CN102952432A - Novel environment-friendly water-based rotary ink and preparation method thereof - Google Patents
Novel environment-friendly water-based rotary ink and preparation method thereof Download PDFInfo
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- CN102952432A CN102952432A CN201210481143XA CN201210481143A CN102952432A CN 102952432 A CN102952432 A CN 102952432A CN 201210481143X A CN201210481143X A CN 201210481143XA CN 201210481143 A CN201210481143 A CN 201210481143A CN 102952432 A CN102952432 A CN 102952432A
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Abstract
The invention belongs to the technical field of water-based ink, in particular to novel environment-friendly water-based rotary ink and a preparation method of the novel environment-friendly water-based rotary ink. The novel environment-friendly water-based rotary ink comprises the following raw materials in parts by weight: 35-45 parts of self-crosslinking water-based acrylic emulsion, 23-29 parts of modified water-based acrylic resin, 14-22 parts of pigment power, 0.1-1.0 part of defoamer, 3-7 parts of surfactant, 3-7 parts of pH (Potential of Hydrogen) stabilizer and 3-7 parts of water. The novel environment-friendly water-based rotary ink prepared by the invention is bright in color, and the linking materials adopted by the novel environment-friendly water-based rotary ink are water-based polymers which are non-toxic and are not harmful to the human body, so the novel environment-friendly water-based rotary ink is a novel green and environment-friendly product; and simultaneously, the water is adopted to replace the traditional petroleum solvent to be used as a diluent, so that the purpose of saving resources can be achieved, the market competitiveness is improved, and the application prospect is wide. The preparation method disclosed by the invention is simple in operation, can reduce the production cost, and is suitable for industrial production.
Description
Technical field
The invention belongs to the water color ink technical field, be specifically related to a kind of novel environment-friendly water-based rotary ink and preparation method thereof.
Background technology
Printing-ink is comprised of pigment, low-melting ink vehicle and auxiliary agent etc., is mainly used in the various printings such as books and periodicals, packing and decorating, building decoration, and along with social demand increases, printing ink kind and output is respective extension and growth also.The U.S. is in the world maximum printing ink producing country and country of consumption, and Japan takes second place, Germany the 3rd, and China occupies the 4th.Develop rapidly along with Chinese national economy, the prosperity of press-packaging industry has driven the manufacturing Fast Growth of printing ink, become one of world printing ink manufacturing big country so that China emerged rapidly between the nearest more than ten years, present domestic printing ink industry size just maintains sustained and rapid growth with the speed more than 10%.
Chinese invention patent ZL200510043020.8 disclose a kind of applicable to various mode of printings, have the black fluorescent ink of good antifalse effect, it mainly comprises 5 ~ 50% fluorescent material, 5 ~ 40% mineral black, 1 ~ 40% blue pigment, 10 ~ 60% binder, 0.1 ~ 40% stopping composition, 2 ~ 60% auxiliary agent; Wherein low-melting ink vehicle is one or more in resol, Synolac, rosin ester, poly-phthalein polyimide resin, modified aqueous acrylic acid resin and the acrylic acid derivative resin, auxiliary agent is that stand linseed oil, wax are removed one or more in stick, siccative, solvent, the tensio-active agent, and stopping composition is colloid calcium, calcium carbonate or aerosil.
Chinese invention patent ZL200910058122.5 discloses a kind of anti-counterfeit printing printing ink, purpose provides a kind of upper conversion printing ink that is applicable to gravure, the component that comprises following weight percent: on change powder 15 ~ 20%, Synolac oil 10 ~ 15%, high acid value resol oil 25 ~ 30%, pure phenolic resin oil 8 ~ 10%, light calcium carbonate 15 ~ 20%, tensio-active agent 5 ~ 7%, polyethylene wax 6 ~ 8%, Dormant oils 2 ~ 4%, siccative 0.3 ~ 0.5%.
The used solvent type ink of thermofixation offset lithography rotary press of in recent years China's introduction contains the petroleum solvent up to 35 ~ 42%, these solvents mainly are comprised of the aromatic hydrocarbons of alkane and 10 ~ 30%, can cause the hazardous solvent concentration in printing place to surpass the permission standard, printed matter surface hazardous solvent residual quantity also will exceed standard greatly; In addition, traditional solvent type ink mostly is the component resin such as phenolic aldehyde, alkyd as main low-melting ink vehicle, and this series products can discharge the obnoxious flavoures such as harmful phenol, formaldehyde in printing process.Solve the toxicity problem of printing ink, make printing ink meet environmental requirement, at first should change ink composition, namely adopt ep-type material preparation novel ink.
Summary of the invention
The object of the invention is to provides a kind of novel environment-friendly water-based rotary ink for deficiency of the prior art, and it is bright-colored, bright, and the low-melting ink vehicle of employing is waterborne polymeric, and is nontoxic, harmless, is a kind of novel Green Product.
Another object of the present invention is to provide a kind of preparation method of novel environment-friendly water-based rotary ink, preparation method of the present invention is simple to operate, has reduced production cost, is fit to suitability for industrialized production.
Purpose of the present invention is achieved through the following technical solutions: a kind of novel environment-friendly water-based rotary ink comprises the raw material of following weight part:
35 ~ 45 parts of self-crosslinking aqueous ACRYLIC EMULSION
23 ~ 29 parts of modified aqueous acrylic acid resins
14 ~ 22 parts in pigment powder
0.1 ~ 1.0 part of defoamer
3 ~ 7 parts in tensio-active agent
3 ~ 7 parts of pH stablizers
3 ~ 7 parts in water.
Self-crosslinking aqueous ACRYLIC EMULSION is BASF SC-1970, and translucent liquid, molecular weight are greater than 200000, and density is 1.04g/mL, and viscosity is 200cps, and the pH value is 8.5, and second-order transition temperature is 50 ℃.The self-crosslinking aqueous ACRYLIC EMULSION of SC-1970 is good at the sticking power of woodenware, paper, and rate of drying is fast; In addition, owing to introduce crosslinked group in the emulsion, so water tolerance, the scuff resistance of paint film after the resin film forming, hardness, resistance to blocking is all than more excellent.
The modified aqueous acrylic acid resin is BASF Joncryl 678, and white circular column solid, molecular weight are 8600, and viscosity is 3500, and softening temperature is 165 ℃, and second-order transition temperature is 85 ℃.Joncryl 678 modified aqueous acrylic acid resins have high-solid lower-viscosity, quick-drying, outstanding porosity and looseness ground fixation, and high gloss, foam is few, and transfer printing is outstanding, the good characteristics such as consistency.
Preferably, the described pigment powder diarylide yellow that is 16 ~ 20 weight parts.
Diarylide yellow is C.I. pigment Yellow 14 (P.Y.14), and available from German BASF, molecular formula is C
34H
30C
L2N
6O
4, molecular weight is 657.55, and fusing point is 320 ~ 336 ℃, and the yellow relative density of ruddiness is 1.14 ~ 1.52, and tap density is 9.5 ~ 12.6lb/gal, median size is 0.12 μ m, specific surface area/(m
2/ g): 35 ~ 53m
2/ g, the pH value is 5.0 ~ 7.5, oil number is 29 ~ 75g/100g, and is water insoluble, is slightly soluble in toluene; In the vitriol oil, be bright-coloured ruddiness orange, change dark green smooth yellow mercury oxide after the dilution into.
Another is preferred, and described pigment powder is the lithol red of 18 ~ 22 weight parts.
Lithol red is C.I. pigment red 4 9:2(P.R.49:2), available from Switzerland's Clariant, molecular formula is C
40H
26N
4O
8S
21/2Ca, molecular weight are 774.90, the red relative density 1.38 ~ 1.96 of gorgeous blue light, and tap density is 11.5 ~ 16.3lb/gal, and median size is 0.19 μ m, and specific surface area is 21 ~ 45m
2/ g, the pH value is 8.0, oil number is 44 ~ 61g/100g, is slightly soluble in ethanol, acetone and the hot water; In the vitriol oil, be the ruddiness purple, change the ruddiness brown precipitate after the dilution into; The chance concentrated nitric acid is brown-red solution; Be slightly soluble in the aqueous sodium hydroxide solution, add hydrochloric acid in the alcoholic solution and become brown purple.
Another is preferred, and described pigment powder is the phthalocyanine blue of 14 ~ 18 weight parts.
Phthalocyanine blue is the C.I. pigment Blue 15: 3(P.B.15:3), available from Britain Niu Bilai, molecular formula is C
32H
16CuN
8, molecular weight is 576.07, and fusing point is 480 ℃, and BG light cyan density is 1.59g/cm
3, tap density is 12.4 ~ 14.1lb/gal, and median size is 123 μ m, and specific surface area is 33 ~ 63m
2/ g, the pH value is 5.5 ~ 8.5, oil number is 34 ~ 85g/100g, water insoluble, ethanol and varsol; In the vitriol oil, be olive colour solution, be blue precipitation after the dilution.
Another is preferred, and described pigment powder is the carbon black of 15 ~ 19 weight parts.
Carbon black is Cabot carbon black M470, and the DBP oil-absorption(number) is 114mL/100g, and specific surface area is 91m
2/ g, density is 360g/L, and ash is 115, and fugitive constituent is 1%.Cabot carbon black M470 has easy dispersion, stronger tinting strength, the characteristics such as purer.
Preferably, described defoamer is silicone antifoam agent.
Silicone antifoam agent is DOW CORNING DC65, is used for the froth breaking of printing ink and paint, improves levelling property and the wettability of printing ink, coating and paint, improves wear resistance and the smoothness of paint.
Preferably, described tensio-active agent comprises the nonionic organic surface active agent of 1.5 ~ 2.5 weight parts and the anion surfactant of 2.5 ~ 3.5 weight parts.
The nonionic organic surface active agent is the high Wet500 of enlightening, and transparent liquid, refractive index are 1.440 ~ 1.450, and density is 0.94 ~ 0.98g/mL, water content≤0.15%.
Anion surfactant is Troysol LAC, light yellow liquid, and water soluble, solid content are 48 ~ 52%, and density is 1.040 ~ 1.070g/mL, and the pH value is 5 ~ 8.
Preferably, described pH stablizer is 2-amino-2 methyl isophthalic acids-propyl alcohol.
2-amino-2 methyl isophthalic acids-propyl alcohol is DOW Chemical AMP-95, white crystals piece or colourless liquid, and molecular formula is C
4H
11NO, molecular weight are 89.14, can be miscible with water, can be dissolved in alcohol.2-amino-2 methyl isophthalic acids-propyl alcohol is mainly used to the pH value of regulation and control water-based inks, and it is stabilized within 8.0 ~ 9.5 scopes, and simultaneously, it can also regulate the viscosity of water-based inks, and printing ink is diluted.
A kind of preparation method of novel environment-friendly water-based rotary ink comprises the steps:
A, the self-crosslinking aqueous ACRYLIC EMULSION of above-mentioned weight part, modified aqueous acrylic acid resin are added stirring and evenly mixing in the pill tank, churning time is 25 ~ 35min; B, the material of mixing among the step a added pigment powder and the defoamer of above-mentioned weight part under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 25 ~ 35min; C, the material of mixing among the step b is ground to fineness below 10 microns with sand mill under 35 ~ 45 ℃ of temperature of constant temperature; D, the material after grinding among the step c added tensio-active agent, pH stablizer and the water of above-mentioned weight part under the state of stirring at low speed, the continuation stirring and evenly mixing, churning time is 25 ~ 35min; Make novel environment-friendly water-based rotary ink.
Preferably, also comprise that step e, the novel environment-friendly water-based rotary ink that will make test after the steps d, adopt and examine grace cup 4# and measure its viscosity, viscosity is 25 ~ 40sec/25 ℃, and tinting strength is 90 ~ 110% of standard, and the pH value is 8.5 ~ 9.0.
Method and the index of check also comprise: fineness≤10 μ M, and yield point value is 40 ~ 50 mm, and viscosity is 4.0 ~ 6.0/32 ℃, and gloss is 60 ~ 80%, color conformance with standard sample.
The present invention compared with prior art has following advantage:
The novel environment-friendly water-based rotary ink of the present invention's preparation is bright-colored, light, the low-melting ink vehicle that adopts is waterborne polymeric, nontoxic, harmless, it is a kind of novel Green Product, adopt simultaneously water to replace traditional petroleum solvent as thinner, played the purpose that economizes on resources, improved the market competitiveness, product discharges without obnoxious flavour in printing and use procedure, improved printing house workman's Working environment, all instruments and machine directly water clean, and have reduced use and convenient transportation to solvent, have reduced the danger in the transportation, save transportation cost, have a extensive future; Preparation method of the present invention is simple to operate, has reduced production cost, is fit to suitability for industrialized production.
Embodiment:
For the ease of those skilled in the art's understanding, the present invention is described in further detail below in conjunction with embodiment 1 ~ 6.
Embodiment 1
A kind of novel environment-friendly water-based rotary ink, comprise following raw material: self-crosslinking aqueous ACRYLIC EMULSION 35Kg, modified aqueous acrylic acid resin 23Kg, phthalocyanine blue 14Kg, silicone antifoam agent 0.1Kg, nonionic organic surface active agent 1.5Kg, anion surfactant 2.5Kg, 2-amino-2 methyl isophthalic acids-propyl alcohol 3Kg, water 3Kg.
A kind of preparation method of novel environment-friendly water-based rotary ink comprises the steps: self-crosslinking aqueous ACRYLIC EMULSION, the modified aqueous acrylic acid resin of above-mentioned weight are added stirring and evenly mixing in the pill tank, and churning time is 25min; The phthalocyanine blue and the silicone antifoam agent that the material of mixing are added above-mentioned weight under the state of stirring at low speed continue stirring and evenly mixing, and churning time is 25min; The material of mixing is ground to fineness below 10 microns with sand mill under 35 ℃ of temperature of constant temperature; Material after grinding is added amino-2 methyl isophthalic acid-third alcohol and waters of nonionic organic surface active agent, anion surfactant, 2-of above-mentioned weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 25min; Make novel environment-friendly water-based rotary ink; The novel environment-friendly water-based rotary ink that makes is tested, and assay is as shown in table 1.
Embodiment 2
A kind of novel environment-friendly water-based rotary ink, comprise following raw material: self-crosslinking aqueous ACRYLIC EMULSION 39Kg, modified aqueous acrylic acid resin 25.5Kg, lithol red 20Kg, silicone antifoam agent 0.5Kg, nonionic organic surface active agent 2Kg, anion surfactant 3Kg, 2-amino-2 methyl isophthalic acids-propyl alcohol 5Kg, water 5Kg.
A kind of preparation method of novel environment-friendly water-based rotary ink comprises the steps: self-crosslinking aqueous ACRYLIC EMULSION, the modified aqueous acrylic acid resin of above-mentioned weight are added stirring and evenly mixing in the pill tank, and churning time is 27min; The lithol red and the silicone antifoam agent that the material of mixing are added above-mentioned weight under the state of stirring at low speed continue stirring and evenly mixing, and churning time is 27min; The material of mixing is ground to fineness below 10 microns with sand mill under 37 ℃ of temperature of constant temperature; Material after grinding is added amino-2 methyl isophthalic acid-third alcohol and waters of nonionic organic surface active agent, anion surfactant, 2-of above-mentioned weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 27min; Make novel environment-friendly water-based rotary ink; The novel environment-friendly water-based rotary ink that makes is tested, and assay is as shown in table 1.
Embodiment 3
A kind of novel environment-friendly water-based rotary ink, comprise following raw material: self-crosslinking aqueous ACRYLIC EMULSION 40Kg, modified aqueous acrylic acid resin 27.5Kg, carbon black 17Kg, silicone antifoam agent 0.5Kg, nonionic organic surface active agent 2Kg, anion surfactant 3Kg, 2-amino-2 methyl isophthalic acids-propyl alcohol 5Kg, water 5Kg.
A kind of preparation method of novel environment-friendly water-based rotary ink comprises the steps: self-crosslinking aqueous ACRYLIC EMULSION, the modified aqueous acrylic acid resin of above-mentioned weight are added stirring and evenly mixing in the pill tank, and churning time is 29min; The carbon black and the silicone antifoam agent that the material of mixing are added above-mentioned weight under the state of stirring at low speed continue stirring and evenly mixing, and churning time is 29min; The material of mixing is ground to fineness below 10 microns with sand mill under 39 ℃ of temperature of constant temperature; Material after grinding is added amino-2 methyl isophthalic acid-third alcohol and waters of nonionic organic surface active agent, anion surfactant, 2-of above-mentioned weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 29min; Make novel environment-friendly water-based rotary ink; The novel environment-friendly water-based rotary ink that makes is tested, and assay is as shown in table 1.
Embodiment 4
A kind of novel environment-friendly water-based rotary ink, comprise following raw material: self-crosslinking aqueous ACRYLIC EMULSION 41Kg, modified aqueous acrylic acid resin 25.5Kg, diarylide yellow 18Kg, silicone antifoam agent 0.5Kg, nonionic organic surface active agent 2Kg, anion surfactant 3Kg, 2-amino-2 methyl isophthalic acids-propyl alcohol 5Kg, water 5Kg.
A kind of preparation method of novel environment-friendly water-based rotary ink comprises the steps: self-crosslinking aqueous ACRYLIC EMULSION, the modified aqueous acrylic acid resin of above-mentioned weight are added stirring and evenly mixing in the pill tank, and churning time is 31min; The diarylide yellow and the silicone antifoam agent that the material of mixing are added above-mentioned weight under the state of stirring at low speed continue stirring and evenly mixing, and churning time is 31min; The material of mixing is ground to fineness below 10 microns with sand mill under 41 ℃ of temperature of constant temperature; Material after grinding is added amino-2 methyl isophthalic acid-third alcohol and waters of nonionic organic surface active agent, anion surfactant, 2-of above-mentioned weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 31min; Make novel environment-friendly water-based rotary ink; The novel environment-friendly water-based rotary ink that makes is tested, and assay is as shown in table 1.
Embodiment 5
A kind of novel environment-friendly water-based rotary ink, comprise following raw material: self-crosslinking aqueous ACRYLIC EMULSION 41Kg, modified aqueous acrylic acid resin 27.5Kg, phthalocyanine blue 16Kg, silicone antifoam agent 0.5Kg, nonionic organic surface active agent 2Kg, anion surfactant 3Kg, 2-amino-2 methyl isophthalic acids-propyl alcohol 5Kg, water 5Kg.
A kind of preparation method of novel environment-friendly water-based rotary ink comprises the steps: self-crosslinking aqueous ACRYLIC EMULSION, the modified aqueous acrylic acid resin of above-mentioned weight are added stirring and evenly mixing in the pill tank, and churning time is 33min; The phthalocyanine blue and the silicone antifoam agent that the material of mixing are added above-mentioned weight under the state of stirring at low speed continue stirring and evenly mixing, and churning time is 33min; The material of mixing is ground to fineness below 10 microns with sand mill under 43 ℃ of temperature of constant temperature; Material after grinding is added amino-2 methyl isophthalic acid-third alcohol and waters of nonionic organic surface active agent, anion surfactant, 2-of above-mentioned weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 33min; Make novel environment-friendly water-based rotary ink; The novel environment-friendly water-based rotary ink that makes is tested, and assay is as shown in table 1.
Embodiment 6
A kind of novel environment-friendly water-based rotary ink, comprise following raw material: self-crosslinking aqueous ACRYLIC EMULSION 45Kg, modified aqueous acrylic acid resin 29Kg, lithol red 22Kg, silicone antifoam agent 1Kg, nonionic organic surface active agent 2.5Kg, anion surfactant 3.5Kg, 2-amino-2 methyl isophthalic acids-propyl alcohol 7Kg, water 7Kg.
A kind of preparation method of novel environment-friendly water-based rotary ink comprises the steps: self-crosslinking aqueous ACRYLIC EMULSION, the modified aqueous acrylic acid resin of above-mentioned weight are added stirring and evenly mixing in the pill tank, and churning time is 35min; The lithol red and the silicone antifoam agent that the material of mixing are added above-mentioned weight under the state of stirring at low speed continue stirring and evenly mixing, and churning time is 35min; The material of mixing is ground to fineness below 10 microns with sand mill under 45 ℃ of temperature of constant temperature; Material after grinding is added amino-2 methyl isophthalic acid-third alcohol and waters of nonionic organic surface active agent, anion surfactant, 2-of above-mentioned weight under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 35min; Make novel environment-friendly water-based rotary ink; The novel environment-friendly water-based rotary ink that makes is tested, and assay is as shown in table 1.
The assay of the novel environment-friendly water-based rotary ink that table 1 embodiment 1 ~ 6 makes
The method of inspection of the novel environment-friendly water-based rotary ink that embodiment 1 ~ 6 makes is: fineness adopts scraper plate fineness instrument to measure, yield point value adopts parallel-plate viscometer to measure, grace cup 4# is examined in the viscosity employing and rotational viscosimeter is measured, viscosity adopts the ink viscosity instrument to measure, gloss adopts the photoelectricity glossometer to measure, the pH value adopts the pH survey meter to measure, and the color employing is scraped the sample contrast and tested, and scrapes the sample contrast after tinting strength adopts and waters down and tests.
As can be seen from Table 1, the novel environment-friendly water-based rotary ink of the present invention's preparation is bright-colored, bright, performance has met or exceeded the indices of traditional solvent type ink, in printing and use procedure, discharge without obnoxious flavour, also surmounting solvent type ink aspect environmental protection and the security far away, find in process of production, the novel environment-friendly water-based rotary ink of the present invention's preparation is to prolonging one times than traditional printing ink the work-ing life of equipment and forme.Preparation method of the present invention is simple to operate, has reduced production cost, is fit to suitability for industrialized production.
Above-described embodiment is the better embodiment of the present invention, but embodiments of the present invention are not restricted to the described embodiments, and the equivalent variations of therefore doing according to the present patent application claim is included within protection scope of the present invention.
Claims (10)
1. novel environment-friendly water-based rotary ink is characterized in that: the raw material that comprises following weight part:
35 ~ 45 parts of self-crosslinking aqueous ACRYLIC EMULSION
23 ~ 29 parts of modified aqueous acrylic acid resins
14 ~ 22 parts in pigment powder
0.1 ~ 1.0 part of defoamer
3 ~ 7 parts in tensio-active agent
3 ~ 7 parts of pH stablizers
3 ~ 7 parts in water.
2. a kind of novel environment-friendly water-based rotary ink according to claim 1, it is characterized in that: described pigment powder is the diarylide yellow of 16 ~ 20 weight parts.
3. a kind of novel environment-friendly water-based rotary ink according to claim 1, it is characterized in that: described pigment powder is the lithol red of 18 ~ 22 weight parts.
4. a kind of novel environment-friendly water-based rotary ink according to claim 1, it is characterized in that: described pigment powder is the phthalocyanine blue of 14 ~ 18 weight parts.
5. a kind of novel environment-friendly water-based rotary ink according to claim 1, it is characterized in that: described pigment powder is the carbon black of 15 ~ 19 weight parts.
6. a kind of novel environment-friendly water-based rotary ink according to claim 1, it is characterized in that: described defoamer is silicone antifoam agent.
7. a kind of novel environment-friendly water-based rotary ink according to claim 1, it is characterized in that: described tensio-active agent comprises the nonionic organic surface active agent of 1.5 ~ 2.5 weight parts and the anion surfactant of 2.5 ~ 3.5 weight parts.
8. a kind of novel environment-friendly water-based rotary ink according to claim 1, it is characterized in that: described pH stablizer is 2-amino-2 methyl isophthalic acids-propyl alcohol.
9. the preparation method of each described a kind of novel environment-friendly water-based rotary ink of claim 1 ~ 8 is characterized in that: comprise the steps:
A, the self-crosslinking aqueous ACRYLIC EMULSION of above-mentioned weight part, modified aqueous acrylic acid resin are added stirring and evenly mixing in the pill tank, churning time is 25 ~ 35min; B, the material of mixing among the step a added pigment powder and the defoamer of above-mentioned weight part under the state of stirring at low speed, continue stirring and evenly mixing, churning time is 25 ~ 35min; C, the material of mixing among the step b is ground to fineness below 10 microns with sand mill under 35 ~ 45 ℃ of temperature of constant temperature; D, the material after grinding among the step c added tensio-active agent, pH stablizer and the water of above-mentioned weight part under the state of stirring at low speed, the continuation stirring and evenly mixing, churning time is 25 ~ 35min; Make novel environment-friendly water-based rotary ink.
10. the preparation method of a kind of novel environment-friendly water-based rotary ink according to claim 9, it is characterized in that: also comprise that step e, the novel environment-friendly water-based rotary ink that will make test after the steps d, employing is examined grace cup 4# and is measured its viscosity, viscosity is 25 ~ 40sec/25 ℃, tinting strength is 90 ~ 110% of standard, and the pH value is 8.5 ~ 9.0.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672985A (en) * | 2015-02-11 | 2015-06-03 | 昆山大世界油墨涂料有限公司 | Ink for surface printing treatment of decorative material |
| CN108373651A (en) * | 2018-04-17 | 2018-08-07 | 中山创美涂料有限公司 | A kind of aqueous PE heat shrink films printing ink and preparation method thereof |
| CN109505174A (en) * | 2018-11-21 | 2019-03-22 | 唐山德方化学有限公司 | A kind of silk ink-jet cloth printing technique |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0974628A2 (en) * | 1998-05-29 | 2000-01-26 | SESTRIERE VERNICI S.r.l. | Universal water-dispersible pigmented pastes, zero V.O.C. |
| JP2001354887A (en) * | 2000-06-14 | 2001-12-25 | Daido Kasei Kogyo Kk | Disazo yellow pigment for offset ink |
| CN101613545A (en) * | 2009-08-12 | 2009-12-30 | 江阴市兰天彩印包装有限公司 | A kind of water color ink and making method that is used for intaglio printing |
| CN102649889A (en) * | 2012-04-18 | 2012-08-29 | 洛阳百林威油墨有限公司 | Flexographic pearlescent water-based ink special for cigarette mark and wine mark and preparation method thereof |
-
2012
- 2012-11-23 CN CN201210481143XA patent/CN102952432A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0974628A2 (en) * | 1998-05-29 | 2000-01-26 | SESTRIERE VERNICI S.r.l. | Universal water-dispersible pigmented pastes, zero V.O.C. |
| JP2001354887A (en) * | 2000-06-14 | 2001-12-25 | Daido Kasei Kogyo Kk | Disazo yellow pigment for offset ink |
| CN101613545A (en) * | 2009-08-12 | 2009-12-30 | 江阴市兰天彩印包装有限公司 | A kind of water color ink and making method that is used for intaglio printing |
| CN102649889A (en) * | 2012-04-18 | 2012-08-29 | 洛阳百林威油墨有限公司 | Flexographic pearlescent water-based ink special for cigarette mark and wine mark and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672985A (en) * | 2015-02-11 | 2015-06-03 | 昆山大世界油墨涂料有限公司 | Ink for surface printing treatment of decorative material |
| CN104672985B (en) * | 2015-02-11 | 2016-04-06 | 昆山大世界油墨涂料有限公司 | A kind of ink for decorative material surface printing treatment |
| CN108373651A (en) * | 2018-04-17 | 2018-08-07 | 中山创美涂料有限公司 | A kind of aqueous PE heat shrink films printing ink and preparation method thereof |
| CN109505174A (en) * | 2018-11-21 | 2019-03-22 | 唐山德方化学有限公司 | A kind of silk ink-jet cloth printing technique |
| CN109505174B (en) * | 2018-11-21 | 2021-12-14 | 唐山德方化学有限公司 | Ink-jet printing and dyeing process for silk |
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Application publication date: 20130306 |