CN102746546A - Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method - Google Patents

Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method Download PDF

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Publication number
CN102746546A
CN102746546A CN2012101968862A CN201210196886A CN102746546A CN 102746546 A CN102746546 A CN 102746546A CN 2012101968862 A CN2012101968862 A CN 2012101968862A CN 201210196886 A CN201210196886 A CN 201210196886A CN 102746546 A CN102746546 A CN 102746546A
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parts
cable material
halogen
power generation
wind power
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CN2012101968862A
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CN102746546B (en
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魏善恒
李小康
陶天宝
陈国林
王敏
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SUZHOU YIPUDUN NEW MATERIAL TECHNOLOGY Co.,Ltd.
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Anhui Huatong Cable Group Co Ltd
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Abstract

The invention discloses a halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method. The cable material comprises the following raw materials, by weight, 90-110 parts of a polyolefin elastomer (POE) 8450/American DuPont, 50-60 parts of PVC resin powder, 40-60 parts of wollastonite powder, 60-80 parts of nanometer attapulgite, 50-80 parts of ethylene-propylene-diene terpolymer rubber, 40-50 parts of nitrile butadiene rubber, 20-30 parts of nanometer pottery clay, 30-40 parts of aluminum hydroxide, 1-4 parts of precipitated white carbon black, 60-80 parts of light calcium carbonate, 3-5 parts of insoluble sulfur, 1-4 parts of triallyl isocyanurate, 3-5 parts of an antiager TPPD, 4-6 parts of dicumyl peroxide (DCP), 3-8 parts of dibasic lead phosphite, 5-7 parts of an antioxidant 1010, 2-5 parts of monoglycerin stearate and 50-70 parts of antimony trioxide. The cable material has the advantages of simple preparation method, excellent electrical property, good heat, ageing and wear resistances, small swelling deformation at a high temperature, secondary vulcanizing processing benefiting, low smoke and fire resistance, and environmental protection and safety.

Description

A kind of halogen-free environment-friendly type used for wind power generation power cable material and preparation method thereof
Technical field
The present invention relates to a kind of halogen-free environment-friendly type used for wind power generation power cable material and preparation method thereof, belong to the CABLE MATERIALS technical field.
Background technology
Along with rapid economic development, electric wire all is widely used in industry-by-industry, field.Along with the frequent generation of electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually.Discharge a large amount of smog during cable fire and deleterious, corrosive gas is Hazard Factor in the fire, in fire, hindered people's safe escape and fire-fighting work, make lives and properties suffer heavy losses.Simultaneously, more and more need use halogen-free environment-friendly type used for wind power generation power cable material along with many occasions such as the development, particularly aviation lead of communication career, automotive industry and computer industry, line for cars, high temperature instrument cable, oil drilling platform cables.
Summary of the invention
The purpose of this invention is to provide a kind of halogen-free environment-friendly type used for wind power generation power cable material and preparation method thereof, preparation method of the present invention is simple, and electrical property is excellent; The heat-resisting ageing-resisting wear resisting property is good, and dilatational strain is little under the high temperature, helps post cure processing; Low-smoke and flame retardant, Environmental Safety.
For realizing the following technical scheme of above-mentioned purpose employing of the present invention:
Halogen-free environment-friendly type used for wind power generation power cable material, the weight part of its constitutive material is: polyolefin elastomer POE 8450/ Dupont 90-110, polyvinyl chloride resin powder 50-60, wollastonite powder 40-60, nano-attapulgite 60-80, terpolymer EP rubber 50-80, paracril 40-50, nanometer potter's clay 20-30, white lake 30-40, precipitated silica 1-4, light calcium carbonate 60-80, insoluble sulfur 3-5, iso-cyanuric acid triallyl ester 1-4, anti-aging agent TPPD 3-5, Di Cumyl Peroxide 99 DCP 4-6, dibasic lead phosphite 3-8, antioxidant 1010 5-7, hard ester acid direactive glyceride 2-5 and ANTIMONY TRIOXIDE SB 203 99.8 PCT 50-70.
Halogen-free environment-friendly type used for wind power generation power cable material, the weight part of its constitutive material is: polyolefin elastomer POE 8450/ Dupont 100, polyvinyl chloride resin powder 55, wollastonite powder 50, nano-attapulgite 70, terpolymer EP rubber 65, paracril 45, nanometer potter's clay 25, white lake 35, precipitated silica 3, light calcium carbonate 70, insoluble sulfur 4, iso-cyanuric acid triallyl ester 3, anti-aging agent TPPD 4, Di Cumyl Peroxide 99 DCP 5, dibasic lead phosphite 5, antioxidant 1010 6, hard ester acid direactive glyceride 3.5 and ANTIMONY TRIOXIDE SB 203 99.8 PCT 60.
The preparation method of halogen-free environment-friendly type used for wind power generation power cable material; May further comprise the steps: the weight part by constitutive material takes by weighing each raw material; Then temperature 100-120 ℃ after banburying 5-7 minute, obtained down finished product in mixing 20-30 minute at temperature 150-170 ℃ again after the banburying.
Beneficial effect of the present invention:
Preparing method of the present invention is simple, and electrical property is excellent, and the heat-resisting ageing-resisting wear resisting property is good, and dilatational strain is little under the high temperature, helps post cure processing, low-smoke and flame retardant, Environmental Safety.
Embodiment
Embodiment 1: halogen-free environment-friendly type used for wind power generation power cable material, the weight part of its constitutive material is: polyolefin elastomer POE 8450/ Dupont 90-110, polyvinyl chloride resin powder 50-60, wollastonite powder 40-60, nano-attapulgite 60-80, terpolymer EP rubber 50-80, paracril 40-50, nanometer potter's clay 20-30, white lake 30-40, precipitated silica 1-4, light calcium carbonate 60-80, insoluble sulfur 3-5, iso-cyanuric acid triallyl ester 1-4, anti-aging agent TPPD 3-5, Di Cumyl Peroxide 99 DCP 4-6, dibasic lead phosphite 3-8, antioxidant 1010 5-7, hard ester acid direactive glyceride 2-5 and ANTIMONY TRIOXIDE SB 203 99.8 PCT 50-70.
The preparation method of halogen-free environment-friendly type used for wind power generation power cable material; May further comprise the steps: the weight part by constitutive material takes by weighing each raw material; Then temperature 100-120 ℃ after banburying 5-7 minute, obtained down finished product in mixing 20-30 minute at temperature 150-170 ℃ again after the banburying.
The CABLE MATERIALS performance data that makes through embodiments of the invention 1:
Temperature resistant grade is high, at 110 ℃ of down continuously long-time steady operations;
Before aging: elongation at break 283%, tensile strength 14N/mm 2
Aging back: (120 ℃, 240h) elongation at break 240%, tensile strength 13N/mm 2
Electrical property: volume specific resistance 1.92*10 12Ohm-meter, disruptive strength 19Kv/mm.
Single testing vertical flammability, after flame time is 7 seconds, burning on the end distance anchor clamps lower edge distance is 280 millimeters; Bunched burning test, char length are 1.5 meters.

Claims (3)

1. a halogen-free environment-friendly type used for wind power generation power cable material is characterized in that the weight part of its constitutive material is: polyolefin elastomer POE 8450/ Dupont 90-110, polyvinyl chloride resin powder 50-60, wollastonite powder 40-60, nano-attapulgite 60-80, terpolymer EP rubber 50-80, paracril 40-50, nanometer potter's clay 20-30, white lake 30-40, precipitated silica 1-4, light calcium carbonate 60-80, insoluble sulfur 3-5, iso-cyanuric acid triallyl ester 1-4, anti-aging agent TPPD 3-5, Di Cumyl Peroxide 99 DCP 4-6, dibasic lead phosphite 3-8, antioxidant 1010 5-7, hard ester acid direactive glyceride 2-5 and ANTIMONY TRIOXIDE SB 203 99.8 PCT 50-70.
2. halogen-free environment-friendly type used for wind power generation power cable material according to claim 1 is characterized in that the weight part of its constitutive material is: polyolefin elastomer POE 8450/ Dupont 100, polyvinyl chloride resin powder 55, wollastonite powder 50, nano-attapulgite 70, terpolymer EP rubber 65, paracril 45, nanometer potter's clay 25, white lake 35, precipitated silica 3, light calcium carbonate 70, insoluble sulfur 4, iso-cyanuric acid triallyl ester 3, anti-aging agent TPPD 4, Di Cumyl Peroxide 99 DCP 5, dibasic lead phosphite 5, antioxidant 1010 6, hard ester acid direactive glyceride 3.5 and ANTIMONY TRIOXIDE SB 203 99.8 PCT 60.
3. the preparation method of a halogen-free environment-friendly type used for wind power generation power cable material as claimed in claim 1; It is characterized in that may further comprise the steps: the weight part by constitutive material takes by weighing each raw material; Then temperature 100-120 ℃ after banburying 5-7 minute, obtained down finished product in mixing 20-30 minute at temperature 150-170 ℃ again after the banburying.
CN201210196886.2A 2012-06-15 2012-06-15 A kind of halogen-free environment-friendly type power cable for wind power generation material and preparation method thereof Active CN102746546B (en)

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CN102977609A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats, and its preparation method
CN102977610A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Cross-linked low-smoke and zero-halogen flame retardant cable material for locomotive vehicles, and its preparation method
CN103214774A (en) * 2013-03-26 2013-07-24 安徽华峰电缆集团有限公司 Polyvinylchloride insulating electric power cable material and preparation method thereof
CN103304916A (en) * 2013-05-14 2013-09-18 安徽旺达铜业发展有限公司 Polyvinyl chloride cable material comprising modified aluminum hydroxide
CN103333429A (en) * 2013-06-05 2013-10-02 安徽荣玖光纤通信科技有限公司 Anti-aging polyvinyl chloride cable material
CN103509257A (en) * 2013-08-30 2014-01-15 安徽天民电气科技有限公司 105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and preparation method thereof
CN103509295A (en) * 2013-10-12 2014-01-15 绿宝电缆（集团）有限公司 Environment-friendly heat-proof composite elastic cable material for cables and cords
CN103554775A (en) * 2013-10-31 2014-02-05 合肥得润电子器件有限公司 Modified polyvinyl chloride insulation material for automobile wire harness
CN104788894A (en) * 2014-05-30 2015-07-22 安徽天彩电缆集团有限公司 Cable sheath for underground mine
CN104788826A (en) * 2014-05-10 2015-07-22 安徽天彩电缆集团有限公司 Aging-resistant EPDM rubber cable sheath material for mine
CN104844981A (en) * 2015-05-29 2015-08-19 合肥得润电子器件有限公司 Wear-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables and preparation method thereof
CN104844976A (en) * 2015-05-29 2015-08-19 合肥得润电子器件有限公司 Heat-resistant nitrile-butadiene rubber modified polyvinyl chloride sheath material for communication cables and preparation method thereof
CN104844980A (en) * 2015-05-29 2015-08-19 合肥得润电子器件有限公司 Nitrile rubber modified polyvinyl chloride jacket material for ageing-resistant communication cable and preparation method of nitrile rubber modified polyvinyl chloride jacket material
CN104844984A (en) * 2015-05-29 2015-08-19 合肥得润电子器件有限公司 Polyvinyl chloride cable material for notebook computer connecting wires and preparation method thereof
CN104861396A (en) * 2015-05-29 2015-08-26 合肥得润电子器件有限公司 Polyvinyl chloride cable material for heat-resistant connecting wire of notebook computer and preparation method of polyvinyl chloride cable material
CN104893149A (en) * 2015-05-29 2015-09-09 合肥得润电子器件有限公司 Nitrile rubber modified polyvinyl chloride jacket material for good-airtightness communication cable and preparation method thereof
CN105367915A (en) * 2015-11-24 2016-03-02 安徽都邦电器有限公司 Anti-aging high-flame-retardant ethylene propylene diene monomer rubber pipe
CN105646979A (en) * 2016-03-08 2016-06-08 苏州科茂电子材料科技有限公司 Direct-current cable insulating material and preparation method thereof
CN106280024A (en) * 2016-08-12 2017-01-04 江苏荣宜电缆有限公司 A kind of antiseptic fire-retardation wind energy cable sheath and insulant and preparation method thereof
CN108676292A (en) * 2018-06-14 2018-10-19 合肥市大卓电力有限责任公司 A kind of erosion resisting insulation CABLE MATERIALS and preparation method thereof
CN109535511A (en) * 2018-12-04 2019-03-29 中石化江钻石油机械有限公司 A kind of heat conductive rubber material and preparation method thereof for drilling tool

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CN102977609A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats, and its preparation method
CN102977610A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Cross-linked low-smoke and zero-halogen flame retardant cable material for locomotive vehicles, and its preparation method
CN102977609B (en) * 2012-11-05 2016-03-16 安徽金桥电缆有限公司 A kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel and preparation method thereof
CN102977610B (en) * 2012-11-05 2016-03-30 安徽金桥电缆有限公司 A kind of cross-linking low smoke halogen-free flame retardant CABLE MATERIALS used for rolling stock and preparation method thereof
CN103214774A (en) * 2013-03-26 2013-07-24 安徽华峰电缆集团有限公司 Polyvinylchloride insulating electric power cable material and preparation method thereof
CN103214774B (en) * 2013-03-26 2016-05-04 安徽华峰电缆集团有限公司 A kind of PVC insulated power cable material and preparation method thereof
CN103304916A (en) * 2013-05-14 2013-09-18 安徽旺达铜业发展有限公司 Polyvinyl chloride cable material comprising modified aluminum hydroxide
CN103304916B (en) * 2013-05-14 2016-06-29 安徽旺达铜业发展有限公司 A kind of polyvinyl chloride cable material containing modified magnesium hydroxide
CN103333429B (en) * 2013-06-05 2016-05-04 安徽荣玖光纤通信科技有限公司 A kind of ageing-resistant polyvinyl chloride cable material
CN103333429A (en) * 2013-06-05 2013-10-02 安徽荣玖光纤通信科技有限公司 Anti-aging polyvinyl chloride cable material
CN103509257A (en) * 2013-08-30 2014-01-15 安徽天民电气科技有限公司 105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and preparation method thereof
CN103509295A (en) * 2013-10-12 2014-01-15 绿宝电缆（集团）有限公司 Environment-friendly heat-proof composite elastic cable material for cables and cords
CN103509295B (en) * 2013-10-12 2016-03-02 绿宝电缆（集团）有限公司 A kind of environment-friendly heatproof composite elastic cable material for wires and cables
CN103554775A (en) * 2013-10-31 2014-02-05 合肥得润电子器件有限公司 Modified polyvinyl chloride insulation material for automobile wire harness
CN104788826A (en) * 2014-05-10 2015-07-22 安徽天彩电缆集团有限公司 Aging-resistant EPDM rubber cable sheath material for mine
CN104788826B (en) * 2014-05-10 2017-08-11 安徽天彩电缆集团有限公司 A kind of mining ageing-resistant EPT rubber cable sheath material
CN104788894A (en) * 2014-05-30 2015-07-22 安徽天彩电缆集团有限公司 Cable sheath for underground mine
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