CN101275043B - Environment-friendly water-soluble plate engraving ink - Google Patents
Environment-friendly water-soluble plate engraving ink Download PDFInfo
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Abstract
The present invention provides an environmental protection water-soluble carving intaglio printing ink, fit for carving intaglio printer, the outstanding advantages are that the printing ink is poisonless and tasteless, no burning, dissolving in water easily; the printing banknote effluent adopts clear water, the printing ink has better non-smear ability, having quick dry, shortening the production cycle of the product, saving the plants, floor for production; since the printing ink has quick dry, the printing ink is especially fit for the safety secret file of the printing deep intaglio, such as bank note, securities, stamp, food package etc.
Description
Technical field
The present invention relates to the printing-ink field, is plate engraving ink specifically.The invention still further relates to the application of said plate engraving ink.
Background technology
It is undisputable fact that plate engraving ink is widely used in the trade mark of printing bank money, Valued Securities, various certificate, tobacco package, drug packaging, famous-brand and high-quality goods etc.Though it is line security printing technology that this technology is generally acknowledged; But because conventional carving intaglio printing ink contains a large amount of vegetables oil, oil-soluble polymers tackiness agent (like plant oil modified alkyd resin adhesiver agent, urethane resin tackiness agent, rosin and verivate polyol ester resin glue thereof, rosin modified phenolic resin tackiness agent, oil soluble pure phenolic resin tackiness agent, epoxy resin binder etc.), tensio-active agent, wax, siccative, solvent (like #200 solvent oil and/or 210 Dormant oils and/or the boiling range solvent that boiling points such as no aromatic hydrocarbons Dormant oils are lower or boiling range is narrower at 170-190 ℃) etc.; There are harm in the environment and the person; Be not suitable for printing to the strict printings such as packing of health conditions requiring; And exist certain combustibility, printing ink smell to reach printing aftertreatment cost height greatly in the conventional carving intaglio printing ink production process with in the use; Environmental pollution is serious; Bring inconvenience for safe and secret typography, for example
CN1390897A, CN1392203A, CN1563221A, CN1560145A, CN1699471A, CN1676547A etc.; These conventional plate engraving inks have the advantage of not adding a cover the paper print money; Be generally back 24 hours of printing time of drying; Because of time of drying longer, make troubles for the depositing of product after the printing with the following technology in the typography; Solvent is volatile in the plate engraving ink, and in printing process, wiping version liquid contains sodium hydroxide and alizarin assistant is many, after being completed for printing, brings severe contamination to environment; Typography requires the narrow range of controlled temperature to ink fountain temperature, forme temperature, coated film roller temperature, colour-collecting roller temperature, wiping version liquid temp etc.
One Chinese patent application number: 01144965.9 patented technology, introduced polyether glycol and non-volatile and innoxious solvent in the plate engraving ink after, have the advantage of not adding a cover the paper printing; Solvent in the plate engraving ink is non-volatile, in printing process or after being completed for printing, does not bring pollution to environment; Typography requires the scope of controlled temperature to compare broad to ink fountain temperature, forme temperature, coated film roller temperature, colour-collecting roller temperature, wiping version liquid temp etc.; Be generally back 24 hours of printing time of drying, because of time of drying longer, make troubles for the depositing of product after the printing with the following technology in the typography; Sodium hydrate content and alizarin assistant content decrease in the wiping version liquid, still contain sodium hydroxide and alizarin assistant but wipe in the version liquid.
One Chinese patent application number: the patented technology of 02801748.x; Introduce UV curing in the plate engraving ink and used resin; Printing press has increased the UV curing apparatus, and moment time of drying accomplishes, and convenience is provided for the depositing with the following technology in the typography of product after printing; Sodium hydrate content and alizarin assistant content decrease in the wiping version liquid, but still contain sodium hydroxide and alizarin assistant.
In order to solve the problem that exists in the above-mentioned technology, reach to wipe in the version liquid and completely abolish sodium hydroxide and alizarin assistant, adopt clear water to wipe version; Moment time of drying accomplishes, and provides convenience for depositing with following typography of printing back product; Solve plate engraving ink easy firing, smell big, there are harm in the environment and the person, make plate engraving ink be fit to the purpose of printing to the strict printings such as packing of health conditions requiring, the contriver has done lot of test, experiment, has accomplished the present invention.
Summary of the invention
The object of the present invention is to provide environment-friendly water-soluble plate engraving ink.Another object of the present invention provides the application of this printing ink.
Environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that this printing ink contains pigment that (A) environment-friendly water-soluble plate engraving ink uses and/or dyestuff and accounts for total 10-90%, (C) environment-friendly water-soluble solubility promoter of forming of total 0-55%, (B) environment-friendly water-soluble polymkeric substance and/or this printing ink of polymer monomer binder constitutes formed of this printing ink and account for the total 0.5-75% that forms of this printing ink, (D) environment-friendly water-soluble plate engraving ink account for the total composition of this printing ink with film coalescence aid and/or neutralizing agent 0.1-52%.
Environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that; Described (A) environment-friendly water-soluble plate engraving ink is with pigment and/or dyestuff; Be selected from used pigment dyestuff of water-soluble paint and/or printing-ink technical field and/or dyestuff, mineral dye, the stopping composition one or more; Like the Huang in organic pigment and/or dyestuff, mineral dye, the stopping composition, red, tangerine, orchid, black, green, white, titanium oxide, silicon-dioxide, lime carbonate, kaolin, wilkinite, aluminium or silver powder, copper or bronze, high-visibility pigment and/or dyestuff etc., these pigment and/or dyestuff can use separately or multiple being used.
Environment-friendly water-soluble plate engraving ink of the present invention is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water soluble oils; Water-soluble modified vegetables oil; The water soluble phenol resin modified vegetable oil; Water soluble phenol resin; Water-soluble trimeric cyanamide and verivate formaldehyde resin thereof; Water-soluble fumaric acid modified Gum Rosin; Water-soluble rosin modified resin; Water-soluble epoxy ester; Water-soluble epoxy resin; The soluble epoxide vinyl resin; Water-soluble poly oxyethane and verivate thereof; Water soluble alkyd resin; Water soluble modified alkyd resin; The water soluble alkyd resin that contains radical; Polyester Resin Water Soluble; The water soluble acrylate resin; Water-soluble poly butadiene resin and modified alkyd resin thereof; Waterborne polyurethane resin; Water-soluble bituminous resins; The water soluble salt of ROHM and verivate thereof; Water-soluble self-crosslinking acrylic; Water-soluble acrylic and derivatives resin thereof; The single component ACRYLIC EMULSION; Acrylate copolymer emulsion; Acrylate copolymer emulsion or single component ACRYLIC EMULSION and with the compound water soluble resin for preparing of addition Gum Rosin; Water-based dispersion resin and/or film-forming resin that polynary monomer copolymerization such as vinylbenzene and/or propenoate and/or N hydroxymethyl acrylamide and/or vinylformic acid and verivate thereof etc. obtains; Z 150PH or vinyl alcohol derivatives base polymer; Acetate emulsion; Vinyl acetate between to for plastic-maleic acid and verivate copolymer emulsion thereof; Vinyl acetate between to for plastic-propenoate and verivate copolymer emulsion thereof; Propenoate and derivative emulsion thereof; The vinyl acetate-styrene copolymer emulsion; Water-soluble poly N-vinyl pyrrolidone; Keto-aldehyde modified soluble acrylate resin; , waterborne organic silicon oil, water-based fluoroalkyl (like fluorine carbon, fluorine silicon etc.), aqueous silicate etc. can be water-soluble resin glue in one or more;
Environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that; Described (C) environment-friendly water-soluble solubility promoter; Be selected from the used alcohol of water-soluble paint and/or printing-ink technical field, ether, ester, ketone, the water equal solvent one or more; Like contract in four Ucar 35 and ether, glycerine and monoether thereof, USP Kosher mono fatty acid ester, butyleneglycol and ether thereof, polyether Glycols, polyether-tribasic alcohol, polyethers tetravalent alcohol, polyethers pentavalent alcohol, polyoxyethylene glycol, W 166, polymer polyatomic alcohol, polyester polyol, ETHYLE ACETATE, acetone, pimelinketone, the water-soluble silicon wet goods one or more of ethanol, n-propyl alcohol, Virahol, the trimethyl carbinol, butanols, terepthaloyl moietie and ether thereof, NSC 6366 and ether thereof, Diethylene Glycol and ether thereof, triethylene glycol and ether thereof, Tetraglycol 99 and ether thereof, DPG and ether thereof, tripropylene glycol and ether thereof, three, these solvents can use separately or multiple being used.
Environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that; Described (D) environment-friendly water-soluble plate engraving ink is with film coalescence aid and/or neutralizing agent, is selected from used all film coalescence aid of water-soluble paint and/or printing-ink technical field and/or in the neutralizing agent one or more.
Environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that; Described (D) environment-friendly water-soluble plate engraving ink is used film coalescence aid, is selected from the film coalescence aid such as metal-salt (as: cobalt of unsaturated organic acid such as naphthenic acid, sad, capric acid, manganese, cerium, vanadium, lanthanum, iron, lithium, lead, zirconium, aluminium, calcium, zinc salt, manganese borate etc.) and/or ammonia/zirconium complex of organic acid and/or nitric acid one or more.
Environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that; Described (D) environment-friendly water-soluble plate engraving ink is used neutralizing agent, is selected from mineral alkali (like sodium hydroxide, Pottasium Hydroxide, Lithium Hydroxide MonoHydrate etc.) and/or inorganic ammonium salt (like bicarbonate of ammonia etc.) and/or is heated the organic amine (like urotropine, urea etc.) that is prone to emit ammonia and/or in inorganic ammonia (like liquefied ammonia, ammoniacal liquor etc.) and/or organic amine (like diethylamine, triethylamine etc.) and/or the thanomin (like Monoethanolamine MEA BASF, diethylolamine, trolamine etc.) etc. one or more.
Environment-friendly water-soluble plate engraving ink of the present invention is characterized in that, the drying mode of this printing ink is one or both or the two or more mixed type in oxypolymerization drying and/or volatile dry and/or infiltration drying and/or the ultraviolet curing.
Environment-friendly water-soluble plate engraving ink of the present invention is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the seasoning time was not more than 16 hours; Drying mode is that volatile dry and/or infiltration are dry, and when printing press was not installed drying plant, printing time of drying was less than 4 hours; Drying mode is that volatile dry and/or infiltration are dry, when printing press is equipped with drying plant, but the moment completion of printing drying; When drying mode is UV curing drying, but the moment completion of printing drying.
Specify
Describe in the face of environment-friendly water-soluble plate engraving ink of the present invention down.
Preparing above-mentioned environment-friendly water-soluble plate engraving ink can adopt three conventional roller ink grinding mills to accomplish.
As the concrete example of water soluble oils in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent, can enumerate the oil and the unsaturated carboxylic acid that have conjugated double bond or isolated double bond in the molecule and carry out the oil that addition reaction obtains; Has the oil of unsaturated double-bond and the oil that unsaturated carboxylic acid reacts acquisition.The above-mentioned oil with conjugated double bond or isolated double bond or unsaturated double-bond is selected from vegetables oil such as tung oil, synourin oil, oleum lini, soya-bean oil, eleostearic acid, dehydrated castor oleic acid, linolenic acid, behenic acid and the acid thereof one or more.Above-mentioned unsaturated carboxylic acid is selected from the unsaturated carboxylic acids such as maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, methene butene dioic acid one or more.For example: water-soluble maleic anhydride modified tung oil, water-soluble maleic anhydride modified flax wet goods paint and/or all water soluble oils and/or the water-soluble modified oil of technical field of ink.These water soluble oilss and/or water-soluble modified oil can use separately or multiple water soluble resin is used, and can also and use with multiple water soluble resin.
As the concrete example of water-soluble modified vegetables oil and/or water soluble phenol resin modified vegetable oil in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent, can enumerate the phenolic resin modified oleum lini of water-soluble xylenol, water-soluble para-tertiary butyl phenol formaldehyde resin modification oleum lini, water-soluble rosin modified phenolic resins and cyclopentadiene modification flax wet goods water-soluble paint and/or all water-soluble modified vegetables oil of technical field of ink.These water-soluble modified vegetables oil can use separately or multiple water soluble resin is used, and can also and use with multiple water soluble resin.
Above-mentioned vegetables oil is selected from that oleum lini, tung oil, synourin oil, Viscotrol C, perilla oil, Chinese catalpa oil, OITICICA are oily, in the soya-bean oil, Oleum Helianthi, wine stone oil, vegetable oil acid, tower fatty acid oil etc. one or more.
As water-soluble modified plant oil modified used resin, be selected from water-soluble paints such as rosin and verivate thereof, vinylbenzene, divinyl, organic isocyanate, vinylformic acid and verivate thereof, epoxy resin, epoxy resin modification vegetables oil, maleic acid and acid anhydride thereof or FUMARIC ACID TECH GRADE modified vegetable oil, resol, rosin modified phenolic resin, aminoresin and/or technical field of ink all can with the chemical substance of vegetables oil and/or vegetable oil acid generation chemical reaction in one or more.
As the concrete example of water soluble phenol resin in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent, can enumerate water-soluble paint and/or all water soluble phenol resins of technical field of ink such as water-soluble xylenol resol, water-soluble para-tertiary butyl phenol formaldehyde resin.These water soluble phenol resins can use separately or multiple water soluble resin is used, and can also and use with multiple water soluble resin.
As the concrete example of water-soluble terpolycyantoamino-formaldehyde resin in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent, can enumerate the water-soluble low molecular weight terpolycyantoamino-formaldehyde resin.
Concrete example as water-soluble rosin modified resin in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent; Can enumerate rosin and unsaturated organic acid and carry out addition reaction generation multi-carboxy compound; With the alcohol moiety esterification, react the water soluble resin that obtains again through amine and/or alkanolamine and/or ammoniacal liquor etc.
As the concrete example of water-soluble epoxy ester and/or water-soluble epoxy resin and/or soluble epoxide vinyl resin in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent, can enumerate water-soluble diphenolic acid epoxy ester resin; Water soluble polyamide solidified glycerol epoxy resin; Water-soluble diphenolic acid epoxy resin through acroleic acid esterification; After vegetable oil acid and the epoxy resin esterification; Again with unsaturated organic acid reaction, water-soluble epoxy ester that paint such as the water-soluble epoxy ester that obtains through operations such as neutralization, dilutions and/or technical field of ink are all and/or in water-soluble epoxy resin and/or the soluble epoxide vinyl resin one or more.These water-soluble epoxy esters and/or water-soluble epoxy resin and/or soluble epoxide vinyl resin can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
Above-mentioned vegetable oil acid, be selected from paint such as linolenic acid, eleostearic acid, dehydrated castor oleic acid, ricinolic acid, perillaseed oleic acid, Chinese catalpa oleic acid, OITICICA oleic acid, behenic acid, Semen Helianthi oleic acid, Semen Vitis viniferae oleic acid, tower fatty acid oil and/or technical field of ink all can with the vegetable oil acid of epoxy resin generation chemical reaction in one or more.
Above-mentioned unsaturated organic acid, be selected from paint such as maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, methene butene dioic acid and/or technical field of ink all can with the unsaturated organic acid of the biochemical reaction of water-soluble epoxy ester fry dried food ingredients in one or more.
Above-mentioned epoxy resin, be selected from paint such as diphenylol propane based epoxy resin and/or aliphatic category epoxy resin and/or heterocyclic epoxy resin (like A-95, B-63, E-03, E-06, E-12, E-14, E-20, E-31, E-35, E-42, E-44, E-51, F-44, F-46, ET-40, EG-02 etc.) and/or technical field of ink all can with the epoxy resin of organic acid generation chemical reactions such as vegetable oil acid and/or vinylformic acid in one or more.
As water soluble alkyd resin and/or water soluble modified alkyd resin in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent and/or contain the water soluble alkyd resin of radical and/or the concrete example of polybutadiene (as polyvalent alcohol or polyprotonic acid) modified alkyd resin, can enumerate Beijing Wan Yang anti-counterfeiting technology Ltd product: water soluble alkyd resin and/or the water soluble modified alkyd resin that paint such as WY-2802 water soluble modified alkyd resin tackiness agent, WY-2801, WY-2803, WY-2805 modified alkyd resin tackiness agent and/or technical field of ink are all and/or contain the water soluble alkyd resin of radical and/or in polybutadiene (as polyvalent alcohol or the polyprotonic acid) modified alkyd resin one or more.These water soluble alkyd resins and/or water soluble modified alkyd resin and/or the water soluble alkyd resin and/or polybutadiene (as polyvalent alcohol or the polyprotonic acid) modified alkyd resin that contain radical can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
Above-mentioned water soluble alkyd resin and/or water soluble modified alkyd resin and/or contain the properties-correcting agent of the water soluble alkyd resin of radical are selected from the used properties-correcting agent of all production water soluble modified alkyd resins of paint such as the acid of water soluble amino resin and/or water soluble phenol resin and/or water-soluble rosin modified phenolic resins and/or ketone resin and/or vegetables oil and/or vegetable oil acid and/or water-soluble acrylic and derivatives resin thereof and/or polybutadiene (as polyvalent alcohol or polyprotonic acid) and/or organic ternary and/or organic tetraprotic acid and/or technical field of ink one or more.
As the concrete example of Polyester Resin Water Soluble in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent, can enumerate in all Polyester Resin Water Solubles of paint such as the water-soluble unsaturated polyester resin stand linseed oil of Beijing ten thousand anti-counterfeiting technology Ltd product: WY-5001, WY-5002 unsaturated polyester resin tackiness agent, six hydroxyl methylated methylol melamine formaldehyde resin modified water-soluble unsaturated polyester resins and/or technical field of ink one or more.These Polyester Resin Water Solubles can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
The water-based dispersion resin that obtains as the water soluble salt of water soluble acrylate resin and/or ROHM and verivate thereof in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent and/or water-soluble self-crosslinking acrylic and/or water-soluble acrylic and derivatives resin thereof and/or single component ACRYLIC EMULSION and/or acrylate copolymer emulsion and/or acrylate copolymer emulsion or single component ACRYLIC EMULSION and with the compound water soluble resin for preparing of addition Gum Rosin and/or vinylbenzene and propenoate and/or N hydroxymethyl acrylamide and/or polynary monomer copolymerization such as vinylformic acid and verivate thereof or the concrete example of film-forming resin and/or keto-aldehyde modified soluble acrylate resin can be enumerated water soluble salt and/or water-soluble self-crosslinking acrylic and/or water-soluble acrylic and derivatives resin thereof and/or single component ACRYLIC EMULSION and/or acrylate copolymer emulsion and/or acrylate copolymer emulsion or the single component ACRYLIC EMULSION of all water soluble acrylate resins of paint such as WY-3100 water soluble acrylic resin that Beijing full printing ink of ten thousand penta own neoasozins ltd produces, WY-3100A water soluble acrylic resin, WY-3208A water soluble acrylic resin, WY-3200 water soluble acrylic resin, WY-3800 ACRYLIC EMULSION, WY-3808 ACRYLIC EMULSION, WY-3807 ACRYLIC EMULSION, WY-3899 ACRYLIC EMULSION and/or technical field of ink and/or ROHM and verivate thereof and the water-based dispersion resin that obtains with the compound water soluble resin for preparing of addition Gum Rosin and/or vinylbenzene and propenoate and/or N hydroxymethyl acrylamide and/or polynary monomer copolymerization such as vinylformic acid and verivate thereof thereof or in film-forming resin and/or the keto-aldehyde modified soluble acrylate resin one or more.These water-soluble acrylic resin and / or water-soluble polyacrylic acid salts and derivatives thereof and / or a water-soluble self-crosslinking acrylic acid and / or water-soluble resin, acrylic acid and derivatives thereof and / or a single component acrylic emulsions and / or acrylic copolymer emulsion and / or acrylic copolymer emulsion or a single component with the addition of rosin emulsion and acrylic resin composite obtained by preparing a water-soluble resin and / or styrene and acrylic acid ester and / or N-methylol acrylamide and / or acrylic acid and its derivatives obtained by copolymerizing monomers polyhydric resin or a film-forming resin, the aqueous dispersion and / or ketone-formaldehyde resin, acrylate-modified water-soluble in one or more of.That is to say, above-mentioned various acrylic resins and outside all water-soluble acrylic ester resinoid of all paint and/or technical field of ink in one or more.These resins can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
Concrete example as water soluble polyurethane resin in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent; Can enumerate vegetables oil (or vegetable oil acid) and carry out alcoholysis (or esterification) with polyvalent alcohol; Alcoholysate (or carboxylate) reacts with isocyanic ester; Add organic acid (like in maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, methene butene dioic acid, organic ternary acid, organic tetraprotic acid etc. one or more) etc. then, be prepared into water-soluble modified ammonia ester oil or water soluble polyurethane resin.On this basis, can also use other resin modification again (as in resol, aminoresin, the epoxy resin etc. a kind of).That is to say, above-mentioned various aqurous ployurethane resinoids and outside all aqurous ployurethane resinoid of all paint and/or technical field of ink in one or more.These aqurous ployurethane resinoids can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
Also can enumerate polyvalent alcohol and/or polyether glycol and isocyanic ester reacts; Add organic acid (like in maleic acid and acid anhydride thereof, FUMARIC ACID TECH GRADE, Ba Dousuan, methene butene dioic acid, organic ternary acid, organic tetraprotic acid etc. one or more) etc. then; Through operations such as neutralizations, be prepared into water soluble polyurethane resin.That is to say, above-mentioned various aqurous ployurethane resinoids and outside all aqurous ployurethane resinoid of all paint and/or technical field of ink in one or more.These aqurous ployurethane resinoids can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
Concrete example as water-soluble bituminous resins in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent; Can enumerate bituminous resins and vegetables oil and/or vegetable oil acid after the high temperature refining; With above-mentioned unsaturated organic acid addition, make water-soluble bituminous resins with salify in the carboxyl of the introducing warp.That is to say, above-mentioned various water-soluble bituminous resins and outside all water-soluble bituminous resins of all paint and/or technical field of ink in one or more.These water-soluble bituminous resinss can use separately or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
Water-soluble bituminous resins is mainly used in the tackiness agent of black ink in printing ink production, can effectively reduce the consumption of carbon black pigment, and does not reduce the blackness of printing ink.
As the concrete example of Z 150PH or vinyl alcohol derivatives base polymer and/or acetate emulsion and/or vinyl acetate between to for plastic-maleic acid and verivate copolymer emulsion and/or vinyl acetate between to for plastic-propenoate and verivate copolymer emulsion and/or propenoate and derivative emulsion and/or vinyl acetate-styrene copolymer emulsion in used (B) water-soluble polymers of environment-friendly water-soluble plate engraving ink and/or the polymer monomer tackiness agent, can enumerate all Z 150PH such as 2499,0588,1788,2488 or in vinyl alcohol derivatives base polymer and/or acetate emulsion and/or vinyl acetate between to for plastic-maleic acid and verivate copolymer emulsion and/or vinyl acetate between to for plastic-propenoate and verivate copolymer emulsion and/or propenoate and derivative emulsion and/or the vinyl acetate-styrene copolymer emulsion one or more of 1799,2099,2499 or SINOPEC Sichuan Vinylon Factory of Yunnan Yun Wei Group Plc.Above-mentioned these Z 150PH or vinyl alcohol derivatives base polymer or copolymer emulsion can use separately in plate engraving ink or be used with multiple water soluble resin, can also and use with multiple water soluble resin.
Concrete example as used (C) environment-friendly water-soluble solubility promoter of environment-friendly water-soluble plate engraving ink; Can enumerate in the used alcohol of water-soluble paint and/or printing-ink technical field, ether, ester, ketone, the water equal solvent one or more; Like ethanol, n-propyl alcohol, Virahol, the trimethyl carbinol, butanols, terepthaloyl moietie and ether thereof, NSC 6366 and ether thereof, Diethylene Glycol and ether thereof, triethylene glycol and ether thereof, Tetraglycol 99 and ether thereof, DPG and ether thereof, tripropylene glycol and ether thereof, three contract four Ucar 35 and ether, glycerine and monoether thereof, USP Kosher mono fatty acid ester, butyleneglycol and ether thereof, polyether Glycols, polyether-tribasic alcohol, polyethers tetravalent alcohol, polyethers pentavalent alcohol, polyoxyethylene glycol, W 166, polymer polyatomic alcohol, polyester polyol, ETHYLE ACETATE, acetone, pimelinketone, water-soluble silicon wet goods, these solvents can use separately or multiple being used.
As the concrete example of used (D) water-soluble plate engraving ink film coalescence aid of environment-friendly water-soluble plate engraving ink, one or more in the film coalescence aid such as the metal-salt of can give an example organic acid and/or nitric acid (as: cobalt of unsaturated organic acid such as naphthenic acid, sad, capric acid, manganese, cerium, vanadium, lanthanum, iron, lithium, lead, zirconium, aluminium, calcium, zinc salt, manganese borate etc.) and/or ammonia/zirconium complex.
As the concrete example of used (D) water-soluble plate engraving ink of environment-friendly water-soluble plate engraving ink with neutralizing agent, mineral alkali of can giving an example (like sodium hydroxide, Pottasium Hydroxide, Lithium Hydroxide MonoHydrate etc.) and/or inorganic ammonium salt (like bicarbonate of ammonia etc.) and/or be heated the organic amine (like urotropine, urea etc.) that is prone to emit ammonia and/or inorganic ammonia (like liquefied ammonia, ammoniacal liquor etc.) and/or and/or organic amine (like diethylamine, triethylamine etc.) and/or and/or thanomin (like Monoethanolamine MEA BASF, diethylolamine, trolamine etc.) etc. in one or more.In carrying out with above-mentioned neutralizing agent and the time, the consumption of neutralizing agent is confirmed with the measuring result of pH value.
For example, be described further as environment-friendly water-soluble plate engraving ink of the present invention, but the present invention does not receive the restriction of these concrete examples below.
Unit: gram
Annotate: 1,1# wipes version liquid (weight %): water 100%
2,2# wipes version liquid (weight %): sodium hydroxide 0.3%, water 99.7%
3, the patience check is by International Monetary Fund's standard test.
4, the grading of water cleaning performance and contamination-proof property ability: 5 grades-fine, 4 grades-good, 3 grades-good, 2 grades-general, 1 grade-poor.
5, printing patience assay is compared grading with former state: 5 grades-do not change, 4 grades-basic not variation, 3 grades-good, 2 grades-general, 1 grade-poor.
6, routine 1-example 5 plate engraving inks adopt three rollings China ink mechanism to do.Low-melting ink vehicle is WY-3100 water soluble acrylic resin, WY-3808 ACRYLIC EMULSION, WY-3809 ACRYLIC EMULSION, the water-soluble solubility promoter of WY-616, the WY-1201 blended wax that Beijing full printing ink of ten thousand penta own neoasozins ltd produces.
The application of environment-friendly water-soluble plate engraving ink of the present invention is characterized in that, this printing ink is applicable to various types of rolled papers and/or sheet-fed engraving plate printer; This printing ink also is applicable to carved gravure wiring printing press and/or common engraving plate printer.
The application of environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that; The version line degree of depth of the forme of engraving plate printer is between the 20-200 micron; Forme is carved by known engraving mode or is corroded with the mode that combines of engraving or by known caustic solution and obtains, and the forme temperature during printing is 50-80 ℃.
The application of environment-friendly water-soluble plate engraving ink of the present invention is characterized in that, when engraving plate printer was equipped with drying plant, bake out temperature (paper surface temperature) was at 50-180 ℃.
The application of environment-friendly water-soluble plate engraving ink of the present invention is characterized in that, in printing process, wipes version liquid and adopts clear water, and wiping the version liquid temp is 25-50 ℃.
Environment-friendly water-soluble plate engraving ink of the present invention is characterized in that, the average acid number 0-55mgKOH/g of this printing ink; The viscosity of printing ink is 3-15Pa.s/40 ℃.
Environment-friendly water-soluble plate engraving ink of the present invention; It is characterized in that, this printing ink is nonflammable, do not have smell, to the environment and the person do not have harm, be fit to the printing security secret document, to printings such as the strict food product pack of health conditions requiring, banknote, various certificate, equity certificates.
To sum up; Above-mentioned various chemical raw materials, compound, water soluble resin, water-soluble binder (but never being limited to these chemical raw materials, compound, water soluble resin, water-soluble binder) etc.; After the technical scheme combination by environment-friendly water-soluble plate engraving ink of the present invention; The plate engraving ink that obtains has nonpoisonous and tasteless; Nonflammable; Soluble in water; Wipe version liquid and adopt clear water; The contamination-proof property of printing ink is very good; Ink setting is rapid; Thick and not sticking; Both the pine and lack; The average acid number 0-55mgKOH/g of printing ink; The viscosity 3-15Pa.s/40 of this printing ink ℃; This printing ink is applicable to various types of rolled papers and/or sheet-fed engraving plate printer; Forme temperature during printing is 50-75 ℃; Printing ink can be filled in edition line, and the printing ink of non-figure line part is prone to wipe clean on the forme; Printing ink in the version line is prone to transfer on the paper; Solid content is high; Because this ink setting is rapid; Be particularly suitable for printing the safe and secret file (like banknote, Valued Securities, stamp, food product pack etc.) of dark version line, use the trace of the printed matter that this printing ink obtains or the ink film thickness that printing ink is stayed paper surface can satisfy properties such as people's required standard.Therefore; Technical scheme of the present invention be with above-mentioned various chemical raw materials, compound, water soluble resin, water-soluble binder and/or above-mentioned beyond various chemical raw materials, compound, water soluble resin, water-soluble binder etc. combine; After processing; The environment-friendly water-soluble plate engraving ink that obtains has above-mentioned property, all belongs to scope of the present invention.
Claims (25)
1. environment-friendly water-soluble plate engraving ink; It is characterized in that; This printing ink contains pigment and/or the dyestuff that (A) environment-friendly water-soluble plate engraving ink uses and accounts for the total 0-55% that forms of this printing ink; (B) the total 10-90% that forms of environment-friendly water-soluble polymkeric substance and/or this printing ink of polymer monomer binder constitutes; (C) the environment-friendly water-soluble solubility promoter accounts for the total 0.5-75% that forms of this printing ink; (D) environment-friendly water-soluble plate engraving ink accounts for the total 0.1-52% that forms of this printing ink with film coalescence aid and/or neutralizing agent
Wherein said (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water soluble oils; Water-soluble trimeric cyanamide and verivate formaldehyde resin thereof; Water-soluble epoxy ester; The soluble epoxide vinyl resin; Water-soluble poly oxyethane and verivate thereof; Polyester Resin Water Soluble; The water soluble acrylate resin; The water-soluble poly butadiene resin; Water-soluble bituminous resins; The water soluble salt of ROHM and verivate thereof; Water-soluble self-crosslinking acrylic; Water-soluble acrylic and derivatives resin thereof; The single component ACRYLIC EMULSION; Acrylate copolymer emulsion; Acrylate copolymer emulsion or single component ACRYLIC EMULSION and with the compound water soluble resin for preparing of addition Gum Rosin; Water-based dispersion resin and/or film-forming resin that the polynary monomer copolymerization of vinylbenzene and/or propenoate and/or N hydroxymethyl acrylamide and/or vinylformic acid and verivate thereof obtains; Z 150PH or vinyl alcohol derivatives base polymer; Acetate emulsion; Vinyl acetate between to for plastic-maleic acid and verivate copolymer emulsion thereof; Vinyl acetate between to for plastic-propenoate and verivate copolymer emulsion thereof; Propenoate and derivative emulsion thereof; The vinyl acetate-styrene copolymer emulsion; Water-soluble poly N-vinyl pyrrolidone; Keto-aldehyde modified soluble acrylate resin; Waterborne organic silicon oil, water-based fluoroalkyl, aqueous silicate can be water-soluble resin glue in one or more;
The average acid number 0-55mgKOH/g of said printing ink; The viscosity of printing ink is 3-15Pa.s/40 ℃.
2. environment-friendly water-soluble plate engraving ink according to claim 1; It is characterized in that; Described (A) environment-friendly water-soluble plate engraving ink is with pigment and/or dyestuff; Be selected from used pigment dyestuff of water-soluble paint and/or printing-ink technical field and/or dyestuff, mineral dye, the stopping composition one or more, these pigment and/or dyestuff can use separately or multiple being used.
3. environment-friendly water-soluble plate engraving ink according to claim 2; It is characterized in that; Described (A) environment-friendly water-soluble plate engraving ink is with pigment and/or dyestuff, is selected from Huang in pigment dyestuff and/or dyestuff, mineral dye, the stopping composition, red, tangerine, orchid, black, green, white, titanium oxide, silicon-dioxide, lime carbonate, kaolin, wilkinite, aluminium or silver powder, copper or bronze, high-visibility pigment and/or dyestuff.
4. environment-friendly water-soluble plate engraving ink according to claim 1 is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from water-soluble modified vegetables oil.
5. environment-friendly water-soluble plate engraving ink according to claim 1 is characterized in that, described (B) environment-friendly water-soluble polymkeric substance and/or polymer monomer tackiness agent are selected from the water soluble phenol resin modified vegetable oil.
6. environment-friendly water-soluble plate engraving ink according to claim 1 is characterized in that said water-based fluoroalkyl is fluorine carbon or fluorine silicon.
7. environment-friendly water-soluble plate engraving ink according to claim 1; It is characterized in that; Described (C) environment-friendly water-soluble solubility promoter; Be selected from the used alcohol of water-soluble paint and/or printing-ink technical field, ether, ester, ketone, the water solvent one or more, these solvents can use separately or multiple being used.
8. environment-friendly water-soluble plate engraving ink according to claim 7 is characterized in that described (C) environment-friendly water-soluble solubility promoter is selected from contract in four Ucar 35 and ether, glycerine and monoether thereof, USP Kosher mono fatty acid ester, butyleneglycol and ether thereof, polyether Glycols, polyether-tribasic alcohol, polyethers tetravalent alcohol, polyethers pentavalent alcohol, polyoxyethylene glycol, W 166, polymer polyatomic alcohol, polyester polyol, ETHYLE ACETATE, acetone, pimelinketone, the water-soluble silicon oil one or more of ethanol, n-propyl alcohol, Virahol, the trimethyl carbinol, butanols, terepthaloyl moietie and ether thereof, NSC 6366 and ether thereof, Diethylene Glycol and ether thereof, triethylene glycol and ether thereof, Tetraglycol 99 and ether thereof, DPG and ether thereof, tripropylene glycol and ether thereof, three.
9. environment-friendly water-soluble plate engraving ink according to claim 1; It is characterized in that; Described (D) environment-friendly water-soluble plate engraving ink is with film coalescence aid and/or neutralizing agent, is selected from used all film coalescence aid of water-soluble paint and/or printing-ink technical field and/or in the neutralizing agent one or more.
10. environment-friendly water-soluble plate engraving ink according to claim 9; It is characterized in that; Described (D) environment-friendly water-soluble plate engraving ink is used film coalescence aid, is selected from the metal-salt of organic acid and/or nitric acid and/or in ammonia/zirconium complex film coalescence aid one or more.
11. environment-friendly water-soluble plate engraving ink according to claim 10 is characterized in that described (D) environment-friendly water-soluble plate engraving ink is selected from cobalt, manganese, cerium, vanadium, lanthanum, iron, lithium, lead, zirconium, aluminium, calcium, zinc salt or the manganese borate of naphthenic acid, sad or capric acid with film coalescence aid.
12. environment-friendly water-soluble plate engraving ink according to claim 9; It is characterized in that; Described (D) environment-friendly water-soluble plate engraving ink is used neutralizing agent, is selected from mineral alkali and/or inorganic ammonium salt and/or is heated to be prone to emit the organic amine of ammonia and/or in inorganic ammonia and/or organic amine and/or the thanomin one or more.
13. environment-friendly water-soluble plate engraving ink according to claim 12 is characterized in that, said mineral alkali is sodium hydroxide, Pottasium Hydroxide or Lithium Hydroxide MonoHydrate.
14. environment-friendly water-soluble plate engraving ink according to claim 12 is characterized in that, said inorganic ammonium salt is a bicarbonate of ammonia.
15. environment-friendly water-soluble plate engraving ink according to claim 12 is characterized in that, the said organic amine that is prone to emit ammonia that is heated is urotropine or urea.
16. environment-friendly water-soluble plate engraving ink according to claim 12 is characterized in that, said inorganic ammonia is liquefied ammonia or ammoniacal liquor.
17. environment-friendly water-soluble plate engraving ink according to claim 12 is characterized in that, said organic amine is diethylamine or triethylamine.
18. environment-friendly water-soluble plate engraving ink according to claim 12 is characterized in that, said thanomin is Monoethanolamine MEA BASF, diethylolamine or trolamine.
19. environment-friendly water-soluble plate engraving ink according to claim 1; It is characterized in that the drying mode of this printing ink is one or both or the two or more mixed type in oxypolymerization drying and/or volatile dry and/or infiltration drying and/or the ultraviolet curing.
20. environment-friendly water-soluble plate engraving ink according to claim 1; It is characterized in that this printing ink is nonflammable, do not have smell, there are not harm in the environment and the person, are fit to the printing security secret document and/or to health conditions requiring strict food product pack and/or banknote and/or various certificate and/or equity certificate printing.
21. a printing process of using environment-friendly water-soluble plate engraving ink according to claim 19 is characterized in that when engraving plate printer was equipped with drying plant, bake out temperature was at 50-180 ℃.
22. the application of environment-friendly water-soluble plate engraving ink according to claim 19 is characterized in that, when the drying mode of this printing ink was the oxypolymerization drying, the seasoning time was not more than 16 hours; Drying mode is that volatile dry and/or infiltration are dry, and when printing press was not installed drying plant, printing time of drying was less than 4 hours; Drying mode is that volatile dry and/or infiltration are dry, when printing press is equipped with drying plant, but the moment completion of printing drying; When drying mode is UV curing drying, but the moment completion of printing drying.
23. the application of environment-friendly water-soluble plate engraving ink of the present invention according to claim 1 is characterized in that, this printing ink is applicable to various types of rolled papers and/or sheet-fed engraving plate printer; This printing ink also is applicable to carved gravure wiring printing press and/or common engraving plate printer.
24. printing process of using environment-friendly water-soluble plate engraving ink according to claim 1; It is characterized in that; The version line degree of depth of the forme of engraving plate printer is between the 20-200 micron; Forme is carved by known engraving mode or is corroded with the mode that combines of engraving or by known caustic solution and obtains, and the forme temperature during printing is 50-80 ℃.
25. a printing process of using environment-friendly water-soluble plate engraving ink according to claim 1 is characterized in that, in printing process, wipes version liquid and adopts clear water, wiping the version liquid temp is 25-50 ℃.
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