CN102070957B - Water-soluble antibacterial ink and antibacterial floorboard manufactured by using same - Google Patents
Water-soluble antibacterial ink and antibacterial floorboard manufactured by using same Download PDFInfo
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- CN102070957B CN102070957B CN 201010615354 CN201010615354A CN102070957B CN 102070957 B CN102070957 B CN 102070957B CN 201010615354 CN201010615354 CN 201010615354 CN 201010615354 A CN201010615354 A CN 201010615354A CN 102070957 B CN102070957 B CN 102070957B
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Abstract
The invention belongs to the technical field of floorboards, and relates to water-soluble antibacterial ink and an antibacterial floorboard manufactured by using the same. The water-soluble antibacterial ink consists of the following components in part by weight: 24 to 35 parts of styrene-acrylate emulsion, 13 to 17 parts of the solution of AgNO3, 11 to 18 parts of Na2SO3 solid powder, 1 to 2 parts of varnish, 20 to 35 parts of deionized water, 121 to 5 parts of alcohol ester, 10 to 15 parts of ethylene-vinyl acetate (EVA) emulsion, 3 to 6 parts of poly ethylene (PE) waterborne wax, 1 to 3 parts of aqueous flatting agent, 1 to 3 parts of aqueous antifoaming agent, and 0.1 to 1 part of nonionic surfactant. The water-soluble antibacterial ink has a good antibacterial effect and long antibacterial duration. The antibacterial floorboard manufactured by using the water-soluble antibacterial ink comprises a surface wear-resistant layer, an antibacterial decoration layer, a substrate layer and a balance layer, wherein the antibacterial decoration layer is manufactured by printing the water-soluble anti-bacterial ink; the production of bacterium, fungi, dust mite and the like fall on the surface of the antibacterial floorboard is inhibited; and the floorboard has long-term health and long service life.
Description
Technical field
The invention belongs to technical field of floor, particularly a kind of water-soluble antibacterial ink and use the antibacterial floor of its preparation.
Background technology
Along with the day by day raising of people's living standard, the continuous reinforcement of health environment-friendly consciousness, people more and more pay attention to function and the class on floor.In the prior art, general floorings only has single ground decoration function, does not have antibiotic function, and bacterium, fungi, dirt mite etc. usually can grow in the floor.The dirt mite can be brought out asthma, and fungi can be brought out the diseases such as rhinitis, asthma acute pneumonia, climbs the victim that the child who plays is maximum and roll on the floor of being everlasting.Scientific statistics, on per 2 square centimeters clean floor, per 5 minutes will lower 2000 bacteriums of sedimentation, if do not carry out regular sterilization, bacterium, fungi, dirt mite etc. will grow the health of harmful to human in a large number.
Chinese utility model patent ZL200620133150.0 discloses a kind of antibacterial reinforced wood floor, and it is comprised of forming laminated sheet material, and the level that glueds joint that is superimposed with each other from top to bottom is: wearing layer, ornament layer, basic unit and balance layer.Wearing layer is the plane materiel of processing through the impreg that adds antibacterial mildew inhibitor.Because wearing layer through the antibacterial mildew inhibitor material processing, therefore, overlays when producing on the floor in the dipping production process, the surface on floor has formed antibacterial and antimildew function.This antibacterial reinforced wood floor will be arranged at the wearing layer on surface through the dip treating of antibacterial and mouldproof agent material, the antibacterial effect of antibacterial mildew inhibitor is poor, and the time length is short, after for some time, this antibacterial reinforced wood floor becomes the floor that only has single ground decoration function easily, and its antibacterial weakens or disappears.
Summary of the invention
The object of the invention is to provides a kind of water-soluble luminous printing ink, its good anti-bacterial effect, antibiotic longer duration for the deficiencies in the prior art.
Another object of the present invention is to provide a kind of antibacterial floor of using above-mentioned water-soluble antibacterial ink preparation, this antibacterial floor can make the breeding that falls within its surperficial bacterium, fungi, dirt mite etc. be suppressed, kill bacterium, fungi, the acarid in floor surface and slit, and then reach long-term health, purify the effect of living environment, safety and environmental protection, long service life.
The object of the present invention is achieved like this.
A kind of water-soluble antibacterial ink, it is comprised of the raw material of following mass parts:
24 parts～35 parts of benzene emulsions
AgNO
313 parts～17 parts of solution
Na
2SO
311 parts～18 parts of pressed powders
1 part～2 parts of stand linseed oil
20 parts～35 parts of deionized waters
Alcohol ester-12 1 part～5 parts
10 parts～15 parts of EVA emulsions
3 parts～6 parts in PE water-based wax
1 part～3 parts of water-based flow agents
1 part～3 parts of water-based defoamers
0.1 part～1 part of nonionogenic tenside,
AgNO
3Solution is silver nitrate solution namely, Na
2SO
3Pressed powder is the S-WAT pressed powder namely, the EVA emulsion be a milky non-plasticizing type acetic acid second rare-ethylene copolymerization emulsions.
Preferably, a kind of water-soluble antibacterial ink, it is comprised of the raw material of following mass parts:
24 parts～30 parts of benzene emulsions
AgNO
313 parts～17 parts of solution
Na
2SO
311 parts～18 parts of pressed powders
1 part～2 parts of stand linseed oil
20 parts～28 parts of deionized waters
Alcohol ester-12 1 part～5 parts
10 parts～15 parts of EVA emulsions
3 parts～6 parts in PE water-based wax
1 part～3 parts of water-based flow agents
1 part～3 parts of water-based defoamers
0.1 part～1 part of nonionogenic tenside.
Preferably, a kind of water-soluble antibacterial ink, it is comprised of the raw material of following mass parts:
30 parts～35 parts of benzene emulsions
AgNO
313 parts～17 parts of solution
Na
2SO
311 parts～18 parts of pressed powders
1 part～2 parts of stand linseed oil
20 parts～35 parts of deionized waters
Alcohol ester-12 1 part～5 parts
10 parts～15 parts of EVA emulsions
3 parts～6 parts in PE water-based wax
1 part～3 parts of water-based flow agents
1 part～3 parts of water-based defoamers
0.1 part～1 part of nonionogenic tenside.
A kind of preparation method of water-soluble antibacterial ink, it comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ room temperature conditions, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 1 hour ~ 2 hours, makes dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 1500 rev/mins ~ 2000 rev/mins stirrer container for stirring 1 hour ~ 2 hours, make the Nano silver solution that particle diameter is 5 ~ 50 nanometers;
(c) under 1 ℃ ~ 40 ℃ room temperature conditions, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble antibacterial ink.
Use the light emitting floor of this water-soluble antibacterial ink preparation, it from top to bottom comprises surface wear-resistant layer, antibiotic ornament layer, substrate layer and balance layer successively, and described antibiotic ornament layer is the antibiotic ornament layer that water-soluble antibacterial ink printing makes.
The light emitting floor of this water-soluble antibacterial ink preparation, it comprises following preparation process:
(a) get a transfer film, then printed decoration pattern on transfer film is printed in water-soluble antibacterial ink on the transfer film with gravure printing machine, forms antibiotic ornament layer, makes with antibiotic ornament layer transfer film;
(b) transfer film after step (a) is processed applies one deck adhesive layer with gravure printing machine or coating machine, then oven dry, and the temperature of oven dry is at 100 ℃ ~ 160 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) processing is needed on substrate layer, the below of substrate layer is provided with balance layer, makes just finished product of antibacterial floor;
(d) step (c) is made antibacterial floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover the layer of surface wearing layer, make the antibacterial floor finished product.
Wherein, in the described step (b), adhesive layer is temperature-sensitive or pressure-sensitive adhesive layer.
Wherein, in the described step (c), the transfer film finished product is needed on substrate layer by temperature-sensitive or pressure-sensitive mode.
Wherein, in the described step (c), substrate layer is the substrate layer of solid wood material or composite board material, and balance layer is made of balance paper.
Wherein, in the described step (d), surface wear-resistant layer is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
Beneficial effect of the present invention: a kind of water-soluble antibacterial ink of the present invention, it is comprised of the raw material of following mass parts: 24 parts～35 parts of benzene emulsions, AgNO
313 parts～17 parts of solution, Na
2SO
311 parts～18 parts of pressed powders, 1 part～2 parts of stand linseed oil, 20 parts～35 parts of deionized waters, alcohol ester-12 1 part～5 parts, 10 parts～15 parts of EVA emulsions, 3 parts～6 parts in PE water-based wax, 1 part～3 parts of water-based flow agents, 1 part～3 parts of water-based defoamers, 0.1 part～1 part of nonionogenic tenside.This its good anti-bacterial effect of water-soluble antibacterial ink, antibiotic longer duration.
A kind of preparation method of water-soluble antibacterial ink, it comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ room temperature conditions, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 1 hour ~ 2 hours, makes dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 1500 rev/mins ~ 2000 rev/mins stirrer container for stirring 1 hour ~ 2 hours, make the Nano silver solution that particle diameter is 5 ~ 50 nanometers;
(c) under 1 ℃ ~ 40 ℃ room temperature conditions, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble antibacterial ink.
The preparation method of this water-soluble antibacterial ink is simple to operate, and production cost is low, is fit to suitability for industrialized production.
Use the light emitting floor of this water-soluble antibacterial ink preparation, it from top to bottom comprises surface wear-resistant layer, antibiotic ornament layer, substrate layer and balance layer successively, and described antibiotic ornament layer is the antibiotic ornament layer that water-soluble antibacterial ink printing makes.
The antibacterial floor of this water-soluble antibacterial ink preparation, the breeding that falls within its surperficial bacterium, fungi, dirt mite etc. is suppressed, kills bacterium, fungi, the acarid in floor surface and slit, and then reach the effect of long-term health, purification living environment, safety and environmental protection, long service life.
Description of drawings
Fig. 1 is the structural representation of the antibacterial floor of a kind of water-soluble antibacterial ink preparation of the present invention.
Reference numeral:
1---surface wear-resistant layer 2---antibiotic ornament layer 3---substrate layer
4---balance layer.
Embodiment
The present invention is further illustrated with specific embodiment for the below, but the present invention is not subjected to the restriction of following embodiment.
Embodiment 1.
A kind of water-soluble antibacterial ink, it is comprised of the raw material of following mass parts: 25 parts of benzene emulsions, AgNO
315 parts of solution, Na
2SO
311 parts of pressed powders, 1 part of stand linseed oil, 21 parts of deionized waters, alcohol ester-12 5 part, 11 parts of EVA emulsions, 6 parts in PE water-based wax, 3 parts of water-based flow agents, 1 part of water-based defoamer, 1 part of nonionogenic tenside.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 1830 of U.S. Lauth OY; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral.
The preparation method of this water-soluble antibacterial ink, it comprises following preparation process:
(a) under 40 ℃ of room temperature conditions, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 0.5 hour, makes dispersion liquid with the stirrer of 800 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 1500 rev/mins stirrer container for stirring 0.5 hour, make the Nano silver solution that particle diameter is 5 nanometers;
(c) under 40 ℃ of room temperature conditions, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 0.5 hour with 800 rev/mins rotating speeds, make water-soluble antibacterial ink.
As shown in Figure 1, use the light emitting floor of this water-soluble antibacterial ink preparation, it from top to bottom comprises surface wear-resistant layer 1, antibiotic ornament layer 2, substrate layer 3 and balance layer 4 successively, the antibiotic ornament layer 2 that described antibiotic ornament layer 2 makes for water-soluble antibacterial ink printing.
Use the light emitting floor of this water-soluble antibacterial ink preparation, it comprises following preparation process:
(a) get a transfer film, printing figure decoration pattern on transfer film, then with gravure printing machine water-soluble antibacterial ink is printed the square reticulate pattern at the figure decoration pattern, like this, water-soluble antibacterial ink is printed on the transfer film, form antibiotic ornament layer 2, make the transfer film with antibiotic ornament layer 2;
(b) apply the pressure-sensitive adhesive layer of one deck with the transfer film of coating machine after step (a) is processed, adhesive layer is covered in antibiotic ornament layer 2, then oven dry, and the temperature of oven dry is at 100 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) processing is needed on substrate layer 3, the below of substrate layer 3 is provided with balance layer 4, makes just finished product of antibacterial floor; Substrate layer 3 is the substrate layer 3 of solid wood material, and balance layer 4 is made of balance paper;
(d) step (c) is made antibacterial floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover layer of surface wearing layer 1, make the antibacterial floor finished product.Surface wear-resistant layer 1 is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
Embodiment 2.
A kind of water-soluble antibacterial ink, it is comprised of the raw material of following mass parts: 24 parts of benzene emulsions, AgNO
317 parts of solution, Na
2SO
316 parts of pressed powders, 1 part of stand linseed oil, 25 parts of deionized waters, alcohol ester-12 1 part, 10 parts of EVA emulsions, 3 parts in PE water-based wax, 1 part of water-based flow agent, 1 part of water-based defoamer, 1 part of nonionogenic tenside.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 18300 of U.S. Lauth OY; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral.
The preparation method of this water-soluble antibacterial ink, it comprises following preparation process:
(a) under 40 ℃ of room temperature conditions, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 1 hour, makes dispersion liquid with the stirrer of 1000 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 1800 rev/mins stirrer container for stirring 1 hour, make the Nano silver solution that particle diameter is 20 nanometers;
(c) under 14 ℃ of room temperature conditions, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 1 hour with 1000 rev/mins rotating speeds, make water-soluble antibacterial ink.
As shown in Figure 1, use the light emitting floor of this water-soluble antibacterial ink preparation, it from top to bottom comprises surface wear-resistant layer 1, antibiotic ornament layer 2, substrate layer 3 and balance layer 4 successively, the antibiotic ornament layer 2 that described antibiotic ornament layer 2 makes for water-soluble antibacterial ink printing.
Use the light emitting floor of this water-soluble antibacterial ink preparation, it comprises following preparation process:
(a) get a transfer film, printing bamboo line decorative pattern on transfer film, then water-soluble antibacterial ink is covered on the bamboo line decorative pattern of justifying with gravure printing machine, like this, water-soluble antibacterial ink is printed on the transfer film, form antibiotic ornament layer 2, make the transfer film with antibiotic ornament layer 2;
(b) with the adhesive layer of the transfer film coating one deck temperature-sensitive of gravure printing machine after step (a) is processed, adhesive layer is covered in antibiotic ornament layer 2, then oven dry, and the temperature of oven dry is at 120 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) processing is needed on substrate layer 3, the below of substrate layer 3 is provided with balance layer 4, makes just finished product of antibacterial floor; Substrate layer 3 is the substrate layer 3 of composite board material, and balance layer 4 is made of balance paper;
(d) step (c) is made antibacterial floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover layer of surface wearing layer 1, make the antibacterial floor finished product.Surface wear-resistant layer 1 is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
Embodiment 3.
A kind of water-soluble antibacterial ink, it is comprised of the raw material of following mass parts: 33 parts of benzene emulsions, AgNO
314 parts of solution, Na
2SO
312 parts of pressed powders, 2 parts of stand linseed oil, 22 parts of deionized waters, alcohol ester-12 1 part, 10 parts of EVA emulsions, 3 parts in PE water-based wax, 1 part of water-based flow agent, 1 part of water-based defoamer, 1 part of nonionogenic tenside.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 18300 of U.S. Lauth OY; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral.
The preparation method of this water-soluble antibacterial ink, it comprises following preparation process:
(a) under 1 ℃ of room temperature condition, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 1 hour, makes dispersion liquid with the stirrer of 1200 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 2000 rev/mins stirrer container for stirring 1 hour, make the Nano silver solution that particle diameter is 50 nanometers;
(c) under 1 ℃ of room temperature condition, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 1 hour with 1200 rev/mins rotating speeds, make water-soluble antibacterial ink.
As shown in Figure 1, use the light emitting floor of this water-soluble antibacterial ink preparation, it from top to bottom comprises surface wear-resistant layer 1, antibiotic ornament layer 2, substrate layer 3 and balance layer 4 successively, the antibiotic ornament layer 2 that described antibiotic ornament layer 2 makes for water-soluble antibacterial ink printing.
Use the light emitting floor of this water-soluble antibacterial ink preparation, it comprises following preparation process:
(a) get a transfer film, printing marblized finish pattern on transfer film, then with gravure printing machine water-soluble antibacterial ink is printed the honeycombed reticulate pattern at the marblized finish pattern, like this, water-soluble antibacterial ink is printed on the transfer film, form antibiotic ornament layer, make the transfer film with antibiotic ornament layer 2;
(b) with the adhesive layer of the transfer film coating one deck temperature-sensitive of coating machine after step (a) is processed, adhesive layer is covered in antibiotic ornament layer 2, then oven dry, and the temperature of oven dry is at 140 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) processing is needed on substrate layer 3, the below of substrate layer 3 is provided with balance layer 4, makes just finished product of antibacterial floor; Substrate layer 3 is the substrate layer 3 of solid wood material, and balance layer 4 is made of balance paper;
(d) step (c) is made antibacterial floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover layer of surface wearing layer 1, make the antibacterial floor finished product.Surface wear-resistant layer 1 is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
Embodiment 4.
A kind of water-soluble antibacterial ink, it is comprised of the raw material of following mass parts: 24 parts of benzene emulsions, AgNO
313 parts of solution, Na
2SO
311 parts of pressed powders, 1 part of stand linseed oil, 30 parts of deionized waters, alcohol ester-12 4 part, 10 parts of EVA emulsions, 3 parts in PE water-based wax, 1 part of water-based flow agent, 2.9 parts of water-based defoamers, 0.1 part of nonionogenic tenside.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 18300 of U.S. Lauth OY; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral.
The preparation method of this water-soluble antibacterial ink, it comprises following preparation process:
(a) under 30 ℃ of room temperature conditions, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 2 hours, makes dispersion liquid with the stirrer of 800 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 1500 rev/mins stirrer container for stirring 2 hours, make the Nano silver solution that particle diameter is 35 nanometers;
(c) under 30 ℃ of room temperature conditions, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 2 hours with 800 rev/mins rotating speeds, make water-soluble antibacterial ink.
As shown in Figure 1, use the light emitting floor of this water-soluble antibacterial ink preparation, it from top to bottom comprises surface wear-resistant layer 1, antibiotic ornament layer 2, substrate layer 3 and balance layer 4 successively, the antibiotic ornament layer 2 that described antibiotic ornament layer 2 makes for water-soluble antibacterial ink printing.
Use the light emitting floor of this water-soluble antibacterial ink preparation, it comprises following preparation process:
(a) get a transfer film, printing marblized finish pattern on transfer film, then water-soluble antibacterial ink is covered on the marblized finish pattern of justifying with gravure printing machine, like this, water-soluble antibacterial ink is printed on the transfer film, form antibiotic ornament layer, make the transfer film with antibiotic ornament layer 2;
(b) apply one deck adhesive layer with the transfer film of gravure printing machine after step (a) is processed, then oven dry, the temperature of oven dry is at 160 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) processing is needed on substrate layer 3, the below of substrate layer 3 is provided with balance layer 4, makes just finished product of antibacterial floor; Substrate layer 3 is the substrate layer 3 of composite board material, and balance layer 4 is made of balance paper.The temperature of transfer printing is 100 ℃ ~ 190 ℃;
(d) step (c) is made antibacterial floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover layer of surface wearing layer 1, make the antibacterial floor finished product.Surface wear-resistant layer 1 is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
The above only is preferred embodiment of the present invention, so all equivalences of doing according to the described structure of patent claim of the present invention, feature and principle change or modify, is included in the patent claim of the present invention.
Claims (10)
1. water-soluble antibacterial ink, it is characterized in that: it is comprised of the raw material of following mass parts:
24 parts～35 parts of benzene emulsions
AgNO
313 parts～17 parts of solution
Na
2SO
311 parts～18 parts of pressed powders
1 part～2 parts of stand linseed oil
20 parts～35 parts of deionized waters
Alcohol ester-12 1 part～5 parts
10 parts～15 parts of EVA emulsions
3 parts～6 parts in PE water-based wax
1 part～3 parts of water-based flow agents
1 part～3 parts of water-based defoamers
0.1 part～1 part of nonionogenic tenside;
This water-soluble antibacterial ink comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ temperature condition, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 1 hour ~ 2 hours, makes dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 1500 rev/mins ~ 2000 rev/mins stirrer container for stirring 1 hour ~ 2 hours, make the Nano silver solution that particle diameter is 5 ~ 50 nanometers;
(c) under 1 ℃ ~ 40 ℃ temperature condition, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble antibacterial ink.
2. a kind of water-soluble antibacterial ink according to claim 1, it is characterized in that: it is comprised of the raw material of following mass parts:
24 parts～30 parts of benzene emulsions
AgNO
313 parts～17 parts of solution
Na
2SO
311 parts～18 parts of pressed powders
1 part～2 parts of stand linseed oil
20 parts～28 parts of deionized waters
Alcohol ester-12 1 part～5 parts
10 parts～15 parts of EVA emulsions
3 parts～6 parts in PE water-based wax
1 part～3 parts of water-based flow agents
1 part～3 parts of water-based defoamers
0.1 part～1 part of nonionogenic tenside.
3. a kind of water-soluble antibacterial ink according to claim 1, it is characterized in that: it is comprised of the raw material of following mass parts:
30 parts～35 parts of benzene emulsions
AgNO
313 parts～17 parts of solution
Na
2SO
311 parts～18 parts of pressed powders
1 part～2 parts of stand linseed oil
20 parts～35 parts of deionized waters
Alcohol ester-12 1 part～5 parts
10 parts～15 parts of EVA emulsions
3 parts～6 parts in PE water-based wax
1 part～3 parts of water-based flow agents
1 part～3 parts of water-based defoamers
0.1 part～1 part of nonionogenic tenside.
4. the preparation method of the described a kind of water-soluble antibacterial ink of claim 1 ~ 3 any one, it is characterized in that: it comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ temperature condition, in container, add benzene emulsion and EVA emulsion, then add AgNO
3Solution container for stirring 1 hour ~ 2 hours, makes dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) with Na
2SO
3Pressed powder adds in the dispersion liquid that step (a) makes, with rotating speed be 1500 rev/mins ~ 2000 rev/mins stirrer container for stirring 1 hour ~ 2 hours, make the Nano silver solution that particle diameter is 5 ~ 50 nanometers;
(c) under 1 ℃ ~ 40 ℃ temperature condition, the Nano silver solution that step (b) is made and deionized water, alcohol ester-12, PE water-based wax, stand linseed oil, water-based flow agent, water-based defoamer, nonionogenic tenside drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble antibacterial ink.
5. application rights requires the light emitting floor of 1 described a kind of water-soluble antibacterial ink preparation, it is characterized in that: it from top to bottom comprises surface wear-resistant layer, antibiotic ornament layer, substrate layer and balance layer successively, and described antibiotic ornament layer is the antibiotic ornament layer that water-soluble antibacterial ink printing makes.
6. the light emitting floor of a kind of water-soluble antibacterial ink preparation according to claim 5, it is characterized in that: it comprises following preparation process:
(a) get a transfer film, then printed decoration pattern on transfer film is printed in water-soluble antibacterial ink on the transfer film with gravure printing machine, forms antibiotic ornament layer, makes with antibiotic ornament layer transfer film;
(b) transfer film after step (a) is processed applies one deck adhesive layer with gravure printing machine or coating machine, then oven dry, and the temperature of oven dry is at 100 ℃ ~ 160 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) processing is needed on substrate layer, the below of substrate layer is provided with balance layer, makes just finished product of antibacterial floor;
(d) step (c) is made antibacterial floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover the layer of surface wearing layer, make the antibacterial floor finished product.
7. the light emitting floor of a kind of water-soluble antibacterial ink preparation according to claim 6, it is characterized in that: in the described step (b), adhesive layer is temperature-sensitive or pressure-sensitive adhesive layer.
8. the light emitting floor of a kind of water-soluble antibacterial ink preparation according to claim 6, it is characterized in that: in the described step (c), the transfer film finished product is needed on substrate layer by temperature-sensitive or pressure-sensitive mode.
9. the light emitting floor of a kind of water-soluble antibacterial ink preparation according to claim 6, it is characterized in that: in the described step (c), substrate layer is the substrate layer of solid wood material or composite board material, and balance layer is made of balance paper.
10. the light emitting floor of a kind of water-soluble antibacterial ink preparation according to claim 6, it is characterized in that: in the described step (d), surface wear-resistant layer is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
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| CN 201010615354 CN102070957B (en) | 2010-12-30 | 2010-12-30 | Water-soluble antibacterial ink and antibacterial floorboard manufactured by using same |
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| CN 201010615354 CN102070957B (en) | 2010-12-30 | 2010-12-30 | Water-soluble antibacterial ink and antibacterial floorboard manufactured by using same |
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| CN102070957B true CN102070957B (en) | 2013-02-13 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104177912A (en) * | 2014-08-07 | 2014-12-03 | 深圳市顾康力化工有限公司 | Mildew-proof antibacterial water-based ink and preparation method thereof |
| CN106318033A (en) * | 2016-08-29 | 2017-01-11 | 佛山市高明区尚润盈科技有限公司 | Method for preparing water-soluble antibacterial deodorizing ink |
| CN106221369A (en) * | 2016-08-29 | 2016-12-14 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of water solublity antibacterial ink |
| CN106084981A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of antibacterial and deodouring gravure water color ink and preparation method thereof |
| CN106084999A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of water solublity deodorization ink |
| CN106084982A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of water-based ink |
| CN106366757A (en) * | 2016-08-29 | 2017-02-01 | 佛山市高明区尚润盈科技有限公司 | Preparation method of water-soluble photochromic ink |
| CN106318025A (en) * | 2016-08-29 | 2017-01-11 | 佛山市高明区尚润盈科技有限公司 | Antibacterial gravure water-borne ink and preparing method thereof |
| CN106189494A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of water solublity antibiotic radiation proof ink |
| CN106084983A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of antibacterial and deodouring gravure water color ink and preparation method thereof |
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