CN102977614B - A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof - Google Patents

A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof Download PDF

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Publication number
CN102977614B
CN102977614B CN201210435457.6A CN201210435457A CN102977614B CN 102977614 B CN102977614 B CN 102977614B CN 201210435457 A CN201210435457 A CN 201210435457A CN 102977614 B CN102977614 B CN 102977614B
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parts
proofness
oxide
protection against
environment
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CN102977614A (en
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姜睿
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Guangzhou Star Conduction Technology Co ltd
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ANHUI JINQIAO CABLE CO LTD
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Abstract

The invention provides the resistance to height of a kind of protection against rodents, low temperature oil-proofness environment-friendly cable material, be made up of the raw material of following weight part: terpolymer EP rubber 20-30 part, trifluoropropyl siloxane 60-80 part, chlorinatedpolyethylene 8-10 part, clorafin 8-10 part, stearic acid 0.5-1.0 part, modification tree ash 1-3 part, triethyl citrate 20-30 part, ferric oxide 4-6 part, molybdic oxide 0.5-1.0 part, precipitated silica? 30-50 part, diatomite 10-13 part, capsaicine 0.5?-1.0 parts, antioxidant H? 0.1-0.3 part, anti-aging agent 4040? 0.2-0.5 part, Vulcanization accelerator TMTD? 0.5-1.5 part, vulcanizing agent DCP? 0.5 ~ 1 part, TDE 3-5 part, antimonous oxide 12-15 part, zinc borate 6-8 part.CABLE MATERIALS of the present invention not only has excellent flame retardancy and not flame-retarding power; During burning, the amount of being fuming is considerably less, do not produce toxic gas, do not produce corrosive gases, and there is good high-low temperature resistant, oil-proofness, wear resistance simultaneously, the existing anti-mouse of the cable be processed into by CABLE MATERIALS of the present invention, termite, to the harm of cable, have effect of low cigarette environmental protection flame retardant simultaneously.

Description

A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof.
Background technology
Along with the fast development of global economy, and the enhancing of mankind's environmental consciousness, the requirement of each field to the quality and performance of electric wire is more and more higher, mouse, termite are one of the three large main harm of harm plastic jacketed cable, optical cable, cause many accidents to occur every year, cause huge loss economically.
Electric wire grandmotherization and the fire that causes also gets more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the production of current halide-free low-smoke fireproof cable material is in polyolefin substrate, add a large amount of clorafins or clorafin to reach flame retardant effect mostly, but, adding of a large amount of inorganic materials, have impact on physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, its at normal temperatures softness, weathering resistance poor, oil-proofness, resistance to low temperature be not fine.
Summary of the invention
The invention provides a kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof.The existing anti-mouse of the cable be processed into by CABLE MATERIALS of the present invention, termite, to the harm of cable, have effect of low cigarette environmental protection flame retardant simultaneously.
The technical solution used in the present invention is:
The resistance to height of a kind of protection against rodents, low temperature oil-proofness environment-friendly cable material, it is characterized in that: be made up of the raw material of following weight part: terpolymer EP rubber 20-30 part, trifluoropropyl siloxane 60-80 part, chlorinatedpolyethylene 8-10 part, clorafin 8-10 part, stearic acid 0.5-1.0 part, modification tree ash 1-3 part, triethyl citrate 20-30 part, ferric oxide 4-6 part, molybdic oxide 0.5-1.0 part, precipitated silica 30-50 part, diatomite 10-13 part, capsaicine 0.5-1.0 part, antioxidant H 0.1-0.3 part, anti-aging agent 40400.2-0.5 part, Vulcanization accelerator TMTD 0.5-1.5 part, vulcanizing agent DCP0.5 ~ 1 part, TDE 3-5 part, antimonous oxide 12-15 part, zinc borate 6-8 part.
Described modification tree ash is prepared by the following method:
(1), tree ash 10-15% salt acid soak 3-4 hour, deionized water wash, then with 10-12% hydrogen peroxide leaching solution bubble 3-4 hour, then with deionized water wash to neutral, dry;
(2), tree ash will be dissolved in be added to the water, add the sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that are equivalent to tree ash weight 2-3% again, high speed 1200-1500 rev/min of stirring, obtain dispersion liquid, dispersion liquid ovendry power is broken into ultrafine powder.
The resistance to height of described protection against rodents, low temperature oil-proofness environment-friendly cable material, it is characterized in that: be made up of the raw material of following weight part: terpolymer EP rubber 25 parts, trifluoropropyl siloxane 70 parts, chlorinatedpolyethylene 9 parts, clorafin 9 parts, stearic acid 0.8 part, modification tree ash 2 parts, triethyl citrate 27 parts, ferric oxide 5 parts, molybdic oxide 0.6 part, precipitated silica 35 parts, 11 parts, diatomite, capsaicine 0.8 part, antioxidant H 0.2 part, 40400.4 parts, anti-aging agent, Vulcanization accelerator TMTD 1.0 parts, vulcanizing agent DCP0.8 part, TDE 4 parts, antimonous oxide 13 parts, zinc borate 7 parts.
The preparation method of described protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material, is characterized in that:
(1) by formula rate, terpolymer EP rubber, trifluoropropyl siloxane, chlorinatedpolyethylene and anti-aging agent class are dropped into mill, mixing 3-4 minute at 70-80 DEG C;
(2) fillers such as diatomite, ferric oxide, precipitated silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material outside sulphur removal agent, promotor is joined in mixing materials, after mixing 4-6 minute, add vulcanizing agent, promotor again, after thin-pass 6-7 time, granulation.
beneficial effect
CABLE MATERIALS of the present invention not only has excellent flame retardancy and not flame-retarding power; During burning, the amount of being fuming is considerably less, does not produce toxic gas, does not produce corrosive gases, and has good high-low temperature resistant, oil-proofness, wear resistance simultaneously.The existing anti-mouse of the cable be processed into by CABLE MATERIALS of the present invention, termite, to the harm of cable, have effect of low cigarette environmental protection flame retardant simultaneously.
Embodiment
Protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material, is made up of the raw material of following weight part: terpolymer EP rubber 25 parts, trifluoropropyl siloxane 70 parts, chlorinatedpolyethylene 9 parts, clorafin 9 parts, stearic acid 0.8 part, modification tree ash 2 parts, triethyl citrate 27 parts, ferric oxide 5 parts, molybdic oxide 0.6 part, precipitated silica 35 parts, 11 parts, diatomite, capsaicine 0.8 part, antioxidant H 0.2 part, 40400.4 parts, anti-aging agent, Vulcanization accelerator TMTD 1.0 parts, vulcanizing agent DCP0.8 part, TDE 4 parts, antimonous oxide 13 parts, zinc borate 7 parts.
Modification tree ash is prepared by the following method:
(1), tree ash 10% salt acid soak 3 hours, deionized water wash, then steep 3 hours with 10-12% hydrogen peroxide leaching solution, then with deionized water wash to neutral, dry;
(2), tree ash will be dissolved in be added to the water, add the sodium laurylsulfate, the zinc oxide of 1%, diatomite, 5% aluminium hydroxide of 2% that are equivalent to tree ash weight 3% again, high speed 1200-1500 rev/min of stirring, obtain dispersion liquid, dispersion liquid ovendry power is broken into ultrafine powder.
Preparation method:
(1) by formula rate, terpolymer EP rubber, trifluoropropyl siloxane, chlorinatedpolyethylene and anti-aging agent class are dropped into mill, mixing 3-4 minute at 70-80 DEG C;
(2) fillers such as diatomite, ferric oxide, precipitated silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material outside sulphur removal agent, promotor is joined in mixing materials, after mixing 4-6 minute, add vulcanizing agent, promotor again, after thin-pass 6-7 time, granulation.
Be pressed into test piece after 160 DEG C × 40min thermal ageing by the CABLE MATERIALS that the present embodiment processes, record its performance as follows:
Project Result
Tensile strength MPa 18.5
Elongation at break % 370
Volume specific resistance Ω .cm 9.0×10 12
Oxygen index % 46
135 DEG C × 168h thermal ageing back draft intensity >= 28.7MPa
Unit mass smoke density 9.3g
Thermal ageing mass loss≤ 20.5g/m2

Claims (3)

1. the resistance to height of protection against rodents, low temperature oil-proofness environment-friendly cable material, it is characterized in that: be made up of the raw material of following weight part: terpolymer EP rubber 20-30 part, trifluoropropyl siloxane 60-80 part, chlorinatedpolyethylene 8-10 part, clorafin 8-10 part, stearic acid 0.5-1.0 part, modification tree ash 1-3 part, triethyl citrate 20-30 part, ferric oxide 4-6 part, molybdic oxide 0.5-1.0 part, precipitated silica 30-50 part, diatomite 10-13 part, capsaicine 0.5-1.0 part, antioxidant H 0.1-0.3 part, anti-aging agent 40400.2-0.5 part, Vulcanization accelerator TMTD 0.5-1.5 part, vulcanizing agent DCP0.5 ~ 1 part, TDE 3-5 part, antimonous oxide 12-15 part, zinc borate 6-8 part,
Described modification tree ash is prepared by the following method:
(1), tree ash 10-15% salt acid soak 3-4 hour, deionized water wash, then soak 3-4 hour with 10-12% hydrogen peroxide solution, then with deionized water wash to neutral, dry;
(2), tree ash is added to the water, add the sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that are equivalent to tree ash weight 2-3% again, high speed 1200-1500 rev/min of stirring, obtain dispersion liquid, dispersion liquid ovendry power is broken into ultrafine powder.
2. the resistance to height of protection against rodents according to claim 1, low temperature oil-proofness environment-friendly cable material, it is characterized in that: be made up of the raw material of following weight part: terpolymer EP rubber 25 parts, trifluoropropyl siloxane 70 parts, chlorinatedpolyethylene 9 parts, clorafin 9 parts, stearic acid 0.8 part, modification tree ash 2 parts, triethyl citrate 27 parts, ferric oxide 5 parts, molybdic oxide 0.6 part, precipitated silica 35 parts, 11 parts, diatomite, capsaicine 0.8 part, antioxidant H 0.2 part, 40400.4 parts, anti-aging agent, Vulcanization accelerator TMTD 1.0 parts, vulcanizing agent DCP0.8 part, TDE 4 parts, antimonous oxide 13 parts, zinc borate 7 parts.
3. a preparation method for protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material as claimed in claim 1 or 2, is characterized in that:
(1) by formula rate, terpolymer EP rubber, trifluoropropyl siloxane, chlorinatedpolyethylene and anti-aging agent class are dropped into mill, mixing 3-4 minute at 70-80 DEG C;
(2) diatomite, ferric oxide, precipitated silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material outside sulphur removal agent, promotor is joined in mixing materials, after mixing 4-6 minute, add vulcanizing agent, promotor again, after thin-pass 6-7 time, granulation.
CN201210435457.6A 2012-11-05 2012-11-05 A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof Active CN102977614B (en)

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CN103304903A (en) * 2013-05-14 2013-09-18 安徽旺达铜业发展有限公司 Cable sheath material comprising modified aluminum hydroxide
CN103333418B (en) * 2013-06-04 2016-05-04 安徽荣玖光纤通信科技有限公司 A kind of cold resistant cable protective cover material
CN103483697A (en) * 2013-08-28 2014-01-01 绿宝电缆(集团)有限公司 Multi-nano-material cable sheath material
CN104592648B (en) * 2015-01-09 2017-01-11 芜湖航天特种电缆厂股份有限公司 Flame-retardant ethylene propylene diene monomer for cable and preparation method of flame-retardant ethylene propylene diene monomer
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CN104672628A (en) * 2015-03-12 2015-06-03 安徽特种电缆集团有限公司 Radiation-resistant cable insulation material for nuclear power plant
CN105330997A (en) * 2015-10-27 2016-02-17 苏州宽温电子科技有限公司 Abrasion-resisting weather-resisting cable sheath material and preparation method thereof
CN105575544A (en) * 2015-12-07 2016-05-11 国网山东莱阳市供电公司 Communication cable capable of preventing saline-alkaline corrosion and rat/ant gnawing
CN105542477A (en) * 2016-03-08 2016-05-04 远东电缆有限公司 Silicone rubber expansion filler for smart energy cable
CN106189261A (en) * 2016-08-08 2016-12-07 安徽埃克森科技集团有限公司 A kind of high-tension switch cabinet Flame-Retardant and Oil-Resistant type flexible cable sheath
CN106832876B (en) * 2016-12-21 2019-10-18 柳州市昌泉贸易有限公司 A kind of preparation method of oil resistant fire-resistant cable material
CN107383677A (en) * 2017-07-25 2017-11-24 合肥达户电线电缆科技有限公司 A kind of environment-friendly cable material and preparation method thereof
CN112226003B (en) * 2020-10-10 2022-07-08 安徽华宇电缆集团有限公司 Rat-proof cable sheath material for ships and warships and preparation method and application thereof

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Inventor after: Zhou Xiaohong

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