CN106042520B - A kind of chromatic pattern metal floor for being used to decorate and preparation method - Google Patents

A kind of chromatic pattern metal floor for being used to decorate and preparation method Download PDF

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Publication number
CN106042520B
CN106042520B CN201610579629.5A CN201610579629A CN106042520B CN 106042520 B CN106042520 B CN 106042520B CN 201610579629 A CN201610579629 A CN 201610579629A CN 106042520 B CN106042520 B CN 106042520B
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layer
metal
floor
pattern
sensitive adhesive
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CN106042520A (en
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王麒钧
王麒宁
王海人
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/162Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/06Flooring or floor layers composed of a number of similar elements of metal, whether or not in combination with other material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)
  • Floor Finish (AREA)

Abstract

The present invention discloses a kind of chromatic pattern metal floor for being used to decorate and preparation method; the chromatic pattern metal floor is color metal decorative pattern " floor plaster " product for decoration, and floor is followed successively by diaphragm, wearing layer, printed decoration layer, metal substrate layer, Performance of Pressure Sensitive Adhesive layer and organosilicon protection sheet from top to bottom.Diaphragm is PVC protection glued membranes, and lower surface and the Performance of Pressure Sensitive Adhesive layer of metal substrate layer bond, and the lower surface of Performance of Pressure Sensitive Adhesive layer is organosilicon protection sheet.The wearing layer is application and Al of the heat cure on printed decoration layer2O3(Or SiO2)Wear-resistant protection coating, or high-temperature bearing merge the Al on printed decoration layer2O3Impregnate abrasion-proof paper protective layer.Gross thickness gross thickness is only 100~2000 μm after the floor attachment.With wear-and corrosion-resistant, damp-proof and moth-proof, be not afraid of it is moist, be not afraid of into water, will not deform, will not go mouldy, anti-microbial property it is good, the advantages that construction is simple is quick, and fire prevention is nontoxic, and cheap.

Description

A kind of chromatic pattern metal floor for being used to decorate and preparation method
Technical field
The present invention relates to a kind of chromatic pattern metal floor for being used to decorate and preparation method, belong to decorating and renovating material technology Field.
Background technology
20 end of the centurys so far, with the fast development of real estate industry of China, various floor China with fast development it Gesture is widely applied, and indoor floor is advantageous to sound-insulating and heat-insulating, improves finishing class and inhabitation office comfort level.City at present Mainly there are a wood floors and plastic floor in popular floor on face, wherein wood floors possess high class, environmentally friendly, wear-resisting, anti-corrosion, The advantages that mothproof, easy maintenance is arranged, weak point is:For a long time using moisture effect it is poor, immersion after it is yielding go bad, flameproof effect Difference, price are relatively expensive;Plastic floor advantage is wear-resisting, easy to clean, water proofing property is good, maintenance is easy, construction is easy and quick, valency Lattice are cheap, and it is convenient to be changed after abrasion, and its weak point is:Resistance to elevated temperatures is poor, and fire protecting performance is poor, there is hypertoxic volatilization after catching fire Thing, change of concurrently mildewing can be also damaged by being chronically in wet environment, and anti-microbial property is poor.
Utility model patent《A kind of Sound insulation flooringses》(CN201520540310) it is to include floor base material layer and compound its Its multilayer material, for the purpose of sound insulation, the metal film layer main function set above floor base material layer is isolation sound, and golden Sound absorbing layer and architectural surface are additionally provided with category film surface, the sound absorbing layer is the extremely soft foaming layer of poly- ammonia ", therefore the floor belongs to shelves Secondary higher plastic floor species;Utility model patent《Environment-friendly type abrasive floor pastes》(CN201520711570) include being attached at The metal foil layer provided with rollet of floor surface, the rollet is interior to be provided with fluorescent material and silica gel filler, pad pasting The bottom surface of layer is provided with gluing oxidant layer.From its structure, the metallic diaphragm positioned at top layer directly contacts with the external world, though groove is anti- It is sliding, but because metal film layer surface is not provided with any wear-resistant material layer, therefore the metallic diaphragm is easy to wear, another aspect metal film Though layer surface is machined with rollet, working as surface has accumulated water, or air pressure and indoor and outdoor temperature difference change cause air pair During stream, these rollet surfaces can adhere to water membrane, therefore prevent that wet and slippery effect is very limited, or even can mislead user and put It is loose vigilant;Utility model patent《Multifunctional floor film》(CN201520295928) floor film disclosed in, functional layer include: Nano silver copper zinc alloy layer, magnetic plastic layer, PVC foam material substrates.Weak point is:Nano silver copper zinc alloy layer for Its bacterium directly contacted has certain killing effect, but the bacterium on the bacterium corpse died to being covered in the first layer surface, just There is no any effect, ground surface is often rubbish and many place of bacterium, and the setting of the film layer can be with the metal floor Use, do not have any effect substantially, simply a conception of species;On the other hand, the basic unit is PVC foam materials, because The design on this floor is thicker.
In view of the above mentioned problem of existing floor material, it is necessary to design a kind of with good wear-resisting, anti-wet and slippery, anti-quarter Draw, anti-soil and fire protecting performance, good decorating effect and extremely cheap can substitute current wood ground in some beta sites A kind of high-grade floor decorative material of plate or plastic floor.
The content of the invention
The purpose of the present invention is the shortcomings of overcoming existing timber floor or plastic floor the problem of proposition for background technology, Design a kind of chromatic pattern metal floor for being used to decorate, and the method for making the chromatic pattern metal floor.
In order to achieve the above object, the present invention uses following scheme:
A kind of chromatic pattern metal floor for being used to decorate, is color metal decorative pattern " floor plaster " product for decoration, The metal floor is followed successively by five-layer structure from top to bottom, including:Diaphragm 1, the wearing layer 2 for setting thickness, set thickness Printed decoration layer 3, metal substrate layer 4, Performance of Pressure Sensitive Adhesive layer 5, organosilicon protection sheet 6;Wherein:Diaphragm 1 and organosilicon protection Paper 6 is temporary protective layer, and wearing layer 2, printed decoration layer 3, metal substrate layer 4 and Performance of Pressure Sensitive Adhesive layer 5 are basic training ergospheres; The diaphragm 1 is PVC protection glued membranes;The lower surface of the metal substrate layer 4 bonds with Performance of Pressure Sensitive Adhesive layer 5;It is described pressure-sensitive The lower surface of glue sticking layer 5 is organosilicon protection sheet 6;It is characterized in that:
The wearing layer 2 is application and Al of the heat cure on printed decoration layer 32O3, or SiO2Wear-resistant protection applies Layer, or high-temperature bearing merge the Al on printed decoration layer 32O3Impregnate abrasion-proof paper protective layer;
Preferably:When wearing layer 2 uses Al2O3When impregnating abrasion-proof paper protective layer, the PVC protection glued membranes set to be nonessential Put.
A kind of chromatic pattern metal floor for being used to decorate as described above, it is characterised in that:The thickness of the wearing layer 2 is 10~1000 μm.
A kind of chromatic pattern metal floor for being used to decorate as described above, it is characterised in that:Described printed decoration layer 3 Thickness is 10~1000 μm, and the pattern of printed decoration layer 3 includes:Wood-grain-imitating pattern, marble grain pattern, carpet line pattern, Granite pattern;Either printed out with foam ink in the upper surface of metal substrate layer 4 with anaglyph pattern.
A kind of chromatic pattern metal floor for being used to decorate as described above, it is characterised in that:The material of the metal substrate layer 4 Matter setting includes:Stainless steel or aluminium alloy, tin alloy, copper alloy;The thickness of the metal substrate layer 4 is set as 0.01~ 1.5mm;The upper surface of metal substrate layer 4 is:Minute surface or dull surface, sand face, mill line or patterned surface;The metal substrate layer 4 wraps Include:Metal foil, metallic plate or winding.
A kind of chromatic pattern metal floor for being used to decorate as described above, it is characterised in that:The Performance of Pressure Sensitive Adhesive layer 5 Thickness is 100~1000 μm.
A kind of chromatic pattern metal floor for being used to decorate as described above, it is characterised in that:The basic training ergosphere it is total Thickness is 100~2000 μm.
A kind of preparation method for the chromatic pattern metal floor for being used to decorate a kind of as described above, it is characterised in that:By such as Lower step is carried out:
Step 1:The hydroxylating and microporous of metal base upper surface
By the stainless steel or aluminium alloy or tin alloy or copper alloy foil (plate) or winding class that thickness is 0.01~1.5mm Metal base, degreases, cleans up, and is then placed on and is respectively containing chemical composition and concentration:
CrO3(5~250g/l) and H2SO4In the chemical oxidation solution of (5~490g/l), or
HNO3(5~250g/l) and H2O2In the chemical oxidation solution of (5~250g/l), or
In NaOH (1~100g/l) chemical solution, or (NH4)2Mo2O7And H2SO4The chemical oxygen of (5~250g/l) Change in solution, be chemically treated, form oh group and/or oxide-film in the metallic substrate surface and largely corrode micro- Hole;
Step 2:Printed decoration layer
By way of the continuous offset printing of drum-type, or trans-printing mode, in the metal base that step 1 is handled well Upper surface print one layer of decorative coating, or with foam ink print one layer have anaglyph decorations coating;Institute The pattern for stating decoration figure layer is arbitrarily set on demand;
Step 3:Coating surface wearing layer
One layer of abrasion-resistant clear coat strong with basal body binding force is coated with the printed decoration layer that step 2 is completed, applies thickness Degree is set as 10~1200 μm, and the component of the clear coat includes:High polymer material and inserts, the high polymer material are Piano lacquer or polyurethane or melamine or melamine resin;The inserts is a nanometer Al2O3Or Nano-meter SiO_22; Coating is heating and curing again, forms robust surface wear-resistant layer;
The wear resistant transparent paint either antiwear epoxy resin paint;
Step 4:Protection is handled
After completing printing wearing layer by step 3, the PVC glued membranes for pasting last layer protectiveness are rolled in wearing layer upper surface; Its advantage is:PVC glued membranes are advantageous to protect wearing layer upper surface in transport or sales process.
Step 5:The metal base back side sets adhesives
In the application of metal base lower surface (or stickup) last layer pressure sensitive adhesive;Its advantage is:Convenient construction, Inventive article is installed:, can be directly laying this color metal after the wipe clean of ground during color metal textured metal floor Textured metal floor, then rolled with roller, construction is simple and quick.In addition, the pressure sensitive adhesive is in use With walking about for personnel, adhesive effect can become better and better, and can so avoid the slip of metal floor.
Step 6:Back-protective processing
In the lower surface of step 5 bonding pressure sensitive adhesive, by rolling mode, one layer of organosilicon protection sheet is pressed.It is beneficial to effect Fruit is:Convenient construction:As long as this layer of paper, which is torn, to be bonded in ground surface metal floor of the present invention;There is this layer in addition Protection sheet is also convenient for sale, transport and the keeping of the metal floor product, prevents pressure sensitive adhesive to be arbitrarily adhered to elsewhere.
A kind of preparation method for the chromatic pattern metal floor for being used to decorate as described above, or enter as follows OK:
Step 1:The hydroxylating and microporous of metal base upper surface
By the stainless steel or aluminium alloy or tin alloy or copper alloy foil (plate) or winding class that thickness is 0.01~1.5mm Metal base, degreases, cleans up, and is then placed on and is respectively containing chemical composition and concentration:
CrO3(5~250g/l) and H2SO4In the chemical oxidation solution of (5~490g/l), or
HNO3(5~250g/l) and H2O2In the chemical oxidation solution of (5~250g/l), or
In NaOH (1~100g/l) chemical solution, or (NH4)2Mo2O7And H2SO4The chemical oxygen of (5~250g/l) Change in solution, be chemically treated, oh group and (or) oxide-film and a large amount of corrosion are formed in the metallic substrate surface Micropore;
Step 2:Printed decoration layer
By way of the continuous offset printing of drum-type, or trans-printing mode, in the metal base that step 1 is handled well Upper surface print one layer of decorative coating, or with foam ink print one layer have anaglyph decorations coating;Institute The pattern for stating decoration figure layer is arbitrarily set on demand;
Step 3:In printed decoration layer surface, Al is set2O3Impregnate abrasion-proof paper protective layer
On the printed decoration layer that step 2 is completed, by high-temperature bearing amalgamation mode, one layer of Al is merged2O3Impregnate wear-resisting Paper;Its advantage is:Strengthen ostentatious wear-resisting, the anti-delineation of colored printing, antifouling property.
Step 4:The metal base back side sets adhesives
In the application of metal base lower surface (or stickup) last layer pressure sensitive adhesive;Its advantage is:Convenient construction, Inventive article is installed:, can be directly laying this color metal after the wipe clean of ground during color metal textured metal floor Textured metal floor, then rolled with roller, construction is simple and quick.In addition, the pressure sensitive adhesive is in use With walking about for personnel, adhesive effect can become better and better, and can so avoid the slip of metal floor.
Step 5:Back-protective processing
In the lower surface of step 5 bonding pressure sensitive adhesive, by rolling mode, one layer of organosilicon protection sheet is pressed.It is beneficial to effect Fruit is:Convenient construction:As long as this layer of paper, which is torn, to be bonded in ground surface metal floor of the present invention;There is this layer in addition Protection sheet is also convenient for sale, transport and the keeping of the metal floor product, prevents pressure sensitive adhesive to be arbitrarily adhered to elsewhere.
The beneficial effects of the invention are as follows:
(1) a kind of chromatic pattern metal floor for being used to decorate of the invention has:Wear-resisting, anti-corrosion, protection against the tide, it is mothproof, be not afraid of tide It is wet, be not afraid of into water, will not deform, will not go mouldy, the features such as anti-microbial property is good.
(2) construction is simple is quick, and use is more, better with ground adhesive effect.
(3) prevent fires, be nontoxic, even if running into fire, will not burn, people's life security will not be endangered, there is timber floor and modeling The incomparable advantage of adhesive floor.
(4), than timber floor environmental protection, the forest reserves can be greatlyd save, there is the social effect being highly profitable.
(5) cheap, this metal chromatic pattern metal floor can use very thin metal base (such as available 304 thick 0.03mm stainless-steel roll bands) make, its cost price can be arrived per several yuans of square meter with low, and this price advantage can So that the color metal textured metal flooring products that are provided of the inventive method in megastore, public place of entertainment, beta site, face When the ground surface such as house decorative applications promoted rapidly.
Brief description of the drawings
Fig. 1 is a kind of chromatic pattern metal floor schematic diagram for being used to decorate of the embodiment of the present invention.
Description of symbols in accompanying drawing:1-diaphragm, 2-wearing layer, 3-printed decoration layer, 4-metal substrate layer, 5-pressure Quick glue sticking layer, 6-organosilicon protection sheet.
Embodiment
Below in conjunction with accompanying drawing, embodiments of the present invention is further illustrated, to make the purpose of the present invention, technical scheme and excellent Point is clearer, below technical scheme in the present invention be clearly and completely described, it is clear that described embodiment is this Invention part of the embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art exist The every other embodiment obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
Refer to the attached drawing 1, a kind of chromatic pattern metal floor for being used to decorate of the present invention include what is be sequentially distributed from top to bottom: Diaphragm 1, the wearing layer 2 for setting thickness, set the printed decoration layer 3 of thickness, metal substrate layer 4, Performance of Pressure Sensitive Adhesive layer 5, have Machine silicon protection sheet 6;Wherein:Diaphragm 1 and organosilicon protection sheet 6 are protective layers, wearing layer 2, printed decoration layer 3, metal base Layer 4 and Performance of Pressure Sensitive Adhesive layer 5 are basic training ergospheres;The diaphragm 1 is PVC glued membranes;The lower surface of the metal substrate layer 4 with Performance of Pressure Sensitive Adhesive layer 5 bonds;The lower surface of the Performance of Pressure Sensitive Adhesive layer 5 is organosilicon protection sheet 6;The wearing layer 2 is application And Al of the heat cure on printed decoration layer 32O3(or SiO2) wear-resistant protection coating, or high-temperature bearing fusion is in printing dress The Al adornd on layer 32O3Impregnate abrasion-proof paper protective layer.When wearing layer 2 uses Al2O3When impregnating abrasion-proof paper protective layer, the PVC is protected Shield glued membrane need not can be set.
The thickness of the wearing layer 2 is 10~1000 μm, and the thickness of described printed decoration layer 3 is 10~1000 μm, institute The thickness for stating metal substrate layer 4 is 0.01~1.5mm, and the thickness of the Performance of Pressure Sensitive Adhesive layer 5 is 100~1000 μm, the base The gross thickness of this functional layer is 100~2000 μm.
The pattern of printed decoration layer 3 includes:Wood-grain-imitating pattern, marble grain pattern, carpet line pattern, granite figure Case;Any pattern that either other patterns true to nature for imitating natural material or user like, can also be and existed with foam ink The upper surface of metal substrate layer 4 is printed out with anaglyph pattern.
The material setting of the metal substrate layer 4 includes:Stainless steel or aluminium alloy, tin alloy, copper alloy;Metal substrate layer 4 upper surface is:Minute surface or dull surface, sand face, mill line or patterned surface;The apparent shape of metal substrate layer 4 is metal foil (plate) Either coiled strip.
A kind of preparation method for the chromatic pattern metal floor for being used to decorate as described above, by different embodiments, says respectively It is bright as follows:
Embodiment one:
304 thick stainless-steel roll bands of 0.1mm are chosen as base material, pretreatment oil removing early stage and cleaning, drying.
Step 1:Substrate surface hydroxylating and microporous
The stainless steel substrate after above-mentioned processing is clean, it is placed on and is respectively containing chemical composition and concentration:CrO3 (50g/l) and H2SO4In the chemical oxidation solution of (100g/l), the chemical oxidation 10min in 85 DEG C of environment of temperature, it is above-mentioned not Steel material surface of becoming rusty forms oh group and porous oxide film, Nian Jie with printing layer thereon and its in order to greatly enhance base material The adhesion of layer material.
Step 2:Printed decoration layer
In the unilateral upper table that have passed through the stainless steel substrate that step 1 is handled well by way of the continuous offset printing of drum-type One layer of Wood-grain-imitating patterned layer is printed in face (front), is dried by the requirement of ink used.
Step 3:Coating surface wear-resistant protection coating
In order to strengthen ostentatious wear-resisting, the anti-delineation of above-mentioned colored printing, antifouling property, first in above-mentioned combination with decorative surfaces It is upper coating one layer of abrasion-resistant clear coat very strong with basal body binding force, the thickness of the coating is about 500 μm, the clear dope into Dividing includes:High polymer material melamine resin and inserts nano-scale alumina.Then, required according to coating, carry out thermosetting Change, form robust surface abrasion resistance protective layer.Above-mentioned wear resistant transparent paint makes method preparation method and coating, solidification Method is as follows:
(1) the preparation of melamine-formaldehyde resin adhesive, raw material and formula (mol ratios) setting:
Melamine: formaldehyde: polyvinyl alcohol: methanol=1: 3: 0.05: 6
First methanol and polyvinyl alcohol are added in reactor by setting mol amounts, 75 DEG C is warming up to, is incubated complete to polyvinyl alcohol Fully dissolved, the formaldehyde measured is then added, adjusting pH value with the sodium hydroxide solution that concentration is 30%, addition measures to 9.5 Melamine, under 89~91 DEG C of environment reaction to water, than number, (measurement of the general amine-formaldehyde resins reaction end of trimerization refers to Mark, GB/T14732-93) it is 1:Be terminal when 2.5, be cooled to 35 DEG C it is standby.
(2) by above-mentioned solid point:Melamine: Al2O3=1: 2 ratio, by way of ultrasonic disperse, by Al2O3 It is even to be dispersed in the melamine-formaldehyde resin adhesive solution of step (1), it is wear resistant transparent paint used in the present invention, the coating is A kind of suspension, the Extemporaneous only in application.
(3), by above-mentioned (2) ready wear resistant transparent paint, it is placed in a circulation stirring groove, by continuous roll coating model, The printed decoration layer surface of coatings to step 2.The container that this step contains coating is a circulation stirring groove, it is therefore an objective to In order to prevent Al2O3Precipitation.
(4) the stainless-steel roll band of coated wear resistant transparent paint is put into oven, temperature is to be carried out at 138~142 DEG C Dry solidification.
In order to both ensure the Al in above-mentioned wear-resistant paint2O3Particle does not deposit, and uniformly divides in suspension system again Dissipate, do not condense, the clear dope used in the present invention can use the viscosity that commercially available Tai Er (Dynea) chemical company develops Appropriateness, special melmac.
Step 4:Protection is handled
Metal base is pasted in the semi-finished product front surface roll-in after the processing of above-mentioned steps one, step 2 and step 3 Last layer PVC adhesive tapes protect glued membrane.
Step 5:Substrate backside sets adhesives
The semi-finished product that metal base have passed through after the processing of one~step 4 of above-mentioned steps are climbed over face, on other side surface One layer of commercially available pressure sensitive adhesive of (back side) application.
Step 6:Back-protective processing
After above-mentioned metal base have passed through above-mentioned steps one to step 5 processing, the one side of pressure sensitive adhesive is being provided with, then lead to The mode of rolling is crossed, presses one layer of organosilicon protection sheet.
After above-mentioned six steps, color metal textured metal floor of the present invention completes.
Embodiment two:
The thick aluminium alloy winding of 0.2mm is chosen as base material, preceding its gives processing oil removing, cleaning and dried.
Step 1:Substrate surface hydroxylating and microporous
The aluminum alloy base material after above-mentioned processing is clean, it is placed on and is respectively containing chemical composition and concentration:NaOH In the chemical solution of (30g/l), the chemical attack 1min under temperature 60 C environment, hydroxyl is formed in above-mentioned aluminum alloy material surface Group and porous membrane layer, in order to greatly enhance base material and printing layer thereon and the adhesion of its lower Nian Jie layer material.
Step 2:Printed decoration layer
One one side of the above-mentioned aluminum alloy base material by way of the continuous offset printing of drum-type after it have passed through step 1 processing One layer of Wood-grain-imitating patterned layer is printed on surface (front), then is dried by the requirement of ink used.
Step 3:Coating surface wear-resistant protection coating
In order to strengthen ostentatious wear-resisting, the anti-delineation of above-mentioned colored printing, antifouling property, first in above-mentioned combination with decorative surfaces One layer of abrasion-resistant clear coat very strong with basal body binding force of upper coating, the thickness of the coating is about 500 μm, the wear resistant transparent paint It is as follows for commercial polyurethane wear-resistant paint, the coating of the wear resistant transparent paint, curing:
(1) upper above-mentioned coating is placed in a circulation stirring groove, by continuous roll coating model, coatings to step Two printed decoration layer surface.
(2) the aluminium alloy winding of coated wear resistant transparent paint is in oven, according to consolidating for commercial polyurethane wear-resistant paint Change the time and solidification is dried in temperature requirement.
Step 4:Protection is handled
Last layer is pasted in the semi-finished product front surface roll-in that metal base have passed through after the processing of one~step 3 of above-mentioned steps PVC adhesive tape glued membranes.
Step 5:Substrate backside sets adhesives
The semi-finished product that metal base have passed through after the processing of one~step 4 of above-mentioned steps are turned over, in other side upper table One layer of commercially available pressure sensitive adhesive of face (back side) application.
Step 6:Back-protective processing
After above-mentioned metal base have passed through the processing of one~step 5 of above-mentioned steps, finally the one of pressure sensitive adhesive is being provided with Face, by way of rolling, press one layer of organosilicon protection sheet.
After above-mentioned six steps, color metal textured metal floor of the present invention completes.
Embodiment three:
304 thick stainless-steel roll bands of 0.1mm are chosen simultaneously to dry as base material, processing oil removing early stage, cleaning.
Step 1:Substrate surface hydroxylating and microporous
The aluminum alloy base material after above-mentioned processing is clean, it is placed on and is respectively containing chemical composition and concentration:CrO3 (50g/l) and H2SO4In the chemical oxidation solution of (100g/l), the chemical oxidation 10min at 85 DEG C of temperature, in above-mentioned stainless steel Material surface forms oh group and porous oxide film, in order to greatly enhance base material and printing layer thereon and its lower adhesive linkage material The adhesion of material.
Step 2:Printed decoration layer
It is unilateral in have passed through the above-mentioned stainless steel substrate that step (1) is handled well one by way of the continuous offset printing of drum-type One layer of Wood-grain-imitating patterned layer is printed on surface (front), is dried by the requirement of ink used.
Step 3:In printed decoration layer surface, Al is set2O3Wear-resistant protective layer
In order to strengthen ostentatious wear-resisting, the anti-delineation of above-mentioned colored printing, antifouling property, above-mentioned metal base is passing through After above-mentioned steps one and step 2, then commercially available reinforced composite floorboard Al2O3Dipping abrasion-proof paper is merged by high-temperature bearing Mode, on above-mentioned printed decoration layer merge one layer of wear-resisting, anti-delineation protective layer.
Al2O3Abrasion-proof paper wearing coat and the hot pressing plasticizing forming method of printed decoration layer:In accordance with Al2O3Impregnate abrasion-proof paper Requirement of the manufacturer to hot press pressure and temperature carries out plasticizing bonding forming.
Step 4:Substrate backside sets adhesives
The semi-finished product that metal base have passed through after the processing of one~step 3 of above-mentioned steps are turned over, on other side surface One layer of commercially available pressure sensitive adhesive of (back side) application.
Step 5:Back-protective processing
After the processing that above-mentioned metal base have passed through one~step 4 of above-mentioned steps, finally the one of pressure sensitive adhesive is being provided with Face, then by way of rolling, press one layer of organosilicon protection sheet.
After above-mentioned five steps, color metal textured metal floor of the present invention completes.
Example IV:
The thick aluminium alloy winding of 0.2mm is chosen as base material, pre-treatment oil removing, cleaning.
Step 1:Substrate surface hydroxylating and microporous
The aluminum alloy base material after above-mentioned processing is clean, it is placed on and is respectively containing chemical composition and concentration:NaOH In the chemical solution of (30g/l), the chemical oxidation 1min under temperature 50 C, oh group is formed in above-mentioned aluminum alloy material surface And porous membrane layer, in order to greatly enhance base material and printing layer thereon and the adhesion of its lower Nian Jie layer material.
Step 2:Printed decoration layer
One one side of the above-mentioned aluminum alloy base material by way of the continuous offset printing of drum-type after it have passed through step 1 processing One layer of Wood-grain-imitating patterned layer is printed in upper surface (front), is dried by the requirement of ink used.
Step 3:In printing layer surface, Al is set2O3Wear-resistant protective layer
In order to strengthen ostentatious wear-resisting, the anti-delineation of above-mentioned colored printing, antifouling property, above-mentioned metal base is passing through After above-mentioned steps one and step 2, then commercially available reinforced composite floorboard Al2O3Dipping abrasion-proof paper is merged by high-temperature bearing Mode, on above-mentioned printed decoration layer merge one layer of wear-resisting, anti-delineation protective layer.
Al2O3Abrasion-proof paper wearing coat and the hot pressing plasticizing forming method of printed decoration layer:In accordance with Al2O3Impregnate abrasion-proof paper Requirement of the manufacturer to hot press pressure and temperature carries out plasticizing bonding forming.
Step 4:Protection is handled
Last layer is pasted in the semi-finished product front surface roll-in that metal base have passed through after the processing of one~step 3 of above-mentioned steps PVC adhesive tape glued membranes.
Step 5:Substrate backside sets adhesives
Metal base have passed through the semi-finished product after 1~step 4 of above-mentioned steps is handled to turn over, on other side surface One layer of commercially available pressure sensitive adhesive of (back side) application.
Step 6:Back-protective processing
After the processing that above-mentioned metal base have passed through 1~step 5 of above-mentioned steps, finally the one of pressure sensitive adhesive is being provided with Face, then by way of rolling, press one layer of organosilicon protection sheet.
After above-mentioned six steps, color metal textured metal floor of the present invention completes.

Claims (4)

1. a kind of chromatic pattern metal floor for being used to decorate, it is the system of " floor plaster " with color metal decorative pattern for decoration Product, the metal floor are followed successively by five-layer structure from top to bottom, including:Diaphragm(1), setting thickness wearing layer(2), setting The printed decoration layer of thickness(3), metal substrate layer(4), Performance of Pressure Sensitive Adhesive layer(5), organosilicon protection sheet(6);Wherein:Diaphragm (1)With organosilicon protection sheet(6)It is protective layer, wearing layer(2), printed decoration layer(3), metal substrate layer(4)And pressure-sensitive adhesive Connect layer(5)It is basic training ergosphere;The diaphragm(1)It is PVC protection glued membranes;The metal substrate layer(4)Lower surface and pressure Quick glue sticking layer(5)Bonding;The Performance of Pressure Sensitive Adhesive layer(5)Lower surface be organosilicon protection sheet(6);It is characterized in that:
The wearing layer(2)It is application and heat cure in printed decoration layer(3)On Al2O3, or SiO2Wear-resistant protection applies Layer;The metal substrate layer(4)Material setting include:Stainless steel or aluminium alloy, tin alloy, copper alloy;Metal substrate layer(4) Upper surface be:Minute surface or dull surface, sand face, mill line or patterned surface;Metal substrate layer(4)Apparent shape include:Metal foil, Metallic plate or winding.
A kind of 2. chromatic pattern metal floor for being used to decorate as claimed in claim 1, it is characterised in that:The printed decoration layer (3)Pattern include:Wood-grain-imitating pattern, marble grain pattern, carpet line pattern, granite pattern;Either with foaming oil Ink is in metal substrate layer(4)Upper surface is printed out with anaglyph pattern.
A kind of 3. chromatic pattern metal floor for being used to decorate as claimed in claim 1, it is characterised in that:The basic training ergosphere Gross thickness be 100~2000 μm, wherein:Wearing layer(2)Thickness be 10~1000 μm, printed decoration layer(3)Thickness be 10~1000 μm, metal substrate layer(4)Thickness be 0.01~1.5mm;Performance of Pressure Sensitive Adhesive layer(5)Thickness be 100~1000 μ m。
A kind of 4. preparation method for the chromatic pattern metal floor for being used to decorate a kind of as claimed in claim 1, it is characterised in that: Carry out as follows:
Step 1:The hydroxylating and microporous of metal base upper surface
Stainless steel or aluminium alloy or tin alloy or copper alloy plate or winding metalloid base material by thickness for 0.01~1.5mm, Degrease, clean up, be then placed on and be respectively containing chemical composition and concentration:
CrO3, concentration is 5~250g/l, H2SO4Concentration be 5~490g/l chemical oxidation solution in, or
HNO3, concentration is 5~250g/l, H2O2Concentration be 5~250g/l chemical oxidation solution in, or
NaOH, concentration are 1~100g/l chemical solution or (NH4)2Mo2O7And H2SO4, concentration is 5~250g/l chemistry Aoxidize in solution, be chemically treated, oh group and/or oxide-film are formed in the metallic substrate surface, and it is a large amount of rotten Lose micropore;
Step 2:Printed decoration layer
By way of the continuous offset printing of drum-type, or trans-printing mode, in the upper of the metal base that step 1 is handled well One layer of decorative coating of surface printing, or print one layer of decorations coating with anaglyph with foam ink;The dress The pattern of decorations figure layer is arbitrarily set on demand;
Step 3:Coating surface wearing layer
One layer of abrasion-resistant clear coat strong with basal body binding force is coated with the printed decoration layer that step 2 is completed, coating layer thickness is set It is set to 10~1200 μm, the component of the clear coat includes:High polymer material and inserts, the high polymer material are pianos Paint or polyurethane or melamine or melamine resin;The inserts is a nanometer Al2O3Or Nano-meter SiO_22;It is right again Coating is heating and curing, and forms robust surface wear-resistant layer;
The wear resistant transparent paint either antiwear epoxy resin paint;
Step 4:Protection is handled
After completing printing wearing layer by step 3, the PVC glued membranes for pasting last layer protectiveness are rolled in wearing layer upper surface;
Step 5:The metal base back side sets adhesives
One layer of pressure sensitive adhesive is either pasted in the application of metal base lower surface;
Step 6:Back-protective processing
In the lower surface of step 5 bonding pressure sensitive adhesive, by rolling mode, one layer of organosilicon protection sheet is pressed.
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CN110344563B (en) * 2018-04-04 2021-09-14 无锡同力塑胶贸易有限公司 Method for producing series plastic plate products with diversified patterns
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CN109868971A (en) * 2019-03-12 2019-06-11 浙江晶通塑胶有限公司 A kind of magnesium oxide plate water-proof floor
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