CN102746550A - Low-smoke halogen-free environmentally-friendly control cable material for fire resistant boat, and its preparation method - Google Patents
Low-smoke halogen-free environmentally-friendly control cable material for fire resistant boat, and its preparation method Download PDFInfo
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- CN102746550A CN102746550A CN2012101923043A CN201210192304A CN102746550A CN 102746550 A CN102746550 A CN 102746550A CN 2012101923043 A CN2012101923043 A CN 2012101923043A CN 201210192304 A CN201210192304 A CN 201210192304A CN 102746550 A CN102746550 A CN 102746550A
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Abstract
The invention discloses a low-smoke halogen-free environmentally-friendly control cable material for a fire resistant boat, and its preparation method. The material comprises the following raw materials, by weight, 90-100 parts of a high-density polyethylene resin, 20-30 parts of polyvinyl chloride, 50-60 parts of antimony trioxide, 10-20 parts of an ethylene-vinyl acetate copolymer, 20-30 parts of ethylvinyl acetate, 1-4 parts of precipitated white carbon black, 80-90 parts of bleached active calcium silicate, 2-5 parts of isocyanate, 1-4 parts of triallyl isocyanurate, 2-4 parts of an antioxidant MB, 1-3 parts of dicumyl peroxide (DCP), 2-4 parts of tribasic lead sulfate, 3-5 parts of an antioxidant 1010, 1-4 parts of ethylene bis-stearamide and 10-20 parts of hydrotalcite. The material has the advantages of simple preparation method, excellent electrical property and reasonable composition raw material formula; and the prepared cable material has the advantages of environmental protection, good heat oil resistance, good thermo-oxidative ageing resistance and the like.
Description
Technical field
The present invention relates to a kind of low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel and preparation method thereof, belong to the CABLE MATERIALS technical field.
Background technology
Along with rapid economic development, electric wire all is widely used in industry-by-industry, field.Along with the frequent generation of electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually.Discharge a large amount of smog during cable fire and deleterious, corrosive gas is Hazard Factor in the fire, in fire, hindered people's safe escape and fire-fighting work, make lives and properties suffer heavy losses.While is along with the development of communication career, automotive industry and computer industry; Particularly many occasions such as aviation lead, line for cars, high temperature instrument cable, oil drilling platform cable more and more need be used low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel.
Summary of the invention
The purpose of this invention is to provide a kind of low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel and preparation method thereof; Preparing method of the present invention is simple, and electrical property is excellent, and the constitutive material prescription is reasonable; Not only environmental protection of the CABLE MATERIALS that makes has performances such as good heat-resisting oiliness and thermo oxidative aging.
For realizing the following technical scheme of above-mentioned purpose employing of the present invention:
Low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel, the weight part of its constitutive material is: high-density polyethylene resin 90-100, SE 20-30, ANTIMONY TRIOXIDE SB 203 99.8 PCT 50-60, Injecatable EVA Copolymer 10-20, ethylene vinyl acetate 20-30, precipitated silica 1-4, bleaching activity Calucium Silicate powder 80-90, isocyanic ester 2-5, iso-cyanuric acid triallyl ester 1-4, antioxidant MB 2-4, Di Cumyl Peroxide 99 DCP 1-3, lead sulfate tribasic 2-4, antioxidant 1010 3-5, the two hard esteramides 1-4 of ethylene group and hydrotalcite 10-20.
Low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel, the weight part of its constitutive material is: high-density polyethylene resin 95, SE 25, ANTIMONY TRIOXIDE SB 203 99.8 PCT 55, Injecatable EVA Copolymer 15, ethylene vinyl acetate 25, precipitated silica 3, bleaching activity Calucium Silicate powder 85, isocyanic ester 4, iso-cyanuric acid triallyl ester 2, antioxidant MB 3, Di Cumyl Peroxide 99 DCP 2, lead sulfate tribasic 3, antioxidant 1010 4, the two hard esteramides 3 of ethylene group and hydrotalcite 15.
The preparation method of low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel; May further comprise the steps: the weight part by constitutive material takes by weighing each raw material, mix, then temperature 110-130 ℃ mixing 10-20 minute; Under 140-150 ℃, plasticated 5-8 minute discharging again.
Advantage of the present invention:
Preparing method of the present invention is simple, and electrical property is excellent, and the constitutive material prescription is reasonable, and not only environmental protection of the CABLE MATERIALS that makes has performances such as good heat-resisting oiliness and thermo oxidative aging.
Embodiment
Embodiment 1:Low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel, the weight part of its constitutive material is: high-density polyethylene resin 95, SE 25, ANTIMONY TRIOXIDE SB 203 99.8 PCT 55, Injecatable EVA Copolymer 15, ethylene vinyl acetate 25, precipitated silica 3, bleaching activity Calucium Silicate powder 85, isocyanic ester 4, iso-cyanuric acid triallyl ester 2, antioxidant MB 3, Di Cumyl Peroxide 99 DCP 2, lead sulfate tribasic 3, antioxidant 1010 4, the two hard esteramides 3 of ethylene group and hydrotalcite 15.The preparation method of low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel; May further comprise the steps: the weight part by constitutive material takes by weighing each raw material, mix, then temperature 110-130 ℃ mixing 10-20 minute; Under 140-150 ℃, plasticated 5-8 minute discharging again.
The low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel performance that the present invention makes:
150 ℃ of life-time service temperature, 180 ℃ of maximum operation (service) temperatures, stretching strength retentivity (149 ℃ in heavy oil, 70h), 63-65%, conservation rate % is stretched out in fracture, and (it is qualified that hardness (changing A) changes+17,180 ℃ of bendings for 149 ℃ in heavy oil, 70h) 70-72%.
Claims (3)
1. a low smoke and zero halogen environmental-protection flame-retardant umbilical cable material peculiar to vessel is characterized in that the weight part of its constitutive material is: high-density polyethylene resin 90-100, SE 20-30, ANTIMONY TRIOXIDE SB 203 99.8 PCT 50-60, Injecatable EVA Copolymer 10-20, ethylene vinyl acetate 20-30, precipitated silica 1-4, bleaching activity Calucium Silicate powder 80-90, isocyanic ester 2-5, iso-cyanuric acid triallyl ester 1-4, antioxidant MB 2-4, Di Cumyl Peroxide 99 DCP 1-3, lead sulfate tribasic 2-4, antioxidant 1010 3-5, the two hard esteramides 1-4 of ethylene group and hydrotalcite 10-20.
2. low smoke and zero halogen environmental-protection flame-retardant according to claim 1 umbilical cable material peculiar to vessel is characterized in that the weight part of its constitutive material is: high-density polyethylene resin 95, SE 25, ANTIMONY TRIOXIDE SB 203 99.8 PCT 55, Injecatable EVA Copolymer 15, ethylene vinyl acetate 25, precipitated silica 3, bleaching activity Calucium Silicate powder 85, isocyanic ester 4, iso-cyanuric acid triallyl ester 2, antioxidant MB 3, Di Cumyl Peroxide 99 DCP 2, lead sulfate tribasic 3, antioxidant 1010 4, the two hard esteramides 3 of ethylene group and hydrotalcite 15.
3. the preparation method of a low smoke and zero halogen environmental-protection flame-retardant as claimed in claim 1 umbilical cable material peculiar to vessel; It is characterized in that may further comprise the steps: the weight part by constitutive material takes by weighing each raw material; Mix; Then temperature 110-130 ℃ mixing 10-20 minute, under 140-150 ℃, plasticated 5-8 minute discharging again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101923043A CN102746550A (en) | 2012-06-12 | 2012-06-12 | Low-smoke halogen-free environmentally-friendly control cable material for fire resistant boat, and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2012101923043A CN102746550A (en) | 2012-06-12 | 2012-06-12 | Low-smoke halogen-free environmentally-friendly control cable material for fire resistant boat, and its preparation method |
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| CN102746550A true CN102746550A (en) | 2012-10-24 |
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| CN2012101923043A Pending CN102746550A (en) | 2012-06-12 | 2012-06-12 | Low-smoke halogen-free environmentally-friendly control cable material for fire resistant boat, and its preparation method |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509224A (en) * | 2013-09-06 | 2014-01-15 | 安徽华鸿电气股份有限公司 | Nano-modified halogen-free wear-resistant cable material |
| CN103509278A (en) * | 2013-09-06 | 2014-01-15 | 安徽华通电缆集团有限公司 | Thermoplastic low-smoke halogen-free flame-retardant PVC cable material |
| CN103540052A (en) * | 2013-09-17 | 2014-01-29 | 晶锋集团股份有限公司 | Ultraviolet-proof electric wire and cable material and preparation method thereof |
| CN103724885A (en) * | 2014-01-10 | 2014-04-16 | 安徽瑞升电气科技有限公司 | Compound cable material |
| CN103937082A (en) * | 2014-03-19 | 2014-07-23 | 安徽电缆股份有限公司 | Light stable cable material |
| CN105218916A (en) * | 2014-06-09 | 2016-01-06 | 南通慧源塑胶有限公司 | A kind of fire-retardant plastic formula |
| CN109096583A (en) * | 2018-08-02 | 2018-12-28 | 安徽扬子线缆有限公司 | A kind of tensile cable and its production method |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509224A (en) * | 2013-09-06 | 2014-01-15 | 安徽华鸿电气股份有限公司 | Nano-modified halogen-free wear-resistant cable material |
| CN103509278A (en) * | 2013-09-06 | 2014-01-15 | 安徽华通电缆集团有限公司 | Thermoplastic low-smoke halogen-free flame-retardant PVC cable material |
| CN103509224B (en) * | 2013-09-06 | 2015-09-30 | 安徽华鸿电气股份有限公司 | A kind of halogen-free wear resistant cable material of nano modification |
| CN103509278B (en) * | 2013-09-06 | 2015-12-02 | 安徽华通电缆集团有限公司 | A kind of Thermoplastic low-smoke halogen-free flame-retardant PVC cable material |
| CN103540052A (en) * | 2013-09-17 | 2014-01-29 | 晶锋集团股份有限公司 | Ultraviolet-proof electric wire and cable material and preparation method thereof |
| CN103724885A (en) * | 2014-01-10 | 2014-04-16 | 安徽瑞升电气科技有限公司 | Compound cable material |
| CN103724885B (en) * | 2014-01-10 | 2016-05-11 | 安徽瑞升电气科技有限公司 | A kind of composite CABLE MATERIALS |
| CN103937082A (en) * | 2014-03-19 | 2014-07-23 | 安徽电缆股份有限公司 | Light stable cable material |
| CN105218916A (en) * | 2014-06-09 | 2016-01-06 | 南通慧源塑胶有限公司 | A kind of fire-retardant plastic formula |
| CN109096583A (en) * | 2018-08-02 | 2018-12-28 | 安徽扬子线缆有限公司 | A kind of tensile cable and its production method |
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Application publication date: 20121024 |
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