CN107987607A - Water-based ink and preparation method thereof - Google Patents
Water-based ink and preparation method thereof Download PDFInfo
- Publication number
- CN107987607A CN107987607A CN201711361489.5A CN201711361489A CN107987607A CN 107987607 A CN107987607 A CN 107987607A CN 201711361489 A CN201711361489 A CN 201711361489A CN 107987607 A CN107987607 A CN 107987607A
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- China
- Prior art keywords
- water
- based ink
- preparation
- thickener
- base resin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
Abstract
The present invention relates to a kind of water-based ink and preparation method thereof, which comprises the following steps:S1, provide water-base resin, thickener, dispersant, crosslinking agent, defoamer and color stuffing, and the water-base resin, thickener, dispersant, crosslinking agent, the mass ratio of defoamer and color stuffing are respectively 20 50%, 0.3 0.8%, 0.5 1%, 1 2.5%, 0.2 0.5% and 12 25%;S2, add the water-base resin and color stuffing into alcohol water, and stirred under 500 2000 revs/min of rotating speed, then the dispersant, crosslinking agent and defoamer are added thereto, and stir evenly, it is eventually adding thickener and the alcohol water, stirred under 100 800 revs/min of rotating speed, obtain the water-based ink.The preparation method safety and environmental protection of the water-based ink, cost are low, efficient, and the water-based ink holding time length being prepared, and have larger application prospect.
Description
Technical field
The present invention relates to a kind of water-based ink and preparation method thereof, belong to ink area.
Background technology
Its composition of water-based ink particularly printed form ink mainly includes:Binder (polymerizing prepolymer), pigment, water and
Other auxiliary agents.Its feature is to employ water-base resin as link stuff, is broadly divided into two types:Water dilution type and moisture dissipate
Type.The resinous type that the former can use has a many kinds, for example, malein acid ester resin, lac, maleic acid resin Modified Shell-lac for Cuprous Surface Anticorrosion,
Urethane, water soluble acrylic resin and water-compatible amino resin etc..The link stuff of water-dispersion type is in water by the list of emulsification
Body polymerization gained, it is two-phase system, and wherein oil phase is disperseed with graininess in water phase, though it can not be dissolved in water, can
It is diluted with water, so it is also assumed that being oil-in-water emulsion type.
Last century Mo, Japanese, South Korea and Southeast Asia etc. have just eliminated countries and regions toluene class printing ink.The U.S.
Off-set oil inkization is just advocated in the eighties in last century, and forbids using solvent-based ink printing plastics in its country.
Printed using water-based ink, it need not use solvent first, only use clear water.Have it is a kind of wrong think,
Addition solvent is The more the better in ink, and such cost is lower.Actually this is not so, the solvent added, was printed entirely
Added in journey.This is because the volatilization of solvent causes ink viscosity to change and add.Print speed printing speed is faster, required allotment it is dilute
The volatility for releasing agent will be faster, and the number for adding solvent is more.This is equal to be constantly increasing printing cost.With ink row
From the point of view of the standard of industry, the colour saturation of ink is high, and viscosity is low to be only ink.Diluent is added in ink, is only used as reducing ink
Viscosity.It is set suitably to print, such as excessive addition, the colour saturation of ink can reduce.The component of binder reduces at the same time, so
Change can not print good product.So water-based ink only adds pure water, and it is disposably to add (before print).In printing process, it
The change of color will not be caused because of the change of viscosity, more will not be as ink, when needing to add diluent in way because printing
Caused waste product, thus substantially increases the qualification rate of printing.The cost of solvent is saved, reduces the appearance of waste product.
This is one of aqueous ink used for plastic cost advantage.
The preparation process of ink generally includes:Packed after dispensing, pre-dispersed, grinding, auxiliary agent adjustment, high speed dispersion, filtering
These links.After rudimentary ink can also disperse only by high-speed stirred or by ball mill, still, generally
Advanced ink such as intaglio plate, flexographic ink generally require by sand mill be ground it is pre-dispersed after carry out high-speed stirred again, this
Ink prepared by sample can be adapted to the requirement of printing equipment.The preparation of water-based ink is also required to carry out the pre-dispersed of sand mill,
In dispensing before pre-dispersed, generally require to add a certain amount of resin, be so conducive to the scattered of mill base, however, carrying out multistage
Easily there is the phenomenon being demulsified in resin after grinding, causes last molding ink the phenomenon being layered easily occur, seriously affects oil
The quality of ink.Someone is also contemplated for being added without resin in the grinding stage, and the ink mill base being prepared disperses inequality, causes printing
Quality decline.
Traditional ink prepares and often uses single resin, is all used in grinding pre-dispersed stage and high speed emulsifying stage
Same resin, such ink can only often embody advantage in a certain respect, and still, single resin ink is often difficult to meet more
The demand of kind technique and function.
The content of the invention
It is an object of the invention to provide a kind of water-based ink and preparation method thereof, preparation method safety and environmental protection, the cost
Water-based ink holding time length that is low, efficient, and being prepared, has larger application prospect.
To reach above-mentioned purpose, the present invention provides following technical solution:A kind of preparation method of water-based ink, including it is following
Step:
S1, provide water-base resin, thickener, dispersant, crosslinking agent, defoamer and color stuffing, the water-base resin, increasing
Thick dose, dispersant, crosslinking agent, the mass ratio of defoamer and color stuffing be respectively 20-50%, 0.3-0.8%, 0.5-1%, 1-
2.5%th, 0.2-0.5% and 12-25%;
S2, add the water-base resin and color stuffing into alcohol water, and is stirred under 500-2000 revs/min of rotating speed
Mix, then add the dispersant, crosslinking agent and defoamer thereto, and stir evenly, be eventually adding the thickener and
Alcohol water, is stirred under 100-800 revs/min of rotating speed, obtains the water-based ink.
Further, in step S2, the time stirred under described 500-2000 revs/min of rotating speed is 1-2h.
Further, in step S2, the time stirred under described 100-800 revs/min of rotating speed is 0.5-1.5h.
Further, the water-base resin is resin aqueous emulsion, and the water-base resin, which is selected from, includes methyl acrylate, benzene
Any of ethene, metering system, acrylic or methacrylic acid late resin.
Further, the defoamer is selected from dimeticone or polyvinylether.
Further, the dispersant is selected from inorganic salt dispersants or high polymer dispersion.
Further, the thickener, which is selected from, includes cellulose ether thickener, Polyacrylic Acid Thickener, polyurethane thickening
Any of agent, the non-polyurethane thickener of hydrophobically modified or inorganic thickening agent.
Further, the crosslinking agent, which is selected from, includes cumyl peroxide, di-tert-butyl peroxide, hydrogen peroxide two
Any of isopropylbenzene or diethylenetriamines.
To reach above-mentioned purpose, present invention also offers a kind of water as obtained by the preparation method of the water-based ink
Property ink.
The beneficial effects of the present invention are:The preparation method safety and environmental protection of the water-based ink of the present invention, cost are low, efficiency
Height, and the water-based ink holding time length being prepared, have larger application prospect.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of specification, below with presently preferred embodiments of the present invention and coordinate attached drawing describe in detail as after.
Brief description of the drawings
Fig. 1 is the process step figure of the preparation method of the water-based ink shown in the present invention.
Embodiment
With reference to the accompanying drawings and examples, the embodiment of the present invention is described in further detail.Implement below
Example is used to illustrate the present invention, but is not limited to the scope of the present invention.
Fig. 1 is referred to, the preparation method of the water-based ink shown in the present invention, comprises the following steps:
S1, provide water-base resin, thickener, dispersant, crosslinking agent, defoamer and color stuffing, the water-base resin, increasing
Thick dose, dispersant, crosslinking agent, the mass ratio of defoamer and color stuffing be respectively 20-50%, 0.3-0.8%, 0.5-1%, 1-
2.5%th, 0.2-0.5% and 12-25%;
S2, add the water-base resin and color stuffing into alcohol water, and is stirred under 500-2000 revs/min of rotating speed
1-2h, then adds the dispersant, crosslinking agent and defoamer thereto, and stirs evenly, be eventually adding the thickener with
And alcohol water, 0.5-1.5h is stirred under 100-800 revs/min of rotating speed, obtains the water-based ink.
In the present invention, the water-base resin is resin aqueous emulsion, the water-base resin be selected from include methyl acrylate,
Any of styrene, metering system, acrylic or methacrylic acid late resin;The defoamer be selected from dimeticone or
Polyvinylether;The dispersant is selected from inorganic salt dispersants or high polymer dispersion;The thickener, which is selected from, includes fibre
Dimension plain ether thickener, Polyacrylic Acid Thickener, polyurethane thickener, the non-polyurethane thickener of hydrophobically modified or inorganic thickening agent
Any of;The crosslinking agent, which is selected from, includes cumyl peroxide, di-tert-butyl peroxide, di-isopropylbenzene hydroperoxide
Or any of diethylenetriamines.
Below in conjunction with specific embodiments come to the present invention illustrated in further detail.
4 parts of isopropanols, 1 part of surfactant and 50 parts of water are mixed, after being warming up to 60 DEG C, add 50 parts thereto
Acrylic emulsion and color stuffing, and the stirring reaction 1.5h under 500-2000 revs/min of rotating speed.Then add thereto
After 0.5 part of dispersant, 1 part of polyvinylether and 0.6 part of cumyl peroxide, with stirring reaction 0.5h at 80 DEG C, 2.5 are added
Part cellulose ether thickener and 2 parts of isopropanols, and the stirring reaction 1h under 150 revs/min of rotating speed, obtain water-based ink.
In summary:The preparation method safety and environmental protection of the water-based ink of the present invention, cost are low, efficient, and are prepared
The water-based ink holding time length, there is larger application prospect.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses the several embodiments of the present invention, its description is more specific and detailed, but simultaneously
Cannot therefore it be construed as limiting the scope of the patent.It should be pointed out that come for those of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (9)
1. a kind of preparation method of water-based ink, it is characterised in that comprise the following steps:
S1, provide water-base resin, thickener, dispersant, crosslinking agent, defoamer and color stuffing, the water-base resin, thickening
Agent, dispersant, crosslinking agent, the mass ratio of defoamer and color stuffing are respectively 20-50%, 0.3-0.8%, 0.5-1%, 1-
2.5%th, 0.2-0.5% and 12-25%;
S2, add the water-base resin and color stuffing into alcohol water, and is stirred under 500-2000 revs/min of rotating speed, with
Add the dispersant, crosslinking agent and defoamer thereto afterwards, and stir evenly, be eventually adding thickener and the alcohol water,
Stirred under 100-800 revs/min of rotating speed, obtain the water-based ink.
2. the preparation method of water-based ink as claimed in claim 1, it is characterised in that in step S2, in the 500-2000
Rev/min rotating speed under time for stirring be 1-2h.
3. the preparation method of water-based ink as claimed in claim 1, it is characterised in that in step S2, in the 100-800
Rev/min rotating speed under time for stirring be 0.5-1.5h.
4. the preparation method of water-based ink as claimed in claim 1, it is characterised in that the water-base resin is water-base resin breast
Liquid, the water-base resin, which is selected from, includes methyl acrylate, styrene, metering system, acrylic or methacrylic acid late resin
Any of.
5. the preparation method of water-based ink as claimed in claim 1, it is characterised in that the defoamer be selected from dimeticone or
Polyvinylether.
6. the preparation method of water-based ink as claimed in claim 1, it is characterised in that the dispersant disperses selected from inorganic salts
Agent or high polymer dispersion.
7. the preparation method of water-based ink as claimed in claim 1, it is characterised in that the thickener, which is selected from, includes cellulose
In the non-polyurethane thickener of ether thickener, Polyacrylic Acid Thickener, polyurethane thickener, hydrophobically modified or inorganic thickening agent
It is any.
8. the preparation method of water-based ink as claimed in claim 1, it is characterised in that the crosslinking agent, which is selected from, includes peroxidating
Any of diisopropylbenzene (DIPB), di-tert-butyl peroxide, di-isopropylbenzene hydroperoxide or diethylenetriamines.
A kind of 9. water-based ink as obtained by the preparation method of water-based ink described in any item of the claim 1 to 8.
Priority Applications (1)
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CN201711361489.5A CN107987607A (en) | 2017-12-18 | 2017-12-18 | Water-based ink and preparation method thereof |
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CN201711361489.5A CN107987607A (en) | 2017-12-18 | 2017-12-18 | Water-based ink and preparation method thereof |
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Cited By (2)
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CN110951013A (en) * | 2019-12-05 | 2020-04-03 | 广州至然科技应用有限公司 | Covering emulsion with improved coloring and covering power performance and preparation method thereof |
CN111621197A (en) * | 2020-05-27 | 2020-09-04 | 江苏云合新材料科技有限公司 | Preparation method of water-based ink |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110951013A (en) * | 2019-12-05 | 2020-04-03 | 广州至然科技应用有限公司 | Covering emulsion with improved coloring and covering power performance and preparation method thereof |
CN111621197A (en) * | 2020-05-27 | 2020-09-04 | 江苏云合新材料科技有限公司 | Preparation method of water-based ink |
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Application publication date: 20180504 |