CN103214902B - Formula of abrasive surface printing ink and printing method - Google Patents

Formula of abrasive surface printing ink and printing method Download PDF

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CN103214902B
CN103214902B CN 201310092582 CN201310092582A CN103214902B CN 103214902 B CN103214902 B CN 103214902B CN 201310092582 CN201310092582 CN 201310092582 CN 201310092582 A CN201310092582 A CN 201310092582A CN 103214902 B CN103214902 B CN 103214902B
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printing
formula
abrasive
surface
ink
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CN 201310092582
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CN103214902A (en )
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李宰勋
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青岛吉必爱斯美容用品有限公司
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Abstract

本发明提供一种研磨面印刷用墨配方,它是由以下重量百分比的物质组成:分子量200000-300000的聚乙烯醇40-60%、分子量400-1000的聚丙二醇20-40%、溶剂染料或颜料3-12%、乙醇0.5-0.8%、表面活性剂1.5-2.0%、TPU聚氨酯2-8%。 The present invention provides a polishing surface of the printed ink formulation, which is the percentage by weight consisting of the following: 40-60% of polyvinyl alcohol molecular weight of 200000-300000, polypropylene glycol molecular weight 400-1000 20-40%, solvent dyes, or 3-12% pigment, 0.5 to 0.8% ethanol, a surfactant 1.5-2.0%, TPU polyurethane 2-8%. 本发明还提供一种研磨面印刷方法,它是以绘图仪将如上所述的研磨面印刷用墨配方喷到指甲或硬角质整理工具的研磨面上。 The present invention also provides a method of printing abrasive surface, which is based on the polished surface as described above plotter printing ink jet formulation to the nails or keratinous hard polishing surface finishing tool. 使用本发明的研磨面印刷用墨及方法,可保证不同颜色的墨水不会混在一起而浸染,研磨面不会形成涂膜,墨水能很好的吸收到研磨面,进而保持高的研磨效率,同时得到清晰的图案设计。 Use abrasive surface printing ink according to the present invention and methods can not ensure the inks of different colors mixed together to dip, polished surface coating film is not formed, the ink can be well absorbed into the polishing surface, so as to maintain high polishing efficiency, At the same time obtain a clear pattern design.

Description

研磨面印刷用墨配方及印刷方法【技术领域】 Polished surface printing ink formulations and printing methods FIELD

[0001] 本发明涉及指甲整理工具的研磨面的印刷,具体地说,涉及一种研磨面印刷用墨配方及印刷方法。 Printing polishing surface [0001] The present invention relates to a finishing nail tools, in particular, printing ink formulations and printing process involves a polishing surface.

【背景技术】 【Background technique】

[0002] 现有的指甲或硬角质整理工具,如指甲锉的研磨面图案的印刷方法是把提前印刷好的带图案设计的印刷用印张附在研磨面上,然后利用热压着方式将印刷的设计焊接到研磨面上,但是该过程中,印刷用印张上的图案设计的油性墨水会在印刷用纸的一面上固着和热熔着,进一步在指甲或硬角质整理工具的研磨面上形成涂膜。 [0002] The conventional nail or keratin hard finishing tools, such as a pattern printing method of the polished surface of the nail file is to advance the printing surface of the printing sheet well attached to the polishing tape design pattern, and then printing by thermal pressing manner the design is welded to the polishing surface, but the process, the printing pattern on the design sheet fixing and oil-based ink will melt on one side of the printing paper is further formed on the polishing surface of the nail or keratin hard finishing tools coating. 这种带涂膜的指甲整理工具的研磨面研磨效率会大打折扣,不利于整理、研磨指甲或硬角质。 This efficiency nails polished surface finishing tool with a coating film will be greatly reduced, is not conducive to finishing, polishing fingernails or hard horny.

[0003] 改进的指甲或硬角质整理工具研磨面图案的印刷方法是:在印刷用印张上固着水性墨水,再在指甲或硬角质整理工具的研磨面上热熔着而将图案印刷于其上。 [0003] improved method of printing a nail or keratin hard abrasive surface finishing tool is a pattern: the printing sheet on the fixing aqueous ink, and then the nails or keratinous hard polishing surface finishing tool and melt the pattern printed thereon . 但是由于指甲或硬角质整理工具的研磨面是由非常精细的凹凸部分构成的,所以该种图案印刷方法得到的整理工具的研磨面易产生水性墨水沿着凹凸部分渗起的问题。 However, due to nails or keratinous hard abrasive surface finishing tool is made of very fine irregular portion, the polishing surface finishing tool of the kind of printing a pattern obtained by the method easy to produce aqueous ink bleeding along the uneven portion played. 尤其当被印刷的图案是由很多颜色构成时,不同颜色的水性墨水混在一起更易产生上述问题。 In particular when the printed pattern is composed of many colors, the aqueous ink of different colors are mixed to generate more problems described above.

[0004] 因此急需一种能够使图案印刷在指甲或硬角质整理工具的研磨面上时,各种颜色的墨水混在一起而形成涂膜而是很好的吸收到研磨面上,进而维持研磨面研磨效率,同时墨水不会发生侵染的研磨面印刷方法。 [0004] Accordingly capable need for a design printed on the nail surface during grinding or finishing keratinous hard tools, a variety of mixed colors of ink form a coating film but a good absorption of the polished surface, and further maintaining the polishing surface grinding efficiency, while polishing surface printing ink does not occur infestation.

【发明内容】 [SUMMARY]

[0005] 本发明的目的是针对现有技术中的不足,提供一种研磨面印刷用墨配方。 [0005] The object of the present invention is directed to the prior art is insufficient, there is provided a polished surface of the printed ink formulation.

[0006] 本发明的再一的目的是,提供一种研磨面印刷方法。 [0006] A further object of the present invention is to provide a method of printing abrasive surface.

[0007] 为实现上述目的,本发明采取的技术方案是: [0007] To achieve the above object, the present invention takes the following technical solution:

[0008] 一种研磨面印刷用墨配方,它是由以下重量百分比的物质组成:分子量200000-300000的聚乙烯醇40-60%、分子量400-1000的聚丙二醇20-40%、溶剂染料或颜料3-12 %、乙醇0.5-0.8%、表面活性剂L 5-2.0%,TPU聚氨酯2-8 %。 [0008] A polished surface of the printed ink formulation, which is the percentage by weight consisting of the following: 40-60% of polyvinyl alcohol molecular weight of 200000-300000, polypropylene glycol molecular weight 400-1000 20-40%, solvent dyes, or 3-12% pigment, 0.5 to 0.8% ethanol, a surfactant L 5-2.0%, TPU polyurethane 2-8%.

[0009] 优选的,它是由以下重量百分比的物质组成:分子量240000的聚乙烯醇60%、分子量800的聚丙二醇30%、溶剂染料或颜料3%、乙醇0.6%、表面活性剂1.8%、TPU聚氨酷4.6!%。 [0009] Preferably, it is made of the following weight percent composition of matter: 60% of 240,000 molecular weight polyvinyl alcohol of molecular weight of polypropylene glycol 800 30% 3% solvent dye or pigment, 0.6% ethanol, 1.8% surfactant, TPU polyurethane cool 4.6!%.

[0010] 所述的溶剂染料或颜料选自酸性黄色23、酸性蓝色9、酸性红色17、酸性红色52、酸性红色249 以及反应性红色180、Carta Black>Direct Blackl9、DirectBlack51 中的一种或几种。 [0010] The solvent is selected from an acidic dye or a pigment yellow 23, acid blue 9, acid red 17, acid red 52, acid red 249 and reactive red 180, Carta Black> Direct Blackl9, DirectBlack51 of one or several.

[0011] 所述的表面活性剂是脂肪醇聚氧乙烯醚和/或十一烷基磺酸钠。 [0011] The surfactant is a polyoxyethylene fatty alcohol ether and / or sodium undecyl.

[0012] 为实现上述第二个目的,本发明采取的技术方案是: [0012] To achieve the above second object, the present invention takes the following technical solution:

[0013] 一种研磨面印刷方法,它是以绘图仪将如上任一所述的研磨面印刷用墨配方喷到指甲或硬角质整理工具的研磨面上,包括以下步骤:[0014] I)给位于喷射对象正下方的绘图仪部分的热线加热,进行印刷同时干燥墨水; [0013] A polished surface printing method, which is based plotter as in any of the polishing surface a jet printing ink formulation to the nails or keratinous hard polishing surface finishing tool, comprising the steps of: [0014] I) subject to the injection hot positioned directly below the heating portion of the plotter, while the printed ink is dried;

[0015] 2)将已喷上墨水的研磨面继续往绘图仪下面排出; Polishing surface [0015] 2) which has been sprayed on the ink continues to discharge below the plotter;

[0016] 3)将已排出的研磨面继续向上方卷起。 [0016] 3) The polished surface has been rolled upwardly discharging continues.

[0017] 本发明优点在于: [0017] The advantages of the present invention comprising:

[0018] 使用本发明的研磨面印刷用墨及方法,可保证不同颜色的墨水不会混在一起而浸染,研磨面不会形成涂膜,墨水能很好的吸收到研磨面,保持高的研磨效率,且能获得清晰的图案设计。 [0018] using a grinding surface of the printed ink of the present invention and the method can not ensure the inks of different colors mixed together to dip, polished surface coating film is not formed, the ink can be well absorbed into the polishing surface, maintaining a high polishing efficiency, and can get a clear pattern design.

【具体实施方式】 【detailed description】

[0019] 下面对本发明提供的具体实施方式作详细说明。 [0019] DETAILED DESCRIPTION Hereinafter, the present invention provides detailed description.

[0020] 本文中,所述的聚乙烯醇英文名称为Polyvinylalcohol ;所述的聚丙二醇英文名称为Polypropyleneglycol ;所述的TPU聚氨酯是Thermoplastic Urethane的简称,中文名称为热塑性聚氨酯弹性体,TPU是由二苯甲烷二异氰酸酯(MDI)、甲苯二异氰酸酯(TDI)和大分子多元醇、扩链剂共同反应聚合而成的高分子材料;所述的乙醇为市售体积分数95%的乙醇。 [0020] As used herein, the English name of polyvinyl Polyvinylalcohol; English name of the polypropylene glycol is Polypropyleneglycol; said polyurethane TPU Thermoplastic Urethane is short, the Chinese name for a thermoplastic polyurethane elastomer, TPU by two phenyl methane diisocyanate (MDI), toluene diisocyanate (TDI) and the macromer polyol, the chain extender were reacted together polymerized polymer materials; the ethanol is commercially available with 95% ethanol.

[0021] 实施例1本发明的研磨面印刷用墨配方一 Polished surface of the printed [0021] Example 1 of the present invention is an ink formulation

[0022] 分子量200000的聚乙烯醇40%、分子量1000的聚丙二醇40%、酸性黄色23 3%,酸性蓝色9 3%、酸性红色17 3.7%、乙醇0.8%、脂肪醇聚氧乙烯醚1.5%、TPU聚氨酯8%。 [0022] molecular weight 200,000 40% polyvinyl alcohol, polyethylene glycol molecular weight of 1000 to 40%, acid yellow 23 3% Acid Blue 9 3% Acid Red 17 3.7%, 0.8% ethanol, fatty alcohol polyoxyethylene ether 1.5 %, TPU polyurethane 8%.

[0023] 实施例2本发明的研磨面印刷用墨配方二 Polished surface of the printed [0023] Example 2 of the present invention with two ink formulations

[0024] 分子量300000的聚乙烯醇60%、分子量400的聚丙二醇20%、酸性蓝色92%、酸性红色17 I %、酸性黄色23 2%,Direct Blackl9 4%,Direct Black51 3%、乙醇0.5%、脂肪醇聚氧乙烯醚2.0 %、TPU聚氨酯5.5%。 [0024] 60% of polyvinyl alcohol molecular weight of 300,000, a molecular weight of polypropylene glycol 400 20% 92% acid blue, acid red 17 I%, ​​acid yellow 23 2%, Direct Blackl9 4%, Direct Black51 3%, ethanol 0.5 %, fatty alcohol polyoxyethylene ether 2.0%, TPU polyurethane 5.5%.

[0025] 实施例3本发明的研磨面印刷用墨配方三 Polished surface of the printed [0025] Example 3 of the present invention with three ink formulations

[0026] 分子量240000的聚乙烯醇60 %、分子量800的聚丙二醇30 %、酸性黄色230.5 %、酸性蓝色9 0.5%、酸性红色52 I %、反应性红色180 1%、乙醇0.^一烷基磺酸钠 [0026] The molecular weight 240,000 60% polyvinyl alcohol, polyethylene glycol of molecular weight of 800 to 30%, 230.5% acid yellow, acid blue 9 0.5%, acid red 52 I%, the reactive red 1 801% ethanol 0.5 a ^ alkyl sulfonate

0.5%,脂肪醇聚氧乙烯醚1.3 %、TPU聚氨酯4.6 %。 0.5% fatty alcohol polyoxyethylene ether 1.3%, TPU polyurethane 4.6%.

[0027] 实施例4本发明的研磨面印刷用墨配方四 Polished surface of the printed [0027] Example 4 of the present invention four ink formulation

[0028] 分子量300000的聚乙烯醇50 %、分子量400的聚丙二醇40 %、酸性黄色230.5 %、酸性蓝色9 1%、酸性红色17 0.5%、酸性红色52 0.5%、酸性红色249 0.5%、反应性红色180 0.5%, Carta BlacklDirect Blackl9 1%、乙醇0.5^^一烷基磺酸钠2%、TPU [0028] 50% of polyvinyl alcohol molecular weight of 300,000, a molecular weight of polypropylene glycol 400 40% 230.5% acid yellow, acid blue 9 1% 0.5% Acid Red 17, Acid Red 52 0.5%, 0.5% Acid Red 249, reactive red 180 0.5%, Carta BlacklDirect Blackl9 1%, ethanol 0.5 sodium alkyl ^^ a 2%, TPU

聚氨酯2%。 2% polyurethane.

[0029] 实施例5本发明的研磨面印刷用墨配方五 Polished surface of the printed [0029] Example 5 of the present invention five ink formulation

[0030] 分子量200000的聚乙烯醇50%、分子量800的聚丙二醇30%、酸性黄色232%、酸性蓝色9 2%、酸性红色17 2%、反应性红色180 2%,Direct Black51 2%、乙醇0.5%、 [0030] molecular weight 200,000 50% polyvinyl alcohol, polyethylene glycol of molecular weight 800 30% 232% acid yellow, acid blue 92% Acid Red 17 2% reactive red 180 2%, Direct Black51 2%, 0.5% ethanol,

十一烷基磺酸钠0.5%,脂肪醇聚氧乙烯醚1.0 %、TPU聚氨酯8 %。 0.5% sodium undecyl, polyoxyethylene fatty alcohol ether 1.0%, TPU polyurethane 8%.

[0031] 实施例6本发明的研磨面印刷用墨配方六 Polished surface of the printed [0031] Example 6 The ink formulation of the present invention six

[0032] 分子量240000的聚乙烯醇40%、分子量1000的聚丙二醇40%、酸性黄色231%、酸性蓝色9 I %、酸性红色17 I %、酸性红色52 I %、反应性红色180 2%,Direct Blackl92 %、乙醇0.6 %、十一烷基磺酸钠2 %、TPU聚氨酯9.4%。 [0032] The molecular weight 240,000 40% polyvinyl alcohol, polyethylene glycol molecular weight of 1000 to 40%, 231% acid yellow, acid blue 9 I%, acid red 17 I%, ​​acid red 52 I%, 1802% reactive red , Direct Blackl92%, 0.6% ethanol, sodium undecyl 2%, TPU polyurethane 9.4%.

[0033] 对比例I [0033] Comparative Example I

[0034] 分子量200000的聚丙二醇甲醚40%、分子量1000的聚丙二醇40%、酸性黄色233%、酸性蓝色9 3%、酸性红色17 3.7%、乙醇0.8%、脂肪醇聚氧乙烯醚1.5%、TPU聚氨酯8%。 Polypropylene glycol methyl ether [0034] 40% of the molecular weight of 200,000, a molecular weight of polypropylene glycol 1000 40%, 233% acid yellow, acid blue 93% Acid Red 17 3.7%, 0.8% ethanol, fatty alcohol polyoxyethylene ether 1.5 %, TPU polyurethane 8%.

[0035] 对比例2 [0035] Comparative Example 2

[0036] 分子量200000的聚乙烯醇35%、分子量1000的聚丙二醇45%、酸性黄色23 3%,酸性蓝色9 3%、酸性红色17 3.7%、乙醇0.8%、脂肪醇聚氧乙烯醚1.5%、TPU聚氨酯8%。 [0036] The molecular weight 200,000 35% polyvinyl alcohol, polyethylene glycol molecular weight of 1000 to 45%, acid yellow 23 3% Acid Blue 9 3% Acid Red 17 3.7%, 0.8% ethanol, fatty alcohol polyoxyethylene ether 1.5 %, TPU polyurethane 8%.

[0037] 对比例3 [0037] Comparative Example 3

[0038] 分子量300000的聚乙烯醇50 %、分子量400的聚丙二醇40 %、酸性黄色230.5 %、酸性蓝色9 1%、酸性红色17 0.5%、酸性红色52 0.5%、酸性红色249 0.5%、反应性红色180 0.5% >Carta Blackl % >Direct Blackl9 I %、乙醇0.6%、十一烷基横酸纳1.4 %、TF1U [0038] 50% of polyvinyl alcohol molecular weight of 300,000, a molecular weight of polypropylene glycol 400 40% 230.5% acid yellow, acid blue 9 1% 0.5% Acid Red 17, Acid Red 52 0.5%, 0.5% Acid Red 249, reactive red 180 0.5%> Carta Blackl%> Direct Blackl9 I%, 0.6% ethanol, undecyl acrylate in horizontal 1.4%, TF1U

聚氨酯2%。 2% polyurethane.

[0039] 实施例7印刷研磨面 [0039] Example 7 embodiment the polished surface of the printing

[0040] 使用上述实施例和对比例的印刷用墨,以绘图仪将其喷到指甲或硬角质研磨工具的研磨面以印刷研磨面: [0040] Using the above Examples and the proportion of printing ink to be sprayed plotter hard to nail keratin grinding tool or polishing surface to the polishing surface printing:

[0041] I)给位于喷射对象正下方的绘图仪部分的热线加热,进行印刷同时干燥墨水; [0041] I) to the wire at the ejection portion of the object is below the plotter heating, drying of the ink while printing;

[0042] 2)将已喷上墨水的研磨面继续往绘图仪下面排出; Polishing surface [0042] 2) which has been sprayed on the ink continues to discharge below the plotter;

[0043] 3)将已排出的研磨面继续向上方卷起。 [0043] 3) The polished surface has been rolled upwardly discharging continues.

[0044] 实施例8产品性能比较 Example 8 Performance Comparison [0044] Embodiment

[0045] 从使用各实施例研磨面印刷用墨喷涂得到的指甲或硬角质研磨工具中随即抽取50个样品,测试其研磨面性能,统计研磨效率、图案侵染情况,研磨效率分高、低两个等级,图案侵染情况包括有或无。 [0045] From each of the embodiments of the polishing surface of the printed using 50 samples randomly selected nails or keratinous hard abrasive tool obtained ink coating, tested polished surface properties, grinding efficiency statistics, pattern infestation, the grinding efficiency at high, low two levels, or a pattern comprising Infecting no. 统计结果如见表1。 Statistical results are shown in Table 1.

[0046] 表1统计结果(个) [0046] Table 1 statistical results (a)

Figure CN103214902BD00051

[0048] 由统计结果可以看出,使用本发明的研磨面印刷用墨,以绘图仪将其喷到指甲或硬角质研磨工具的研磨面来印刷图案的方法可令研磨面保持高的研磨效率,同时墨水不会发生侵染。 [0048] As can be seen from the statistical results, the present invention is the use of a polishing surface of the printed ink in order to discharge it to a plotter or a hard horny nail polishing surface grinding tool may be a method to make the printed pattern to maintain the polished surface of high grinding efficiency while the ink infection does not occur.

[0049] 以上所述仅是本发明的优选实施方式,对于本技术领域的普通技术人员,在不脱离本发明方法的前提下,作出的改进和补充也视为本发明的保护范围。 [0049] The above are only preferred embodiments of the present invention, the present art for the ordinary skill in the art, without departing from the method of the present invention, improvements and additions made in the protection scope of the present invention.

Claims (3)

  1. 1.一种研磨面印刷用墨配方,其特征在于,它是由以下重量百分比的物质组成:分子量240000的聚乙烯醇60 %、分子量800的聚丙二醇30 %、溶剂染料或颜料3 %、乙醇0.6 %、表面活性剂1.8 %、TPU聚氨酯4.6%,所述的溶剂染料或颜料选自酸性黄色23、酸性蓝色9、酸性红色17、酸性红色52、酸性红色249以及反应性红色180、Carta Black、DirectBlackl9> Direct Black51 中的一种或几种。 A printing ink formulation polished surface, characterized in that it is the percentage by weight consisting of the following: 60% polyvinyl alcohol molecular weight of 240,000, a molecular weight of polypropylene glycol 800 30% 3% Solvent Dyes or pigments, ethanol 0.6% surfactant 1.8%, TPU 4.6% polyurethane, said solvent selected from an acidic dye or a pigment yellow 23, acid blue 9, acid red 17, acid red 52, acid red 249 and reactive red 180, Carta Black, DirectBlackl9> one or more Direct Black51 in.
  2. 2.根据权利要求1所述的研磨面印刷用墨配方,其特征在于,所述的表面活性剂是脂肪醇聚氧乙烯醚和/或十一烷基磺酸钠。 2. The polishing surface according to claim 1, said printing ink formulation, wherein said surfactant is a polyoxyethylene fatty alcohol ether and / or sodium undecyl.
  3. 3.一种研磨面印刷方法,其特征在于,它是以绘图仪将权利要求1-2任一所述的研磨面印刷用墨配方喷到指甲或硬角质整理工具的研磨面上,包括以下步骤: 1)给位于喷射对象正下方的绘图仪部分的热线加热,进行印刷同时干燥墨水; 2)将已喷上墨水的研磨面继续往绘图仪下面排出; 3)将已排出的研磨面继续向上方卷起。 A method of printing abrasive surface, characterized in that it is based on the polishing surface plotter printing according to any one of claims 1-2 is sprayed onto the polishing surface of the fingernail or rigid tool finishing keratinous ink formulation, comprising step: 1) to the wire at the ejection target directly below the plotter portion of the heating, printing is performed while drying ink; 2) which has been sprayed on the polishing surface of the ink continues to drain to the plotter below; 3) the polished surface has been exhausted to continue rolled upward.
CN 201310092582 2013-03-13 2013-03-13 Formula of abrasive surface printing ink and printing method CN103214902B (en)

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