CN102977609A - Oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats, and its preparation method - Google Patents
Oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats, and its preparation method Download PDFInfo
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- CN102977609A CN102977609A CN2012104354909A CN201210435490A CN102977609A CN 102977609 A CN102977609 A CN 102977609A CN 2012104354909 A CN2012104354909 A CN 2012104354909A CN 201210435490 A CN201210435490 A CN 201210435490A CN 102977609 A CN102977609 A CN 102977609A
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- 239000000463 material Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000000779 smoke Substances 0.000 title abstract description 6
- 239000003063 flame retardant Substances 0.000 title abstract description 4
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title abstract 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- HIHIPCDUFKZOSL-UHFFFAOYSA-N ethenyl(methyl)silicon Chemical compound C[Si]C=C HIHIPCDUFKZOSL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920002635 polyurethane Polymers 0.000 claims abstract description 9
- 239000004814 polyurethane Substances 0.000 claims abstract description 9
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 9
- 239000004945 silicone rubber Substances 0.000 claims abstract description 9
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 7
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- OKISUZLXOYGIFP-UHFFFAOYSA-N 4,4'-dichlorobenzophenone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=C(Cl)C=C1 OKISUZLXOYGIFP-UHFFFAOYSA-N 0.000 claims abstract description 6
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 claims abstract description 6
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims abstract description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 4
- 239000004927 clay Substances 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 12
- 238000012986 modification Methods 0.000 claims description 11
- 230000004048 modification Effects 0.000 claims description 11
- 238000004079 fireproofing Methods 0.000 claims description 10
- 150000004820 halides Chemical class 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229920013649 Paracril Polymers 0.000 claims description 8
- 229960004643 cupric oxide Drugs 0.000 claims description 8
- 235000012254 magnesium hydroxide Nutrition 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 230000036571 hydration Effects 0.000 claims description 5
- 238000006703 hydration reaction Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 230000003712 anti-aging effect Effects 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- -1 hydrogen magnesium hydroxides Chemical class 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- 239000005751 Copper oxide Substances 0.000 abstract 1
- 229920000459 Nitrile rubber Polymers 0.000 abstract 1
- XUGISPSHIFXEHZ-GPJXBBLFSA-N [(3r,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C1C=C2C[C@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-GPJXBBLFSA-N 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- WGKLIJDVPACLGG-UHFFFAOYSA-N trizinc diborate hydrate Chemical compound O.[Zn++].[Zn++].[Zn++].[O-]B([O-])[O-].[O-]B([O-])[O-] WGKLIJDVPACLGG-UHFFFAOYSA-N 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
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- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats. The cable material is prepared from the following raw materials, by weight, 20-30 parts of polyurethane, 60-80 parts of methyl vinyl silicone rubber, 8-10 parts of acrylonitrile-butadiene rubber, 8-10 parts of magnesium hydroxide, 0.5-1.0 part of butyl stearate, 1-3 parts of barium stearate, 8-12 parts of triglycol dioctate, 4-6 parts of copper oxide, 0.5-1.0 parts of molybdenum trioxide, 30-50 parts of fumed silica, 10-13 parts of modified argil, 0.5-1.0 part of an antioxidant H, 0.1-0.3 parts of an antioxidant AW, 0.5-1.5 parts of a promoter NOBS, 0.2-0.5 parts of a vulcanizing agent DCBP, 8-10 parts of triphenyl phosphate, 12-15 parts of antimony (III) oxide and 6-8 parts of zinc borate hydrate. The cable material has the advantages of excellent flame retardation, very less smoke in combustion, no generation of toxic gases or corrosive gases, good low temperature resistance, good oil resistance, and good abrasion resistance.
Description
Technical field
The present invention relates to the CABLE MATERIALS field, be specifically related to a kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel and preparation method thereof.
Background technology
Fast development along with global economy, and the enhancing of human environmental consciousness, each field is more and more higher to the requirement of the quality and performance of electric wire, the fire that causes because of wearing out of electric wire, cable also gets more and more, how to reduce the incidence of fire and presence of fire the time mortality ratio, low cigarette, Halogen, fire-retardant, developing direction that environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the at present production of halide-free low-smoke fireproof cable material is to add a large amount of magnesium hydroxide or magnesium hydroxides to reach flame retardant effect in polyolefin substrate mostly, yet, the adding of a large amount of inorganic materials, affected physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, poor, oil-proofness of softness, weathering resistance, resistance to low temperature are not fine at normal temperatures for they.
Summary of the invention
The invention provides a kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel and preparation method thereof.
The technical solution used in the present invention is:
A kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel, it is characterized in that: the raw material by following weight part is made: polyurethane(s) 20-30 part, methyl vinyl silicone rubber 60-80, paracril 8-10, magnesium hydroxide 8-10 part, butyl stearate 0.5-1.0 part, barium stearate 1-3, triglycol two 2-ethylhexoate 8-12 parts, cupric oxide 4-6 part, molybdic oxide 0.5-1.0 part, gas-phase silica 30-50 part, modification potter's clay 10-13,0.5-1.0 part of antioxidant H, antioxidant A W 0.1-0.3 part, accelerant NOBS 0.5-1.5 part, vulcanizing agent DCBP 0.2-0.5, triphenylphosphate 8-10, antimonous oxide 12-15, hydration zinc borate 6-8.
Described modification potter's clay prepares by the following method:
(1), potter's clay is with 10-15% salt acid soak 3-4 hour, deionized water wash, again with 10-12% hydrogen peroxide leaching solution bubble 3-4 hour, again with deionized water wash to neutral, oven dry;
(2), will be dissolved in potter's clay is added to the water, add again sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that is equivalent to potter's clay weight 2-3%, high speed 1200-1500 rev/min of stirring obtains dispersion liquid, and the dispersion liquid ovendry power is broken into ultrafine powder
Described oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel, it is characterized in that: the raw material by following weight part is made: 25 parts of polyurethane(s), methyl vinyl silicone rubber 70, paracril 15,9 parts of hydrogen magnesium hydroxides, 0.6 part of butyl stearate, barium stearate 2,10 parts of triglycol two 2-ethylhexoates, 5 parts of cupric oxide, 0.8 part of molybdic oxide, 40 parts of gas-phase silicas, modification potter's clay 12,0.8 part of antioxidant H, 0.2 part of antioxidant A W, 0.8 part of accelerant NOBS, vulcanizing agent DCBP 0.4, triphenylphosphate 9, antimonous oxide 14, hydration zinc borate 7.
The preparation method of described oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel is characterized in that:
(1) presses formula rate polyurethane(s), methyl vinyl silicone rubber, paracril and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 80-95 ℃;
(2) fillers such as modification potter's clay, cupric oxide, gas-phase silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, the extruder plastication granulation, get final product, the extrusion temperature of extruding machine is 120-165 ℃.
Beneficial effect
CABLE MATERIALS of the present invention not only has excellent flame retardancy and flame-retarding power not; The amount of being fuming is considerably less during burning, does not produce toxic gas, does not produce corrosive gases, and has simultaneously good low temperature resistant, oil-proofness, wear resistance.
Embodiment
Oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel is made by the raw material of following weight part: 25 parts of polyurethane(s), methyl vinyl silicone rubber 70, paracril 15,9 parts of hydrogen magnesium hydroxides, 0.6 part of butyl stearate, barium stearate 2,10 parts of triglycol two 2-ethylhexoates, 5 parts of cupric oxide, 0.8 part of molybdic oxide, 40 parts of gas-phase silicas, modification potter's clay 12,0.8 part of antioxidant H, 0.2 part of antioxidant A W, 0.8 part of accelerant NOBS, vulcanizing agent DCBP 0.4, triphenylphosphate 9, antimonous oxide 14, hydration zinc borate 7.
Described modification potter's clay prepares by the following method:
(1), potter's clay is with 10-15% salt acid soak 3-4 hour, deionized water wash, again with 10-12% hydrogen peroxide leaching solution bubble 3-4 hour, again with deionized water wash to neutral, oven dry;
(2), will be dissolved in potter's clay is added to the water, add again sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that is equivalent to potter's clay weight 2-3%, high speed 1200-1500 rev/min of stirring obtains dispersion liquid, and the dispersion liquid ovendry power is broken into ultrafine powder
The preparation method:
(1) presses formula rate polyurethane(s), methyl vinyl silicone rubber, paracril and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 80-95 ℃;
(2) fillers such as modification potter's clay, cupric oxide, gas-phase silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, the extruder plastication granulation, get final product, the extrusion temperature of extruding machine is 120-165 ℃.
The CABLE MATERIALS that processes with present embodiment is pressed into test piece after 160 ℃ * 40min thermal ageing, and it is as follows to record its performance:
| Project | The result |
| Tensile strength MPa | 10.5 |
| Elongation at break % | 360 |
| Volume specific resistance Ω .cm | 6.5×10 12 |
| Oxygen index % | 39 |
| 135 ℃ * 168h thermal ageing back draft intensity 〉= | 20.7MPa |
| The unit mass smoke density | 14.3g |
| The thermal ageing mass loss≤ | 20.8g/m2 |
Claims (3)
1. oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel, it is characterized in that: the raw material by following weight part is made: polyurethane(s) 20-30 part, methyl vinyl silicone rubber 60-80, paracril 8-10, magnesium hydroxide 8-10 part, butyl stearate 0.5-1.0 part, barium stearate 1-3, triglycol two 2-ethylhexoate 8-12 parts, cupric oxide 4-6 part, molybdic oxide 0.5-1.0 part, gas-phase silica 30-50 part, modification potter's clay 10-13,0.5-1.0 part of antioxidant H, antioxidant A W 0.1-0.3 part, accelerant NOBS 0.5-1.5 part, vulcanizing agent DCBP 0.2-0.5, triphenylphosphate 8-10, antimonous oxide 12-15, hydration zinc borate 6-8;
Described modification potter's clay prepares by the following method:
(1), potter's clay is with 10-15% salt acid soak 3-4 hour, deionized water wash, again with 10-12% hydrogen peroxide leaching solution bubble 3-4 hour, again with deionized water wash to neutral, oven dry;
(2), will be dissolved in potter's clay is added to the water, add again sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that is equivalent to potter's clay weight 2-3%, high speed 1200-1500 rev/min of stirring obtains dispersion liquid, and the dispersion liquid ovendry power is broken into ultrafine powder.
2. oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel according to claim 1, it is characterized in that: the raw material by following weight part is made: 25 parts of polyurethane(s), methyl vinyl silicone rubber 70, paracril 15,9 parts of hydrogen magnesium hydroxides, 0.6 part of butyl stearate, barium stearate 2,10 parts of triglycol two 2-ethylhexoates, 5 parts of cupric oxide, 0.8 part of molybdic oxide, 40 parts of gas-phase silicas, modification potter's clay 12,0.8 part of antioxidant H, 0.2 part of antioxidant A W, 0.8 part of accelerant NOBS, vulcanizing agent DCBP 0.4, triphenylphosphate 9, antimonous oxide 14, hydration zinc borate 7.
3. the preparation method of an oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel as claimed in claim 1 or 2 is characterized in that:
(1) presses formula rate polyurethane(s), methyl vinyl silicone rubber, paracril and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 80-95 ℃;
(2) fillers such as modification potter's clay, cupric oxide, gas-phase silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, the extruder plastication granulation, get final product, the extrusion temperature of extruding machine is 120-165 ℃.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210435490.9A CN102977609B (en) | 2012-11-05 | 2012-11-05 | A kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210435490.9A CN102977609B (en) | 2012-11-05 | 2012-11-05 | A kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102977609A true CN102977609A (en) | 2013-03-20 |
| CN102977609B CN102977609B (en) | 2016-03-16 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103289416A (en) * | 2013-05-22 | 2013-09-11 | 吴江市德佐日用化学品有限公司 | Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material |
| CN103524868A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Low-temperature-resistant oil-resistant low-smoke halogen-free flame-retardant polyolefin cable material |
| CN103665887A (en) * | 2013-11-29 | 2014-03-26 | 山东永泰化工有限公司 | Method for preparing oil-proof high-temperature-resistant silicone rubber |
| CN103849134A (en) * | 2014-01-20 | 2014-06-11 | 库群星 | Light-conducting insulating material of electric wire |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746672A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Silicone rubber insulation cable material and its preparation method |
| CN102746671A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Environmental-crack-resistant low-temperature compensation cable material and its preparation method |
| CN102746546A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method |
-
2012
- 2012-11-05 CN CN201210435490.9A patent/CN102977609B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746672A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Silicone rubber insulation cable material and its preparation method |
| CN102746671A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Environmental-crack-resistant low-temperature compensation cable material and its preparation method |
| CN102746546A (en) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289416A (en) * | 2013-05-22 | 2013-09-11 | 吴江市德佐日用化学品有限公司 | Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material |
| CN103450709B (en) * | 2013-08-19 | 2016-01-13 | 铜陵瑞莱科技有限公司 | The resistant to elevated temperatures iron oxide green of a kind of surface-coating |
| CN103524868A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Low-temperature-resistant oil-resistant low-smoke halogen-free flame-retardant polyolefin cable material |
| CN103665887A (en) * | 2013-11-29 | 2014-03-26 | 山东永泰化工有限公司 | Method for preparing oil-proof high-temperature-resistant silicone rubber |
| CN103849134A (en) * | 2014-01-20 | 2014-06-11 | 库群星 | Light-conducting insulating material of electric wire |
| CN103849134B (en) * | 2014-01-20 | 2016-04-27 | 库群星 | The guide-lighting insulating material of a kind of electric wire |
| CN104008800A (en) * | 2014-04-23 | 2014-08-27 | 晶锋集团股份有限公司 | Shock-absorption cable |
| CN104008796A (en) * | 2014-04-23 | 2014-08-27 | 晶锋集团股份有限公司 | Reinforced flat cable |
| CN105330915A (en) * | 2015-12-14 | 2016-02-17 | 苏州鑫德杰电子有限公司 | Anti-aging cable sheath material and preparation method thereof |
| CN105670295A (en) * | 2016-03-04 | 2016-06-15 | 韩静静 | Rubber preparation raw material applied to outdoor corrosion-resistant cables |
| CN105968821A (en) * | 2016-06-20 | 2016-09-28 | 安徽海容电缆有限公司 | Wear-resisting and low-temperature-resisting cable material |
| CN105885434A (en) * | 2016-06-26 | 2016-08-24 | 安徽我要遛遛信息技术有限公司 | Fireproof and flame-retardant communication cable material and preparation method thereof |
| CN106832876A (en) * | 2016-12-21 | 2017-06-13 | 柳州市昌泉贸易有限公司 | A kind of preparation method of oil resistant fire-resistant cable material |
| CN107083065A (en) * | 2017-05-24 | 2017-08-22 | 李盛祥 | A kind of corrosion-resistant halogen-free anti-flaming polyolefin material and preparation method thereof |
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