CN102093778B - Water soluble luminous ink and luminous floor prepared by using same - Google Patents
Water soluble luminous ink and luminous floor prepared by using same Download PDFInfo
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- CN102093778B CN102093778B CN 201010616698 CN201010616698A CN102093778B CN 102093778 B CN102093778 B CN 102093778B CN 201010616698 CN201010616698 CN 201010616698 CN 201010616698 A CN201010616698 A CN 201010616698A CN 102093778 B CN102093778 B CN 102093778B
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Abstract
The invention belongs to the technical field of floors and relates to water soluble luminous ink and a luminous floor prepared by using the same. The water soluble luminous ink comprises the following raw materials in percentage by mass: 25 to 35 percent of acrylic emulsion, 15 to 19 nano luminous powder, 20 to 35 percent of deionized water, 1 to 5 percent of alcohol ester-12, 10 to 15 percent of ethylene vinyl acetate (EVA) emulsion, 3 to 6 percent of polyethylene (PE) aqueous wax, 1 to 3 percent of aqueous leveling agent, 0.1 to 1 percent of aqueous defoamer, and 1 to 2 percent of color fixing agent. The water soluble luminous ink can absorb and store light energy, has good luminous effect and can emit light constantly. The luminous floor prepared by the water soluble luminous ink comprises a luminous icon layer, a substrate layer and a balance layer in turn from top down, wherein the luminous icon layer is printed by the water soluble luminous ink, can automatically and constantly emit light in a dark environment for directing a user without electric energy, and is safe, environmentally-friendly and long in service life.
Description
Technical field
The invention belongs to technical field of floor, particularly a kind of water-soluble luminous printing ink and use the light emitting floor of its preparation.
Background technology
Along with the raising of people's life, people more and more pay attention to function and the class on floor.In the prior art, the floor only has single ground decoration function, and after turning off the light night, ground is very dark.When lamp switch was distant apart from the head of a bed, often needing feels about in the dark left the bed and looks for the switch of lamp everywhere, very inconvenient, especially for child, the elderly, has larger potential safety hazard; Therefore, the family that has in the corridor, wall installed night-light, not only increased spending, also consumes electric energy.The more important thing is that in the dark surrounds of outage, in case of emergency, the floor of prior art does not have the function of indication escaping.
Chinese utility model patent ZL03222739.6 discloses a kind of light-emitting composite flooring, it comprises the tack coat between ornament layer and the wearing layer, be provided with the luminous minitype particle of a plurality of energy in the tack coat between described ornament layer and wearing layer, described minitype particle is a kind of fluorescent material, is distributed in the described tack coat to the uniform particles of this fluorescent material; By the tack coat on the floor a plurality of light-emitting particles are set, after the floor was installed, after The night screen has hung down, a plurality of light-emitting particles that arrange in the tack coat were sustainable luminous.This utility model is distributed in fluorescent material in the tack coat, and the brightness of the light that sends of fluorescent material is fainter, and illumination effect is poor; And the time length is short, and after for some time, light-emitting composite flooring becomes the floor that only has single ground decoration function easily, and its lighting function weakens or disappears.
Summary of the invention
The object of the invention is to provides a kind of water-soluble luminous printing ink for the deficiencies in the prior art, and it can absorb and store luminous energy, and illumination effect is good, and lighting time interval is long.
Another object of the present invention is to provide a kind of light emitting floor of using above-mentioned water-soluble luminous printing ink preparation, it can be automatic in dark surrounds, lasting luminous, is user's direction indication, do not consume electric energy, safety and environmental protection, long service life.
The object of the present invention is achieved like this.
A kind of water-soluble luminous printing ink, it is comprised of the raw material of following mass percent:
Benzene emulsion 25% ~ 35%
Nano level luminescent powder 15% ~ 19%
Deionized water 20% ~ 35%
Alcohol ester-12 1% ~ 5%
EVA emulsion 10% ~ 15%
PE water-based wax 3% ~ 6%
Water-based flow agent 1% ~ 3%
Water-based defoamer 0.1% ~ 1%
Laking agent 1% ~ 2%,
The EVA emulsion be a milky non-plasticizing type acetic acid second rare-ethylene copolymerization emulsions.
Preferably, a kind of water-soluble luminous printing ink, it is comprised of the raw material of following mass percent:
Benzene emulsion 25% ~ 30%
Nano level luminescent powder 15% ~ 19%
Deionized water 20% ~ 30%
Alcohol ester-12 1% ~ 5%
EVA emulsion 10% ~ 15%
PE water-based wax 3% ~ 6%
Water-based flow agent 1% ~ 3%
Water-based defoamer 0.1% ~ 1%
Laking agent 1% ~ 2%.
Preferably, a kind of water-soluble luminous printing ink, it is comprised of the raw material of following mass percent:
Benzene emulsion 30% ~ 35%
Nano level luminescent powder 15% ~ 19%
Deionized water 30% ~ 35%
Alcohol ester-12 1% ~ 5%
EVA emulsion 10% ~ 15%
PE water-based wax 3% ~ 6%
Water-based flow agent 1% ~ 3%
Water-based defoamer 0.1% ~ 1%
Laking agent 1% ~ 2%.
Wherein, described nano level luminescent powder is nano level calcium halophosphate activated by antimony andmanganese luminescent powder.
A kind of preparation method of water-soluble luminous printing ink, it comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ room temperature conditions, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 1 hour ~ 2 hours, make dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) under 1 ℃ ~ 40 ℃ room temperature conditions, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble luminous printing ink.
A kind of light emitting floor of water-soluble luminous printing ink preparation, it from top to bottom comprises luminous icon layer, substrate layer and balance layer successively, described luminous icon layer is the luminous icon layer that water-soluble luminous printing ink printing makes.
Use the light emitting floor of this water-soluble luminous printing ink preparation, it comprises following preparation process:
(a) get a transfer film, use gravure printing machine, water-soluble luminous printing ink printing illuminated diagram is marked on the transfer film, make the transfer film with luminous icon layer;
(b) transfer film after step (a) is processed applies one deck adhesive layer with gravure printing machine or coating machine, then oven dry, and the temperature of oven dry is at 100 ℃ ~ 160 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) is processed is needed on substrate layer by temperature-sensitive or pressure-sensitive mode, and the below of substrate layer is provided with balance layer, makes light emitting floor.
Preferably, a kind of light emitting floor of water-soluble luminous printing ink preparation, it from top to bottom comprises surface protecting layer, ornament layer, luminous icon layer, substrate layer and balance layer successively, described luminous icon layer is the luminous icon layer that water-soluble luminous printing ink printing makes.
Preferably, use the light emitting floor of this water-soluble luminous printing ink preparation, it comprises following preparation process:
(a) get a transfer film, printed decoration pattern on transfer film makes the transfer film with ornament layer;
(b) use gravure printing machine, water-soluble luminous printing ink printing illuminated diagram is marked on the transfer film after step (a) is processed, make the transfer film with ornament layer and luminous icon layer;
(c) transfer film after step (b) is processed applies one deck adhesive layer with gravure printing machine or coating machine, then oven dry, and the temperature of oven dry is at 100 ℃ ~ 160 ℃, makes the transfer film finished product;
(d) the transfer film finished product after step (c) processing is needed on substrate layer by temperature-sensitive or pressure-sensitive mode, the below of substrate layer is provided with balance layer, makes just finished product of light emitting floor;
(e) step (d) is made light emitting floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover the layer of surface protective layer, make the light emitting floor finished product.
Wherein, in the described step (e), surface protecting layer is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
Beneficial effect of the present invention: a kind of water-soluble luminous printing ink of the present invention, it is comprised of the raw material of following mass percent: benzene emulsion 25% ~ 35%, nano level luminescent powder 15% ~ 19%, deionized water 20% ~ 35%, alcohol ester-12 1% ~ 5%, EVA emulsion 10% ~ 15%, PE water-based wax 3% ~ 6%, water-based flow agent 1% ~ 3%, water-based defoamer 0.1% ~ 1%, laking agent 1% ~ 2%.
This water-soluble luminous printing ink can absorb the light sources such as natural light, daylight light, UV-light and store luminous energy, saving resource and expense, and illumination effect is good, and lighting time interval reaches more than 10 hours or 10 hours.
A kind of preparation method of water-soluble luminous printing ink, it comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ room temperature conditions, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 1 hour ~ 2 hours, make dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) under 1 ℃ ~ 40 ℃ room temperature conditions, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble luminous printing ink.
The preparation method of this water-soluble luminous printing ink is simple to operate, and production cost is low, is fit to suitability for industrialized production.
A kind of light emitting floor of water-soluble luminous printing ink preparation, it from top to bottom comprises luminous icon layer, substrate layer and balance layer successively, described luminous icon layer is the luminous icon layer that water-soluble luminous printing ink printing makes.
The light emitting floor of this water-soluble luminous printing ink preparation can be automatic in dark surrounds, lasting luminous, is user's direction indication, do not consume electric energy, safety and environmental protection, long service life.It does not affect the original fineness in floor, and environmental protection, nontoxic is harmless, can realize that in the dark automatic luminous reached more than 10 hours after absorbing various visible lights, and nontoxic, harmless, no radioactivity pollute, and has good weathering resistance, long service life.In case of emergency, such as fire etc., the fluorescence that the present invention sends can make the people escape at leisure, plays the effect of trail guide.At night or the outage situation under, the fluorescence that the present invention sends can provide the light of certain brightness, the user can carry out certain activity; In addition, the fluorescence that the present invention sends provides a kind of soft light environment, gives the sentiment of a kind of romance of people.
Description of drawings
Fig. 1 is the structural representation of light emitting floor of a kind of water-soluble luminous printing ink preparation of embodiments of the invention 1.
Fig. 2 is the structural representation of light emitting floor of a kind of water-soluble luminous printing ink preparation of embodiments of the invention 2 ~ embodiment 4.
Reference numeral:
1---luminous icon layer 2---substrate layer 3---balance layer
4---ornament layer 5---surface protecting layer.
Embodiment
The present invention is further illustrated with specific embodiment for the below, but the present invention is not subjected to the restriction of following embodiment.
A kind of water-soluble luminous printing ink, it is comprised of the raw material of following mass percent: benzene emulsion 35%, nano level luminescent powder 19%, deionized water 20%, alcohol ester-12 2%, EVA emulsion 15%, PE water-based wax 4%, water-based flow agent 2.9%, water-based defoamer 0.1%, laking agent 2%.The nano level luminescent powder is nano level calcium halophosphate activated by antimony andmanganese luminescent powder.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 1830 of U.S. Lauth OY; Nano-luminescent powder adopts the nano-luminescent powder of the SP-CP-KB-WP of upstream luminescent material company limited; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral; Laking agent adopts the laking agent of Zhengzhou Hao Feng equipment company limited.
The preparation method of this water-soluble luminous printing ink comprises following preparation process:
(a) under 30 ℃ of room temperature conditions, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 2 hours, make dispersion liquid with the stirrer of 800 rev/mins rotating speeds;
(b) under 30 ℃ of room temperature conditions, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 1 hour with 800 rev/mins rotating speeds, make water-soluble luminous printing ink.
As shown in Figure 1, use the light emitting floor of this water-soluble luminous printing ink preparation, it from top to bottom comprises luminous icon layer 1, substrate layer 2 and balance layer 3 successively, the luminous icon layer that described luminous icon layer 1 makes for water-soluble luminous printing ink printing.
Use the light emitting floor of this water-soluble luminous printing ink preparation, it comprises following preparation process:
(a) get a transfer film, use gravure printing machine, water-soluble luminous printing ink is printed sagittate illuminated diagram be marked on the transfer film, form luminous icon layer 1, make the transfer film with luminous icon layer 1;
(b) transfer film after step (a) is processed applies one deck adhesive layer with gravure printing machine or coating machine, and adhesive layer is covered in luminous icon layer 1, then oven dry, and the temperature of oven dry is 100 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) is processed is needed on substrate layer 2 by temperature-sensitive or pressure-sensitive mode, and the below of substrate layer 2 is provided with balance layer 3, makes light emitting floor.Substrate layer 2 is the substrate layer of solid wood material, and balance layer 3 is made of balance paper.The temperature of transfer printing is 100 ℃ ~ 190 ℃.
A kind of water-soluble luminous printing ink, it is comprised of the raw material of following mass percent: benzene emulsion 25%, nano level luminescent powder 16%, deionized water 29%, alcohol ester-12 5%, EVA emulsion 15%, PE water-based wax 6%, water-based flow agent 2%, water-based defoamer 1%, laking agent 1%.The nano level luminescent powder is nano level calcium halophosphate activated by antimony andmanganese luminescent powder.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 1830 of U.S. Lauth OY; Nano-luminescent powder adopts the nano-luminescent powder of the SP-CP-KB-WP of upstream luminescent material company limited; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral; Laking agent adopts the laking agent of Zhengzhou Hao Feng equipment company limited.
The preparation method of this water-soluble luminous printing ink comprises following preparation process:
(a) under 40 ℃ of room temperature conditions, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 1 hour, make dispersion liquid with the stirrer of 800 rev/mins rotating speeds;
(b) under 40 ℃ of room temperature conditions, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 0.5 hour with 800 rev/mins rotating speeds, make water-soluble luminous printing ink.
As shown in Figure 2, use the light emitting floor of this water-soluble luminous printing ink preparation, it from top to bottom comprises surface protecting layer 5, ornament layer 4, luminous icon layer 1, substrate layer 2 and balance layer 3 successively, the luminous icon layer that described luminous icon layer 1 makes for water-soluble luminous printing ink printing.
Use the light emitting floor of this a kind of water-soluble luminous printing ink preparation, it comprises following preparation process:
(a) get a transfer film, simulated grain decorative pattern on transfer film forms ornament layer 4, makes the transfer film with ornament layer 4;
(b) use gravure printing machine, the illuminated diagram of water-soluble luminous printing ink printing rhombus reticulate pattern is marked on the transfer film after step (a) is processed, form luminous icon layer 1, luminous icon layer 1 is covered in ornament layer 4, makes the transfer film with ornament layer 4 and luminous icon layer 1;
(c) with the adhesive layer of the transfer film coating one deck temperature-sensitive of gravure printing machine after step (b) is processed, adhesive layer is covered in luminous icon layer 1, then oven dry, and the temperature of oven dry is at 160 ℃, makes the transfer film finished product;
(d) the transfer film finished product after step (c) processing is needed on substrate layer 2 by temperature-sensitive or pressure-sensitive mode, the below of substrate layer 2 is provided with balance layer 3, makes just finished product of light emitting floor; Substrate layer 2 is the substrate layer of solid wood material; Balance layer 3 is made of balance paper;
(e) step (d) is made light emitting floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover layer of surface protective layer 5, make the light emitting floor finished product.Surface protecting layer 5 is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
A kind of water-soluble luminous printing ink, it is comprised of the raw material of following mass percent: benzene emulsion 35%, nano level luminescent powder 15%, deionized water 33%, alcohol ester-12 1%, EVA emulsion 10%, PE water-based wax 3%, water-based flow agent 1%, water-based defoamer 1%, laking agent 1%.The nano level luminescent powder is nano level calcium halophosphate activated by antimony andmanganese luminescent powder.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 1830 of U.S. Lauth OY; Nano-luminescent powder adopts the nano-luminescent powder of the SP-CP-KB-WP of upstream luminescent material company limited; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral; Laking agent adopts the laking agent of Zhengzhou Hao Feng equipment company limited.
The preparation method of this water-soluble luminous printing ink comprises following preparation process:
(a) under 1 ℃ of room temperature condition, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 1 hour, make dispersion liquid with the stirrer of 1200 rev/mins rotating speeds;
(b) under 1 ℃ of room temperature condition, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 1 hour with 1200 rev/mins rotating speeds, make water-soluble luminous printing ink.
As shown in Figure 2, use the light emitting floor of this water-soluble luminous printing ink preparation, it from top to bottom comprises surface protecting layer 5, ornament layer 4, luminous icon layer 1, substrate layer 2 and balance layer 3 successively, the luminous icon layer that described luminous icon layer 1 makes for water-soluble luminous printing ink printing.
Use the light emitting floor of this water-soluble luminous printing ink preparation, it comprises following preparation process:
(a) get a transfer film, printing emmarble pattern forms ornament layer 4 on transfer film, makes the transfer film with ornament layer 4;
(b) use gravure printing machine, the illuminated diagram of water-soluble luminous printing ink printing honeycombed reticulate pattern is marked on the transfer film after step (a) is processed, form luminous icon layer 1, luminous icon layer 1 is covered in ornament layer 4, makes the transfer film with ornament layer 4 and luminous icon layer 1;
(c) apply the pressure-sensitive adhesive layer of one deck with the transfer film of coating machine after step (b) is processed, adhesive layer is covered in luminous icon layer 1, then oven dry, and the temperature of oven dry is at 160 ℃, makes the transfer film finished product;
(d) the transfer film finished product after step (c) processing is needed on substrate layer 2 by temperature-sensitive or pressure-sensitive mode, the below of substrate layer 2 is provided with balance layer 3, makes just finished product of light emitting floor; Substrate layer 2 is the substrate layer of composite floor board material; Balance layer 3 is made of balance paper;
(e) step (d) is made light emitting floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover layer of surface protective layer 5, make the light emitting floor finished product.Surface protecting layer 5 is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
A kind of water-soluble luminous printing ink, it is comprised of the raw material of following mass percent: benzene emulsion 30%, nano level luminescent powder 16%, deionized water 30%, alcohol ester-12 3%, EVA emulsion 12%, PE water-based wax 5%, water-based flow agent 2%, water-based defoamer 1%, laking agent 1%.The nano level luminescent powder is nano level calcium halophosphate activated by antimony andmanganese luminescent powder.The benzene emulsion of present embodiment adopts the benzene emulsion of the HYDRO-REZ 1830 of U.S. Lauth OY; Nano-luminescent powder adopts the nano-luminescent powder of the SP-CP-KB-WP of upstream luminescent material company limited; The EVA emulsion adopts the Guangzhou river in Henan Province to contain the EVA707 of Chemical trade company limited; PE water-based wax adopts the PE water-based wax of the Aquatec4101 of U.S. Lauth OY; The water-based flow agent adopts 455 water-based flow agent of the Taiwan modest company of moral; The water-based defoamer adopts 0506 water-based defoamer of the Taiwan modest company of moral; Laking agent adopts the laking agent of Zhengzhou Hao Feng equipment company limited.
The preparation method of this water-soluble luminous printing ink comprises following preparation process:
(a) under 1 ℃ of room temperature condition, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 1 hour, make dispersion liquid with the stirrer of 1000 rev/mins rotating speeds;
(b) under 14 ℃ of room temperature conditions, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 1 hour with 1000 rev/mins rotating speeds, make water-soluble luminous printing ink.
As shown in Figure 2, use the light emitting floor of this water-soluble luminous printing ink preparation, it from top to bottom comprises surface protecting layer 5, ornament layer 4, luminous icon layer 1, substrate layer 2 and balance layer 3 successively, the luminous icon layer that described luminous icon layer 1 makes for water-soluble luminous printing ink printing.
The light emitting floor of this a kind of water-soluble luminous printing ink preparation, it comprises following preparation process:
(a) get a transfer film, printing bamboo line decorative pattern forms ornament layer 4 on transfer film, makes the transfer film with ornament layer 4;
(b) use gravure printing machine, the illuminated diagram of water-soluble luminous printing ink printing star reticulate pattern is marked on the transfer film after step (a) is processed, form luminous icon layer 1, luminous icon layer 1 is covered in ornament layer 4, makes the transfer film with ornament layer 4 and luminous icon layer 1;
(c) with the adhesive layer of the transfer film coating one deck temperature-sensitive of gravure printing machine after step (b) is processed, then dry, the temperature of oven dry is at 140 ℃, makes the transfer film finished product;
(d) the transfer film finished product after step (c) processing is needed on substrate layer 2 by temperature-sensitive or pressure-sensitive mode, the below of substrate layer 2 is provided with balance layer 3, makes just finished product of light emitting floor; Substrate layer 2 is the substrate layer of solid wood material; Balance layer 3 is made of balance paper;
(e) step (d) is made light emitting floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover layer of surface protective layer 5, make the light emitting floor finished product.Surface protecting layer 5 is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
The above only is preferred embodiment of the present invention, so all equivalences of doing according to the described structure of patent claim of the present invention, feature and principle change or modify, is included in the patent claim of the present invention.
Claims (9)
1. water-soluble luminous printing ink, it is characterized in that: it is comprised of the raw material of following mass percent:
Benzene emulsion 25% ~ 35%
Nano level luminescent powder 15% ~ 19%
Deionized water 20% ~ 35%
Alcohol ester-12 1% ~ 5%
EVA emulsion 10% ~ 15%
PE water-based wax 3% ~ 6%
Water-based flow agent 1% ~ 3%
Water-based defoamer 0.1% ~ 1%
Laking agent 1% ~ 2%;
Wherein, described nano level luminescent powder is nano level calcium halophosphate activated by antimony andmanganese luminescent powder;
Described water-soluble luminous printing ink comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ conditions, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 1 hour ~ 2 hours, make dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) under 1 ℃ ~ 40 ℃ conditions, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble luminous printing ink.
2. a kind of water-soluble luminous printing ink according to claim 1, it is characterized in that: it is comprised of the raw material of following mass percent:
Benzene emulsion 25% ~ 30%
Nano level luminescent powder 15% ~ 19%
Deionized water 20% ~ 30%
Alcohol ester-12 1% ~ 5%
EVA emulsion 10% ~ 15%
PE water-based wax 3% ~ 6%
Water-based flow agent 1% ~ 3%
Water-based defoamer 0.1% ~ 1%
Laking agent 1% ~ 2%.
3. a kind of water-soluble luminous printing ink according to claim 1, it is characterized in that: it is comprised of the raw material of following mass percent:
Benzene emulsion 30% ~ 35%
Nano level luminescent powder 15% ~ 19%
Deionized water 30% ~ 35%
Alcohol ester-12 1% ~ 5%
EVA emulsion 10% ~ 15%
PE water-based wax 3% ~ 6%
Water-based flow agent 1% ~ 3%
Water-based defoamer 0.1% ~ 1%
Laking agent 1% ~ 2%.
4. the preparation method of the described a kind of water-soluble luminous printing ink of claim 1 ~ 3 any one, it is characterized in that: it comprises following preparation process:
(a) under 1 ℃ ~ 40 ℃ conditions, add benzene emulsion and EVA emulsion in the container, then add the nano level luminescent powder, container for stirring 1 hour ~ 2 hours, make dispersion liquid with the stirrer of 800 rev/mins ~ 1200 rev/mins rotating speeds;
(b) under 1 ℃ ~ 40 ℃ conditions, the dispersion liquid that step (a) is made and deionized water, alcohol ester-12, PE water-based wax, water-based flow agent, water-based defoamer, laking agent drop in the Scattered Kettle, stirred 0.5 hour ~ 1 hour with 800 rev/mins ~ 1200 rev/mins rotating speeds, make water-soluble luminous printing ink.
5. application rights requires the light emitting floor of 1 described a kind of water-soluble luminous printing ink preparation, it is characterized in that: it from top to bottom comprises luminous icon layer, substrate layer and balance layer successively, and described luminous icon layer is the luminous icon layer that water-soluble luminous printing ink printing makes.
6. the light emitting floor of a kind of water-soluble luminous printing ink preparation according to claim 5, it is characterized in that: it comprises following preparation process:
(a) get a transfer film, use gravure printing machine, water-soluble luminous printing ink printing illuminated diagram is marked on the transfer film, make the transfer film with luminous icon layer;
(b) transfer film after step (a) is processed applies one deck adhesive layer with gravure printing machine or coating machine, then oven dry, and the temperature of oven dry is at 100 ℃ ~ 160 ℃, makes the transfer film finished product;
(c) the transfer film finished product after step (b) is processed is needed on substrate layer by temperature-sensitive or pressure-sensitive mode, and the below of substrate layer is provided with balance layer, makes light emitting floor.
7. the light emitting floor of a kind of water-soluble luminous printing ink preparation according to claim 5, it is characterized in that: it from top to bottom comprises surface protecting layer, ornament layer, luminous icon layer, substrate layer and balance layer successively, and described luminous icon layer is the luminous icon layer that water-soluble luminous printing ink printing makes.
8. the light emitting floor of a kind of water-soluble luminous printing ink preparation according to claim 7, it is characterized in that: it comprises following preparation process:
(a) get a transfer film, printed decoration pattern on transfer film makes the transfer film with ornament layer;
(b) use gravure printing machine, water-soluble luminous printing ink printing illuminated diagram is marked on the transfer film after step (a) is processed, make the transfer film with ornament layer and luminous icon layer;
(c) transfer film after step (b) is processed applies one deck adhesive layer with gravure printing machine or coating machine, then oven dry, and the temperature of oven dry is at 100 ℃ ~ 160 ℃, makes the transfer film finished product;
(d) the transfer film finished product after step (c) processing is needed on substrate layer by temperature-sensitive or pressure-sensitive mode, the below of substrate layer is provided with balance layer, makes just finished product of light emitting floor;
(e) step (d) is made light emitting floor and just carry out Wear-resistant Treatment in the surface of finished product, make it cover the layer of surface protective layer, make the light emitting floor finished product.
9. the light emitting floor of a kind of water-soluble luminous printing ink preparation according to claim 8, it is characterized in that: in the described step (e), surface protecting layer is made by the overlay paper impregnated melamine resin of high-abrasive material aluminium sesquioxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010616698 CN102093778B (en) | 2010-12-30 | 2010-12-30 | Water soluble luminous ink and luminous floor prepared by using same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010616698 CN102093778B (en) | 2010-12-30 | 2010-12-30 | Water soluble luminous ink and luminous floor prepared by using same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102093778A CN102093778A (en) | 2011-06-15 |
| CN102093778B true CN102093778B (en) | 2013-04-24 |
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| CN104312267A (en) * | 2014-11-11 | 2015-01-28 | 合肥皖为电气设备工程有限责任公司 | Anti-freezing printing ink and preparation method thereof |
| CN104604552B (en) * | 2015-01-29 | 2017-02-22 | 宁波远鸿生物科技有限公司 | Making method for luminous preserved flowers |
| CN113858844A (en) * | 2021-10-28 | 2021-12-31 | 深圳市柯尼达医疗设备有限公司 | Antistatic wear-resistant PET medical film |
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| CN2797499Y (en) * | 2005-04-22 | 2006-07-19 | 杨波 | Luminous floor |
| CN101921509A (en) * | 2010-08-23 | 2010-12-22 | 东莞市英科水墨有限公司 | Water soluble strippable dye transfer color paste and preparation method thereof |
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| KR100740537B1 (en) * | 2005-12-01 | 2007-07-19 | 주식회사 진광화학 | Water-soluble Coating Composition for Solvent Ink-jet Printing Banner Textile and Using thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN2797499Y (en) * | 2005-04-22 | 2006-07-19 | 杨波 | Luminous floor |
| CN101921509A (en) * | 2010-08-23 | 2010-12-22 | 东莞市英科水墨有限公司 | Water soluble strippable dye transfer color paste and preparation method thereof |
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