccant film coalescence aid of oxypolymerization accounts for the 0.1-15% of this total weight.

57. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 56, it is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the desiccant wax of oxypolymerization accounted for the 5-12% of this total weight.

58. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 56, it is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the desiccant wax of oxypolymerization accounted for the 6-10% of this total weight.

59., it is characterized in that the desiccant film coalescence aid of oxypolymerization accounts for the 1-10% of this total weight according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 56.

60., it is characterized in that the desiccant film coalescence aid of oxypolymerization accounts for the 2-8% of this total weight according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 56.

61. according to claim 1 or the 54 described water-soluble screen printing inks that are equal to the water-base gravure ink of plate engraving ink and/or are equal to this printing ink, it is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the seasoning time was not more than 8 hours; Drying mode is that volatile dry and/or infiltration are dry, and when printing press was not installed drying plant, printing time of drying was less than 4 hours; Drying mode is that volatile dry and/or infiltration are dry, when printing press is equipped with drying plant, but printing drying moment finish; Drying mode is that UV solidifies when dry, but printing drying moment finishes.

62. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 56, it is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the seasoning time was not more than 8 hours.

63. according to each described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink in claim 1 and 13, it is characterized in that, when the drying mode of this printing ink is UV curing drying, described (B) water-soluble polymers and/or polymer monomer tackiness agent be selected from the water-soluble diphenolic acid Resins, epoxy of acroleic acid esterification, by polyether glycol and organic acid reaction, one or more in the polyester acrylate resin that acroleic acid esterification obtains again.

64. according to the described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink of claim 62, it is characterized in that, when the drying mode of this printing ink is UV curing drying, described (B) water-soluble polymers and/or polymer monomer tackiness agent be selected from the water-soluble diphenolic acid Resins, epoxy of acroleic acid esterification, by polyether glycol and organic acid reaction, one or more in the polyester acrylate resin that acroleic acid esterification obtains again.

65. according to each described application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink among the claim 1-64, it is characterized in that this printing ink is applicable to various types of rolled papers and/or sheet-fed gravure machine.

66. according to the described application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of claim 65, it is characterized in that, the version line degree of depth of the forme of gravure machine is between the 20-200 micron, and forme is carved by known engraving mode or corroded the mode that combines with engraving or by known caustic solution acquisition.

67. according to the described application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of claim 66, it is characterized in that, the version line of the forme of gravure machine is based on lines, the site be auxilliary or dotted line in conjunction with or all forms by lines, a wherein dark edition line structure must have the line of ink marker of holding.

68. according to each described application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink among the claim 65-67, it is characterized in that, in printing process, the unnecessary printing ink of non-graphic part is by scraper or scrapes device for ink and scrape totally or wipe clean by a wiping edition device on the forme.

69., it is characterized in that the bake out temperature of gravure machine or paper surface temperature are at 50-180 ℃ according to the described application that is equal to the water-base gravure ink of plate engraving ink and/or is equal to the water-soluble screen printing ink of this printing ink of claim 68.

70. according to each described water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink among the claim 1-3; it is characterized in that, use the trace of the printed matter that this printing ink obtains or the ink film thickness that printing ink is stayed paper surface to be the 20-180 micron.

71. the water-soluble screen printing ink that is equal to the water-base gravure ink of plate engraving ink and/or is equal to this printing ink according to claim 1, it is characterized in that this printing ink is nonflammable, do not have smell, there are not harm in the environment and the person, are fit to the printing security secret document and/or to food product pack and/or banknote and/or the various certificate and/or the equity certificate printing of health conditions requiring strictness.