CN104530519A - Halogen-free low-smoke fire-resistant cable material, and preparation method thereof - Google Patents
Halogen-free low-smoke fire-resistant cable material, and preparation method thereof Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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Abstract
The invention discloses a halogen-free low-smoke fire-resistant cable material, and a preparation method thereof. The halogen-free low-smoke fire-resistant cable material is used for solving problems of conventional cable materials that great harm are caused for escapees and rescuers, and environmental pollution is also caused by large amount of toxic smoke and corrosive gas generated in combustion of conventional flame-resistant cable in fire. The halogen-free low-smoke fire-resistant cable material is composed of a polyolefin, a fire retardant, a char-forming catalyst, a nano synergistic fire retardant, a filler, a lubricant, and an anti-oxidant; or is composed of a polyolefin, a fire retardant, a char-forming catalyst, a nano synergistic fire retardant, a filler, a lubricant, a compatilizer, a silane coupling agent, and an anti-oxidant. The preparation method comprises following steps: step 1, material weighing; step 2, mixing; step 3, kneading using a kneading machine; and step 4, extruding granulation, and obtaining of the halogen-free low-smoke fire-resistant cable material. The halogen-free low-smoke fire-resistant cable material is excellent in flame resistance, low in smoke, and excellent in mechanical properties; and the preparation method is simple.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS and preparation method thereof.
Background technology
Supply of electric power has become the indispensable part of world economy develop rapidly, and electric wire spreads all trades and professions as the carrier of supply of electric power.The insulating polymeric material used due to electric wire belongs to inflammable material, in electric energy transmitting process, often cause cable fire by internal cause (cable self-heating, short circuit etc.) and external cause (fire etc.), lives and properties are caused damage.Traditional flame retardant cable mainly adopts halogen containing polymers (as PVC) and halogen containing flame-retardant (chloride or brominated compound) by mixing acquisition good flame-retardance energy, but fire still can cause the burning of cable, and cable produces a large amount of poison gas in combustion, corrosive gases can make people suffocate, poisoning, not only greatly harm but also contaminate environment are caused to survivor and rescue personnel.Therefore, how to obtain a kind of halide-free low-smoke fireproof cable material and seem very necessary.
Summary of the invention
The object of the invention is to solve existing flame retardant cable to burn in a fire and produce a large amount of poison gas and corrosive gases, great injury is caused to survivor and rescue personnel, and the problem of contaminate environment, and a kind of halide-free low-smoke fireproof cable material and preparation method thereof is provided.
A kind of halide-free low-smoke fireproof cable material is made up of 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants and 2 parts ~ 4 parts oxidation inhibitor by weight.
A kind of halide-free low-smoke fireproof cable material is made up of 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 5 parts ~ 10 parts compatilizers, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor by weight;
Described polyolefine by weight mark is made up of 30 parts ~ 70 parts Low Density Polyethylenes and 30 parts ~ 70 parts ethylene-vinyl acetate copolymers;
Described fire retardant is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide;
Described char forming catalyst is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture;
Described nanometer synergistic flame retardant is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets; Described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, back flow reaction 3h ~ 4h at temperature is 60 DEG C ~ 80 DEG C again, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm;
Described weighting agent is one in nano-calcium carbonate, calcined kaolin and wollastonite or wherein several mixture;
Described lubricant is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax;
Described compatilizer is a kind of or wherein several mixture in maleic anhydride grafted polyethylene, maleic anhydride graft EVA and maleic anhydride graft POE;
Described silane coupling agent is a kind of or wherein several mixture in γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-aminopropyl triethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and N-(β-aminoethyl)-γ-aminopropyl triethoxysilane;
Described oxidation inhibitor is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.
A preparation method for halide-free low-smoke fireproof cable material, specifically completes according to the following steps:
One, weighing: take 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 5 parts ~ 10 parts compatilizers, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor by weight;
Two, mix: 50 parts that take in step one ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor are carried out mixing 5min ~ 8min in high-speed mixer, obtains mixed mixture; Again take in step one 100 parts of polyolefine, 5 parts ~ 10 parts compatilizers and mixed mixture are mixed 5min ~ 8min in high-speed mixer, obtain mixed raw material;
Three, adopt milling machine carry out kneading: be mixing 10min ~ 20min in the milling machine of 120 DEG C ~ 140 DEG C in temperature by the mixed raw material obtained in step 2, obtain mixing after raw material;
Four, extruding pelletization: adopt each barrel zone temperature to be that the raw material after mixing is carried out extruding pelletization by the Dual inoculation of 130 DEG C ~ 160 DEG C, obtain halide-free low-smoke fireproof cable material;
Described polyolefine by weight mark is made up of 60 parts of Low Density Polyethylenes and 40 parts of ethylene-vinyl acetate copolymers;
Fire retardant described in step one is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide;
Char forming catalyst described in step one is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture;
Nanometer synergistic flame retardant described in step one is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets; Described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, back flow reaction 3h ~ 4h at temperature is 60 DEG C ~ 80 DEG C again, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm;
Weighting agent described in step one is one in nano-calcium carbonate, calcined kaolin and wollastonite or wherein several mixture;
Lubricant in step one described in step one is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax;
Compatilizer described in step one is a kind of or wherein several mixture in maleic anhydride grafted polyethylene, maleic anhydride graft EVA and maleic anhydride graft POE;
Silane coupling agent described in step one is a kind of or wherein several mixture in γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-aminopropyl triethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and N-(β-aminoethyl)-γ-aminopropyl triethoxysilane;
Oxidation inhibitor described in step one is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.
Advantage of the present invention:
One, the invention provides a kind of halide-free low-smoke fireproof cable material, a kind of halide-free low-smoke fireproof cable material provided by the invention, by adding modified Nano synergistic flame retardant on the basis of conventional inorganic fire retardant, significantly improves the flame retardant properties of cable; A kind of halide-free low-smoke fireproof cable material of the present invention flame retardant properties is high, low cigarette, good mechanical property, and dielectric properties are excellent, and preparation technology is simple;
Two, the tensile strength of halide-free low-smoke fireproof cable material that prepared by the present invention is 11MPa ~ 13MPa, and elongation at break is 190% ~ 220%, and oxygen index is 34% ~ 38%, 20 DEG C of volume specific resistances is 2.1 × 10
12Ω m ~ 7.7 × 10
12Ω m, smoke density has flame 87 ~ 104, smoke density nonflame 123 ~ 142.
Embodiment
Embodiment one: present embodiment is that a kind of halide-free low-smoke fireproof cable material is made up of 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants and 2 parts ~ 4 parts oxidation inhibitor by weight.
The advantage of present embodiment:
One, present embodiment provides a kind of halide-free low-smoke fireproof cable material, and a kind of halide-free low-smoke fireproof cable material that present embodiment provides, by adding modified Nano synergistic flame retardant on the basis of conventional inorganic fire retardant, significantly improves the flame retardant properties of cable; A kind of halide-free low-smoke fireproof cable material of present embodiment flame retardant properties is high, low cigarette, good mechanical property, and dielectric properties are excellent, and preparation technology is simple;
Two, the tensile strength of halide-free low-smoke fireproof cable material that prepared by present embodiment is 11MPa ~ 13MPa, and elongation at break is 190% ~ 220%, and oxygen index is 34% ~ 38%, 20 DEG C of volume specific resistances is 2.1 × 10
12Ω m ~ 7.7 × 10
12Ω m, smoke density has flame 87 ~ 104, smoke density nonflame 123 ~ 142.
Embodiment two: present embodiment and embodiment one difference are: described polyolefine by weight mark is made up of 30 parts ~ 70 parts Low Density Polyethylenes and 30 parts ~ 70 parts ethylene-vinyl acetate copolymers.Other steps are identical with embodiment one.
Embodiment three: one of present embodiment and embodiment one or two difference is: described fire retardant is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide.Other steps are identical with embodiment one or two.
Embodiment four: one of present embodiment and embodiment one to three difference is: described char forming catalyst is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture.Other steps are identical with embodiment one to three.
Embodiment five: one of present embodiment and embodiment one to four difference is: described nanometer synergistic flame retardant is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets.Other steps are identical with embodiment one to four.
Embodiment six: one of present embodiment and embodiment one to five difference is: described weighting agent is a kind of or wherein several mixture in nano-calcium carbonate, calcined kaolin and wollastonite.Other steps are identical with embodiment one to five.
Embodiment seven: one of present embodiment and embodiment one to six difference is: described lubricant is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax; Described oxidation inhibitor is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.Other steps are identical with embodiment one to six.
Embodiment eight: one of present embodiment and embodiment one to seven difference is: described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, back flow reaction 3h ~ 4h at temperature is 60 DEG C ~ 80 DEG C again, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm.Other steps are identical with embodiment one to seven.
Embodiment nine: present embodiment is that a kind of halide-free low-smoke fireproof cable material is made up of 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 5 parts ~ 10 parts compatilizers, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor by weight;
Described polyolefine by weight mark is made up of 30 parts ~ 70 parts Low Density Polyethylenes and 30 parts ~ 70 parts ethylene-vinyl acetate copolymers;
Described fire retardant is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide;
Described char forming catalyst is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture;
Described nanometer synergistic flame retardant is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets; Described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, back flow reaction 3h ~ 4h at temperature is 60 DEG C ~ 80 DEG C again, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm;
Described weighting agent is one in nano-calcium carbonate, calcined kaolin and wollastonite or wherein several mixture;
Described lubricant is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax;
Described compatilizer is a kind of or wherein several mixture in maleic anhydride grafted polyethylene, maleic anhydride graft EVA and maleic anhydride graft POE;
Described silane coupling agent is a kind of or wherein several mixture in γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-aminopropyl triethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and N-(β-aminoethyl)-γ-aminopropyl triethoxysilane;
Described oxidation inhibitor is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.
The advantage of present embodiment:
One, present embodiment provides a kind of halide-free low-smoke fireproof cable material, and a kind of halide-free low-smoke fireproof cable material that present embodiment provides, by adding modified Nano synergistic flame retardant on the basis of conventional inorganic fire retardant, significantly improves the flame retardant properties of cable; A kind of halide-free low-smoke fireproof cable material of present embodiment flame retardant properties is high, low cigarette, good mechanical property, and dielectric properties are excellent, and preparation technology is simple;
Two, the tensile strength of halide-free low-smoke fireproof cable material that prepared by present embodiment is 11MPa ~ 13MPa, and elongation at break is 190% ~ 220%, and oxygen index is 34% ~ 38%, 20 DEG C of volume specific resistances is 2.1 × 10
12Ω m ~ 7.7 × 10
12Ω m, smoke density has flame 87 ~ 104, smoke density nonflame 123 ~ 142.
Embodiment ten: present embodiment is that a kind of preparation method of halide-free low-smoke fireproof cable material specifically completes according to the following steps:
One, weighing: take 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 5 parts ~ 10 parts compatilizers, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor by weight;
Two, mix: by 50 parts ~ 100 parts fire retardants taken in step one, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor carry out mixing 5min ~ 8min in high-speed mixer, obtain mixed mixture; Again take in step one 100 parts of polyolefine, 5 parts ~ 10 parts compatilizers and mixed mixture are mixed 5min ~ 8min in high-speed mixer, obtain mixed raw material;
Three, adopt milling machine carry out kneading: be mixing 10min ~ 20min in the milling machine of 120 DEG C ~ 140 DEG C in temperature by the mixed raw material obtained in step 2, obtain mixing after raw material;
Four, extruding pelletization: adopt each barrel zone temperature to be that the raw material after mixing is carried out extruding pelletization by the Dual inoculation of 130 DEG C ~ 160 DEG C, obtain halide-free low-smoke fireproof cable material;
Described polyolefine by weight mark is made up of 60 parts of Low Density Polyethylenes and 40 parts of ethylene-vinyl acetate copolymers;
Fire retardant described in step one is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide;
Char forming catalyst described in step one is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture;
Nanometer synergistic flame retardant described in step one is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets; Described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, back flow reaction 3h ~ 4h at temperature is 60 DEG C ~ 80 DEG C again, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm;
Weighting agent described in step one is one in nano-calcium carbonate, calcined kaolin and wollastonite or wherein several mixture;
Lubricant in step one described in step one is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax;
Compatilizer described in step one is a kind of or wherein several mixture in maleic anhydride grafted polyethylene, maleic anhydride graft EVA and maleic anhydride graft POE;
Silane coupling agent described in step one is a kind of or wherein several mixture in γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-aminopropyl triethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and N-(β-aminoethyl)-γ-aminopropyl triethoxysilane;
Oxidation inhibitor described in step one is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.
The advantage of present embodiment:
One, present embodiment provides a kind of halide-free low-smoke fireproof cable material, and a kind of halide-free low-smoke fireproof cable material that present embodiment provides, by adding modified Nano synergistic flame retardant on the basis of conventional inorganic fire retardant, significantly improves the flame retardant properties of cable; A kind of halide-free low-smoke fireproof cable material of present embodiment flame retardant properties is high, low cigarette, good mechanical property, and dielectric properties are excellent, and preparation technology is simple;
Two, the tensile strength of halide-free low-smoke fireproof cable material that prepared by present embodiment is 11MPa ~ 13MPa, and elongation at break is 190% ~ 220%, and oxygen index is 34% ~ 38%, 20 DEG C of volume specific resistances is 2.1 × 10
12Ω m ~ 7.7 × 10
12Ω m, smoke density has flame 87 ~ 104, smoke density nonflame 123 ~ 142.
Adopt following verification experimental verification advantage of the present invention:
Test one: a kind of preparation method of halide-free low-smoke fireproof cable material, specifically completes according to the following steps:
One, weighing: take 60 parts of Low Density Polyethylenes, 40 parts of ethylene-vinyl acetate copolymers, 30 parts of zinc borates, 45 parts of magnesium hydroxides, 4 portions of triphenylphosphates, 10 parts of nano-calcium carbonates, 3 parts of Zinic stearass, 3 parts of stearic acid, 1 part of polyethylene wax, 5 parts of maleic anhydride grafted polyethylenes, 2 parts of silane coupling agents, 2 parts of antioxidants and 1 part of modified hydrotalcite by weight;
Silane coupling agent described in step one is γ-glycidyl ether oxygen propyl trimethoxy silicane;
Modified Nano hydrotalcite described in step one is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 500 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/LNaOH solution regulator solution is 10, back flow reaction 3h at temperature is 70 DEG C again, ageing 1h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite;
Oxidation inhibitor described in step one is antioxidant 1010;
Two, mix: the 30 parts of zinc borates taken in step one, 45 parts of magnesium hydroxides, 4 parts of triphenylphosphates, 10 parts of nano-calcium carbonates, 3 parts of Zinic stearass, 3 parts of stearic acid, 1 part of polyethylene wax, 2 parts of silane coupling agents, 2 parts of antioxidants and 1 part of modified hydrotalcite are carried out mixing 5min ~ 8min in high-speed mixer, obtains mixed mixture; Again 60 parts of Low Density Polyethylenes, 40 parts of ethylene-vinyl acetates, 5 parts of maleic anhydride grafted polyethylenes and mixed mixtures are mixed 5min ~ 8min in high-speed mixer, obtain mixed raw material;
Three, adopt milling machine carry out kneading: be mixing 15min in the milling machine of 120 DEG C ~ 140 DEG C in temperature by the mixed raw material obtained in step 2, obtain mixing after raw material;
Four, extruding pelletization: adopt each barrel zone temperature to be that the raw material after mixing is carried out extruding pelletization by the Dual inoculation of 150 DEG C, obtain halide-free low-smoke fireproof cable material.
Test two: a kind of preparation method of halide-free low-smoke fireproof cable material, specifically completes according to the following steps:
One, weighing: take 40 parts of Low Density Polyethylenes, 60 parts of ethylene-vinyl acetate copolymers, 7 parts of maleic anhydride graft EVA, 30 parts of zinc borates, 45 parts of magnesium hydroxides, 4 portions of triphenylphosphates, 20 parts of calcined kaolins, 3 parts of Zinic stearass, 1 part of polyethylene wax, 1 part of silane coupling agent, 0.5 part of modified Nano hydrotalcite and 3 parts of oxidation inhibitor by weight;
Silane coupling agent described in step one is γ-aminopropyl triethoxysilane;
Modified Nano hydrotalcite described in step one is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 500 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/LNaOH solution regulator solution is 10, back flow reaction 3h at temperature is 70 DEG C again, ageing 1h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite;
Oxidation inhibitor described in step one is antioxidant 618;
Two, mix: the 30 parts of zinc borates taken in step one, 45 parts of magnesium hydroxides, 4 parts of triphenylphosphates, 20 parts of calcined kaolins, 3 parts of Zinic stearass, 1 part of polyethylene wax, 1 part of silane coupling agent, 0.5 part of modified Nano hydrotalcite and 3 parts of oxidation inhibitor are carried out mixing 5min ~ 8min in high-speed mixer, obtains mixed mixture; Again 40 parts of Low Density Polyethylenes, 60 parts of ethylene-vinyl acetate copolymers, 7 parts of maleic anhydride graft EVA and mixed mixtures are mixed 5min ~ 8min in high-speed mixer, obtain mixed raw material;
Three, adopt milling machine carry out kneading: be mixing 15min in the milling machine of 120 DEG C ~ 140 DEG C in temperature by the mixed raw material obtained in step 2, obtain mixing after raw material;
Four, extruding pelletization: adopt each barrel zone temperature to be that the raw material after mixing is carried out extruding pelletization by the Dual inoculation of 150 DEG C, obtain halide-free low-smoke fireproof cable material.
Test three: a kind of preparation method of halide-free low-smoke fireproof cable material, specifically completes according to the following steps:
One, weighing: take 45 parts of Low Density Polyethylenes, 55 parts of ethylene-vinyl acetate copolymers, 5 parts of maleic anhydride graft EVA, 20 parts of zinc borates, 25 parts of magnesium hydroxides, 20 parts of aluminium hydroxides, 4 parts of aluminum phenylphosphinate, 15 parts of calcined kaolins, 3 parts of Zinic stearass, 3 parts of stearic acid, 1 part of polyethylene wax, 1.5 parts of silane coupling agents, 1 part of graphite nanosheets and 4 parts of oxidation inhibitor by weight;
Silane coupling agent described in step one is N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane;
The particle diameter of the graphite nanosheets described in step one is 10nm;
Oxidation inhibitor described in step one is antioxidant 300;
Two, mix: the 20 parts of zinc borates taken in step one, 25 parts of magnesium hydroxides, 20 parts of aluminium hydroxides, 4 parts of aluminum phenylphosphinate, 15 parts of calcined kaolins, 3 parts of Zinic stearass, 3 parts of stearic acid, 1 part of polyethylene wax, 1.5 parts of silane coupling agents, 1 part of graphite nanosheets and 4 parts of oxidation inhibitor are carried out mixing 5min ~ 8min in high-speed mixer, obtains mixed mixture; Again 45 parts of Low Density Polyethylenes, 55 parts of ethylene-vinyl acetate copolymers, 5 parts of maleic anhydride graft EVA and mixed mixtures are mixed 5min ~ 8min in high-speed mixer, obtain mixed raw material;
Three, adopt milling machine carry out kneading: be mixing 15min in the milling machine of 120 DEG C ~ 140 DEG C in temperature by the mixed raw material obtained in step 2, obtain mixing after raw material;
Four, extruding pelletization: adopt each barrel zone temperature to be that the raw material after mixing is carried out extruding pelletization by the Dual inoculation of 150 DEG C, obtain halide-free low-smoke fireproof cable material.
Test four: a kind of preparation method of halide-free low-smoke fireproof cable material, specifically completes according to the following steps:
One, weighing: take 35 parts of Low Density Polyethylenes, 65 parts of ethylene-vinyl acetate copolymers, 5 parts of maleic anhydride graft POE, 30 parts of zinc borates, 25 parts of magnesium hydroxides, 20 parts of aluminium hydroxides, 4 portions of triphenylphosphates, 15 parts of wollastonites, 3 parts of stearic acid, 1 part of polyethylene wax, 2.5 parts of silane coupling agents, 0.5 part of graphite nanosheets and 3 parts of oxidation inhibitor by weight;
Silane coupling agent described in step one is N-(β-aminoethyl)-γ-aminopropyl triethoxysilane;
The particle diameter of the graphite nanosheets described in step one is 10nm;
Oxidation inhibitor described in step one is antioxidant 300;
Two, mix: by taking 30 parts of zinc borates in step one, 25 parts of magnesium hydroxides, 20 parts of aluminium hydroxides, 4 parts of triphenylphosphates, 15 parts of wollastonites, 3 parts of stearic acid, 1 part of polyethylene wax, 2.5 parts of silane coupling agents, 0.5 part of graphite nanosheets and 3 parts of oxidation inhibitor carry out mixing 5min ~ 8min in high-speed mixer, obtain mixed mixture; Again 35 parts of Low Density Polyethylenes, 65 parts of ethylene-vinyl acetate copolymers, 5 parts of maleic anhydride graft POE and mixed mixtures are mixed 5min ~ 8min in high-speed mixer, obtain mixed raw material;
Three, adopt milling machine carry out kneading: be mixing 15min in the milling machine of 120 DEG C ~ 140 DEG C in temperature by the mixed raw material obtained in step 2, obtain mixing after raw material;
Four, extruding pelletization: adopt each barrel zone temperature to be that the raw material after mixing is carried out extruding pelletization by the Dual inoculation of 150 DEG C, obtain halide-free low-smoke fireproof cable material.
Carry out the test of mechanical property, electrical property and flame retardant properties according to national standard to the halide-free low-smoke fireproof cable material that test one, test two, test three and test four obtain, as shown in table 1, table 1 is the detected result of flame retardant properties, mechanical property and electrical property.
Table 1
Claims (10)
1. a halide-free low-smoke fireproof cable material, is characterized in that a kind of halide-free low-smoke fireproof cable material is made up of 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants and 2 parts ~ 4 parts oxidation inhibitor by weight.
2. a kind of halide-free low-smoke fireproof cable material according to claim 1, it is characterized in that described polyolefine by weight mark be made up of 30 parts ~ 70 parts Low Density Polyethylenes and 30 parts ~ 70 parts ethylene-vinyl acetate copolymers.
3. a kind of halide-free low-smoke fireproof cable material according to claim 1, is characterized in that described fire retardant is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide.
4. a kind of halide-free low-smoke fireproof cable material according to claim 1, is characterized in that described char forming catalyst is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture.
5. a kind of halide-free low-smoke fireproof cable material according to claim 1, is characterized in that described nanometer synergistic flame retardant is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets.
6. a kind of halide-free low-smoke fireproof cable material according to claim 1, is characterized in that described weighting agent is a kind of or wherein several mixture in nano-calcium carbonate, calcined kaolin and wollastonite.
7. a kind of halide-free low-smoke fireproof cable material according to claim 1, is characterized in that described lubricant is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax; Described oxidation inhibitor is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.
8. a kind of halide-free low-smoke fireproof cable material according to claim 5, is characterized in that described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, in temperature be again? DEG C ~? back flow reaction 3h at DEG C ~ 4h, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm.
9. a halide-free low-smoke fireproof cable material, is characterized in that a kind of halide-free low-smoke fireproof cable material is made up of 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 5 parts ~ 10 parts compatilizers, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor by weight;
Described polyolefine by weight mark is made up of 30 parts ~ 70 parts Low Density Polyethylenes and 30 parts ~ 70 parts ethylene-vinyl acetate copolymers;
Described fire retardant is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide;
Described char forming catalyst is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture;
Described nanometer synergistic flame retardant is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets; Described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, back flow reaction 3h ~ 4h at temperature is 60 DEG C ~ 80 DEG C again, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm;
Described weighting agent is one in nano-calcium carbonate, calcined kaolin and wollastonite or wherein several mixture;
Described lubricant is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax;
Described compatilizer is a kind of or wherein several mixture in maleic anhydride grafted polyethylene, maleic anhydride graft EVA and maleic anhydride graft POE;
Described silane coupling agent is a kind of or wherein several mixture in γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-aminopropyl triethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and N-(β-aminoethyl)-γ-aminopropyl triethoxysilane;
Described oxidation inhibitor is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.
10. a preparation method for halide-free low-smoke fireproof cable material, is characterized in that what a kind of preparation method of halide-free low-smoke fireproof cable material specifically completed according to the following steps:
One, weighing: take 100 parts of polyolefine, 50 parts ~ 100 parts fire retardants, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 5 parts ~ 10 parts compatilizers, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor by weight;
Two, mix: by 50 parts ~ 100 parts fire retardants taken in step one, 2 parts ~ 5 parts char forming catalysts, 0.5 part ~ 2 parts nanometer synergistic flame retardants, 15 parts ~ 20 parts weighting agents, 2 parts ~ 7 parts lubricants, 1 part ~ 3 parts silane coupling agents and 2 parts ~ 4 parts oxidation inhibitor carry out mixing 5min ~ 8min in high-speed mixer, obtain mixed mixture; Again take in step one 100 parts of polyolefine, 5 parts ~ 10 parts compatilizers and mixed mixture are mixed 5min ~ 8min in high-speed mixer, obtain mixed raw material;
Three, adopt milling machine carry out kneading: be mixing 10min ~ 20min in the milling machine of 120 DEG C ~ 140 DEG C in temperature by the mixed raw material obtained in step 2, obtain mixing after raw material;
Four, extruding pelletization: adopt each barrel zone temperature to be that the raw material after mixing is carried out extruding pelletization by the Dual inoculation of 130 DEG C ~ 160 DEG C, obtain halide-free low-smoke fireproof cable material;
Described polyolefine by weight mark is made up of 60 parts of Low Density Polyethylenes and 40 parts of ethylene-vinyl acetate copolymers;
Fire retardant described in step one is a kind of or wherein several mixture in zinc borate, magnesium hydroxide and aluminium hydroxide;
Char forming catalyst described in step one is one in ammonium polyphosphate, aluminum phenylphosphinate and triphenylphosphate or wherein several mixture;
Nanometer synergistic flame retardant described in step one is one or both the mixture in modified Nano hydrotalcite and graphite nanosheets; Described modified Nano hydrotalcite is prepared according to the following steps: first hydrotalcite is calcined 6h at temperature is 400 DEG C ~ 600 DEG C, obtain bimetallic oxide LDO; By weight 2 parts of bimetallic oxide LDO are dissolved in 100 parts of distilled water, dripping 100 parts of concentration is again the lauryl sodium sulfate aqueous solution of 0.01mol/L, to re-use concentration be the pH value of 1mol/L ~ 3mol/LNaOH solution regulator solution is 10, back flow reaction 3h ~ 4h at temperature is 60 DEG C ~ 80 DEG C again, ageing 1h ~ 2h again, carry out centrifugation again, by the solid matter after centrifugation at 80 DEG C of dry 24h, obtain modified Nano hydrotalcite; The thickness of described graphite nanosheets is 5nm ~ 20nm;
Weighting agent described in step one is one in nano-calcium carbonate, calcined kaolin and wollastonite or wherein several mixture;
Lubricant in step one described in step one is a kind of or wherein several mixture in Zinic stearas, stearic acid and polyethylene wax;
Compatilizer described in step one is a kind of or wherein several mixture in maleic anhydride grafted polyethylene, maleic anhydride graft EVA and maleic anhydride graft POE;
Silane coupling agent described in step one is a kind of or wherein several mixture in γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-aminopropyl triethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and N-(β-aminoethyl)-γ-aminopropyl triethoxysilane;
Oxidation inhibitor described in step one is the mixture of one or more in antioxidant 1010, antioxidant 618 and antioxidant 300.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN105061860A (en) * | 2015-08-06 | 2015-11-18 | 安徽电信器材贸易工业有限责任公司 | Fiber sheath material used at severe cold region |
| CN105061861A (en) * | 2015-08-06 | 2015-11-18 | 安徽电信器材贸易工业有限责任公司 | Tracking-resistance sheath material used for fiber |
| CN105400117A (en) * | 2015-11-23 | 2016-03-16 | 厦门理工学院 | Anti-dripping intumescent flame retardant PBS (poly(butylene succinate)) and preparation method thereof |
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| CN109593259A (en) * | 2018-11-19 | 2019-04-09 | 苏州亨利通信材料有限公司 | The preparation method of fast ceramic cable material of polyolefin |
| CN115850845A (en) * | 2022-12-02 | 2023-03-28 | 广东安拓普聚合物科技有限公司 | High-flame-retardant polyolefin sheath material for automobile electronic wire |
| CN116230308A (en) * | 2023-05-06 | 2023-06-06 | 中齐电缆有限公司 | Flame-retardant high-voltage cable |
| CN116253947A (en) * | 2023-02-01 | 2023-06-13 | 江苏馨德高分子材料股份有限公司 | Halogen-free low-smoke flame-retardant polyolefin sheath material and preparation process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101817952A (en) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | Soft low-smoke halogen-free flame-retardant polyolefin cable material and preparation method thereof |
| CN102250409A (en) * | 2011-06-13 | 2011-11-23 | 上虞市佳华高分子材料有限公司 | Synergistic flame-retardant low-smoke halogen-free polyolefin cable material and preparation method thereof |
| CN102485782A (en) * | 2010-12-03 | 2012-06-06 | 上海特缆电工科技有限公司 | Crosslinked, oil-resistant, low temperature-resistant, low-smoke, halogen-free and flame-retardant cable material and its preparation method |
| WO2013152224A1 (en) * | 2012-04-06 | 2013-10-10 | Polyone Corporation | Polyolefin intumescent phosphorous flame retardant system |
| CN103865165A (en) * | 2014-03-21 | 2014-06-18 | 中利科技集团股份有限公司 | Low-smoke, halogen-free and flame retardant polyolefin cable material and preparation method thereof |
-
2014
- 2014-11-21 CN CN201410675451.5A patent/CN104530519B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101817952A (en) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | Soft low-smoke halogen-free flame-retardant polyolefin cable material and preparation method thereof |
| CN102485782A (en) * | 2010-12-03 | 2012-06-06 | 上海特缆电工科技有限公司 | Crosslinked, oil-resistant, low temperature-resistant, low-smoke, halogen-free and flame-retardant cable material and its preparation method |
| CN102250409A (en) * | 2011-06-13 | 2011-11-23 | 上虞市佳华高分子材料有限公司 | Synergistic flame-retardant low-smoke halogen-free polyolefin cable material and preparation method thereof |
| WO2013152224A1 (en) * | 2012-04-06 | 2013-10-10 | Polyone Corporation | Polyolefin intumescent phosphorous flame retardant system |
| CN103865165A (en) * | 2014-03-21 | 2014-06-18 | 中利科技集团股份有限公司 | Low-smoke, halogen-free and flame retardant polyolefin cable material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 韩志东 等: "氧化镍负载纳米石墨微片/聚乙烯的热稳定性", 《哈尔滨理工大学学报》 * |
| 韩志东 等: "聚乙烯/水滑石复合材料的结构及其热降解行为", 《哈尔滨理工大学学报》 * |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN109517258A (en) * | 2018-11-19 | 2019-03-26 | 苏州亨利通信材料有限公司 | Heat insulation type ceramic Low-smoke flame retardant cable material |
| CN115850845A (en) * | 2022-12-02 | 2023-03-28 | 广东安拓普聚合物科技有限公司 | High-flame-retardant polyolefin sheath material for automobile electronic wire |
| CN116253947A (en) * | 2023-02-01 | 2023-06-13 | 江苏馨德高分子材料股份有限公司 | Halogen-free low-smoke flame-retardant polyolefin sheath material and preparation process thereof |
| CN116253947B (en) * | 2023-02-01 | 2023-10-27 | 江苏馨德高分子材料股份有限公司 | Halogen-free low-smoke flame-retardant polyolefin sheath material and preparation process thereof |
| CN116230308A (en) * | 2023-05-06 | 2023-06-06 | 中齐电缆有限公司 | Flame-retardant high-voltage cable |
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Effective date of registration: 20210721 Address after: 214400 Qing Yang Zhen Nan Chen Cun, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: JIANGYIN YUANDA ELECTRICAL MATERIAL Co.,Ltd. Address before: 150080 No. 52, Xuefu Road, Nangang District, Heilongjiang, Harbin Patentee before: HARBIN University OF SCIENCE AND TECHNOLOGY |