CN102989590A - 一种硫化锑金矿物浮选分离方法 - Google Patents
一种硫化锑金矿物浮选分离方法 Download PDFInfo
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- CN102989590A CN102989590A CN2012105216893A CN201210521689A CN102989590A CN 102989590 A CN102989590 A CN 102989590A CN 2012105216893 A CN2012105216893 A CN 2012105216893A CN 201210521689 A CN201210521689 A CN 201210521689A CN 102989590 A CN102989590 A CN 102989590A
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- antimony
- gold
- flotation
- flotation separation
- mineral
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- 238000005188 flotation Methods 0.000 title claims abstract description 57
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 48
- 239000011707 mineral Substances 0.000 title claims abstract description 48
- 238000000926 separation method Methods 0.000 title claims abstract description 38
- IQKRELJEFLIJLS-UHFFFAOYSA-N [Au][Sb]=S Chemical compound [Au][Sb]=S IQKRELJEFLIJLS-UHFFFAOYSA-N 0.000 title abstract 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000010931 gold Substances 0.000 claims abstract description 39
- 229910052737 gold Inorganic materials 0.000 claims abstract description 39
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 37
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000012141 concentrate Substances 0.000 claims abstract description 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- KAPYVWKEUSXLKC-UHFFFAOYSA-N [Sb].[Au] Chemical compound [Sb].[Au] KAPYVWKEUSXLKC-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- 229920002472 Starch Polymers 0.000 claims abstract description 6
- 239000012190 activator Substances 0.000 claims abstract description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 6
- 239000004088 foaming agent Substances 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 235000019698 starch Nutrition 0.000 claims abstract description 6
- 239000008107 starch Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 11
- 229940007424 antimony trisulfide Drugs 0.000 claims description 9
- NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 claims description 9
- 239000003814 drug Substances 0.000 claims description 6
- XEIPQVVAVOUIOP-UHFFFAOYSA-N [Au]=S Chemical compound [Au]=S XEIPQVVAVOUIOP-UHFFFAOYSA-N 0.000 claims description 5
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims description 5
- 229940116901 diethyldithiocarbamate Drugs 0.000 claims description 5
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 claims description 5
- 239000006260 foam Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 2
- 238000011084 recovery Methods 0.000 abstract description 11
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229950004394 ditiocarb Drugs 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 abstract 1
- AAJRIJBGDLLRAE-UHFFFAOYSA-M sodium;butoxymethanedithioate Chemical compound [Na+].CCCCOC([S-])=S AAJRIJBGDLLRAE-UHFFFAOYSA-M 0.000 abstract 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052569 sulfide mineral Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 description 9
- MJLGNAGLHAQFHV-UHFFFAOYSA-N arsenopyrite Chemical compound [S-2].[Fe+3].[As-] MJLGNAGLHAQFHV-UHFFFAOYSA-N 0.000 description 7
- 229910052683 pyrite Inorganic materials 0.000 description 5
- 239000011028 pyrite Substances 0.000 description 5
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- 238000011017 operating method Methods 0.000 description 3
- 229910052959 stibnite Inorganic materials 0.000 description 3
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 2
- 241000722270 Regulus Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- FAWGZAFXDJGWBB-UHFFFAOYSA-N antimony(3+) Chemical compound [Sb+3] FAWGZAFXDJGWBB-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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CN201210521689.3A CN102989590B (zh) | 2012-12-07 | 2012-12-07 | 一种硫化锑金矿物浮选分离方法 |
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CN201210521689.3A CN102989590B (zh) | 2012-12-07 | 2012-12-07 | 一种硫化锑金矿物浮选分离方法 |
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CN102989590A true CN102989590A (zh) | 2013-03-27 |
CN102989590B CN102989590B (zh) | 2014-05-28 |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103223377A (zh) * | 2013-04-16 | 2013-07-31 | 中南大学 | 一种低品位氧化锑矿浮选分离方法 |
CN103433143A (zh) * | 2013-09-17 | 2013-12-11 | 长沙有色冶金设计研究院有限公司 | 一种卡林型金矿浮选方法 |
CN103657865A (zh) * | 2013-12-03 | 2014-03-26 | 安徽朝山新材料股份有限公司 | 一种低品位金矿捕收剂及其制备方法 |
CN104128245A (zh) * | 2014-07-09 | 2014-11-05 | 湖南安化渣滓溪矿业有限公司 | 一种辉锑矿的浮选工艺 |
CN104741242A (zh) * | 2015-03-24 | 2015-07-01 | 新疆星塔矿业有限公司 | 一种用于金锑分离的浮选药剂 |
CN105080728A (zh) * | 2015-09-30 | 2015-11-25 | 广西大学 | 一种硫化锑与含金黄铁矿的浮选分离方法 |
CN106391321A (zh) * | 2016-12-07 | 2017-02-15 | 广西大学 | 一种方铅矿与砷钴矿的浮选分离方法 |
CN106492996A (zh) * | 2016-11-02 | 2017-03-15 | 广西大学 | 一种辉锑矿与雄黄的浮选分离方法 |
CN106540800A (zh) * | 2016-10-20 | 2017-03-29 | 昆明理工大学 | 一种回收含锑金矿浮选尾矿中金及微细粒锑矿物的方法 |
CN106733210A (zh) * | 2016-12-13 | 2017-05-31 | 锡矿山闪星锑业有限责任公司 | 一种硫化锑矿的选矿方法 |
CN107377230A (zh) * | 2017-08-02 | 2017-11-24 | 白银金锑矿贸有限公司 | 一种提高含锑金精矿中锑金品位的浮选富集方法 |
US9885095B2 (en) | 2014-01-31 | 2018-02-06 | Goldcorp Inc. | Process for separation of at least one metal sulfide from a mixed sulfide ore or concentrate |
CN110075992A (zh) * | 2018-01-26 | 2019-08-02 | 临武县南方矿业有限责任公司 | 硝酸锑在矿物浮选中的用途及铅锑矿的选矿方法 |
CN114471960A (zh) * | 2022-02-16 | 2022-05-13 | 矿冶科技集团有限公司 | 金锑矿的选矿方法 |
CN114832947A (zh) * | 2022-05-05 | 2022-08-02 | 广西华锡集团股份有限公司 | 铁闪锌矿与脆硫铅锑矿浮选药剂及浮选方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US5837210A (en) * | 1995-04-18 | 1998-11-17 | Newmont Gold Company | Method for processing gold-bearing sulfide ores involving preparation of a sulfide concentrate |
CN1799698A (zh) * | 2006-01-09 | 2006-07-12 | 昆明理工大学 | 从含锡多金属硫化矿的选矿尾矿中回收有价矿物的方法 |
CN102371212A (zh) * | 2011-10-19 | 2012-03-14 | 昆明理工大学 | 铅锌硫化矿强化分散低高碱度部分优先混合浮选技术 |
-
2012
- 2012-12-07 CN CN201210521689.3A patent/CN102989590B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5837210A (en) * | 1995-04-18 | 1998-11-17 | Newmont Gold Company | Method for processing gold-bearing sulfide ores involving preparation of a sulfide concentrate |
CN1799698A (zh) * | 2006-01-09 | 2006-07-12 | 昆明理工大学 | 从含锡多金属硫化矿的选矿尾矿中回收有价矿物的方法 |
CN102371212A (zh) * | 2011-10-19 | 2012-03-14 | 昆明理工大学 | 铅锌硫化矿强化分散低高碱度部分优先混合浮选技术 |
Non-Patent Citations (3)
Title |
---|
于雪: "《含砷金锑矿的浮选分离研究》", 《中国优秀硕士学位论文全文数据库(电子期刊)》 * |
赵军伟等: "《硫化矿浮选分离有机抑制剂研究的进展》", 《矿产保护与利》 * |
金华爱等: "《硫化锑矿石中伴生金的综合回收》", 《矿产综合利用》 * |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103223377A (zh) * | 2013-04-16 | 2013-07-31 | 中南大学 | 一种低品位氧化锑矿浮选分离方法 |
CN103433143A (zh) * | 2013-09-17 | 2013-12-11 | 长沙有色冶金设计研究院有限公司 | 一种卡林型金矿浮选方法 |
CN103657865A (zh) * | 2013-12-03 | 2014-03-26 | 安徽朝山新材料股份有限公司 | 一种低品位金矿捕收剂及其制备方法 |
CN103657865B (zh) * | 2013-12-03 | 2016-01-13 | 安徽朝山新材料股份有限公司 | 一种低品位金矿捕收剂及其制备方法 |
US10370739B2 (en) | 2014-01-31 | 2019-08-06 | Goldcorp, Inc. | Stabilization process for an arsenic solution |
US9885095B2 (en) | 2014-01-31 | 2018-02-06 | Goldcorp Inc. | Process for separation of at least one metal sulfide from a mixed sulfide ore or concentrate |
US11124857B2 (en) | 2014-01-31 | 2021-09-21 | Goldcorp Inc. | Process for separation of antimony and arsenic from a leach solution |
CN104128245A (zh) * | 2014-07-09 | 2014-11-05 | 湖南安化渣滓溪矿业有限公司 | 一种辉锑矿的浮选工艺 |
CN104741242A (zh) * | 2015-03-24 | 2015-07-01 | 新疆星塔矿业有限公司 | 一种用于金锑分离的浮选药剂 |
CN105080728B (zh) * | 2015-09-30 | 2017-09-19 | 广西大学 | 一种硫化锑与含金黄铁矿的浮选分离方法 |
CN105080728A (zh) * | 2015-09-30 | 2015-11-25 | 广西大学 | 一种硫化锑与含金黄铁矿的浮选分离方法 |
CN106540800A (zh) * | 2016-10-20 | 2017-03-29 | 昆明理工大学 | 一种回收含锑金矿浮选尾矿中金及微细粒锑矿物的方法 |
CN106540800B (zh) * | 2016-10-20 | 2018-12-14 | 昆明理工大学 | 一种回收含锑金矿浮选尾矿中金及微细粒锑矿物的方法 |
CN106492996A (zh) * | 2016-11-02 | 2017-03-15 | 广西大学 | 一种辉锑矿与雄黄的浮选分离方法 |
CN106391321A (zh) * | 2016-12-07 | 2017-02-15 | 广西大学 | 一种方铅矿与砷钴矿的浮选分离方法 |
CN106733210A (zh) * | 2016-12-13 | 2017-05-31 | 锡矿山闪星锑业有限责任公司 | 一种硫化锑矿的选矿方法 |
CN106733210B (zh) * | 2016-12-13 | 2019-11-15 | 锡矿山闪星锑业有限责任公司 | 一种硫化锑矿的选矿方法 |
CN107377230A (zh) * | 2017-08-02 | 2017-11-24 | 白银金锑矿贸有限公司 | 一种提高含锑金精矿中锑金品位的浮选富集方法 |
CN110075992A (zh) * | 2018-01-26 | 2019-08-02 | 临武县南方矿业有限责任公司 | 硝酸锑在矿物浮选中的用途及铅锑矿的选矿方法 |
CN110075992B (zh) * | 2018-01-26 | 2021-07-16 | 临武县南方矿业有限责任公司 | 一种取代硝酸铅浮选铅锑矿的药剂制度及选矿方法 |
CN114471960A (zh) * | 2022-02-16 | 2022-05-13 | 矿冶科技集团有限公司 | 金锑矿的选矿方法 |
CN114471960B (zh) * | 2022-02-16 | 2023-08-04 | 矿冶科技集团有限公司 | 金锑矿的选矿方法 |
CN114832947A (zh) * | 2022-05-05 | 2022-08-02 | 广西华锡集团股份有限公司 | 铁闪锌矿与脆硫铅锑矿浮选药剂及浮选方法 |
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Effective date of registration: 20160106 Address after: 730900 1-01, 2 North of West fluoride (01), Baiyin District, Gansu, Baiyin, China Patentee after: BAIYIN JINDI MINERAL TRADE CO.,LTD. Address before: 530004 the Guangxi Zhuang Autonomous Region XiXiangTang Nanning University Road No. 100 Patentee before: Guangxi University Patentee before: Guangxi Golden Finger Mining Technology Co.,Ltd. |
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Address after: 730900 Two Blocks 1-01 on the Northwest Side of Fluoride Salt in Baiyin District, Baiyin City, Gansu Province Patentee after: Silver, Gold and Antimony Mining Technology Co.,Ltd. Address before: 730900 Two Blocks 1-01 on the Northwest Side of Fluoride Salt in Baiyin District, Baiyin City, Gansu Province Patentee before: BAIYIN JINDI MINERAL TRADE CO.,LTD. |
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